Results Of Element Analysis Research Articles

Texture and Geochemistry of Multi‐stage Hydrothermal Scheelite in the Mamupu Cu‐Au‐Mo(‐W) Deposit, Eastern Tibet: Implications for Tungsten Mineralization in the Yulong Belt

AbstractMultistage tungsten mineralization was recently discovered in the Mamupu copper‐polymetallic deposit in the southern Yulong porphyry copper belt (YPCB), Tibet. This study reports the results of cathodoluminescence, trace element and Sr isotope analyses of Mamupu scheelite samples, undertaken in order to better constrain the mechanism of W mineralization and the sources of the ore‐forming fluids. Three different types of scheelite are identified in the Mamupu deposit: scheelite A (Sch A) mainly occurs in breccias during the prograde stage, scheelite B (Sch B) forms in the chlorite‐epidote alteration zone in the retrograde stage, while scheelite C (Sch C) occurs in distal quartz sulfide veins. The extremely high Mo content and negative Eu anomaly in Sch A represent high oxygen fugacity in the prograde stage. Compared with ore‐related porphyries, Sch A has a similar REE pattern, but with higher ΣREE, more depleted HREE and slightly lower (87Sr/86Sr)i ratios. These features suggest that Sch A is genetically related to ore‐related porphyries, but extensive interaction with carbonate surrounding rocks affects the final REE and Sr isotopic composition. Sch B shows dark (Sch B‐I) and light (Sch B‐II) domains under CL imaging. From Sch B‐I to Sch B‐II, LREEs are gradually depleted, with MREEs being gradually enriched. Sch C has the highest LREE/HREE ratio, which indicates that it inherited the geochemical characteristics of fluids after the precipitation of HREE‐rich minerals, such as diopside and garnet, in the early prograde stage. The Mo content in Sch B and Sch C gradually decreased, indicating that the oxygen fugacity of the fluids changed from oxidative in the early stages to reductive in the later, the turbulent Eu anomaly in Sch B and Sch C indicating that the Eu anomaly in the Mamupu scheelite is not solely controlled by oxygen fugacity. The extensive interaction of magmatic‐hydrothermal fluids and carbonate provides the necessary Ca2+ for the precipitation of scheelite in the Mamupu deposit.

3D Hybrid modeling for the ultrasonic phased array inspection of porosity in heavy plates: Simulation and experimental validation

Quantitative NDT modeling and simulation tools are important in design and fabrication of ultrasonic phased array probes with optimum characteristics and reduce the number of experimental efforts and development time. In order to achieve high accuracy (Amplitude deviation < 1 dB) with a low computational time in the simulation, the modeling tools require not only the high-frequency approximation of the ultrasonic wave propagation but also the high-precision electro-acoustic coupling model. This paper describes a computationally efficient 3D time-dependent hybrid model for the simulation of ultrasonic phased array inspection of porosity in heavy plates. This method combines the results of both 3D finite element analysis (PZFLex-FEA) and the semi-analytical ultrasonic simulation “Ray-Tracing”. As a first step, we demonstrate the FEA modeling of an ultrasonic phased array probe, which includes the full 1-3 piezocomposite design with the arrangement of array elements, conducting electrodes, multi-phase backing material, acoustical matching layer and electrical circuit of a 50 Ohm coaxial cable. In the current FEA simulation, we considered the acoustical and electrical cross-talk between the adjacent elements of an ultrasonic array sensor. In the second step, the FEA-simulated ultrasonic pulse-echo signal and its frequency spectrum of an array element in the farfield region are further used as the reference input signal in the CIVA-UT software to simulate the imaging of porosity in heavy plates, quantitatively. The design of the 3D wedge-geometry of the application specific array sensor is modeled and optimized using the CIVA raytracing and multi-phase backing models. The real excitation pulse of the industrial ultrasonic testing equipment “ROMIS (ROSEN Modular Inspection System)” is also included in the simulation to achieve high accuracy in the current hybrid modeling. The dependency of the detectability of the porosity on the frequency of the array sensor and the active element group so-called “Virtual Probe” are quantitatively analyzed. Finally, the 3D hybrid model simulated Time Corrected Gain (TCG) curves of the porosity like defects in the reference steel plates are compared with the real experiments and a good quantitative agreement is achieved.

