Emission Process Research Articles

Diurnal emission variation of ozone precursors: Impacts on ozone formation during Sep. 2019

With the issue of ozone (O3) pollution having increasingly gained visibility and prominence in China, the Chinese government explored various policies to mitigate O3 pollution. In some provinces and cities, diurnal regulations of O3 precursor were implemented, such as shifting O3 precursor emission processes to nighttime and offering preferential refueling at night. However, the effectiveness of these policies remains unverified, and their impact on the O3 generation process requires further elucidation. In this study, we utilized a regional climate and air quality model (WRF-Chem, v4.5) to test three scenarios aimed at exploring the impact of diurnal industry emission variation of O3 precursors on O3 formation. Significant O3 variations were observed mainly in urban areas. Shifting volatile organic compounds (VOCs) to nighttime have slight decreased daytime O3 levels while moving nitrogen oxides (NOx) to nighttime elevates O3 levels. Simultaneously moving both to nighttime showed combined effects. Process analysis indicates that the diurnal variation in O3 was mainly attributed to chemical process and vertical mixing in urban areas, while advection becomes more important in non-urban areas, contributing to the changes in O3 and O3 precursors levels through regional transportation. Further photochemical analysis reveals that the O3 photochemical production in urban areas was affected by reduced daytime O3 precursors emissions. Specifically, decreasing VOCs lowered the daytime O3 production by reducing the ROx radicals (ROx = HO + HO˙2 + RO˙2), whereas decreasing NOx promoted the daytime O3 production by weakening ROx radical loss. Our results demonstrate that diurnal regulation of O3 precursors will disrupt the ROx radical and O3 formation in local areas, resulting in a change in O3 concentration and atmospheric oxidation capacity, which should be considered in formulating new relevant policies.

Inclined surface mixed convection flow of viscous fluid with porous medium and Soret effects

Abstract The combined heat and mass transfer phenomenon is a significant aspect of engineering and industrial processes. This phenomenon finds applications in various areas such as air conditioning, cooling and heating control of electronic devices, reactors, chemical systems, and emission processes. This research model focuses on the analysis of mixed convection flow of a viscous fluid with heat and mass transfer on an inclined surface with porous medium characteristics. The study also considers external heat transfer effects, radiation, Soret influence, and chemical reactions. A perturbation solution is derived in closed form, and the impact of various parameters on the thermal behavior is investigated. A comparative analysis of the heating and cooling regimes in plate flow is conducted, revealing a reduction in velocity in the heated plate regime with changes in the permeability parameter and an increase in concentration phase due to the Soret number.

Influence of Grid Aperture Ratio on Electron Transmittance and Electron Beam Spot Size in Field Emission Processes of Carbon Nanotubes

Field emission is an important work mode for electron sources, and carbon nanotubes (CNTs) have been extensively studied for their good emission properties. It is well known that the parameters of the grid deeply influence the field emission performance of CNTs, a relationship that requires further elucidation. Therefore, in this study, the relationship between the grid aperture ratio and electron transmittance was studied through simulations and experiments. This study’s results indicate that the electron transmittance improved as the grid aperture ratio increased. Meanwhile, electron beam spot simulations and imaging experiments indicate that an increased grid aperture ratio will expand the cathode electron divergence, leading to a larger electron beam spot size. These results demonstrate that there is a trade-off in maintaining the grid aperture ratio between high electron transmittance and relatively small electron beam spot size, and the optimum grid aperture ratio is between 75% and 85%. These results will provide a reference for the design and optimization of X-ray tubes and other electron sources.

Analysis and design of fast flow liquid Li divertor for fusion nuclear science facility (FNSF) using coupled plasma boundary and LM MHD/heat transfer codes *

