Electron Distribution Research Articles

Enhanced co-production of hydrogen and ethanol from brown algae fermentation by supplementing nano zero-valent iron (nZVI)

Nano zero-valent iron (nZVI) has been shown to facilitate biofuel production, notably in hydrogen generation. However, its effect on bioethanol production is rarely studied, and even less so on its impact on hydrogen and ethanol co-production. This study therefore conducted ethanol-type hydrogen-producing fermentation with brown algae to explore the effect of nZVI. With the supplementation of nZVI, fermentation was accelerated and the production of hydrogen and ethanol were both significantly enhanced. At the optimal nZVI concentration of 100 mg/L, the production of hydrogen and ethanol increased by 71.44% and 65.11%, respectively. A high hydrogen yield of 2.32 mol/mol-mannitol was achieved. The ethanol yield (1.86 mol/mol-mannitol) reached 93% of the theoretical maximal yield with a high selectivity of 91.09%. Electron distribution analysis showed that nZVI increased the total electron amounts of fermentation, and directed more electrons to ethanol than hydrogen. The reduced redox potential (ORP) and increased NADH level further confirmed the role of nZVI. Moreover, nZVI fostered Fe2+ availability to hydrogen-producing bacteria, enhancing the enzymes hydrogenase and alcohol dehydrogenase, as well as cell biomass. The bioenergy conversion efficiency (BioECE) improved from 19.08% to 31.74% with 100 mg/L nZVI treatment. This study provided a first demonstration regarding the role of nZVI in hydrogen and ethanol co-production, highlighting the great potential of multiple bioenergy recovery from marine biomass.

Mechanical and optical properties of porous black Al2O3: Experimental, DFT, and wave optics investigation

Porous black Al2O3 was fabricated by gel casting and pressureless sintering (PS). MnO2 and Fe2O3 incorporated in Al2O3 led to the formation of MnAl2O4 and FeAl2O4 at ≥1200 °C, enhancing its opacity. The influence of various MnO2 content and sintering temperature on the mechanical and optical properties of porous black Al2O3 was investigated. The results showed that as MnO2 content and sintering temperature increased, porosity decreased, bulk density increased, compressive strength increased, and opacity increased. Using density functional theory (DFT), the intrinsic properties of MnAl2O4 and FeAl2O4 were investigated, including band structure (BS), electron distribution, partial density of states (PDOS), and optical properties such as refractivity, absorption, dielectric constant, conductivity, and dissipation factor across various wavelengths. These DFT calculations were incorporated into the wave optics model to assess the response and impedance matching of porous black Al2O3 to transverse electric (TE) and transverse magnetic (TM) waves with various MnAl2O4 content.

Asymmetrically Coordinated Calcium Single Atom for High-Performance Oxygen Reduction Reaction.

S-block single atoms represent an ideal catalyst for the oxygen reduction reaction (ORR) as they can suppress the Fenton reaction. However, the symmetry of the s/p orbitals tends to generate either an excessively strong or weak interaction with intermediates. Herein, Ca single atoms coordinated with -S, -OP, and three N atoms (Ca/NPS-HC) were fabricated to modulate the adsorption of intermediates and promote the efficiency of s-block ORR catalysts. The experimental results from ORR demonstrated that the Ca/NPS-HC catalyst exhibited outstanding catalytic capability with a half-wave potential of 0.89 V, a kinetic current density of 56.6 mA cm-2 at 0.85 V, and a Tafel slope of 42 mV dec-1, outperforming commercial Pt/C. The detailed mechanistic studies revealed that the asymmetric coordination of Ca single atoms led to the symmetry-breaking of electron distribution in Ca single atoms, attenuating the s-p hybridization from the intermediate adsorption process, and thereby minimizing the energy barrier of the whole ORR.

H/O edge passivated B/N co-doped armchair graphene nanoribbon field-effect transistors, based on first principles

This study employs the nonequilibrium Green’s function method in conjunction with density functional theory to fabricate and analyze a Graphene Nanoribbon Field-Effect Transistor (GNRFET). The co-doping of B and N creates built-in electric fields, thereby reducing leakage current. The results demonstrate effective control performance of planar gates, as evidenced by an increase in IDS with rising gate voltage. Furthermore, a negative differential conductance phenomenon is observed at bias voltages exceeding 0.7 V, exhibiting correlation with transmission spectra and energy band structures. To precisely illustrate the electron distribution within the doped scattering region, calculations involving transport paths, the molecular projection self-consistent Hamiltonian (MPSH), and the emission eigenvalues and eigenstates of the device are conducted. This research provides a reference for exploring and developing smaller and more energy-efficient AGNR field effect transistor designs and implementations. The principal objective of this paper is to investigate the potential applications of these smaller, more energy-efficient devices.

