Element Geochemistry Research Articles

Elemental Geochemistry on Paleoenvironment Reconstruction: Proxies on Miocene-Pliocene of Marine to Fluvial Sediment in Serpong, Banten, Indonesia

Research of the depositional environment using geological mapping, petrography, gamma-ray (GR) log, palynology, and foraminifera fossils of the Bojongmanik Formation has led to the formation of several different conclusions about the transition to the marine environment, which are attractive to revisit. The expected results of this research are to determine the paleoenvironment of the Bojongmanik and Serpong Formations based on elemental geochemistry, the development of paleoenvironment proxies based on portable X-ray fluorescence (pXRF) in fluvial to transitional environments studies, and the contribution of paleoenvironment analysis to GR-log facies interpretation. The research methodology starts with GR-log facies analysis, Pearson’s correlation, paleoenvironment analysis based on elemental affinity and elemental ratio, and comparing the paleoenvironment with GR-log-based facies. The paleoenvironment analysis based on elemental geochemistry resulted in the Bojongmanik Formation in the research area deposited at the tidal point bar, lagoon, and shoreface, while the Serpong Formation was deposited at the fluvial point bar and floodplain. Compared to previous research, the Bojongmanik Formation in the research area could be stratigraphically related to the upper Bojongmanik Formation. Proxies based on elemental geochemical affinities of carbonate-associated, carbonate-productivity, terrigenous-associated elements, and redox-sensitive trace elements show contrast changes between facies. Proxies based on the specific ratio show a detailed paleoenvironment for paleoclimate (Sr/Cu), paleosalinity (Sr/Ba), paleoredox (Cu/Zn), paleo-hydrodynamics and water depth (Zr/Rb and Fe/Mn), sediment provenance (Cr/Zr), and siliciclastic-dominated (Zr + Rb)/Sr. Adding a geochemistry element-based paleoenvironment analysis benefits from a more specific justification for GR-log facies interpretation.

Fire-Induced Changes in Geochemical Elements of Forest Floor in Southern Siberia

Fire-Induced Changes in Geochemical Elements of Forest Floor in Southern Siberia

Impacts of farmland decontamination on 137Cs transfers in rivers after Fukushima nuclear accident: Evidence from a retrospective sediment core study

Following the Fukushima Daiichi Nuclear Power Plant disaster in March 2011, the Japanese government initiated an unprecedented decontamination programme to remediate 137Cs-contaminated soils and allow population return. This programme involved the removal of topsoil under farmland and residential land, and its replacement with “fresh soil” composed of granitic saprolite. However, decontamination was limited to these two land uses, without remediating forests, which cover 70 % of the surface area in the affected region. In this unprecedented context, the specific impact of this unique decontamination programme on 137Cs transfers in river systems remains to be quantified at the catchment scale. In this study, based on the analysis of a sediment core collected in June 2021 in the Mano Dam reservoir draining a decontaminated catchment, the effects of soil decontamination on particle-bound 137Cs dynamics and sediment source contributions in response to a succession of extreme precipitation events were retrospectively assessed. The sequence of sediment layer deposition and its chronology were reconstructed through the analysis of several diagnostic properties (organic matter, elemental geochemistry, visible colourimetry, granulometry) and contextual information. During abandonment (2011–2016), cropland contribution decreased (31 %). Concurrently, 137Cs activity and deposition flux decreased (19 and 29%year−1, respectively). Following decontamination (2017), sediment transfer increased (270 %) in response to increased contributions from decontaminated cropland and “fresh soil” (625 % and 180 % respectively). Meanwhile, forest contributions remained stable. In contrast, 137Cs activity dropped (65 %), although 137Cs deposition flux remained constant. Forests acted as a stable source of 137Cs. Accordingly, 137Cs deposition flux after decontamination (2016–2021) was similar to that observed during the 5-years period of land abandonment (2011–2016), as a result of the regrowth of spontaneous vegetation over farmland, protecting soil against erosion. Future research should further investigate the impact of longer land abandonment that prevailed in some regions decontaminated lately on the 137Cs fluxes in the rivers.