The SOLPS-ITER code is utilized to analyze the boundary plasma associated with a fast-flow lithium (Li) divertor configuration in the fusion nuclear science facility (FNSF) tokamak and identify operational regimes with acceptable divertor and core conditions. Plasma transport from the SOLPS-ITER code has been coupled with a liquid metal (LM) MHD/heat transfer code to model a Li open-surface divertor design and assess its impact on the scrape-off-layer (SOL) and core plasma performance. Simulations with only Neon (Ne) impurity seeding have been conducted to evaluate its impact on meeting FNSF design demands for the divertor and upstream plasma parameters. Simulation results indicate that Ne seeding significantly mitigates divertor heat flux but potentially reduces both upstream electron and main ion density due to fuel dilution. The combined application of Ne seeding and deuterium (D2) puffing is required to satisfy the FNSF design requirements on upstream density ( ne,sepOMP ∼1× 1020 m−3) and divertor energy flux ( q⊥,maxOdiv < 10 MW m−2). D2 puffing plays a role in counteracting upstream density drops and augmenting energy and momentum losses through atomic and molecular processes.The inlet Li flow velocity is systematically varied across a wide range to identify acceptable flows and corresponding LM surface temperatures. This comprehensive analysis identifies the acceptable Li flow parameters, LM surface temperature, and emitted Li fluxes necessary to meet the major design constraints. The emitted Li fluxes exhibit minimal impact on the main plasma at surface temperatures up to approximately ∼525 ∘C, corresponding emitted Li fluxes of up to φ Li ∼2 ×1023 atoms s−1. Uncertainties in the Li emission processes from the surface are also investigated, primarily influencing Li loss in the lower surface temperature range ( <525∘ C), with simulation results indicating a minor impact on the divertor and upstream plasma. Conversely, evaporation predominantly drives the Li loss processes at higher surface temperature ranges ( >525∘ C), contaminating both the divertor and upstream plasma.

Ultrafast Resonant Photon Emission from a Molecule Driven by a Strong Coherent Field in Terms of Complex Spectral Analysis

In this study, we investigate the time–frequency-resolved resonant photon emission from a molecular vibrational oscillator driven by a monochromatic coherent external field. Using the complex spectral analysis of the Liouvillian, which integrates irreversible dissipative phenomena into quantum theory, we elucidate the fundamental processes of photon emission. Indeed, our analytical approach successfully decomposes the emission spectrum into two intrinsic contributions: one from a resonance eigenmode and another from continuous eigenmodes. These components are responsible for incoherent luminescence and coherent scattering photon emission processes, respectively. Our results show that while spontaneous emission dominates in the early stages of the emission process, coherent scattering gradually becomes more pronounced with time. Furthermore, destructive quantum interference between the two components plays a key role in determining the overall shape of the emission spectrum.

Gamma-ray variability and multi-wavelength insights into the unprecedented outburst from 4C 31.03

The blazar 4C31.03 recently underwent a major γ-ray outburst at the beginning of 2023 after a prolonged quiescent phase. Fermi-LAT reported a daily average flux of 5×10−6 phs cm−2 s−1, which is about 60 times its average value. We investigated this extraordinary outbreak through temporal and multi-wavelength analysis. From the statistical analysis of the γ-ray lightcurves using Bayesian blocks, we identified 3 epochs of prominent flares. The fastest flux decay during this major outburst was observed within 5.5±0.7 hours. The highest energy of γ-ray photons found from the source during the active phase is ∼82GeV. Using the transparency of γ-rays against pair production and light crossing time argument, we could obtain the minimum jet Doppler factor as 17 corresponding to the flaring state. The broadband spectral energy distribution study performed using synchrotron, SSC and EC emission processes supports the external Compton scattering of IR photons as the likely mechanism for the γ-ray emission from the source. The results of this study support the scenario of the emission region in 4C31.03, being located beyond the Broad line region from the central blackhole. The long-term γ-ray flux distribution depicts a double log-normal variability, indicating that two distinct flux states are active in this energy band. The index distribution also reveals a two distinct variability pattern and hints that the γ-ray spectrum can be more precisely described by two photon indices.

Unraveling the drivers for interannual variabilities of N2O fluxes from forests soils across climatic zones

Forest soils are an important source of nitrous oxide (N2O), however, field observations of N2O emission have often exhibited large variabilities when compared with managed agricultural lands. In the last decade, the number of forest N2O studies has increased more than tenfold, but only a few of them have looked into the interannual flux variabilities from the regional scale. Here, we have collected 30 long-term N2O monitoring studies (≥ 2 years) based on a global database, and extracted variabilities (VARFlux) as well as relative variabilities (VAR%, in proportions) of annual N2O fluxes. The relationship of mean annual precipitation (MAP), mean annual temperature (MAT), and nitrogen (N) deposition with flux variabilities was examined to explore the underlying mechanisms for N2O emission on a long-term scale. Our results show that mean VARFlux is 0.43 kg N ha−1 yr−1 and VAR% is 28.68%. Across climatic zones, the subtropical forests have the largest annual N2O fluxes, as well as the largest fluctuations among annual budgets, while the tropics were the smallest. We found that the regulating factors for VARFlux and VAR% are fundamentally different, i.e., MAT and N input determine the annual fluxes as well as VARFlux while MAP and other limiting soil parameters determine VAR%. The relative contributions of different seasons to flux variabilities were also explored, indicating that N2O fluxes of warm and cool seasons are more responsible for the fluctuations in annual fluxes of the (sub)tropical and temperate forests, respectively. Overall, despite the limitation in interpretations due to few long-term studies from literature, this work highlights that significant interannual variabilities are common phenomena for N2O emission from different climatic zones forest soils; by unraveling the divergent drivers for VARFlux and VAR%, we have provided the possibility of improving N2O simulation models for constraining the heterogeneity of N2O emission processes from climatic zones forest soils.