Characterization of induced quasi-two-dimensional transport in n-type InxGa1−xAs1 − yBiy bulk layer

The temperature-dependent transport properties of n-type InGaAsBi epitaxial alloys with various doping densities are investigated by conducting magnetoresistance (MR) and Hall Effect (HE) measurements. The electronic band structure of the alloys and free electron distribution were calculated using Finite Element Method (FEM). Analysis of the oscillations in the transverse (Hall) resistivity shows that quasi-two-dimensional electron gas (Q-2D) in the bulk InGaAsBi epitaxial layer (three-dimensional, 3D) forms at the sample surface under magnetic field even though there is no formation of the spacial two-dimensional electron gas (2DEG) at the interface between InGaAs and InP:Fe interlayer. The formation of Q-2D in the 3D epitaxial layer was verified by temperature and magnetic field dependence of the resistivity and carrier concentration. Analysis of Shubnikov-de Haas (SdH) oscillations in longitudinal (sample) resistivity reveals that the electron effective mass in InGaAsBi alloys are not affect by Bi incorporation into host InGaAs alloys, which verifies the validity of the Valence Band Anti-Crossing (VBAC) model. The Hall mobility of the nondegenerate samples shows the conventional 3D characteristics while that of the samples is independence of temperature for degenerated samples. The scattering mechanism of the electrons at low temperature is in long-range interaction regime. In addition, the effects of electron density on the transport parameters such as the effective mass, and Fermi level are elucidated considering bandgap nonparabolicity and VBAC interaction in InGaAsBi alloys.

Revealing the ESIPT process in benzoxazole fluorophores within polymeric matrices through theory and experiment.

The impact of the polymeric matrix on the photophysical characteristics of monomeric dyes responsive to excited-state intramolecular proton transfer (ESIPT) was investigated through UV-Vis absorption as well as steady-state and time-resolved emission spectroscopies. For this purpose, two benzoxazole monomers (M1 and M2) with acryloyl groups at different positions in their molecular structures were employed to facilitate covalent bonding within a styrene chain. Our findings reveal significant variations in their excited-state properties due to the proximity of the acryloyl groups, which affects the energy barrier of the ESIPT reaction, the emission wavelength, and the balance between the normal and tautomeric forms. The experimental results were corroborated through theoretical investigations at the DFT/TDDFT level, specifically using the B3LYP-D3/def2-TZVP methodology. Three notable observations emerged: donor/acceptor groups at the meta/para positions induced electron distribution changes, causing red-shifted emission for M2; in the polymer film, particularly in PM1, intramolecular hydrogen bond deactivation favored N* emission over T* emission; and the zwitterionic character of the T* species. This study underscores the advantages of functionalization in polymers, which can lead to colorless films and prevalent N* or T* emission, and contributes valuable insights into molecular design strategies for tailoring the photophysical properties of polymeric materials.

Dual-Band Photomultiplication-Type Organic Photodetectors with Ultrahigh Signal-to-Noise Ratios.

A series of dual-band photomultiplication (PM)-type organic photodetectors (OPDs) were fabricated by employing a donor(s)/acceptor (100:1, wt/wt) mixed layer and an ultrathin Y6 layer as the active layers, as well as by using PNDIT-F3N as an interfacial layer near the indium tin oxide (ITO) electrode. The dual-band PM-type OPDs exhibit the response range of 330-650 nm under forward bias and the response range of 650-850 nm under reverse bias. The tunable spectral response range of dual-band PM-type OPDs under forward or reverse bias can be explained well from the trapped electron distribution near the electrodes. The dark current density (JD) of the dual-band PM-type OPDs can be efficiently suppressed by employing PNDIT-F3N as the anode interfacial layer and the special active layers with hole-only transport characteristics. The light current density (JL) of the dual-band PM-type OPDs can be slightly increased by incorporating wide-bandgap polymer P-TPDs with relatively large hole mobility (μh) in the active layers. The signal-to-noise ratios of the optimized dual-band PM-type OPDs reach 100,980 under -50 V bias and white light illumination with an intensity of 1.0 mW·cm-2, benefiting from the ultralow JD by employing wide-bandgap PNDIT-F3N as the anode interfacial buffer layer and the increased JL by incorporating appropriate P-TPD in the active layers.

