Electron Beam Powder Bed Fusion Research Articles

Characterization of copper & stainless steel interface produced by electron beam powder bed fusion

Unalloyed copper (Cu) powder was deposited and melted onto a pre-existing stainless steel substrate using electron beam powder bed fusion (EB-PBF) additive manufacturing (AM) to form dense, bimetallic structures. The AM fabricated Cu was fully dense, and with strength properties consistent with recent reports on EB-PBF of Cu. The overall bimetallic structures exhibited total elongation of 25–35%, and was dominated by plastic deformation in the Cu region. Tensile failures were typically observed in the Cu portion of the bimetallic bodies demonstrating that the interface was not the source of mechanical failure. The interface region of the bimetallics contained areas of liquid phase separated Cu and Iron (Fe) + Chromium (Cr) rich regions resulting from a metastable miscibility gap in the Cu and Fe phase diagram. Metallurgical and mechanical examinations of the bimetallic structures showed the interface region transitions from an Fe rich mixture to a Cu rich mixture within a few AM layers.

Cyclic Crack Growth in Chemically Tailored Isotropic Austenitic Steel Processed by Electron Beam Powder Bed Fusion.

The present study analyzes the cyclic crack propagation behavior in an austenitic steel processed by electron beam powder bed fusion (PBF-EB). The threshold value of crack growth as well as the crack growth behavior in the Paris regime were studied. In contrast to other austenitic steels, the building direction during PBF-EB did not affect the crack propagation rate, i.e., the crack growth rates perpendicular and parallel to the building direction were similar due to the isotropic microstructure characterized by equiaxed grains. Furthermore, the influence of significantly different building parameters was studied and, thereby, different energy inputs causing locally varying manganese content. Crack growth behavior was not affected by these changes. Even a compositional gradation within the same specimen, i.e., crack growth through an interface of areas with high and areas with low manganese content, did not lead to a significant change of the crack growth rate. Thus, the steel studied is characterized by a quite robust cyclic crack growth behavior independent from building direction and hardly affected by typical parameter deviations in the PBF-EB process.

Surface residual stress and phase stability in unstable β-type Ti–15Mo–5Zr–3Al alloy manufactured by laser and electron beam powder bed fusion technologies

The differences between the physicochemical properties of the laser and electron beam powder bed fusion (L- and EB-PBF) methods are yet to be explored further. In particular, the differences in the residual stress and phase stability of alloys with unstable phases remain unexplored. The present work is the first to systematically investigate how the heat source type and process parameters affect the surface residual stress and phase stability of an unstable β-type titanium alloy, Ti–15Mo–5Zr–3Al. The surface residual stress and β-phase behavior were studied using high-precision X-ray diffraction (HP-XRD). Significant differences were observed between the two methods. The L-PBF-made specimens exhibited tensile residual stresses of up to 400 MPa in the surface area. HP-XRD analysis revealed a stress-induced lattice distortion, interpreted as a transitional state between the β-phase and α”-phase. In contrast, the EB-PBF-made specimens showed no significant residual stress and had an undistorted β-phase coexisting with the hexagonal α-phase caused by elemental partitioning. This study provides new insights into the previously neglected effects of L-PBF and EB-PBF in unstable β-type titanium alloys.

Influence of geometry on columnar to equiaxed transition during electron beam powder bed fusion of IN718

Correlation between spot-melt scan parameters (linear spot-density aka areal energy density), build geometry, and solidification microstructure evolution (columnar vs equiaxed) in a powder bed fusion technology is investigated. It is shown that to maintain the equiaxed solidification microstructure evolution in electron beam powder bed additive manufacturing (AM), the areal energy density per layer needs to be scaled with respect to the 2D cross-sectional area of the layer being melted. Samples with two different cross-sectional areas (40 × 40 mm and 20 × 20 mm) have been fabricated with varying areal energy densities. For a given square cross-section (20 × 20 mm), increasing the areal energy density (4.8 MJ/sq.m to 14.7 MJ/sq.m) transitioned the solidification microstructure from columnar to equiaxed. The observed microstructure data (Electron Back Scattered Diffraction - EBSD) is quantified by calculating the principal component (PC) score using a spatial statistics methodology. The sample with equiaxed grains is found to have a low PC score while the sample with columnar grain had a high PC score. A semi-analytical model is used to simulate the heat transfer and the local solidification conditions as a function of processing parameters (linear spot-density). The result from the heat transfer model is correlated with previously quantified microstructure data. Space-Time analysis of the melt pattern is done and correlated with the observed microstructure. In addition, from the findings, appropriate parameters have been used to additively manufacture a turbine blade with site-specific or hybrid solidification microstructure (traditional fabrication possible via a patented method of localized cold working and heat treatment).

