Electron Volts Research Articles

Pulsed X-Ray and Cathodoluminescence of Pure and Alloyed Zinc Selenide Single Crystals

The paper studies the amplitude and spectral-kinetic behavior of pulsed X-ray and cathodoluminescence of non-alloyed zinc selenide (ZnSe) single crystals and those alloyed by gallium, tellurium and samarium. At 300 K, the spectra of pulsed cathodoluminescence of pure ZnSe single crystals show a 490 nm illumination at ~20 ns pulse time. Two spectral bands are observed in alloyed ZnSe single crystals, band edge at ~477 nm and with maximum at ~600 nm at a pulse time of ~20 ns and ~5 μs, respectively. The intensity ratio of these peaks depends on the electron-beam energy density and the geometry of spectrum measurements. X-ray luminescence spectra of the alloyed ZnSe single crystals show an ~600 nm illumination, the intensity of which depends on the type of impurity. The possibility of applying the pure and alloyed ZnSe single crystals is discussed herein for the development of amplitude-time characteristic sensors of electron beams and X-ray radiation energy ranging from tens to hundreds of kiloelectronvolts.

Dependence of Megaelectron Volt Time-of-Flight Secondary Ion Mass Spectrometry Secondary Molecular Ion Yield from Phthalocyanine Blue on Primary Ion Stopping Power.

Time-of-flight secondary ion mass spectrometry (TOF SIMS) is a well-established mass spectrometry technique used for the chemical analysis of both organic and inorganic materials. In the last ten years, many advances have been made to improve the yield of secondary molecular ions, especially those desorbed from the surfaces of organic samples. For this reason, cluster ion beams with kiloelectron volt energies for the excitation were mostly used. Alternatively, single-ion beams with megaelectron volt energies can be applied, as was done in the present work. It is well-known that a secondary molecule/ion yield depends strongly on the primary ion stopping power, but the nature of this dependence is not completely clear. Therefore, in the present work, the secondary ion yield from the phthalocyanine blue (C32H16CuN8, organic pigment) was measured for the various combinations of ion masses, energies, and charge states. Measured values were compared with the existing models for ion sputtering. An increase in the secondary yield with the primary ion energy, electronic stopping, velocity, and charge state was found for different types of primary ions. Although this general behavior is valid for all primary ions, there is no single parameter that can describe the measured results for all primary ions at once.

Detector Upgrade for Fast MeV X-Ray Imaging for Severe Accidents Experiments

Digital X-ray imaging systems for megaelectronvolt (MeV)-range photon beams are based on a combination of a scintillator screen and either a camera or an amorphous silicon array. To limit dose rate on electronics and enhance imaging device lifetime, the scintillator screen can be mirror-coupled to the camera. Performances of such devices are a compromise between exposure time and spatial resolution. These technical characteristics are especially scintillator-dependent. In this article, we present, in the first part, a performance evaluation of six different scintillators with a 9-MeV Bremsstrahlung X-ray source. The tested scintillators are composed of one microstructured CsI:Tl scintillator, two phosphor [Gd2O2S (GOS)] screens, and three transparent scintillators. These scintillators present a wide range of density, thickness, and conversion efficiency. The scintillator’s performance assessment is based on the combination of light output and spatial resolution. The results are helpful to guide design and engineering of high-energy imaging devices adapted to specific requirements. In the second part, imaging performance comparison is done between our current GOS screen detector and a new CsI screen detector.

Electron Scattering in Liquid Water and Amorphous Ice: A Striking Resemblance.

The lack of accurate low-energy electron scattering cross sections for liquid water is a substantial source of uncertainty in the modeling of radiation chemistry and biology. The use of existing amorphous ice scattering cross sections for the lack of liquid data has been discussed controversially for decades. Here, we compare experimental photoemission data of liquid water with corresponding predictions using amorphous ice cross sections, with the aim of resolving the debate regarding the difference of electron scattering in liquid water and amorphous ice. We find very similar scattering properties in the liquid and the ice for electron kinetic energies up to a few hundred electron volts. The scattering cross sections recommended here for liquid water are an extension of the amorphous ice cross sections. Within the framework of currently available experimental data, our work answers one of the most debated questions regarding electron scattering in liquid water.