Features of the genesis of manganese ores of the Kvirila deposit, Georgia (according to the data carbon and oxygen isotope composition and rare earth elements geochemistry)

Features of the genesis of manganese ores of the Kvirila deposit, Georgia (according to the data carbon and oxygen isotope composition and rare earth elements geochemistry)

Genesis of the Neoarchean Algoma-type banded iron formation: constraints from Fe isotope and element geochemistry of the Qian’an iron deposit, eastern North China craton

The Neoarchean Qian’an BIF deposit in eastern Hebei, eastern North China Craton has attracted extensive attention of study in the last decades, but the genesis, e.g., Fe sources, metallogenic mechanism, as well as tectonic attributes of the BIFs remains highly disputed. Based on field investigations, microscopic observations and geochemical analysis, this study tries to unravel the source characteristics of ore-forming materials in the Qian’an deposit. The results show that the chemical compositions of the BIF ore samples are mainly composed of TFe2O3 and SiO2, with minor Al2O3 and TiO2. The total trace element contents of the samples are relatively low. The PAAS-normalized REE distribution patterns of the ores show LREE depletion and HREE enrichment, with robust positive anomalies of Eu, Y and La. These characteristics indicate that the BIFs are attributed to dominant chemical precipitation originated from paleo-ocean with obvious volcanic hydrothermal contributions and minor clastic input. Their positive to no Ce anomalies and positive δ56Femagnetite values unveil that the iron was precipitated at low oxygen fugacity. These results, in collaboration with evidence from previous lithological, structural geology, metamorphic P-T paths, geochemistry, geochronology and numerical modeling studies, support a mantle plume model to explain the complicated tectono-thermal processes, and the sources of BIFs in Eastern Hebei, eastern North China Craton.

Insights into the indium enrichment of the Ashele VMS Cu-Zn deposit, Altay, NW China

Indium (In) is a critical metal used in the photovoltaic and semiconductor industries, which have exhibited extraordinary growth in demand. Indium is produced as a by-product of mining from different ore deposits (e.g., epithermal, sediment-hosted, and skarn). Volcanogenic massive sulfide (VMS) deposits are an important source of In; however, the mechanism of In enrichment is not fully understood. Here, we combine mineralogy with in situ trace element and S-Pb isotope geochemistry to reveal the enrichment of indium in the Ashele VMS Cu-Zn deposit (1.08 Mt. Cu, 0.43 Mt. Zn) located in Altay, NW China. The Ashele deposit is hosted in the metamorphosed Devonian felsic-bimodal volcanic rocks. This deposit consists of seafloor hydrothermal, metamorphic hydrothermal, and supergene stages. The seafloor hydrothermal stage comprises macro-scale Cu-rich bands (chalcopyrite, pyrite, and minor sphalerite) and Zn-rich bands (sphalerite, pyrite, and minor chalcopyrite). Indium is mainly hosted by chalcopyrite (mean 178 ppm) and sphalerite (mean 214 ppm) and occurs in the lattice. Mineral assemblages and trace element geochemistry suggest that the Cu-rich bands were deposited under high temperatures (> 300–350 °C) and sulfur fugacity (−7.2 to −4.9), whereas the Zn-rich bands were formed under lower temperatures (180–220 °C) and sulfur fugacity (−15.7 to −11.5). The interlayered Cu-rich and Zn-rich bands may reflect the oscillating temperature and sulfur fugacity variations. In situ S isotopic compositions of sulfides cluster within two ranges: 1–3 ‰ and 3–6 ‰, suggesting two endmembers: volcanic origin and reduced seawater sulfate. Pb isotopic ratios are similar to those of the host volcanic rocks, indicating that the metals may be derived from the felsic volcanic system. During metamorphism, the indium may be retained, but Cu contents of sphalerite become more homogeneous. Most In-rich VMS deposits worldwide are hosted by the felsic-dominant system in island arc and back-arc settings. These tectonic settings are conducive to the production of felsic volcanic systems, which are more likely to contain In mineralization. This study highlights the enrichment mechanism of indium in VMS deposits and suggests that the South Altay could become an important source of In.