Multi-physics modeling of side roughness generation mechanisms in powder bed fusion

Surface roughness is a serious concern in powder bed fusion (PBF) additive manufacturing, especially for aerospace and biomedical applications. An adequate surface quality of as-built components is desired due to difficulty in post-processing of interior sides and intricate geometries of printings. The side surface draws more attention than the top surface and a comprehensive understanding of side roughness mechanisms is required to interpret effectively. However, observation of side roughness formation in experiments is yet difficult. In this paper, the formation process of the side surfaces in electron beam PBF is analyzed by a 3-D mesoscale multi-physics simulation, so as to provide an insight view into side roughness mechanisms from the viewpoint of heat and mass transfer. The melting process and the resulting side surface morphologies of thin-walled parts are exclusively analyzed. It turns out that the melted traces in cases with a relatively low heat input generally have greater fluctuations than in cases with a high heat input, which leads to a higher side roughness. The proposed investigation reveals that the melt pool flow driven by surface tension is the main cause of track shape fluctuation. This fluctuation is driven by the random distribution of powder particles and the Plateau–Rayleigh instability, which describes the disintegration into a chain of drops. An analytical estimation of minimum limit of side roughness in as-built parts and the mechanisms for the generation of the side roughness are depicted systematically, based on which some improvement measures are proposed finally. This will help improve surface quality in metal additive manufacturing.

Comparison of microstructure, crystallographic texture, and mechanical properties in Ti–15Mo–5Zr–3Al alloys fabricated via electron and laser beam powder bed fusion technologies

Depending on the application, establishing a strategy for selecting the type of powder bed fusion technology—from electron beam (EB-PBF) or laser powder bed fusion (L-PBF)—is important. In this study, we focused on the β-type Ti–15Mo–5Zr–3Al alloy (expected for hard-tissue implant applications) as a model material, and we examined the variations in the microstructure, crystallographic texture, and resultant mechanical properties of specimens fabricated by L-PBF and EB-PBF. Because the melting mode transforms from the conduction mode to the keyhole mode with an increase in the energy density in L-PBF, the relative density of the L-PBF-built specimen decreases at higher energy densities, unlike that of the EB-PBF-built specimen. Although both EB-PBF and L-PBF can obtain cubic crystallographic textures via bidirectional scanning with a 90° rotation in each layer, the formation mechanisms of the textures were found to be different. The <100> texture in the build direction is mainly derived from the vertically grown columnar cells in EB-PBF, whereas it is derived from the vertically and horizontally grown columnar cells in L-PBF. Consequently, different textures were developed via bidirectional scanning without rotation in each layer: the <110> and <100> aligned textures along the build direction in L-PBF and EB-PBF, respectively. The L-PBF-built specimen exhibited considerably better ductility, but slightly lower strength than the EB-PBF-built specimen, under the conditions of the same crystallographic texture and relative density. We attributed this to the variation in the microstructures of the specimens; the formation of the α-phase was completely absent in the L-PBF-built specimen. The results demonstrate the importance of properly selecting the two technologies according to the material and its application.