Design of novel pentagonal 2D transitional-metal sulphide monolayers for hydrogen evolution reaction

Due to the unique properties and diverse applications, two-dimensional (2D) nanomaterials have been widely investigated in these years. In this work, a group of new pentagonal 2D transitional-metal sulphide monolayers (MS, M = Fe, Mn, and V) are designed based on density-functional-theory (DFT) calculations. We show that all three monolayer structures are thermally, dynamically and mechanically stable. We find that FeS, MnS and VS are metallic, and FeS and MnS are also magnetic, in which the magnetic moments are contributed by the Fe and Mn atoms, respectively. We further find that these MS monolayers show high activities for hydrogen evolution reactions (HER) as the calculated Gibbs free energies are close to zero electron volt (eV), especially for FeS and VS. Our findings broaden the family of noble-metal-free two-dimensional materials, and also help to develop low cost commercial HER catalysts.

Counterstreaming Strahls and Heat Flux Dropouts as Possible Signatures of Local Particle Acceleration in the Solar Wind

Abstract Suprathermal electrons with energies of ∼70 eV and above are observed at 1 au as dispersionless halo electrons and magnetic field-aligned beams of strahls. For a long time, it has been thought that both populations originate only from the solar corona, and that the only active process impacting their properties in the solar wind is scattering. This view has consequently impacted the interpretation of typical patterns of pitch-angle distributions (PADs) of suprathermal electrons. Meanwhile, recent observational studies supported by numerical simulations have shown that there is an unaccounted population of electrons accelerated to suprathermal energies at reconnecting current sheets (RCSs) and 3D dynamical plasmoids (or 2D magnetic islands (MIs)) directly in the heliosphere. We present multispacecraft observations of counterstreaming strahls and heat flux dropouts in PADs within a region filled with plasmoids and RCSs unaffected by interplanetary shocks, comparing observed PAD features with those predicted by particle-in-cell simulations. We show typical PAD patterns determined by local acceleration of thermal-core electrons up to hundreds of electron volts. Resulting PAD views depend on properties and topology of particular RCSs, MIs, and plasma/magnetic field parameters. Our study suggests that solar wind-borne suprathermal electrons coexist with those of solar origin. Therefore, some of heat flux dropout and bidirectional strahl events can be explained by local dynamical processes involving magnetic reconnection. Possible implications of the results for the interpretation of the actively debated decrease in the strahl/halo relative density with heliocentric distance and puzzling features of suprathermal electrons observed at crossings of the heliospheric current sheet and cometary comas are also discussed.

Ultrafast x-ray and electron scattering of free molecules: A comparative evaluation.

Resolving gas phase molecular motions with simultaneous spatial and temporal resolution is rapidly coming within the reach of x-ray Free Electron Lasers (XFELs) and Mega-electron-Volt (MeV) electron beams. These two methods enable scattering experiments that have yielded fascinating new results, and while both are important methods for determining transient molecular structures in photochemical reactions, it is important to understand their relative merits. In the present study, we evaluate the respective scattering cross sections of the two methods and simulate their ability to determine excited state molecular structures in light of currently existing XFEL and MeV source parameters. Using the example of optically excited N-methyl morpholine and simulating the scattering patterns with shot noise, we find that the currently achievable signals are superior with x-ray scattering for equal samples and on a per-shot basis and that x-ray scattering requires fewer detected signal counts for an equal fidelity structure determination. Importantly, within the independent atom model, excellent structure determinations can be achieved for scattering vectors only to about 5 Å−1, leaving larger scattering vector ranges for investigating vibrational motions and wavepackets. Electron scattering has a comparatively higher sensitivity toward hydrogen atoms, which may point to applications where electron scattering is inherently the preferred choice, provided that excellent signals can be achieved at large scattering angles that are currently difficult to access.