Geochemical Split Among the Suspended and Mud Sediments in the Nethravati River: Insights to Compositional Similarity of Peninsular Gneiss and the Deccan Basalt Derived Sediments, and Its Implications on Tracing the Provenance in the Indian Ocean

AbstractMajor, trace, and rare earth element (REE) geochemistry of sediments from a tropical mountain river is investigated to understand the behavior of chemical elements during weathering and transportation in a Peninsular Gneissic terrain. The results from this study are compared with the Deccan Basalt‐derived River sediments and the eastern Arabian Sea sediments with an intent to highlight the challenges associated with the provenance determination of sediments along the continental margin of India. The geochemistry of suspended particulate matter (SPM) and mud sediments (<63 μm) of the Nethravati River indicate that sediments are derived from a relatively homogenous lithology, characterized by intermediate rocks of tonalitic (low‐Al TTGs) composition. The tectonic origin of the source rocks discriminated using sediment geochemistry suggests an ocean island arc origin. The sediments experience intense chemical weathering in the source region. The elemental composition and their inter‐element relationships suggest differential chemical weathering of mineral phases fractionate mafic components and their secondary mineral products in SPM, and mixed sources dominated by felsic components and their secondary mineral products in mud sediments. Intense chemical weathering induces significant geochemical splits among the suspended and mud sediments. The transport of mafic‐biased sediments from Peninsular India to Oceans, and the geochemical similarity with Deccan Basalt‐derived sediments makes it challenging to track the Peninsular Gneiss‐derived sediment provenance along the continental margin of India using conventional elemental geochemistry. The inferences from this study have important implications for determining the sediment provenance along the continental margin of India.

Unlocking clues on the provenance of the Zigzag Formation in Mountain Province, Northern Luzon, Philippines using sedimentary geochemistry

Abstract Provenance analysis using whole-rock geochemical data was carried out on the Late Oligocene to Early Miocene Zigzag Formation in southwestern Mountain Province, North Luzon, Philippines. Major and trace element geochemistry of the siliciclastic samples from the Zigzag Formation revealed a first-cycle mafic source of the detrital materials. This is consistent with other discrimination diagrams such as those using La, Sc, and Th to determine the provenance. Tectonic discrimination diagrams suggest an oceanic island arc signature for the source rocks of the Zigzag Formation. The Cretaceous to Eocene Lepanto Metavolcanics is proposed to be the source of the detrital materials comprising this clastic sequence. The results present additional information on the current understanding of the evolution of the Central Cordillera.

Forearc Variability and the Geochemical Diversity of Suprasubduction Zone Ophiolites: Insights From the Leka Ophiolite Complex, Norway

AbstractNew whole‐rock major and trace element geochemistry from the Leka Ophiolite Complex in Norway is presented and compared to the geochemical evolution and proposed tectonomagmatic processes recorded in the Izu‐Bonin‐Mariana system. These data demonstrate that the Leka Ophiolite Complex formed as forearc lithosphere during subduction initiation. A new high‐precision zircon U‐Pb date on forearc basalt constrains the timing of subduction initiation in the “Leka sector” of the Iapetus Ocean to 491.36 ± 0.17 Ma. The tectonomagmatic record of the Leka Ophiolite Complex captures only the earliest stages of subduction initiation and is thereby distinct from some other Appalachian–Caledonian ophiolites of similar age. The diversity of Appalachian–Caledonian ophiolite records may represent differing preservation and exposure of a variable forearc lithosphere.

The Fagradalsfjall and Sundhnúkur Fires of 2021–2024: A single magma reservoir under the Reykjanes Peninsula, Iceland?

AbstractThe Reykjanes Peninsula (RP) hosts several volcanic lineaments that have been periodically active over the last 4000 years. Since 2021, following a ca. 800‐year quiescence, eight eruptions have occurred on the RP, with more expected in the future. To better understand the origins of this renewed volcanism and help forecast future eruptions, we examine (i) if the ongoing volcanism is fed from a single or multiple magma storage zone(s) or from several smaller reservoirs and; (ii) where the zone(s) are located (i.e. mantle or lower or upper crustal depths). Using major and trace element geochemistry, oxygen isotopes, and seismic tomography we rule out a single, RP‐scale, deep‐seated magma storage zone. Instead we propose the presence of a ca. 10‐km‐wide region of crustal‐level (9–12 km) magma accumulation beneath the Fagradalsfjall volcanic lineament that fed both the 2021–23 eruptions of the Fagradalsfjall Fires and the 2023–24 eruptions of the Sundhnúkur Fires.

