Electron Spin Resonance Study Of Radicals Research Articles

An electron spin-resonance study of radicals in single crystals

An ESR study of centres in x-irradiated ammonium perchlorate single crystals is carried out that is aimed at resolving the controversy that has recently arisen over the possible occurrence of low-temperature phase transitions in the compound (room temperature structure: orthorhombic; space group Pnma). The ESR spectra are recorded as a function of the orientation of the magnetic field H in the three orthogonal crystallographic planes at 300 K, 77 K, and 4.2 K, and also as a function of temperature for H parallel to the principal z-component of the hyperfine coupling tensor. The analysis of the spectra shows that while the -tensor remained axial over the entire temperature range 2.0052(3), 2.0055(3), 2.0057(3) and 2.0090(3), 2.0096(3), 2.0105(3) at 300 K, 77 K, and 4.2 K respectively), , which is rhombic at room temperature , , and at 300 K) becomes more axial as the temperature is lowered , , and at 77 K, and , , and at 4.2 K). No changes in the spectra attributable to any phase transition were observed, and we conclude that does not undergo any phase transition below room temperature. Furthermore, it is found that during radiative decomposition the mirror-related Cl - O bonds, even though weaker than the other Cl - O bonds, do not break, thus confirming our earlier conclusion that mirror symmetry is preserved during radiation damage.

An ESR study of radicals in CaCO3 produced by 1.6 MeV He+- and γ-irradiation

The effects of charged-particle irradiation on the formation of defects in CaCO3 have been studied using electron spin resonance (ESR). An orthorhombic CO2− was dominant in powdered synthetic aragonite irradiated by 1.6 MeV He+, while both orthorhombic and isotropic CO2− were observed in α-irradiated aragonite powder. G-values (number of defects per 100 eV) for α-and γ-rays were obtained to be Gα = 0.0041 and Gγ = 0.27 for aragonite leading to a k-value (γ-ray efficiency) of 0.015.

Electron spin resonance study of neutral radicals derived from cyclic and acyclic carbonate esters

An electron-spin resonance study of radicals formed from cyclic and acyclic carbonate esters by loss of a hydrogen atom is reported. The radicals were generated photolytically near room temperature in solutions containing 1 % H 2O 2. Spectra were analyzed and couplings are discussed for two radicals formed from diethyl carbonate, two from propylene carbonate (4-methyl-1,3-dioxolan-2-one), and one each from dimethyl carbonate and ethylene carbonate (1,3-dioxolan-2-one).