Comparison of analytical and numerical methods for estimating notch strains**

AbstractIn fatigue assessments, local strains and stresses can be easily evaluated using accurate finite element analysis in a case of an individual fatigue‐critical notch or structural detail. In practical design and analysis of global models, the consideration of local notch effects using suitable estimation rules in the combination with linear elastic analysis is reasonable. Various notch rules exist but the current knowledge lacks understanding how applicable different notch rules are for estimating notch strains from elastic stresses. This work studies the Neuber′s rules for sharp and mild notches, Glinka′s equivalent strain energy density method, the correction of Neuber′s rule proposed by Sonsino for mild notches, as well as the Seeger‐Beste method. The application of different estimation rules for notch strains, applied to the elastic‐perfectly plastic steel material and to Ramberg‐Osgood material model for the aluminum material, including work hardening effect, was studied in this work by comparing the estimations with the corresponding experimental data and finite element analysis results. The Neuber′s rule for mild notches and Sonsino′s averaging method gave best correlations with the experimental data and numerical (finite element analysis) results and can be thus recommended for such analyses in compatible cases studied in this work.

Optimization and fatigue assessment of girders with large-dimension corrugated steel webs

In recent years, large-dimension Corrugated Steel Webs (CSW) has increasingly become an available solution for long-span bridges to reduce deadweight and improve prestressing efficiency. Compared to conventional CSW used in small-span bridge girders, girders with large-dimension CSW in long-span bridges are more susceptible to fatigue cracking under repetitive traffic loads. However, the specifications aimed for small-dimension CSW may resulted in unsafe fatigue detail categories. This paper investigated the fatigue performance of large-dimension CSW girders for bridges. The reasonable corrugation angles of girders with CSW were obtained using Grey Relational analysis. The fatigue detail category corresponding to optimized corrugation angles was suggested based on the Theory of Critical Distance (TCD). The Finite Element Analysis (FEA) results indicate that the hot spot stress concentration factor (Ks) on the web-flange weld toe increases with the corrugation angle and decreases with the bend radius. When the corrugation angle and the bend radius are fixed, Ks increases with the corrugation wavelength. By developing a balanced fatigue and shear buckling performance scheme, the optimized corrugation angles of wavelength 1000 ∼ 2000 mm are between 30° and 45°. There is a negative correlation between the fatigue detail categories of CSW girders and corrugation wavelengths. In general, the fatigue detail category of wavelength 1600 ∼ 2000 mm under four-point bending can be classified into a range between 50 and 71 for Eurocode 3, Category D and Category E′ design curves for AASHTO, FAT 50 and FAT 71 for IIW respectively.

Comparison of stress distribution in fully porous and dense-core porous scaffolds in dental implantation

The aim of this study is to compare the stress distribution in porous scaffolds with different structures with similar geometric parameters to study a new approach in dental implantation. Three-dimensional finite element models of the fully porous and dense-core porous scaffolds with defined porosity parameters including space diameter and thickness with two porosity patterns were embedded in the jaw bone model with cortical and cancellous bone. The cylindrical shape was considered as the main shape of the scaffolds. To evaluate the mechanical performance, the Von Mises stress was compared in the models under static and dynamic masticatory loading. Incidentally, to validate the modeling results, experimental strain gauge tests were performed on four specimens fabricated from Ti6Al4V. Finally, the stress distribution in the models was compared with the results of previous studies on commercial implants. The results of the finite element analysis show that there are considerable differences in the magnitude of the equivalent stress in the models in static and dynamic phases. Also, changes in the defined geometric parameters have significant effects on the stress distribution in terms of Von Mises stress in the overall models. The experimental results indicated good agreement with those of the modeling. It can be concluded that some porous structures with optimal geometries can be proposed as a new structure for dental implants. However, considering the physiology of bone when confronted with porous structures, further studies such as in vivo experiments are needed in this field.