Systematic approach to measure the performance of microchannel-plate photomultipliers

In this paper, we present our approach to systematically measure numerous performance parameters of microchannel plate photomultiplier tubes. The experimental setups, the analyses and selected results are discussed. Although the techniques used may be different in other locations, the document is intended as a guide for comparable measurements with other types of microchannel plate photomultiplier tubes. Measurements are shown for the following performance parameters: spectral and spatial quantum efficiency, collection efficiency, gain as a function of voltage, position and magnetic field, time resolution, rate capability and lifetime. By using a dedicated 3-axis stepper and an FPGA-based data acquisition system, also inner PMT parameters are measured as a function of the active area, such as relative detection efficiency, dark count rate, time resolution, recoil electron and afterpulse distributions, as well as charge sharing and electronic crosstalk. In addition, some of the parameters are investigated inside a strong magnetic field. For many of these measurements, the change of most setup parameters and the subsequent analysis can be controlled semi-automatically by software scripts.

To plasma electrons motion theory in high-frequency fields

The article is dedicated to the kinetic theory of plasma, where the problem of interaction of high-frequency electric fields with weakly non-uniform plasma is investigated using kinetic equations with binary collision integrals for plasma particles. A new methodology for determining the expression of the averaged highfrequency pressure force is proposed based on solving the kinetic equation and using the method of successive approximations (separation of slow motions and fast oscillations) under the limiting conditions. An expression for the averaged quasi-potential force is derived based on the kinetic equation for the electron distribution function in weakly inhomogeneous magnetoactive plasma, taking into account electrons collisions with fixed ions and the presence of a longitudinally inhomogeneous high-frequency electric field using wellknown methods of theoretical and mathematical physics, such as successive approximations, averaging over the effective field oscillation period, and integration over trajectories. The amplitude of the field is a slowly varying function in both time and space coordinates. The obtained expression allows us to estimate the influence of collisions of plasma particles on the Miller force, and under limiting conditions it coincides with the known expressions for the high-frequency pressure force derived from the equation of plasma electrons motion in high-frequency fields. In all calculations, the contribution of the magnetic component of the electromagnetic field is neglected, which is quite justified for the longitudinal electric field.

Electrocatalytic Reduction of Carbon Dioxide in Acidic Electrolyte with Superior Performance of a Metal-Covalent Organic Framework over Metal-Organic Framework.

CO2 electroreduction (CO2RR) to generate valuable chemicals in acidic electrolytes can improve the carbon utilization rate in comparison to that under alkaline conditions. However, the thermodynamically more favorable hydrogen evolution reaction under an acidic electrolyte makes the CO2RR a big challenge. Herein, robust metal phthalocyanine(Pc)-based (M = Ni, Co) conductive metal-covalent organic frameworks (MCOFs) connected by strong metal tetraaza[14]annulene (TAA) linkage, named NiPc-NiTAA and NiPc-CoTAA, are designed and synthesized to apply in the CO2RR in acidic electrolytes for the first time. The optimal NiPc-NiTAA exhibited an excellent Faradaic efficiency (FECO) of 95.1% and a CO partial current density of 143.0 mA cm-2 at -1.5 V versus the reversible hydrogen electrode in an acidic electrolyte, which is 3.1 times that of the corresponding metal-organic framework NiPc-NiN4. The comparison tests and theoretical calculations reveal that in-plane full π-d conjugation MCOF with a good conductivity of 3.01 × 10-4 S m-1 accelerates migration of the electrons. The NiTAA linkage can tune the electron distribution in the d orbit of metal centers, making the d-band center close to the Fermi level and then activating CO2. Thus, the active sites of NiPc and NiTAA collaborate to reduce the *COOH formation energy barrier, favoring CO production in an acid electrolyte. It is a helpful route for designing outstanding conductive MCOF materials to enhance CO2 electrocatalysis under an acidic electrolyte.

Critical assessment of the x-ray restrained wave function approach: Advantages, drawbacks, and perspectives for density functional theory and periodic abinitio calculations.