Microstructure and mechanical properties of hierarchical porous parts of Ti-6Al-4V alloy obtained by powder bed fusion techniques

PurposeThis paper aims to describe the obtainment of Ti-6Al-4V parts with a hierarchical arrangement of pores by additive manufacturing, aiming at designing orthopedic implants.Design/methodology/approachThe experimental methodology compares microstructural and mechanical properties of Menger pre-fractal sponges of Ti-6Al-4V alloy, manufactured by laser powder bed fusion (LPBF) and electron beam powder bed fusion (EBPBF), with three different porosity volumes. The pore arrangement followed the formation sequence of the Menger sponge, with hierarchical order from 1 to 3.FindingsThe LPBF parts presented a martensitic microstructure, while the EBPBF parts presented an α + ß microstructure, independently of its wall thickness. The LPBF parts presented higher mechanical resistance and effective stiffness than the EBPBF parts with similar porosity volume. The stiffness values of the Menger pre-fractal sponges of Ti-6Al-4V alloy, between 4 and 29 GPa, are comparable to those of the cortical bone. Furthermore, the deformation behavior presented by the Menger pre-fractal sponges of Ti-6Al-4V alloy did not follow the Gibson and Ashby model's prediction.Originality/valueTo the best of the authors' knowledge, this is the first study to obtain Menger pre-fractal sponges of Ti-6Al-4V alloy by LPBF and EBPBF. The deformation behavior of the obtained porous parts was contrasted with the Gibson and Ashby model's prediction.

High Wear Resistance and Mechanical Performance of NiAl Bronze Developed by Electron Beam Powder Bed Fusion

This work reports the additively manufactured NiAl bronze alloys via electron beam powder bed fusion (EB-PBF) that exhibit improved wear resistance without an increase of friction, exceeding those of conventional hot-rolled counterparts. High wear resistance is attributed to the formation of a Cu–O-rich transfer layer, and to exceptional mechanical strength induced by integrated effects including uniformly distributed precipitation, grain refinement, martensitic transformation around stacking faults, and a modulus mismatch between precipitates and the matrix. The simulation results indicate that the effect of the precipitate distribution on the internal stress field of the matrix is dependent on the external force direction. For the shear force, the uniformly distributed precipitates promote the overall stress concentration of the matrix, leading to its high work-hardening capability that plays a role in improving the wear resistance. This study reveals the potential of the EB-PBF technique to develop alloys with high wear resistance.

In Situ CT Tensile Testing of an Additively Manufactured and Heat-Treated Metastable ß-Titanium Alloy (Ti-5Al-5Mo-5V-3Cr)

Additive manufacturing has been considered a suitable process for developing high-performance parts of medical or aerospace industries. The electron beam powder bed fusion process, EB-PBF, is a powder bed fusion process carried out in a vacuum, in which the parts are melted using a highly focused electron beam. The material class of metastable β-titanium alloys, and especially Ti-5Al-5Mo-5V-3Cr, show great potential for use as small and highly complex load-bearing parts. Specimens were additively manufactured with optimised process parameters and different heat treatments used in order to create tailored mechanical properties. These heat-treated specimens were analysed with regard to their microstructure (SEM) and their mechanical strength (tensile testing). Furthermore, in situ tensile tests, using a Deben CT5000 and a YXLON ff35 industrial µ-CT, were performed and failure-critical defects were detected, analysed and monitored. Experimental results indicate that, if EB-PBF-manufactured Ti-5553 is heat-treated differently, a variety of mechanical properties are possible. Regarding their fracture mechanisms, failure-critical defects can be detected at different stages of the tensile test and defect growth behaviour can be analysed.

Electron-optical in-situ metrology for electron beam powder bed fusion: calibration and validation

A major advantage of metal additive manufacturing is the possibility for tool-free production of complex shaped parts. Currently, the geometrical and dimensional accuracy of these parts can only be reliably controlled by time and cost intensive post-process inspection, e.g. using x-ray computed tomography (XCT). The current investigation demonstrates the first in-situ metrology technique for electron beam powder bed fusion (PBF-EB) using electron-optical imaging (ELO). After a calibration experiment, the approach was validated for a PBF-EB build job by comparing in-situ ELO imaging data to XCT data of an as-built part. The quantitative comparison showed a remarkable high agreement between both imaging techniques. It is demonstrated that ELO imaging is capable of making accurate predictions on the geometrical and dimensional accuracy of the as-build part. This result is the basis of new possibilities for in-situ process and quality control in PBF-EB.