Engineering perovskites with anions

Solar Cells The bandgap of the perovskite top layer in tandem silicon solar cells must be tuned to ∼1.7 electron volts. Usually, the cation composition is varied because the bromine-rich anion compositions with wide bandgaps are structurally unstable. Kim et al. show that by using phenethylammonium as a two-dimensional additive, along with iodine and thiocyanate, bromine-rich perovskite films can be stabilized. A tandem silicon cell delivered >26% certified power conversion efficiency, and a perovskite device maintained 80% of its initial power conversion efficiency of >20% after 1000 hours under illumination. Science , this issue p. [155][1] [1]: /lookup/doi/10.1126/science.aba3433

Preliminary study: Measurement of ion beam energy spreads produced by a Penning ionization gauge-type ion source using electromagnets for a mega-electron volt compact ion microbeam system.

The energy spreads of ion beams generated from a penning ionization gauge-type ion source with electromagnets were measured using a parallel electrostatic analyzer. The ion source was developed to be installed in a mega-electron volt (MeV) compact ion microbeam system. A gaseous ion beam of expectedly high brightness and narrow energy spread was generated from the ion source to form a microbeam. To produce such an ion beam, a high-density plasma with a small volume was generated using a strong magnetic field in the ion source. The beam energy spread width was of particular importance because it forms an ion microbeam by reducing the chromatic aberration at a focusing lens. In this report, the energy spread was investigated by changing the parameters of the ion source, e.g., extraction voltage, excitation current of electromagnets, vacuum, and anode voltage. The investigation showed that spread widths are influenced by the extraction voltage, vacuum, and anode voltage. The minimum width of ∼5.0 ± 0.1 eV was obtained at a beam energy of 200 eV. This value is acceptable for the MeV compact ion microbeam system.

Electron Acceleration and Thermalization at Magnetotail Separatrices

AbstractIn this study we use the Magnetospheric Multiscale mission to investigate the electron acceleration and thermalization occurring along the magnetic reconnection separatrices in the magnetotail. We find that initially cold electron lobe populations are accelerated toward the X line forming beams with energies up to a few kiloelectron volts, corresponding to a substantial fraction of the electron thermal energy inside the exhaust. The accelerated electron populations are unstable to the formation of electrostatic waves which develop into nonlinear electrostatic solitary waves. The waves' amplitudes are large enough to interact efficiently with a large part of the electron population, including the electron beam. The wave‐particle interaction gradually thermalizes the beam, transforming directed drift energy to thermal energy.

High-Energy Particles and Radiation in Star-Forming Regions

Non-thermal particles and high-energy radiation can play a role in the dynamical processes in star-forming regions and provide an important piece of the multiwavelength observational picture of their structure and components. Powerful stellar winds and supernovae in compact clusters of massive stars and OB associations are known to be favourable sites of high-energy particle acceleration and sources of non-thermal radiation and neutrinos. Namely, young massive stellar clusters are likely sources of the PeV (petaelectronvolt) regime cosmic rays (CRs). They can also be responsible for the cosmic ray composition, e.g., 22Ne/20Ne anomalous isotopic ratio in CRs. Efficient particle acceleration can be accompanied by super-adiabatic amplification of the fluctuating magnetic fields in the systems converting a part of kinetic power of the winds and supernovae into the magnetic energy through the CR-driven instabilities. The escape and CR propagation in the vicinity of the sources are affected by the non-linear CR feedback. These effects are expected to be important in starburst galaxies, which produce high-energy neutrinos and gamma-rays. We give a brief review of the theoretical models and observational data on high-energy particle acceleration and their radiation in star-forming regions with young stellar population.