Optically induced charge-transfer in donor-acceptor-substituted p- and m- C2B10H12 carboranes

Icosahedral carboranes, C2B10H12, have long been considered to be aromatic but the extent of conjugation between these clusters and their substituents is still being debated. m- and p-Carboranes are compared with m- and p-phenylenes as conjugated bridges in optical functional chromophores with a donor and an acceptor as substituents here. The absorption and fluorescence data for both carboranes from experimental techniques (including femtosecond transient absorption, time-resolved fluorescence and broadband fluorescence upconversion) show that the absorption and emission processes involve strong intramolecular charge transfer between the donor and acceptor substituents via the carborane cluster. From quantum chemical calculations on these carborane systems, the charge transfer process depends on the relative torsional angles of the donor and acceptor groups where an overlap between the two frontier orbitals exists in the bridging carborane cluster.

Study on harmless treatment and valuable elements recovery of neutralization residue from acid wastewater of copper mine

Recently, the common practice for treating metallurgical acidic wastewater involves neutralization with lime emulsion, resulting in residue that is typically landfilled or stockpiled. This contributes to long-term land occupation and environmental pollution. In this study, neutralization residue from a mine underwent comprehensive analysis using XRD, XRF, SEM-EDS, and other techniques. Utilizing acidic wastewater from the local mine as a leaching agent, the leaching characteristics of the residue were systematically investigated, and subsequent toxicity testing was conducted. Copper and iron, enriched in the leachate, were recovered employing the “pre-iron removal – sulfurization – pH compliance” process. Leaching experiments revealed the feasibility of mitigating toxicity by adjusting the pH of local mine wastewater (pH 1.5) with sulfuric acid and reacting with the residue at a ratio of 3:1 (mL/g), under conditions of 25 °C for 120 min. Under these optimized conditions, the recovery rates for Cu, Fe, As, Zn, and Ni reached 99.42%, 96.71%, 88.89%, 99.23%, and 98.21%, respectively. Toxicity testing classified the leaching residue as non-hazardous general solid waste for discharge. Recovery experiments demonstrated optimal conditions for the process, including pre-iron removal at pH 4, H2O2 10 mL/L 30 min, 25 °C, sulfurization with NaHS at 2 g/L, 20 min, 25 °C, and an emission process at pH 7.5, 60 min and 25 °C. The pre-iron removal residue (grade 45.54%) is conducive to entry into the iron plants for refinement processes aimed at enhancing its grade before entering the market, while the sulfide residue, with a copper grade of 57%, hold commercial potential. The remaining liquid adhere to established discharge standards. This process is characterized by a waste-to-waste and waste-to-treasure paradigm, demonstrating robust process stability.