Property Improvement of Additively Manufactured Ti64 by Heat Treatment Characterized by In Situ High Temperature EBSD and Neutron Diffraction

Among various off-equilibrium microstructures of additively manufactured Ti-6Al-4V alloy, electron beam powder bed fusion, in which three dimensional metallic objects are fabricated by melting the ingredient powder materials layer by layer on a pre-heated bed, results in a specimen that is nearly free of the preferred orientation of the α-Ti phase as well as a low beta phase fraction of ∼1 wt%. However, when further heat treatment of up to 1050 ∘C was applied to the material in our previous study, a strong texture aligning the hexagonal basal plane of α phase with the build direction and about 6% β phase appeared at room temperature. In this study, to understand the mechanism of this heat treatment, the grain level microstructure of the additively manufactured Ti-6Al-4V was investigated using in situ high temperature EBSD up to 1000 ∘C, which allows the tracking of individual grains during a heat cycle. As a result, we found a random texture originating from the fine grains in the initial material and observed a significant suppression of α phase nucleation in the slow cooling after heating to 950 ∘C within the α and β dual phase regime but close to the the β-transus temperature at ∼980 ∘C, which led to a coarse microstructure. Furthermore, the texture resulting from phase transformation of the additively manufactured Ti-6Al-4V assuming nucleation at the grain boundaries was modeled, using the double Burgers orientation relationship for the first time. The model successfully reproduced the measured texture, suggesting that the texture enhancement of the α phase by the additional heat treatment derives also from the variant selection during the phase transformation and nucleation on grain boundaries.

Manufacturing of Tool Steels by PBF-EB

Additive manufacturing (AM) of metals is stimulating the tool making industry. Moreover, besides the production of lost forms, AM processes are now being used to directly generate tools, molds or parts, leading to massive time savings. In the case of material development for AM, the challenge is to operate with carbon-containing iron-based materials distinguished by high strength and hardness, as well as high corrosion resistance and thermal conductivity. Often, those materials are susceptible to crack formation during processing. Using Electron Beam Powder Bed Fusion (PBF-EB), the challenge of crack formation can be overcome by using high process temperatures in the range 800–900 °C. In this paper, results on the processing of a cold-working tool steel (X65MoCrWV3-2) and a hot-working steel (X37CrMoV5-1) will be presented. These include the processing window, processing strategies to minimize the density of cracks and properties with respect to microstructure and hardness.

Position-dependent mechanical characterization of the PBF-EB-manufactured Ti6Al4V alloy

By means of additive manufacturing, the production of components with nearly unlimited geometrical design complexity is feasible. Especially, powder bed fusion techniques such as electron beam powder bed fusion (PBF-EB) are currently focused. However, equal material properties are mandatory to be able to transfer this technique to a wide scope of industrial applications. Within the scope of this work, the mechanical properties of the PBF-EB-manufactured Ti6Al4V alloy are investigated as a function of the position on the building platform. It can be stated that as-built surface roughness changes within building platform whereby highest surface roughness detected by computed tomography (Ra = 46.0 ± 5.3 µm) was found for specimens located in the front of the building platform. In contrast, no significant differences in relative density could be determined and specimens can be assumed as nearly fully dense (> 99.9%). Furthermore, all specimens are affected by an undersized effective diameter compared to the CAD data. Fatigue tests revealed that specimens in the front of the building platform show slightly lower performance at higher stress amplitudes as compared to specimens in the back of the building platform. However, process-induced notch-like defects based on the surface roughness were found to be the preferred location for early crack initiation.