The x-ray restrained wave function (XRW) method is a quantum crystallographic technique to extract wave functions compatible with experimental x-ray diffraction data. The approach looks for wave functions that minimize the energies of the investigated systems and also reproduce sets of x-ray structure factors. Given the strict relationship between x-ray structure factors and electron distributions, the strategy practically allows determining wave functions that correspond to given (usually experimental) electron densities. In this work, the capabilities of the XRW approach were further tested. The aim was to evaluate whether the XRW technique could serve as a tool for suggesting new exchange-correlation functionals for density functional theory or refining existing ones. Additionally, the ability of the method to address the influences of the crystalline environment was also assessed. The outcomes of XRW computations were thus compared to those of traditional gas-phase, embedding quantum mechanics/molecular mechanics, and fully periodic calculations. The results revealed that, irrespective of the initial conditions, the XRW computations practically yield a consensus electron density, in contrast to the currently employed density functional approximations (DFAs), which tend to give a too large range of electron distributions. This is encouraging in view of exploiting the XRW technique to develop improved functionals. Conversely, the calculations also emphasized that the XRW method is limited in its ability to effectively address the influences of the crystalline environment. This underscores the need for a periodic XRW technique, which would allow further untangling the shortcomings of DFAs from those inherent to the XRW approach.

Direct Observation of Magnetic Reconnection Resulting From Interaction Between Magnetic Flux Rope and Magnetic Hole in the Earth's Magnetosheath

AbstractWe report in situ observation of magnetic reconnection between magnetic flux rope (MFR) and magnetic hole (MH) in the magnetosheath by the Magnetospheric Multiscale mission. The MFR was rooted in the magnetopause and could be generated by magnetopause reconnection therein. A thin current sheet was generated due to the interaction between MFR and MH. The sub‐Alfvénic ion bulk flow and the Hall field were detected inside this thin current sheet, indicating an ongoing reconnection. An elongated electron diffusion region characterized by non‐frozen‐in electrons, magnetic‐to‐particle energy conversion, and crescent‐shaped electron distribution was detected in the reconnection exhaust. The observation provides a mechanism for the dissipation of MFRs and thus opens a new perspective on the evolution of MFRs at the magnetopause. Our work also reveals one potential fate of the MHs in the magnetosheath which could reconnect with the MFRs and further merge into the magnetopause.

Simulation of electrical rectification effect in two-dimensional MoSe2/WSe2 lateral heterostructures

Two-dimensional (2D) transition metal dichalcogenides lateral heterostructures exhibit excellent performance in electrics and optics. The electron transport of the heterostructures can be effectively regulated by ingenious design. In this study, we construct a monolayer MoSe2/WSe2 lateral heterostructure, covalently connecting monolayer MoSe2 and monolayer WSe2. Using the Extended Huckel Theory method, we explored current-voltage characteristics under varied conditions, including altering carrier density, atomic replacement and interface angles. Calculations demonstrate a significant electrical rectification ratio (ERR) ranging from 200 to 800. Additionally, Employing Density Functional Theory with non-equilibrium Green’s function method, we investigated electronic properties, attributing the rectification effect to electronic state distribution differences, asymmetric transmission coefficients and band bending of projected local density of states. The expandability of the interfacial energy barrier enhances the rectification effect through adjustments in carrier concentration, atomic replacements and interface size. However, these enhancements introduce challenges such as increased electron-boundary scattering and reduced ambipolarity, resulting in a lower ERR. This study provides valuable theoretical insights for optimizing 2D electronic diode devices, offering avenues for precise control of the rectification effect.

Enhanced humidity sensing performance of a triple-electrode ionization sensor utilizing carbon nanotubes

This paper introduces a novel ionization humidity sensor featuring a carbon nanotube triple-electrode design, aimed at achieving sensitivities of 381.67 %RH−1 in nitrogen and 11.83 %RH−1 in air, a detection ranges from 25.8 % RH to 100 % RH in nitrogen and 30 % RH to 100 % RH in air, and response times of 11 s and recovery times of 5 s. The sensor leverages the exponential relationship between collecting current and relative humidity, enhanced by the exceptional adsorption properties of CNTs, particularly their large surface area which allows for efficient water molecule attraction, to offer superior performance across diverse detection environments. Two structural configurations are proposed to optimize the sensor’s efficiency: one integrating carbon nanotubes directly onto the cathode and another utilizing a silicon strip as a substrate for CNT growth. The design’s effectiveness is further validated through simulations that calculate electron distribution, positive ion concentration, and collected current, highlighting the sensor’s potential for high-precision humidity detection in real-world applications.