Miniaturized Multi-Cantilever MEMS Resonators with Low Motional Impedance.

Microelectromechanical system (MEMS) cantilever resonators suffer from high motional impedance (Rm). This paper investigates the use of mechanically coupled multi-cantilever piezoelectric MEMS resonators in the resolution of this issue. A double-sided actuating design, which utilizes a resonator with a 2.5 μm thick AlN film as the passive layer, is employed to reduce Rm. The results of experimental and finite element analysis (FEA) show agreement regarding single- to sextuple-cantilever resonators. Compared with a standalone cantilever resonator, the multi-cantilever resonator significantly reduces Rm; meanwhile, the high quality factor (Q) and effective electromechanical coupling coefficient (Kteff2) are maintained. The 30 μm wide quadruple-cantilever resonator achieves a resonance frequency (fs) of 55.8 kHz, a Q value of 10,300, and a series impedance (Rs) as low as 28.6 kΩ at a pressure of 0.02 Pa; meanwhile, the smaller size of this resonator compared to the existing multi-cantilever resonators is preserved. This represents a significant advancement in MEMS resonators for miniaturized ultra-low-power oscillator applications.

Shear Field-Controlled Synthesis of Nitrogen-Doped Carbon Nanochains Forest with High-Density sp3 Defects for Efficient CO2 Electroreduction Reaction.

Defect engineering and nitrogen doping being effective strategies for modulating the surface chemical state of the carbon matrix have been widely explored to promote the catalytic activity in the territory of electrochemical energy storage and conversion devices. However, the controllable synthesis of carbon material with high-density specific defects and high nitrogen doping is still full of challenges. Here, we first synthesize one-dimensional necklace-like nitrogen-doped carbon nanochains (N-CNCs) with abundant defects on carbon fiber paper (CFP) by chemical vapor deposition (CVD) method. The resultant nanostructures are a bunch of interconnected carbon spheres with a hollow structure at the internode and present the complete one-dimensional nanochain configuration. Specifically, the N-CNCs with a corrugated surface possesses high content of sp3 defects (31.2%) and nitrogen (23.6 at %). Combining finite element analysis and experimental results, it reveals that the robust shear field generated by etching gas releasing from thermal decomposition of melamine in situ modulates the CVD process via changing the size and force environment of the metal catalyst droplets for formation of N-CNCs. Benefiting from the high ratio of sp3/sp2 and nitrogen doped on the surface, the N-CNCs@CFP displays a superior electrocatalytic performance for CO2RR, delivering CO Faradaic efficiency of 95.9% and a current density of 23.2 mA cm-2 at -0.86 V vs RHE. This work provides promising synthesis strategy and some inspirations for construction of ultradense and specific defects coupling with nitrogen doping sites into carbon materials to achieve high-efficiency electrocatalysis applications.

Numerical modeling of RC column reinforced by new strategy using fiberglass tape and cloth

This paper presents the results of finite element analysis (FE) to study the axial compression behavior of reinforced concrete columns wrapped with tapes and fiberglass cloths according to different techniques using ABAQUS software. In the beginning, columns are modeled as 3D solid elements with a concrete damage plasticity model (CDPM), as the columns in this study are considered to be low compressive strength reinforced concrete and the rebar as 3D mesh elements. And once assembled, the specimen is wrapped with tape and cloth in the form of three-dimensional shell elements. Then, in order to analyze the behavior of the ultimate loads, the deformation of the confinement material, and the distribution of deformations in the concrete, the controlled displacement method used to apply the uniaxial compression loads to the specimen. Finally, a new mixed confinement model between partial confinement and complete has been proposed using a database of the results of a numerical simulation for confined concrete by fiberglass tapes and cloths. And it was found that the confinement strategy proposed in this study is very effective for the behavior of the reinforced concrete column, as the stress decreases significantly with the expansion and widening of the confinement stiffness of concrete in the plastic phase which improves the axial stress resistance.