The role of microstructural characteristics of additively manufactured Alloy 718 on tool wear in machining

This study aims to provide a fundamental understanding of the role of microstructural characteristics influencing tool wear when machining Alloy 718 fabricated using Powder Bed Fusion (PBF). The effects of preferred crystallographic orientation (texture), shape and distribution of grains, local misorientation, type and amount of precipitates as well as the type, size and amount of abrasive carbides, nitrides and oxides on tool wear are investigated in as-built condition and after the standard solutionising and double-aging treatment. The microstructures of workpiece materials and the surfaces of worn tools were examined using different material characterisation techniques, including Scanning Electron Microscopy (SEM), energy-dispersive X-ray spectroscopy (EDS) and electron backscatter diffraction (EBSD). A dislocation-based approach was used to reveal the cumulative effects of the microstructural characteristics on deformation behaviour and the thermo-mechanical loads on the tools during cutting. The analyses suggest that texture and the extent of material work-hardening prior to the onset of crack formation markedly influence the amount of plastic work and thus heat generation when machining Electron Beam Powder Bed Fusion (EB-PBF) material. The higher heat generation in the cutting zones provokes thermally-induced wear mechanisms like diffusion-dissolution and oxidation. In addition, the larger amount of hard oxide inclusions present in EB-PBF material leads to higher wear by abrasion. In contrast to the prevailing experimental approaches in this field, the present investigation is built on a physics-based framework to understand the fundamental aspects that govern material deformation and heat generation in cutting and, consequently, tool wear mechanisms. This framework can be used for machinability assessment of any alloy manufactured by different additive manufacturing (AM) technologies and for optimising the process-chain, including printing strategies and thermal post-treatments, to improve the machinability of AM alloys by tailoring their microstructure.

Microstructure-property gradients in Ni-based superalloy (Inconel 738) additively manufactured via electron beam powder bed fusion

Electron beam powder bed fusion (E-PBF) can produce nickel-based superalloy components with minimal cracking and post-processing. This is due to the reduced thermal gradients and high print temperatures accessible through innovative beam scanning strategies compared to other AM processes. However, variations in thermal signature along the build direction inherent in alloys printed using E-PBF can drive significant changes in the microstructure and associated mechanical properties. In this work, through complementary local property measurements we observed a 127 – 145% increase in mean elastic modulus and 7–9% increase in mean hardness, as a function of build height, of an as-fabricated non-weldable Ni-based superalloy, Inconel 738. These properties were attributed primarily to variations in the γ′ character with build height, revealed through a multi-scale microstructural characterisation. The results highlight the influence of the thermal signatures on the microstructural-property relationships of E-PBF Inconel 738.

Columnar-to-equiaxed grain transition in powder bed fusion via mimicking casting solidification and promoting in situ recrystallization

Columnar grain structure typically formed along the build direction in the electron beam-powder bed fusion (EB-PBF) technique leads to anisotropic physical and mechanical properties. In this study, casting solidification condition was mimicked, and in situ recrystallization was promoted in EB-PBF to facilitate columnar-to-equiaxed grain structure transition in Alloy 718. This is achieved via a unique linear melting strategy coupled with a specific selection of process parameters in EB-PBF. It was found that site-specific melting using line order number (LON) function affected the cooling rate and temperature gradient, which controlled grain morphology and texture. A high LON resulted in a large equiaxed grain zone with a random texture, whereas a fixed LON with a high areal energy density led to a strong texture. The main driving force in the formation of cracks and shrinkage defects during the transition was investigated. A high LON at a fixed areal energy density reduced the average total shrinkage defects and crack length. The hardness was decreased through the transition, which was linked to the reduction in the size of the γ″ precipitates.

In-situ electron optical measurement of thermal expansion in electron beam powder bed fusion

Thermal expansion plays an important role during additive manufacturing by electron beam powder bed fusion because it strongly affects the quality of the manufactured parts. However, prediction and control of thermal expansion is a difficult task due to the high complexity of part geometries and the corresponding temperature distribution. Therefore, powerful process monitoring tools are required to improve insight into the process. In the current study, the capabilities of in-situ acquisition of electron optical images are assessed with respect to measurement of thermal expansion. For this purpose, a large series of electron-optical images was recorded during cooling down of a PBF-EB build job. The subsequent image analysis revealed that the image quality is high enough to monitor thermal shrinkage of the part and to quantify thermal strain with remarkable accuracy. These findings are very promising and give rise to new applications of in-situ electron-optical observation with regard to temperature management and validation of numerical frameworks. • Electron-optical imaging enables in-situ observation of thermal expansion. • Strain and coefficient of thermal expansion are derived with high accuracy. • Expansion is used to estimate temperature where thermocouple measurement failed.