Geochemical characteristics of the modern Yellow River Delta sediments and their response to evolution of the sedimentary environment

IntroductionSedimentary evolution and river channel changes of large river delta (e.g. Huang River, Changjiang River) in response to environmental changes have been one of the key issues in global change research.MethodsThis study reconstructed sedimentary environment changes in the modern Yellow River Delta (YRD), based on grain size and elemental chemical analysis of two short cores (YDC and YDG) from the southern region of the Qing 8 course delta of the modern YRD. ResultsThe results indicated that the cores YDC and YDG sediment were dominated by silt (58.47% and 67.6%, respectively) with varied grain-size variations and poor sediment sorting. The cores YDC and YDG sediments are both predominantly composed of the major element SiO2, and have an average content of 55.53% and 58.45%, respectively. The R-mode factor analysis showed the content of chemical substances of core sediments was controlled by three factors: grain size, sedimentary provenance, and marine sedimentary dynamics. DiscussionBefore the diversion of the Yellow River to the Qing 8 course in 1996, the two cores sediment were mainly sources from the Yellow River, and both cores were in the delta-front sedimentary environment under weak hydrodynamic conditions. After the Yellow River was diverted to the Qing 8 course, the cores YDC and YDG experienced significant erosion under the nearshore strong waves and tides. And then the sedimentary environment of the YRD changed from siltation to erosion. The results of the study would be helps to further our understanding of the changes in sediment grain size and geochemical element characteristics in the Yellow River estuary, and reveal the evolution of its sedimentary environment.

Uranium enrichment driven by paleomarine condition and event deposition: Insights from the lower Cambrian Niutitang Formation organic-rich shales in northeastern Guizhou, South China

Organic-rich shale related uranium (U) mineralization has attracted widespread attention as a strategic and clean alternative to fossil energy and a paleoceanic redox proxy. A comprehensive study of mineralogy, organic geochemistry and elemental geochemistry of the lower Cambrian Niutitang Formation organic-rich shales in northeastern Guizhou, South China was conducted to address this issue. SEM-EDS results showed that the U occurrence state in the Niutitang Formation shales is dominated by nanoscale U minerals, mainly including coffinite, brannerite, U-bearing apatite and U-bearing xenotime. Various states of U are closely associated with organic matter, apatite, pyrite and clay minerals. Based on geochemical indexes, paleomarine condition and event deposition jointly drove the U enrichment in the Niutitang shales, in which hydrothermal activities and/or volcanic eruptions increased U fluxes in seawater and euxinic environment with high primary productivity provided a favorable condition for U reduction. The adsorption, complexation and reduction of UO22+ by organic matter and the formation of uranyl phosphate complexes by the combination of phosphate and UO22+ accelerated U immobilization and enrichment from bottom water to sediments. The microbial activities (e.g., BSR) in this process created favorable euxinic conditions and released inorganic-phase P to provide available ligands for UO22+. The U enrichment models of the lower Cambrian Niutitang shales in northeastern Guizhou were established. This paper provides a new insight into the U enrichment mechanism in organic-rich shales, and may also have implications for the applicability of U as redox proxy and the exploration of organic-rich shale related U deposits.

Combined geochronological U-Pb, Hf isotopes and trace element zircon studies from Piedra Alta Terrane, Rio de la Plata Craton (West Uruguay, South America): A geodynamic model

