The aim of this work was to analyse the origin of the exhaust gases containing large amount of carbon dioxide (CO2) and methane (CH4) from self-heating coal waste dump and its potential health and environmental impact. Air samples were collected from the coal waste dump and its vicinity in Nowa Ruda − Słupiec (NR-S), Southwestern Poland, during ground survey campaigns in spring (March 30, 2019) and winter (December 1, 2019). In order to detect the origin of the exhaust plume emission, stable carbon isotopic composition (δ13C) of CH4 and CO2 was measured using a cavity ring-down spectrometer (CRDS). We investigated the gases collected from the hotspots at the surface of the coal-mine dump, from the air above the dump and finally from surroundings of the dump. This allowed to estimate the stage and magnitude of CH4 oxidation inside the coal dump. Many gas seeps from the places, where the dump is actively burning were identified during the ground surveys. CH4 mole fraction in those seeps (hot-spots) reached up to 10,000 ppm. Methane found in the most of the air samples collected from the dump was strongly enriched in 13C, with an average of −27.4 ± 5.8‰, which is heavier than methane coming out from formerly excavated coal seams what indicate coal pyrolysis as the predominant source of methane seeps. The covarying with methane, CO2 mole fraction from active burn dump sites reached up to 73,000 ppm with an average δ13C value of −27.3 ± 8.4‰. Therefore, CO2 resembles isotopically it's predominant precursor, the pyrolytic methane, via incomplete combustion in the shallow oxygenated parts of the hot spots.Substantial amounts of methane escape from the self-ignited spots on the NR-S coal waste dump, however, the mobile surveys did not reveal the enhanced methane mole fraction at the ground level in distance between 1 and 3 km from the dump. Even at distances of 150 m from the hot spots impact was limited, implying convective transport of these localized hot pollutant plumes. The results highlight changes in the fire intensity, prevailing winds, dump architecture, and surface roughness in the surrounding regions are the most important factors of air pollutant emission from complex coal mine dump system.