A stochastic scan strategy for grain structure control in complex geometries using electron beam powder bed fusion

Spatial control of microstructure within a three-dimensional component has been a dream of materials scientists for centuries. However, limitations in traditional manufacturing processes prevent detailed control over the distribution of microstructures in a single part. Here, we demonstrate the ability to control grain structure and crystallographic texture during metal additive manufacturing for arbitrary cross-sections of a practical size, with profound implications for the design and optimization of next-generation products. The key to this advance is a new geometry agnostic scan path algorithm that manipulates the spatial distribution of solidification conditions. Utilizing a fundamental understanding of solidification dynamics and a model of the heat transfer during processing, we have designed this algorithm to manipulate the natural competition between epitaxial dendrite growth and grain nucleation. With this algorithm, we successfully controlled the grain structure of Ni-based superalloy IN718 in the shape of the Mona Lisa.

The effects of powder reuse on the mechanical response of electron beam additively manufactured Ti6Al4V parts

High cost of metal powders has increased the demand for recycling of unmelted powder in electron beam powder bed fusion additive manufacturing process. However, powder characteristics are likely to change during manufacturing, recovery and reuse. It is important to track the evolution of powder characteristics at different stages of recycling to produce components with consistent properties. The present work evaluates the changes in Ti6Al4V powder properties during manufacturing by characterising powder particles at different locations in the powder bed; recovery and reuse, through evaluating the effects of the powder recovery system and sieving for 10 build cycles. Heterogeneous powder degradation occurred during manufacturing with the particles closer to the melt zone showing higher oxygen content and thicker α laths with β phase boundaries. Most of them had a hard-sintered and agglomerated powder morphology in contrast to particles at the edges of the powder bed. Recovery and reuse resulted in a refined particle size distribution, but only marginal change in powder morphology. The increased oxygen caused a slight increase in the yield and tensile strengths of the build. The effect of powder reuse on material elongation, hardness and Charpy impact energy was negligible. The high cycle fatigue performance deteriorated with reuse due to the increased lack-of-fusion defects. This might be attributed to the voids formed in the powder bed due to decrease in the number of fine particles coupled with an increase in the number of high-aspect ratio particles.

Solidification texture, variant selection, and phase fraction in a spot-melt electron-beam powder bed fusion processed Ti-6Al-4V

The effect of a spot melt strategy on the solidification texture, variant selection, phase fraction, and their variations along the build height was investigated in comparison to a conventional linear melt strategy. Ti-6Al-4V alloy samples were manufactured by an electron-beam powder bed fusion process using two different melt strategies and characterized using high-energy synchrotron x-ray diffraction. The linear and spot melt cases resulted in β<100> cube and fiber textures, respectively, with the cube/fiber axis nearly parallel to the build direction. The α phase exhibited Burgers orientation relationship (BOR) with the parent β phase for both melt strategies. Although all of the key texture components and the BOR between the α and β phases were consistently observed in both cases along the build height, there were several measurable differences between the two. At the top of the build height, the β<100> build texture intensity was stronger in the linear case. However, the texture intensity in the linear case decreased gradually from the top to near the substrate, whereas the spot melt case did not show this trend. Moreover, the BOR was examined along the build height and the results showed that there is a distinct variant selection in the spot melt case, unlike the linear case. Specifically, the planar variants sharing ( 1 ̅ 01 ) β || ( 0002 ) α with [ 2 ̅ 2 ̅ 2 ̅ ] β and [ 2 2 ̅ 2 ] β were the most prominent in the spot melt, but no preference was identified in the directional variants. The β phase fraction was slightly lower in the spot melt case compared to the linear case. In both the cases, the β phase fraction decreased moving towards the substrate but remained significantly higher than that of the powder feedstock. Overall, the novel spot melt strategy produced a more homogeneous microstructure in terms of both the phase fraction and texture across the build height.