Summary In the argon—helium plasmas, the emission lines of singly-ionized copper, which cannot be excited in the pure argon plasma, can be observed in the visible wavelength region. These lines are identified to the 3 d 9 4 f —3 d 9 4 d , 3 d 9 5 d —3 d 9 5 p , or 3 d 9 6 s —3 d 9 4 p transitions. The collisional reactions occurring and the resonance energy transfer between copper atoms and helium ions are a feasible mechanism for the observed excitations.
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