This work delves into the intricate Paleoproterozoic geological setting of Uruguay, focusing on the Rio de la Plata Craton (RPC) and its prominent constituent Piedra Alta Terrane (PAT). The PAT constitutes the core of the RPC, characterized as a complex geological entity that encompasses a granite-migmatite basement, metamorphic belts, granite intrusions, and Proterozoic magmatism. To the west, it interfaces with the Transbrasiliano-Kandi tectonic corridor, bounded by the Late-Neoproterozoic Pampia Terrane. The PAT s southeastern boundary extends to Sierra de Tandil and perhaps to Sierra de La Ventana, demarcating its limits with Phanerozoic rocks of the North Patagonian Massif. The Sarandí del Yí shear zone defines the eastern limit of the PAT. Despite varied interpretations of the Piedra Alta Terrane’s significance, it is important to note that consensus prevails regarding its four major associations: a granite-gneiss-migmatitic basement complex, three volcanosedimentary belts of low to medium metamorphic grade, diverse late igneous intrusions, and extensional Statherian magmatism (1.79 Ga), represented by tholeiitic gabbroic dikes. In this study, a novel tectonic model for the PAT evolution emerges, supported by an extensive zircon dataset comprising new U-Pb ages, Hf isotopes, and trace element geochemistry. The analytical core involves U-Pb analyses on zircon for dating igneous rocks and establishing the provenance and maximum age of deposition of metavolcanosedimentary sequences. Lu-Hf isotopic analyses on the same zircon crystals provide petrogenetic insights, revealing episodes of crustal growth and minor recycling. Trace element geochemistry and zircon εHf(t) data further accentuate these findings, hinting at mantle source enrichment due to subduction within an intraoceanic magmatic-arc arc setting.

Two stages of gold mineralization in the Hebaoshan deposit: Evidence from the U-Pb dating and trace element geochemistry of rutile, monazite and apatite

The Hebaoshan gold deposit (41.5 t Au @ 3.5 g/t) is located in the southeastern region of the South China Block, central part of the Wuyishan metallogenic belt. The ore-hosting rocks in this area are predominantly Precambrian metasedimentary rocks and Caledonian granitic rocks. Two hydrothermal mineralization stages can be distinguished: a quartz-sericite-pyrite-native gold (stage I) and a chlorite-quartz-sericite-chalcopyrite-electrum (stage II), with hydrothermal monazite and rutile are firstly identified in separate stages. The complex geological history of the region has resulted in ongoing debates regarding the age of gold mineralization and the genesis of the major gold deposits in this area. In order to precisely constrain the mineralization age of the deposit and further establish a genetic model for the ore deposit, LA-ICP-MS U-Pb dating and trace element analysis on accessory minerals were conducted. Based on the textures mineral assemblages, and geochemical features of the accessory minerals, magmatic apatite, hydrothermal rutile, and both magmatic and hydrothermal monazite were identified. The U-Pb ages of magmatic apatite and monazite are determined to be 445.3 ± 15.80, 441.3 ± 15.10 Ma and 446.57 ± 1.03 Ma, respectively, suggesting that these ages represent the emplacement ages of the Caledonian intrusive rocks. The ages of hydrothermal monazite and hydrothermal rutile are determined to be 238.46 ± 2.01 Ma (single-mineral analysis), 238.46 ± 2.01 Ma (in-suit analysis) and 179.54 ± 7.28 Ma, respectively, suggesting that represent two mineralization events during the Late Triassic to early Jurassic in the Hebaoshan area. These data provide new constraints on the mineralization process in the Hebaoshan deposit and excludes the link between gold mineralization and the intrusion of the Caledonian granites. Regionally, It is speculated that the two mineralization events at Hebaoshan are respectively associated with intracontinental orogenic movements between the Yangtze Block and Cathaysia Block, the flat-slab subduction of the Paleo-Pacific Plate (stage I), and the subsequent extensional tectonics related to the collision between the Yangtze Block and Cathaysia Block (stage II).Our study indicates that the timing of multiple episodic mineralization can be constrained by analysis of accessory minerals, which provides a geological basis for better genetic model for the deposit and provide geological evidence for unraveling the relationships between magmatic activities and mineralization events in the region.

Major, Trace and Rare Earth Elements Geochemistry of Bottom Sediments in the Retiro Baixo Reservoir after the B1 Tailings Dam Rupture, Paraopeba River (Brazil)

Major, Trace and Rare Earth Elements Geochemistry of Bottom Sediments in the Retiro Baixo Reservoir after the B1 Tailings Dam Rupture, Paraopeba River (Brazil)

Coupling of Paleosedimentary Environment and Lithofacies: Implications for Shale Oil Enrichment in the Lianggaoshan Formation, Northeastern Sichuan Basin, China.