Effect of sintering on stress distribution of thermal barrier coatings for high temperature blade

In the process of long-term high temperature service, thermal barrier coatings (TBCs) will inevitably be sintered, leading to pores healing and porosity decline, which will affect the microstructure and the stability of mechanical properties of TBCs. To understand the relationship between the microstructural changes of sintered TBCs and the mechanical properties, in this work, the cross-sectional microstructure of TBCs at different sintering times were investigated by scanning electron microscopy (SEM). After calculating the porosity and pore size distribution, two-dimensional (2D) numerical models were developed for five different porosities (16 %–12 %) by an improved reconstruction method with layer-by-layer labeling. Based on the results of finite element (FE) analysis after thermal cycling, it was found that the coating's irregular pore structures lead to stress concentration, which affects the mechanical properties of the coating to a great extent. For the whole TC layer, the level of stresses increases and the absolute value of maximum stress augments significantly by 46 % associated with the doubled increase of stress concentration areas with the densification of coating. For the local areas of TC layer, the changes in pore morphology led to a more complex variation in local stress fields. At the TC/BC interface, the Mises stress level tends to increase with decreasing porosity during sintering. At the TC surface, coatings with lower porosities cause higher stresses near this region. The insights gained from the numerical results contribute to a better understanding of the failure behavior of real TBCs systems and help to further remedy the deficiencies and difficulties of the experimental work.

Enhancing Structural Vibration Damping in Marine Machinery: A Comprehensive Numerical Investigation with Modal and Harmonic Analysis

This article presents a comprehensive study on the damping of vibrations in a motor-pump assembly using viscoelastic and constrained layer damping treatments. The assembly's structural model, designed using SolidWorks software, is subjected to modal and harmonic analyses in ANSYS. The primary goal is to mitigate vibration amplitudes originating from the motor and pump to enhance the assembly's operational performance. Three damping treatments are investigated: Free Layer Damping (FLD), Sandwich Constrained Layer Damping (CLD), and a novel Multilayer CLD approach. The viscoelastic material is modeled using the Prony series method, and its properties are incorporated into the finite element analysis Results demonstrate that the application of damping treatments significantly reduces vibration amplitudes compared to the untreated structure. Among the treatments, the Multilayer CLD approach exhibits the highest damping efficiency, reducing the maximum amplitude by approximately 52% compared to the base structure. The study showcases the advantages of utilizing viscoelastic and constrained layer damping techniques for enhancing vibration control and operational stability in industrial assemblies. The research findings contribute to the field of structural dynamics and vibration control, offering valuable insights into the design and optimization of mechanical systems subjected to dynamic loads. This study opens avenues for further research and practical applications aimed at improving the performance and reliability of motor-pump assemblies and similar industrial equipment.

Seismic intensity measures and predictive equations for the evaluation of earthquake—induced crest settlements of earth dams

AbstractIn this paper the results of 2D dynamic finite element analyses of a zoned earth dam are presented and discussed with the aim of detecting proper intensity measures able to describe the variation of the crest permanent settlement with the characteristics of the input ground motion. A large set of horizontal components of earthquake records has been selected and used as input motion considering both upstream and downstream directions. This allowed to explore the activation of plastic mechanisms in the dam embankment and the amplification of the horizontal accelerations. Starting from the analysis results, two original intensity measures, related to the amplitude, energy and frequency content of the input motion, have been detected and original empirical predictive formulas have also been derived to estimate the permanent crest settlement of the dam. The effectiveness of the proposed intensity measures and the reliability of the novel relationships between these intensity measures and earthquake‐induced permanent crest settlements have been checked against (i) numerical results of further dynamic analyses carried out for the same dam using additional sets of input motions, (ii) numerical results available in the literature for two other earth dams and (iii) field data relative to the crest settlements induced in four earth dams by two recent large earthquakes. The whole set of analysis results allowed defining an empirical equation that appears as a promising general predictive tool for the earthquake‐induced crest settlement of earth dams.