KINETIC CHARACTERISTICS OF THERMOLYSIS PROCESSES OF WASTE RUBBER PRODUCTS

In this paper, the kinetic parameters of various stages of the processes occurring during the thermal decomposition of waste rubber products are determined. To study the physico-chemical and chemical transformations occurring in waste samples of rubber products with temperature changes, a thermal analysis was carried out. It has been established that the processes of thermal destruction of the carbon component of rubber products are similar to the processes occurring during pyrolysis of solid natural combustible minerals, and conditionally consist of four stages. On the basis of the derivatogram, the temperatures of the endothermic minima were determined, and the temperatures of the processes were determined from the beginning of the peaks of the effects on the DTA curve. To determine the kinetic parameters of various stages of the process of thermal destruction of rubber products without air access, the Arrhenius law was used as the initial equation, which describes the dependence of the reaction rate constant on temperature. It is established that a first-order kinetic equation is acceptable for the process of thermal decomposition of waste rubber products during pyrolysis, activation energies and pre-exponential multipliers of each stage of thermal decomposition are calculated. The lowest reaction rate is observed in the temperature range of 510-780 °C, respectively, this stage is limiting and determines the rate of the process. Based on the results of thermal analysis, a method has been proposed and developed that allows to obtain a refined solid carbon-containing pyrolysis residue by calcining it at a temperature of 800-850 °C in an oxygen-free environment until the complete cessation of gas emission processes. The data obtained are necessary for modeling the pyrolysis process of rubber products on a production scale. Based on laboratory studies and experimental data obtained, it is possible to optimize existing pyrolysis plants for rubber waste. For citation: Makarevich E.A., Papin A.V., Cherkasova T.G. Kinetic characteristics of thermolysis processes of waste rubber products. ChemChemTech [Izv. Vyssh. Uchebn. Zaved. Khim. Khim. Tekhnol.]. 2024. V. 67. N 5. P. 107-113. DOI: 10.6060/ivkkt.20246705.6937.

Radiation Process in Relativistic MHD Waves: The Case of Circularly Polarized Alfvén Waves

Turbulence in highly magnetized plasma can be relativistic and induce an electric field comparable to the background magnetic field. Such a strong electric field can affect the emission process of nonthermal electrons. As the first step toward elucidating the emission process in relativistic turbulence, we study the radiation process of electrons in relativistic circularly polarized Alfvén waves. While the induced electric field boosts the average energy of low-energy electrons with a Larmor radius smaller than the wavelength, the emissivity for such electrons is suppressed because of the elongated gyromotion trajectory. The trajectory of high-energy electrons is shaken by the small-scale electric field, which enhances the emissivity. Since the effective Lorentz factor of E × B drift is ≃2 in the circularly polarized Alfvén waves, the deviation from the standard synchrotron emission is not so prominent. However, a power-law energy injection in the waves can produce a concave photon spectrum, which is similar to the GeV extra component seen in GRB spectra. If the turbulence electric field is responsible for the GeV extra component in GRBs, the estimates of the typical electron energy and magnetic field should be largely altered.

Efficiency of Nonthermal Pulsed Emission from Eight MeV Pulsars

We report on the properties of pulsed X-ray emission from eight MeV pulsars using XMM-Newton, NICER, NuSTAR, and HXMT data. For five of the eight MeV pulsars, the X-ray spectra can be fit by a broken power-law model with a break energy of ∼5–10 keV. The photon indices below and above the break energy are ∼1 and ∼1.5, respectively. In comparison with the X-ray emission of the Fermi-LAT pulsars, the MeV pulsars have a harder spectrum and a higher radiation efficiency in the 0.3–10 keV energy bands. When isotropic emission is assumed, the emission efficiency in the keV–MeV bands is estimated to be η MeV ∼ 0.01–0.1, and this is similar to the efficiency of the GeV emission of the Fermi-LAT pulsars with a similar spin-down power. To explain the observed efficiency of the MeV pulsars, we estimate the required pair multiplicity as 104–7, which depends on the emission process (curvature radiation or synchrotron radiation) and on the location in the magnetosphere. The high multiplicity indicates that the secondary pairs that are created by a pair-creation process of the GeV photons produce the X-ray/soft gamma-ray emission of the MeV pulsars. We speculate that the difference between MeV pulsars and Fermi-LAT pulsars can be attributed to the difference in viewing angle measured from the spin axis if the emission originates from a region inside the light cylinder (canonical gap model) or to the difference in the inclination angle of the magnetic axis if the emission is produced in the equatorial current sheet outside the light cylinder.

Numerical investigation on the ion-neutral relaxation phenomenon of ion emission from plasma sheath at atmospheric pressure

Collisions between ions and neutral particles are often ignored in plasma numerical simulations. However, when studying plasma jets, the collision between neutral particles and ions is significant for ion transport, so calculations cannot ignore this. Therefore, this study adopted a two-fluid model and numerically simulated the process of ion emission from the sheath edge in atmospheric pressure plasma. In this study, particle collisions are treated as Maxwellian particle collisions. We analyze the influence of several parameters, such as sheath thickness and potential drop within the sheath. We also discuss the relaxation phenomenon of relative motion between ions and neutral particles. The research results show a transition from a non-equilibrium state to an equilibrium state in the ion migration region. Based on this change process, the ion migration region can be divided into relaxation and equilibrium zones. The relaxation zone is very thin, where the velocity and temperature of ions vary greatly. In the equilibrium zone, ions and neutral particles can be regarded as a single fluid. This study explores the interaction theory between neutral particles and ions in numerical simulations of plasmas.