The sedimentary environment is paramount in dictating depositional processes, ecological settings, and hydrodynamic conditions, all of which are pivotal to the aggregation of organic-rich sediments. A synergistic interplay is observed among the paleosedimentary environment, lithofacies, and enrichment of shale oil. Utilizing an analysis of elemental geochemistry and organic geochemical parameters-such as total organic carbon (TOC) content-this study endeavors to identify the predominant factors that govern the enrichment of organic matter (OM). It reconstructs the evolutionary trajectory of the paleosedimentary environment and introduces a dynamic model for shale oil enrichment within the Jurassic Lianggaoshan Formation of the Sichuan Basin. The results indicate that the Lianggaoshan Formation shale can be categorized into five lithological types, including high TOC felsic-rich shale (A), moderate TOC felsic-rich shale (B), moderate TOC felsic-rich mudstone (C), low TOC felsic-rich shale (D), and low TOC felsic-rich mudstone (E), and high TOC felsic-rich shale has the highest TOC and oil content. The shales of the Lianggaoshan Formation were deposited in an environment characterized by abundant terrestrial input, humid climate, freshwater conditions, reduced oxygen levels, and thriving primary productivity. OM enrichment is mainly controlled by the combination of a humid paleoclimate, high primary productivity, and other factors. The paleoenvironment deposited by lithofacies A coincides with the paleoenvironment conducive to OM enrichment, which makes lithofacies A become the dominant lithofacies for shale oil enrichment. Additionally, the sedimentary environment evolution characteristics and shale oil enrichment model of the Lianggaoshan Formation were established based on geochemical parameters. The paleosedimentary environment of the Lianggaoshan Formation from bottom to top is more and more unfavorable. The No.1 submember of the Lianggaoshan Formation is the most potential shale submember for shale oil exploration due to the paleosedimentary environment that promoted the deposition of lithofacies A and OM enrichment.

Navigating the complexity of detrital rutile provenance: methodological insights from the Neotethys Orogen in Anatolia

Abstract. Sedimentary provenance is a powerful tool for reconstructing convergent margin evolution. However, single mineral approaches, like detrital zircon, have struggled to track sediment input from mafic and metamorphic sources. Detrital rutile complements detrital zircon datasets by offering a path forward in sedimentary provenance reconstructions where metamorphic terranes are potential source regions. However, U–Pb geochronology in rutile can be difficult due to low uranium concentrations and incorporation of common Pb, and multiple workflows are currently in use. Here, we investigate U–Pb and trace element data reduction, processing, and common Pb correction workflows using new detrital rutile U–Pb geochronology and trace element geochemistry results from the Late Cretaceous to Eocene Central Sakarya and Sarıcakaya basins in Anatolia. A significant number of analyses were rejected (54 %) due to signal intensity limitations, namely low U, low Pb, anomalous signal, and inclusions. We identify this as a universal limitation of large-n detrital rutile studies and recommend the systematic reporting of the amount of discarded analysis and the processes for rejection in all studies using detrital rutile U–Pb geochronology. Additionally, we show that (1) the 208Pb and 207Pb common Pb reduction schemes produce similar age distributions and can be used interchangeably, while (2) the Stacey–Kramers distance is a suitable metric for quantifying U–Pb discordance, but a discordance filter is not recommended. (3) Instead, filtering U–Pb data by a power law function based on the corrected date uncertainty is appropriate. (4) The exclusion of low uranium concentration rutile biases date distributions and favors pelitic-derived, higher Zr-in-rutile temperature, and higher U–Pb concordance grains. (5) Paired U–Pb and trace elements can be used to evaluate potential bias in U–Pb data rejection, which reveals that data rejection does not bias the provenance interpretations. Finally, (6) The signature of sediment recycling can be identified through U–Pb dates and Zr-in-rutile temperatures. To better navigate the complexity of detrital rutile datasets and to facilitate the standardization of data reporting approaches, we provide open-access code as Jupyter notebooks for data processing and analysis steps, including common Pb corrections, uncertainty filters, discordance calculations, and trace element analysis.