Predicting the web crippling capacity of cold-formed steel lipped channels using hybrid machine learning techniques

Cold-Formed Steel Lipped (CFSL) channels are susceptible to a localized failure mechanism known as web crippling, triggered by concentrated loads or reactions applied to the web of the section. These loads induce buckling and distortion in the web, ultimately leading to the member's collapse. It is a challenging task to accurately determine the web crippling capacity of a CFSL channel due to its complexity and various influencing factors. This paper presents hybrid soft computing techniques for accurately predicting the web crippling capacity of CFSL channels subjected to two flange load cases. The developed soft computing techniques combine Artificial Neural Networks (ANN) with either Genetic Algorithms (GA) or Particle Swarm Optimization (PSO) to improve computational efficiency and accuracy. The finite element models of CFSL channels are developed and validated by experimental results and then employed to generate a database, which is used to train machine learning models, including ANN, GA-ANN, and PSO-ANN. Analysis is undertaken on the reliability of existing design formulas for determining the web crippling capacity of CFSL channels. It is shown that the PSO-ANN model outperforms the other models in terms of prediction accuracy. The existing design codes and formulas are not reliable in estimating the web crippling capacity of CFSL channels. However, the proposed model yields good correlation with finite element analysis results. A user- friendly graphical interface tool is developed for the practical design of cold-formed steel lipped channels.

Finite Element Analysis on the Seismic Performance of Concrete-Filled Steel Tube Columns with a Multiple-Chamber Round-Ended Cross-Section

This study proposes a form of concrete-filled steel tube column with a multiple-chamber round-ended cross-section (M-CFST). Longitudinal and transverse stiffening ribs divide the circular-ended section into different chambers, strengthening the steel tube’s confinement effect on the core concrete and improving the component’s seismic performance. A three-dimensional finite element (FE) solid model of the M-CFST is created by employing the FE software ABAQUS. Quasi-static analysis is conducted to investigate the influence of parameters, such as chamber arrangement, aspect ratio, and axial compression ratio, on flexural hysteresis performance. Moreover, the failure modes, hysteresis curves, skeleton curves, strain development, and energy dissipation of the components are analyzed. The results show the following: (1) The FE model presented in this study can simulate the quasi-static behavior of CFST columns accurately, and the calculated results are in good agreement with the measured values. (2) The seismic performance of the composite column is excellent, with a large number of chambers leading to a robust hysteresis curve for the composite columns, resulting in increased bearing capacity and energy dissipation capacity. However, the energy dissipation performance of the specimen with a two-chamber arrangement is slightly lower than that with a single-chamber arrangement. (3) The results of the finite element analysis suggest that the long and short sides of the CFST columns with a large length–width ratio should be arranged to be relatively close in length.

Single missing molar with wide mesiodistal length restored using a single or double implant-supported crown: A self-controlled case report and 3D finite element analysis.

Based on a self-controlled case, this study evaluated the finite element analysis (FEA) results of a single missing molar with wide mesiodistal length (MDL) restored by a single or double implant-supported crown. A case of a missing bilateral mandibular first molar with wide MDL was restored using a single or double implant-supported crown. The implant survival and peri-implant bone were compared. FEA was conducted in coordination with the case using eight models with different MDLs (12, 13, 14, and 15 mm). Von Mises stress was calculated in the FEA to evaluate the biomechanical responses of the implants under increasing vertical and lateral loading, including the stress values of the implant, abutment, screw, crown, and cortical bone. The restorations on the left and right sides supported by double implants have been used for 6 and 12 years, respectively, and so far have shown excellent osseointegration radiographically.The von Mises stress calculated in the FEA showed that when the MDL was >14 mm, both the bone and prosthetic components bore more stress in the single implant-supported strategy. The strength was 188.62-201.37 MPa and 201.85-215.9 MPa when the MDL was 14 mm and 15 mm, respectively, which significantly exceeded the allowable yield stress (180 MPa). Compared with the single implant-supported crown, the double implant-supported crown reduced peri-implant bone stress and produced a more appropriate stress transfer model at the implant-bone interface when the MDL of the single missing molar was ≥14 mm.