Current developments and trends in quantum crystallography.

Quantum crystallography is an emerging research field of science that has its origin in the early days of quantum physics and modern crystallography when it was almost immediately envisaged that X-ray radiation could be somehow exploited to determine the electron distribution of atoms and molecules. Today it can be seen as a composite research area at the intersection of crystallography, quantum chemistry, solid-state physics, applied mathematics and computer science, with the goal of investigating quantum problems, phenomena and features of the crystalline state. In this article, the state-of-the-art of quantum crystallography will be described by presenting developments and applications of novel techniques that have been introduced in the last 15 years. The focus will be on advances in the framework of multipole model strategies, wavefunction-/density matrix-based approaches and quantum chemical topological techniques. Finally, possible future improvements and expansions in the field will be discussed, also considering new emerging experimental and computational technologies.

How Depletion Layers Govern the Dynamic Plasmonic Response of In-Doped CdO Nanocrystals.

Doped metal oxide nanocrystals exhibit a localized surface plasmon resonance that is widely tunable across the mid- to near-infrared region, making them useful for applications in optoelectronics, sensing, and photocatalysis. Surface states pin the Fermi level and induce a surface depletion layer that hinders conductivity and refractive index sensing but can be advantageous for optical modulation. Several strategies have been developed to both synthetically and postsynthetically tailor the depletion layer toward particular applications; however, this understanding has primarily been advanced in Sn-doped In2O3 (ITO) nanocrystals, leaving open questions about generalizing to other doped metal oxides. Here, we quantitatively analyze the depletion layer in In-doped CdO (ICO) nanocrystals, which is shown to have an intrinsically wide depletion layer that leads to broad plasmonic modulation via postsynthetic chemical reduction and ligand exchange. Leveraging these insights, we applied depletion layer tuning to enhance the inherently weak plasmonic coupling in ICO nanocrystal superlattices. Our results demonstrate how an electronic band structure dictates the radial distribution of electrons and governs the response to postsynthetic modulation, enabling the design of tunable and responsive plasmonic materials.

Fine-tuning photophysical properties in pyrene derivatives: Unravelling the impact of substitution patterns with incorporation of a strong electron-donating group

To investigate the impact of substitution patterns on the photophysical properties of pyrene derivatives, six novel pyrene derivatives A1-A6 were synthesised by directly coupling anthracene with pyrene units. The objective was to explore the influence of strong electron-donating groups and substitution patterns on their photophysical behaviour. Experimental and theoretical studies were conducted to analyse the photophysical properties of these compounds, revealing a clear dependence on the position of substitution within the pyrene core. Analysis of molecular orbitals revealed significant contributions from both pyrene and anthracene moieties, with deviations from typical electronic distributions attributed to the presence of electron-donating groups. The energy gap values remained consistent across derivatives, contrary to previous findings involving acceptor motif substitutions. Structural analyses indicated deviations from planarity with significant changes in angles upon excitation. The emission spectra of mono- and disubstituted pyrene derivatives predominantly exhibited a single broad maximum with slight shoulders in each solvent. However, the emission spectra of the tetrasubstituted compound (A6) displayed a vibrational structure with three maxima in all solvents, reminiscent of pyrene itself but red-shifted by approximately 30 nm. Furthermore, the central maximum for compound A6 was around 20 nm blue-shifted compared to the other compounds, although its shoulder at around 440 nm corresponded to a maximum observed in other pyrene derivatives. Typically, 1,3,6,8-tetrasubstituted pyrene derivatives, compared to their disubstituted analogues, exhibited red-shifted emission maxima associated with increased π-conjugation due to additional units on the pyrene core. A comprehensive analysis was performed on the absorption and emission spectra of the pyrene derivatives in solvents of various polarities and in the solid state. The fluorescence intensity was influenced by solvent polarity, with A6 showing limited sensitivity (similar quantum efficiency of approximately 45 % in all solvents). Moreover, the quantum yield decreases with the increasing number of anthracene substituents, being the lowest for tetrasubstituted A6. Bi-exponential decay and shorter lifetimes were observed for A1-A6 compared to known compounds, with quantum yields decreasing as solvent polarity increased. In the solid state, emission peaks shifted towards longer wavelengths, with A1 exhibiting the highest quantum yield attributed to steric hindrance. At low temperatures (77 K), emission spectra displayed redshifts, and longer lifetimes were observed. Spectrometric tests in THF/water mixtures indicated luminescence quenching at higher water fractions.