Effect of a tightly focused chirped Gaussian laser pulse on electron acceleration in helical undulator

The chirped-pulse inverse free electron laser (CIFEL) interaction has been investigated by considering a tightly focused chirped Gaussian laser pulse and a helical undulator in vacuum. We consider the more realistic description of a laser, i.e., seventh-order calculation in the spatial term and first-order calculation in the temporal term. Numerical calculations show that better electron acceleration can be achieved using a tightly focused chirped Gaussian laser pulse in the CIFEL scheme. The investigation shows that a 10 MeV electron can be accelerated up to a few giga-electron volts energy with the present available laser parameters.

Efficient, stable silicon tandem cells enabled by anion-engineered wide-bandgap perovskites.

Maximizing the power conversion efficiency (PCE) of perovskite/silicon tandem solar cells that can exceed the Shockley-Queisser single-cell limit requires a high-performing, stable perovskite top cell with a wide bandgap. We developed a stable perovskite solar cell with a bandgap of ~1.7 electron volts that retained more than 80% of its initial PCE of 20.7% after 1000 hours of continuous illumination. Anion engineering of phenethylammonium-based two-dimensional (2D) additives was critical for controlling the structural and electrical properties of the 2D passivation layers based on a lead iodide framework. The high PCE of 26.7% of a monolithic two-terminal wide-bandgap perovskite/silicon tandem solar cell was made possible by the ideal combination of spectral responses of the top and bottom cells.

Nanoscale electronic inhomogeneity in FeSe0.4Te0.6 revealed through unsupervised machine learning

We report on an apparent low-energy nanoscale electronic inhomogeneity in FeSe$_{0.4}$Te$_{0.6}$ due to the distribution of selenium and tellurium atoms revealed through unsupervised machine learning. Through an unsupervised clustering algorithm, characteristic spectra of selenium- and tellurium-rich regions are identified. The inhomogeneity linked to these spectra can clearly be traced in the differential conductance and is detected both at energy scales of a few electron volts as well as within a few millielectronvolts of the Fermi energy. By comparison with ARPES, this inhomogeneity can be linked to an electron-like band just above the Fermi energy. It is directly correlated with the local distribution of selenium and tellurium. There is no clear correlation with the magnitude of the superconducting gap, however the height of the coherence peaks shows significant correlation with the intensity with which this band is detected, and hence with the local chemical composition.

Tuning band gaps with three halides

Solar Cells Tandem solar cells can boost solar cell efficiency by using two active layers to absorb the solar spectrum more completely, provided that the two cells are current-matched. Inorganic-organic perovskites tuned to the appropriate wide band gap (∼1.7 electron volts) as top cells that contained iodine and bromine or bromine and chlorine have short carrier diffusion lengths and undergo photo-induced phase segregation. Xu et al. now report a method for incorporating chloride that allows for fabrication of stable triple-halide perovskites with a band gap of 1.67 electron volts. Two-terminal tandem silicon solar cells made with this material had a power conversion efficiency of 27%. Science , this issue p. [1097][1] [1]: /lookup/doi/10.1126/science.aaz5074

Triple-halide wide-band gap perovskites with suppressed phase segregation for efficient tandems.

Wide-band gap metal halide perovskites are promising semiconductors to pair with silicon in tandem solar cells to pursue the goal of achieving power conversion efficiency (PCE) greater than 30% at low cost. However, wide-band gap perovskite solar cells have been fundamentally limited by photoinduced phase segregation and low open-circuit voltage. We report efficient 1.67-electron volt wide-band gap perovskite top cells using triple-halide alloys (chlorine, bromine, iodine) to tailor the band gap and stabilize the semiconductor under illumination. We show a factor of 2 increase in photocarrier lifetime and charge-carrier mobility that resulted from enhancing the solubility of chlorine by replacing some of the iodine with bromine to shrink the lattice parameter. We observed a suppression of light-induced phase segregation in films even at 100-sun illumination intensity and less than 4% degradation in semitransparent top cells after 1000 hours of maximum power point (MPP) operation at 60°C. By integrating these top cells with silicon bottom cells, we achieved a PCE of 27% in two-terminal monolithic tandems with an area of 1 square centimeter.