Lateral behavior of wood frame shear wall using PVC wood-plastic composite (WPC) veneer panels

With the growing awareness of environmental protection and green ecology, there has been significant attention on the utilization of new energy-saving and environmentally friendly materials in building structures. This article proposes a novel structure for PVC wood-plastic composite wall panels. The structure comprises Polyvinyl Chloride (PVC) wood-plastic composite materials as the facing panel and SPF (Spruce-Pine-Fir) dimensional lumber as the wall framework, connected using self-tapping screws. In this study, two standard composite wall panel specimens were subjected to testing using both monotonic loading and low-cycle reciprocating loading methods. Finite element models of the composite wall panels were created using ANSYS Workbench software for analysis, investigating the lateral performance of PVC wood-plastic composite wall panels. The analysis results indicate that PVC wood-plastic composite wall panels exhibit favorable shear strength, elastic lateral stiffness, and lateral deformation as shear walls. The shear wall model can be accurately represented in finite element software, with minimal discrepancy between experimental and finite element analysis results. Consequently, the utilization of PVC wood-plastic composite wall panels as shear walls holds promise for future applications in the structural field.

Apple mechanical damage mechanism and harvesting test platform design

Abstract Apple is easily damaged in the process of the mechanical harvesting, which reduces the fruit’s quality. It is of great significance to study the damage principle of apple in the transport process of picking platform. In this study, the apple compression test was carried out. The compression and drop process of the fruit was analyzed by the finite element analysis (FEA). The experimental platform of apple harvesting was designed, the conveying process of apple was analyzed. The results of compression finite element analysis showed that when the compression force is greater than 15.0 N, both radial compression and axial compression will be damaged. The results of drop finite element analysis showed that when the drop direction is axial, the maximum contact stress of the peel and kernel decreases with the increase of drop angle, the maximum contact stress of the pulp increases first and then decreases. When the drop direction is radial, the maximum contact stress between pulp and kernel decreases with the increase of drop angle, the maximum contact stress of the peel first decreases and then increases. The simulation results of the harvesting platform transportation showed that the damage rate of apples is less than 10 % when the sub-conveyor belt speed is 0.02 m–0.04 m/s. This study can provide theoretical guidance for the design of the harvesting test platform and the reduction of the damage of apples during transportation.

Friction Characteristics and Lubrication Properties of Spherical Hinge Structure of Swivel Bridge

A spherical hinge structure is a key swivel bridge element that must be considered when evaluating friction characteristics and lubrication properties to meet the rotation requirement. Polytetrafluoroethylene (PTFE)-based spherical hinge sliders and lubrication coating have been employed for over 20 years, but with the growing tonnage of swivel bridge construction, their capacity to accommodate the required lubrication properties can be exceeded. In this manuscript, the optimal friction coefficient of the spherical hinge is obtained through the finite element analysis method. Four lubrication coatings and four spherical hinge sliders are prepared and tested through a self-developed rotation friction coefficient test, four-ball machine test, dynamic shear rheological test, and compression and shear performance test to evaluate the lubrication and friction properties of the spherical hinge structure. The results of the finite element analysis show that the optimum rotation friction coefficient of the spherical hinge structure is 0.031–1.131. The test results illustrate that the friction coefficient, wear scar diameter, maximum non-seize load, phase transition point, and thixotropic ring area of graphene lubrication coating are 0.065, 0.79 mm, 426 N, 14.6%, and 64,878 Pa/s. The graphene lubrication coating has different degrees of improvement compared with conventional polytetrafluoroethylene lubrication coating, showing more excellent lubrication properties, bearing capacity, thixotropy, and structural strength. Compressive and shear tests demonstrate that polyether ether ketone (PEEK) has good compressive and shear mechanical properties. The maximum compressive stress of PEEK is 87.7% higher than conventional PTFE, and the shear strength of PEEK is 6.07 times higher than that of PTFE. The research results can provide significantly greater wear resistance and a lower friction coefficient of the spherical hinge structure, leading to lower traction energy consumption and ensuring smooth and precise bridge rotation.