Improving the accuracy of sediment source fingerprinting under particle sorting

Sediment fingerprinting has proven highly efficient and rapid in identifying the sources and hotspots of sediment, thereby facilitating the targeted implementation of control measures. However, the unpredictable effect of particle sorting during sediment transport on source identification has increased the uncertainty associated with this method. Here, laboratory sieving experiments were carried out to simulate particle sorting during sediment transport. The conservatism of the five widely used tracers (geochemical elements, mid-infrared, near-infrared, visible, and color properties) and the accuracy of sediment source fingerprinting were investigated in the process of sorting. The results highlight that selected tracers exhibited high source contribution prediction accuracy (mean MAE 6.6 %) without particle sorting, with the exception of the color tracer. In contrast, the predictive ability of all tracers significantly reduced (mean MAE 16.2 %) in simulated particle sorting groups (especially for 125–31 μm) due to the enrichment of fine particles. Moreover, the correction factor failed to improve the accuracy of source contribution prediction in this study. The uncertainty caused by particle sorting can be effectively resolved by narrowing the source and sediment particle sizes to <63 μm (for all five tracers) or <31 μm (except for color tracer). This study contributes a deeper understanding of the role of particle size in sediment source fingerprinting, providing valuable insights to guide future tracer selection and associated particle size criteria.

Elemental geochemistry insights into source inputs, paleo-productivity, and paleo-depositional conditions of the Montney Formation

The analysis of the elemental composition of sediments provides valuable information about input sources, paleoredox conditions, or paleoproductivity. In this study, 1498 rock samples from six wells within the Triassic Montney Formation in Central Alberta, Western Canada, were analyzed using energy-dispersive X-ray fluorescence (ED-XRF). Wavelength dispersive X-ray fluorescence measurements were used to build and validate a Montney-specific calibration to interpret elemental concentrations from the ED-XRF dataset. The calibration accounted for heterogeneities, matrix variations and unique elemental associations that may be present within the Montney Formation. Sediment input sources are interpreted based on cross-plots of proxy elements to be terrigenous, carbonates and biogenic in origins. Analysis of multiple paleoredox proxies indicated the environment of deposition to be mainly oxic. The ratios of potassium (K) to rubidium (Rb) were used as a paleoclimate proxy. Results suggest the predominance of low chemical weathering attributed to a hot and arid paleoclimate during deposition of Montney Formation sediments. Phosphorous concentrations were determined to be strongly associated with Ca, as such it was interpreted to be inorganically sourced, thereby precluding it from being used to assess paleoproductivity. Excess Si interpreted to be biogenically sourced was used in interpreting moderate and high paleoproductivity for the Montney formation. This work demonstrates the versality of matrix-specific calibrated ED-XRF measurements as a valuable, cost efficient, standalone technique in geochemical analysis for characterizing geological formations.

Different effects of natural siltation, damming and pollution on two adjacent lakes of Dongting Lake Wetland: Evidence from paleolimnology

Evaluating the influences of hydrology on lotic floodplain lakes has been difficult due to concurrent effects of different human activities in the catchment. This study aims to explore the responses of floodplain lakes to natural siltation and damming by studying grain size and geochemical elements in 210Pb-dated sediment cores from two adjacent lakes with different hydrological conditions in the same catchment, including a hydrologically-isolated lake (Donghu Lake) and a hydrologically-connected lake (East Dongting Lake) in the middle Yangtze floodplain. The results showed that the riverine sediment supply declined in Donghu Lake after its isolation from the Yangtze River due to natural siltation in the 1910s. In East Dongting Lake, the riverine sediment supply remained relatively stable before the operation of the Three Gorges Dam (TGD) in 2003 CE, and then declined rapidly in response to a decrease in riverine sediment supply. Total phosphorus and total organic carbon in Donghu Lake increased after the “reform and opening-up” in the late 1970s, whereas they remained at low concentrations in East Dongting Lake before the TGD operation in 2003 CE. Hydrological isolation from the Yangtze River reduced the influxes of riverine sediments, but promoted nutrient enrichment and primary production in East Dongting Lake through extending water residence times. Stable element composition in Donghu Lake after 2003 CE suggested that the TGD operation had minor effects on hydrologically-isolated lakes. The comparison between hydrologically-closed and hydrologically-free lakes within the same catchment provides an effective method to identify different effects of natural siltation, damming and environmental pollution.