Efficient tandem solar cells with solution-processed perovskite on textured crystalline silicon.

Stacking solar cells with decreasing band gaps to form tandems presents the possibility of overcoming the single-junction Shockley-Queisser limit in photovoltaics. The rapid development of solution-processed perovskites has brought perovskite single-junction efficiencies >20%. However, this process has yet to enable monolithic integration with industry-relevant textured crystalline silicon solar cells. We report tandems that combine solution-processed micrometer-thick perovskite top cells with fully textured silicon heterojunction bottom cells. To overcome the charge-collection challenges in micrometer-thick perovskites, we enhanced threefold the depletion width at the bases of silicon pyramids. Moreover, by anchoring a self-limiting passivant (1-butanethiol) on the perovskite surfaces, we enhanced the diffusion length and further suppressed phase segregation. These combined enhancements enabled an independently certified power conversion efficiency of 25.7% for perovskite-silicon tandem solar cells. These devices exhibited negligible performance loss after a 400-hour thermal stability test at 85°C and also after 400 hours under maximum power point tracking at 40°C.

Growing perovskite on textured silicon

Solar Cells Wide–band gap perovskites could boost the efficiency of silicon solar cells by forming tandem cells, but usually the perovskite must be grown on a smoothed side of the silicon cell because the material grown on the rough light-trapping side often does not fully coat the silicon surface and its rough texture is prone to phase separation. Hou et al. grew thick films of a perovskite with a band gap of ∼1.68 electron volts and used a passivant, 1-butanethiol, to limit its phase separation. The tandem cells had a certified power conversion efficiency of 25.7% and had negligible losses after 400 hours of operation. Science , this issue p. [1135][1] [1]: /lookup/doi/10.1126/science.aaz3691

Soft X-ray Radiation and Monte Carlo Simulations: Good Tools to Describe the Radiation Chemistry of Sub-keV Electrons.

The description of the biological effects of ionizing radiation requires a good knowledge of the dose deposition processes at both the cellular and molecular scales. However, experimental studies on the energy deposition specificity of sub-keV electrons, produced by most radiations, including high-energy photons and heavy ions, are scarce. Soft X-rays (0.2-2 keV) are here used to probe the physical and physico-chemical events occurring upon exposure of liquid water to sub-keV electrons. Liquid water samples were irradiated with a monochromatic photon beam at the SOLEIL synchrotron. Hydroxyl radical quantification was conducted through HO• scavenging using benzoate to form fluorescent hydroxybenzoate. The yields of HO• radicals exhibit a minimum around 1.5 keV, in good agreement with indirect observation. Moreover, they are relatively independent of the benzoate concentration in the range investigated, which corresponds to scavenging times of 170 ns to 170 ps. These results provide evidence that sub-keV electrons behave as high linear energy transfer particles, since they are able to deposit tens to hundreds of electronvolts in nanometric volumes.

Experimental Results of Electron Method for Remote Spacecraft Charge Sensing

AbstractRemote charge sensing is a technique that can provide valuable insight into spacecraft‐environment interactions, as well as enable missions that leverage electrostatic interactions between multiple spacecraft or involve docking maneuvers in harsh charging environments. The concept discussed in this paper uses a co‐orbiting servicing spacecraft to measure the energies of secondary electrons or photoelectrons that are emitted from the target object with initial energies of a few electron volts. The electrons are accelerated toward the servicing spacecraft, which is at a known positive potential (relative to the target), where they are measured by an energy analyzer. Given the potential of the servicing spacecraft, the potential of the target can be accurately determined. Results are presented from experiments conducted in a vacuum chamber to investigate the touchless sensing concept. Specifically, the feasibility and accuracy of the electron method is considered for different materials, charge scenarios, and relative geometries. The results show that the surface potential of a flat plate can be accurately determined for a range of metallic surface materials, voltages, and relative angles.