Flexible composite structure with customizable in-plane Poisson’s ratio under large deformation

Regulating the inherent Poisson's ratio of soft elastic materials under large deformation is important for their application in emerging fields, such as morphing structures and stretchable electronics. In this study, we selected a composite in which an auxetic honeycomb was embedded in a soft material to regulate the in-plane Poisson's ratio. Based on a cantilever beam model, a theoretical model was established to guide the design optimization of composite structures. The macroscopic constitutive relation and in-plane Poisson's ratio of the composite structures with different configurations were predicted by the theoretical model, which were consistent with the finite element analysis results. In the 30% strain range, the slope of the Poisson's ratio–strain curve decreases with an increase in the length of the inclined bar, and the in-plane Poisson's ratio increases with an increase in the angle between the transverse bar and the inclined bar. In addition, we propose an optimization design method with the in-plane Poisson's ratio as the objective function and then optimize and fabricate a skin structure with an in-plane Poisson's ratio of approximately zero for the morphing wings. The achievements of this study provide theoretical guidance for regulating the in-plane Poisson's ratio of thin flexible layers.

Flexural performance of cold-formed square tube splice joints connected by self-tapping screws

Experimental studies and numerical simulations are performed to investigate flexural performance of cold-formed square tube (CFST) splice joints connected by self-tapping screws. Seven specimens were fabricated from the external steel plate and inner sleeve using self-tapping screws and underwent variations in screw quantity. Refined finite element models were developed and calibrated using a dataset of test results from cold-formed square tube splice joints. Subsequently, an extensive parametric study was undertaken to expand the CFST splice joints data pool, covering the CFST strength, thickness, screw diameter, spacing, as well as the number of rows and columns screws. Finally, a dependable design method for the flexural bearing capacity of CFST splice joints was derived from the experimental and finite element analysis results. The conclusions are as follows: (1) The flexural performance of inner sleeve specimens surpasses that of external steel plate specimens significantly. (2) Variations in steel strength and thickness minimally impacted the flexural bearing capacity of the specimens. Alterations in screw diameter, longitudinal spacing, rows and columns notably influenced the flexural performance of the specimens. (3) A comparison revealed that the proposed design method exhibited higher accuracy and safety in calculating the flexural bearing capacity of CFST splice joints.

Multi-spectroscopic characterization of organic salt components in medicinal plant

The characterization of structure of organic salts in complex mixtures has been a difficult problem in analytical chemistry. In the analysis of Scutellariae Radix (SR), the pharmacopoeia of many countries stipulates that the quality control component is baicalin (≥9% by high performance liquid chromatography (HPLC)). The component with highest response in SR was also baicalin detected by liquid chromatography-mass spectrometry (LC-MS). However, in the attenuated total reflection Fourier transform infrared spectroscopy, the carbonyl peak of glucuronic acid of baicalin did not appear in SR. The results of element analysis, time of flight secondary ion mass spectrometry, matrix assisted laser desorption ionization mass spectrometry and solid-state nuclear magnetic resonance all supported the existence of baicalin magnesium salt. Based on this, this study proposes an analysis strategy guided by infrared spectroscopy and combined with multi-spectroscopy techniques to analyze the structure of organic salt components in medicinal plant. It is meaningful for the research of mechanisms, development of new drugs, and quality control.