Numerical Study on the Optical Properties of III-V Quaternary Compounds Aluminium Gallium Indium Phosphide Light Emitting Diode

The research works the quaternary compounds of AlGaInP (Aluminium Gallium Indium Phosphide) LEDs that provide luminescence intensity in high-brightness LEDs. AlGaInP LEDs, which are direct bandgap semiconductors with green color emission and a wavelength ranging from 500 to 565 nm, are important in electronics display and liquid crystal backlight applications. Depend on carrier concentration, the desired colors and luminescence intensity, the mole fraction of the quaternary compound is changed and also the bandgap energy. The paper contributions the carrier distribution of holes and electrons, the density of states, and the fermi-dirac distribution function calculated. Based on the carrier concentration, luminescence intensity versus photon energy has been determined. These simulation results are presented using MATLAB simulation with theoretical approach.

Repairable body-centered cubic Fe0 anchoring on porous hollow nitrogen-doped carbon spheres with adjusting electron distribution for efficient electrocatalytic ammonia synthesis

Electrocatalytic nitrogen reduction reaction (ENRR) is a promising and efficient method for ammonia production. However, ENRR is restricted by the adsorption and activation of N2. Herein, an efficient nitrogen reduction reaction (NRR) electrocatalyst loaded with zero valent iron (ZVI) particles onto porous nitrogen-doped carbon (NC) hollow spheres is reported. The optimal Fe@10N3C-950 exhibits excellent performance with high ammonia (NH3) yield (152.28 µg h−1 mgcat−1) and Faradaic efficiency (FE, 54.55 %) at − 0.3 V (versus reversible hydrogen electrode, vs. RHE). Bader charge shows that the adsorbed N2 acquires more electrons from Fe sites with body-centered cubic (BCC) structure to better activate N2. Moreover, i-t experiments are performed before electrocatalytic NH3 production to effectively eliminate the effect of oxidation on ZVI and thus, maintain high ENRR activity for Fe@10N3C-950. Theoretical calculations indicate that nitrogen doping not only reduces the Gibbs free energy of rate determining step (RDS), but the BCC-structured Fe can also decrease the energy barriers of N2 activation and RDS.

Novel organic dibranched photosensitizers featuring spiro-fluorene for efficient hydrogen generation from water

Four new metal-free organic photosensitizers featuring either a mono-anchoring donor–π–acceptor (D–π–A) or di-anchoring donor–(π–acceptor)2 (D(–π–A)2) architecture containing a spirobifluorene or spiro[fluorene-9,9′-xanthene] central donor core was prepared. These photosensitizers were subsequently tested for their efficiency in the photocatalytic production of H2, in combination with a Pt/TiO2 catalyst. Additionally, electrochemical, photophysical, and computational studies were conducted. The computational studies were specifically carried out to ascertain the electronic distribution within the photosensitizers. The influence of the molecular design on the efficiency of H2 production was examined. The di-anchoring photosensitizers notably amplified the spectral response in the visible light region, reduce aggregation on TiO2 and enhanced charge transfer. Among the fabricated photocatalytic systems, the di-anchoring photosensitizers exhibited superior photocatalytic efficiency compared to their mono-anchoring counterparts. Among all the photosensitizers, the spiro[fluorene-9,9′-xanthene]-based di-anchoring photosensitizer X2 possessing photocatalytic system demonstrated remarkable performance, producing 406.3 μmol (10.07 mL) of hydrogen over a period of 47 h under blue light irradiation. This performance corresponds to a turnover number (TON) of 6674, a turnover frequency (TOFi) of 445 h−1, an initial hydrogen production activity (activityi) of 278140 and an apparent quantum yield (AQYi%) of 4.762. The bulky spiro[fluorene-9,9′-xanthene] component endowed the photosensitizers with photostability, as confirmed by their high hydrogen production efficiency over 152 h of extended irradiation, yielding 12.69 mL of hydrogen. This study revealed, for the first time, that the bulky spiro-fluorene structure contributes positive synergistic effects to hydrogen production. It demonstrates that dibranched photosensitizers containing spiro-fluorene are promising candidates for achieving high and stable hydrogen production activity.