Dwarf Pulses of 10 Pulsars Detected by FAST

How pulsars radiate is a long-standing problem. Detailed polarization measurements of individual pulses shed light on currently unknown emission processes. Recently, based on supersensitive observations, dwarf pulses have been recognized as weak narrow pulses often appearing during the nulling state. In this study, we report the detection of dwarf pulses from 10 pulsars, PSRs B0525+21, B1237+25, J1538+2345, J1824−0127, J1851−0053, B1901+10, J1939+10, B1944+17, B2000+40, and J2112+4058, based on observations conducted with the Five-hundred-meter Aperture Spherical radio Telescope. Dwarf pulses of five pulsars are clearly discernible in the two-dimensional distribution of pulse intensity and pulse width. For the other five pulsars, PSRs J1538+2345, J1824−0127, J1939+10, B2000+40, and J2112+4058, only a few dwarf pulses are detected from pulse stacks. The dwarf pulses can emerge in both cone and core emission components for PSR B1237+25, and the polarization angles of these dwarf pulses are mostly in the orthogonal polarization mode of normal pulses for PSR B1944+17. In general, pulsars with detected dwarf pulses tend to be located within the “death valley” region of the distribution of pulsar periods and period derivatives.

Is it possible to develop a digital twin for noise monitoring in manufacturing?

Noise monitoring is important in the context of manufacturing because it can help maintain a safe and healthy workspace for employees. Current approaches for noise monitoring in manufacturing are based on acoustic sensors, whose measured sound pressure levels (SPL) are shown as bar/curve charts and acoustic heat maps. In such a way, the noise emission and propagation process is not fully addressed. This paper proposes a digital twin (DT) for noise monitoring in manufacturing using augmented reality (AR) and the phonon tracing method (PTM). In the proposed PTM/AR-based DT, the noise is represented by 3D particles (called phonons) emitting and traversing in a spatial domain. Using a mobile AR device (HoloLens 2), users are able to visualize and interact with the noise emitted by machine tools. To validate the feasibility of the proposed PTM/AR-based DT, two use cases are carried out. The first use case is an offline test, where the noise data from a machine tool are first acquired and used for the implementation of PTM/AR-based DT with different parameter sets. The result of the first use case is the understanding between the AR performance of HoloLens 2 (frame rate) and the setting of the initial number of phonons and sampling frequency. The second use case is an online test to demonstrate the in-situ noise monitoring capability of the proposed PTM/AR-based DT. The result shows that our PTM/AR-based DT is a powerful tool for visualizing and assessing the real-time noise in manufacturing systems.

Highly efficient upconversion luminescence in narrow-bandgap Y2Mo4O15.

Lanthanide-doped upconversion (UC) materials have been extensively investigated for their unique capability to convert low-energy excitation into high-energy emission. Contrary to previous reports suggesting that efficient UC luminescence (UCL) is exclusively observed in materials with a wide bandgap, we have discovered in this study that Y2Mo4O15:Yb3+/Tm3+ microcrystals, a narrowband material, exhibit highly efficient UC emission. Remarkably, these microcrystals do not display any four- or five-photon UC emission bands. This particular optical phenomenon is independent of the variation in doping ion concentration, temperature, phonon energy, and excitation power density. Combining theoretical calculations and experimental results, we attribute the vanishing emission bands to the strong interaction between the bandgap of the Y2Mo4O15 host matrix (3.37 eV) and the high-energy levels (1I6 and 1D2) of Tm3+ ions. This interaction can effectively catalyze the UC emission process of Tm3+ ions, which leads to Y2Mo4O15:Yb3+/Tm3+ microcrystals possessing very strong UCL intensity. The brightness of these microcrystals outshines commercial UC NaYF4:Yb3+,Er3+ green phosphors by a factor of 10 and is 1.4 times greater than that of UC NaYF4:Yb3+,Tm3+ blue phosphors. Ultimately, Y2Mo4O15:Yb3+/Tm3+ microcrystals, with their distinctive optical characteristics, are being tailored for sophisticated anti-counterfeiting and information encryption applications.

