Measurements of the warm carrier coefficient β, which describes the deviations from Ohm's law at medium electric field strengths, are reported forn-type silicon andn-type germanium for different impurity concentrations and for different crystallographic orientations. Due to the anisotropy of β we can divide into deviations from Ohm's law in one valley of the many valley-semiconductors and into intervalley scattering between the different valleys. Both effects decrease with increasing electron concentration. Additional we observe a maximum in intervalley scattering with the inset of dominating impurity scattering.
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