Simulating vacuum arc initiation by coupling emission, heating and plasma processes

Vacuum arcing poses significant challenges for high-field vacuum devices, underscoring the importance of understanding it for their efficient design. A detailed description of the physical mechanisms involved in vacuum arcing is yet to be achieved, despite extensive research. In this work, we further develop the modeling of the physical processes involved in the initiation of vacuum arcing, starting from field emission and leading to plasma onset. Our model concurrently combines particle-in-cell with Monte Carlo collisions (PIC-MCC) simulations of plasma processes with finite element-based calculations of electron emission and the associated thermal effects. Including the processes of evaporation, impact ionization and direct field ionization allowed us to observe the dynamics of plasma buildup from an initially cold cathode surface. We simulated a static nanotip at various local fields to study the thresholds for thermal runaway and plasma initiation, identifying the significance of various interactions. We found that direct field ionization of neutrals has a significant effect at high fields on the order of 10 GV/m. Furthermore, we find that cathode surface interactions such as evaporation, sputtering and bombardment heating play a major role in the initiation of vacuum arcs. Consequently, the inclusion of these interactions in vacuum arc simulations is imperative.

ON THE PHYSICAL NATURE OF FIELD EMISSION FROM ZnO NANOSHEETS

The performed analysis allows us to determine the physical nature of the field emission process from ZnO nanosheets. It is shown that the possible range of effective values of the work function at the top of the nanosheet corresponds to the field enhancement factor β of the order of 20000. Such values of β and a nanosheet height of the order of μm correspond to subnanometer values of the radius of the nanosheet top, which is in good agreement with the experimentally known fact that the field emission from the nanostructured surface almost all comes from the top few atoms of the nanoprotrusion. Thus, the effective emission occurs only from a very small part of the total cathode surface, but the large value of the field enhancement factor β provides a noticeable emission current density of the order of magnitude of 3∙10-4 А/m2 for a turn on field of the order of magnitude of 3∙106 V/m.

Efficient prediction of attosecond two-colour pulses from an X-ray free-electron laser with machine learning

X-ray free-electron lasers are sources of coherent, high-intensity X-rays with numerous applications in ultra-fast measurements and dynamic structural imaging. Due to the stochastic nature of the self-amplified spontaneous emission process and the difficulty in controlling injection of electrons, output pulses exhibit significant noise and limited temporal coherence. Standard measurement techniques used for characterizing two-coloured X-ray pulses are challenging, as they are either invasive or diagnostically expensive. In this work, we employ machine learning methods such as neural networks and decision trees to predict the central photon energies of pairs of attosecond fundamental and second harmonic pulses using parameters that are easily recorded at the high-repetition rate of a single shot. Using real experimental data, we apply a detailed feature analysis on the input parameters while optimizing the training time of the machine learning methods. Our predictive models are able to make predictions of central photon energy for one of the pulses without measuring the other pulse, thereby leveraging the use of the spectrometer without having to extend its detection window. We anticipate applications in X-ray spectroscopy using XFELs, such as in time-resolved X-ray absorption and photoemission spectroscopy, where improved measurement of input spectra will lead to better experimental outcomes.

Evolutionary Optimized, Monocrystalline Gold Double Wire Gratings as a Novel SERS Sensing Platform.

Achieving reliable and quantifiable performance in large-area surface-enhanced Raman spectroscopy (SERS) substrates poses a formidable challenge, demanding signal enhancement while ensuring response uniformity and reproducibility. Conventional SERS substrates often made of inhomogeneous materials with random resonator geometries, resulting in multiple or broadened plasmonic resonances, undesired absorptive losses, and uneven field enhancement. These limitations hamper reproducibility, making it difficult to conduct comparative studies with high sensitivity. This study introduces an innovative approach that addresses these challenges by utilizing monocrystalline gold flakes to fabricate well-defined plasmonic double-wire resonators through focused ion-beam lithography. Inspired by biological strategy, the double-wire grating substrate (DWGS) geometry is evolutionarily optimized to maximize the SERS signal by enhancing both excitation and emission processes. The use of monocrystalline material minimizes absorption losses and ensures shape fidelity during nanofabrication. DWGS demonstrates notable reproducibility (RSD=6.6%), repeatability (RSD=5.6%), and large-area homogeneity >104µm2. It provides a SERS enhancement for sub-monolayer coverage detection of 4-Aminothiophenol analyte. Furthermore, DWGS demonstrates reusability, long-term stability on the shelf, and sustained analyte signal stability over time. Validation with diverse analytes, across different states of matter, including biological macromolecules, confirms the sensitive and reproducible nature of DWGSs, thereby establishing them as a promising platform for future sensing applications.