Electrolytic Treatment Research Articles

Correction: Muñoz-Fernández et al. A new ultrasound-guided percutaneous electrolysis and exercise treatment in patellar tendinopathy: three case reports. Frontiers in Bioscience-Landmark. 2021; 26: 1166-1175.

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Galvanic corrosion protection of Al-alloy in contact with carbon fibre reinforced polymer through plasma electrolytic oxidation treatment

Al-alloy/carbon fibre reinforced polymer (CFRP) joint systems offer exceptionally lightweight, superior fatigue behaviour and impact resistance for aerospace applications. Nevertheless, the galvanic corrosion at the joint interfaces accelerates the adhesive failure and strength damage. In this work, oxidation of Al 7075 alloy was studied by employing plasma electrolytic oxidation (PEO) and thin film sulphuric acid anodizing (TFSAA) methods, addressing their galvanic corrosion (GC) protection performance in contact with CFRP. Structural and electrochemical characterisations were carried out in tandem with varied oxidation process parameters, revealing that high voltage PEO resulted in crystallized compact ceramic coating and thus improved GC protection. A decrease in the GC current by ~ 90% has been achieved by using the PEO coating at 700 V compared with the ~ 12% current reduction of commercial TFSAA coating. Further microstructure studies revealed that the improved GC protection of the crystallized PEO coating was realized by suppressing the initiation and propagation of localized pitting due to the improved electrical isolation between the Al-alloy/CFRP interfaces. A high voltage PEO process provides sufficient energy to produce uniform and crystalline ceramic coating consisting of Al2O3 and mullite, which give rise to improved corrosion protection.

Electrolysis catalyzed ozonation for advanced wastewater treatment

The prohibitive cost of advanced oxidation processes (AOPs) necessitates the development of innovative variations to increase their applicability. This investigation evaluated the combination of ozonation and electrolysis using iron electrodes as a catalytic ozonation AOP for the mineralization of organic compounds in water. The operating parameters of initial pH and current density were optimized using response surface methodology (RSM) to maximize total organic carbon (TOC) removal from a dextrose based synthetic wastewater. The process was most effective for TOC removal in alkaline conditions (initial pH of 9), although performance compared to ozonation alone was more significantly enhanced in acidic conditions (initial pH of 3). TOC removal was found to increase as current density increased from 4 to 12 mA/cm2, regardless of initial pH, primarily due to the increased rate of catalyst addition from the sacrificial anode. It was determined that the initial pH of the system presented a more statistically significant effect on TOC removal than current density, although both parameters were determined to be relevant. Under optimal conditions of 12 mA/cm2 and an initial pH of 9, 63% TOC removal was achieved after 60 min of treatment. Catalyst dosage using electrochemical and chemical approaches was compared, finding that electrochemical catalyst dosage was preferred for TOC removal, illustrated by the pseudo-first order rate constant of observed TOC removal, which was 51–76% higher using the electrochemical approach. Using an indirect measurement method involving tert-Butyl alcohol, hydroxyl radicals were detected during the combined ozonation and electrolysis treatment. Radical production was found to be linked to the conditions which favoured TOC removal. The results of this study have demonstrated the ability of an electrochemical catalytic ozonation process to enhance the removal of organic contaminants in wastewater compared to ozonation alone, established the advantages of harnessing an electrochemically generated catalyst, and characterized the effect of key operating parameters on TOC removal performance and hydroxyl radical production.

Enhanced Plasticity and Corrosion Resistance in Mg-Zn-Ca-Cu Amorphous Alloy Composite via Plasma Electrolytic Oxidation Treatment

In this study, a dendrite-reinforced Mg-based amorphous alloy composite was prepared through an in situ precipitation strategy. After plasma electrolytic oxidation (PEO) treatment, the Mg85.1Zn12.7Ca2Cu0.2 amorphous alloy composite exhibited enhanced plasticity and corrosion resistance in a simulated body fluid solution (SBF). The PEO-treated composite showed a significant plastic strain of 10.5 ± 1.1%, as well as outstanding strain-hardening behavior. The enhancement of plasticity may be attributed to the in-situ formed coating, which can not only serve as a propagation barrier for shear bands but can also introduce nucleation sites in the bands as a result of stress mismatch and compositional heterogeneity. The corrosion density in the SBF decreased by three orders compared with the composite substrate. The spontaneous formation of apatite on the porous layer demonstrated that the prepared PEO coating has high bioactivity. The current work may provide a fundamental basis for developing biomedical Mg-based alloys with excellent comprehensive mechanical properties and corrosion resistance.

Amorphous coatings on tantalum formed by plasma electrolytic oxidation in aluminate electrolyte and high temperature crystallization treatment

In this paper, amorphous coatings on tantalum obtained by plasma electrolytic oxidation (PEO) in alkaline sodium aluminate electrolyte (2–10 g/l NaAlO2 + 2 g/l KOH) are investigated. It was found that the amorphous component of the oxide coatings increased with NaAlO2 concentration in the electrolyte. The coatings obtained in the electrolyte of 10 g/l NaAlO2 + 2 g/l KOH are completely amorphous. Subsequently, the amorphous coatings were subjected to vacuum heat treatment at 600, 800, 900 and 1300 °C to study their crystallization behavior. The results show that crystallization does not occur at 600 °C. However, crystallization occurred partially at 800 °C and completed at 1300 °C, with orthorhombic AlTaO4 as the main phase structure. Nanoindentation tests show that hardness of the coating at dense regions increases after crystallization, but defects and cracks in the coating are also increased after heat treatment. The amorphous coatings have excellent corrosion resistance, but the defects generated in the crystallized coatings are detrimental to the corrosion performance. The reason for the formation of amorphous coatings may be derived from rapid cooling and the glass-forming ability of the binary system of Ta2O5 and Al2O3.

Comparison of Nature and Synthetic Zeolite for Waste Battery Electrolyte Treatment in Fixed-Bed Adsorption Column

To support a sustainable energy development, CO2 reduction for carbon neutralization and water-splitting for hydrogen economy are two feasible technical routes, both of which require a significant input of renewable energies. To efficiently store renewable energies, secondary batteries will be applied in great quantity, so that a considerable amount of energy needs to be invested to eliminate the waste battery electrolyte pollution caused by heavy metals including Cu2+, Zn2+ and Pb2+. To reduce this energy consumption, the removal behaviors of these ions by using clinoptilolite and zeolite A under 5, 7 and 10 BV h−1 in a fixed-bed reactor were investigated. The used zeolites were then regenerated by a novel NH4Cl solution soaking, coupled with the ultrasonication method. Further characterizations were carried out using scanning electron microscopy, N2 adsorption and desorption test, and wide-angle X-ray diffraction. The adsorption breakthrough curves revealed that the leaching preference of clinoptilolite was Pb2+ > Cu2+ > Zn2+, while the removal sequence for zeolite A was Zn2+ > Cu2+ > Pb2+. The maximum removal percentage of Zn2+ ions for clinoptilolite under 5 BV h−1 was 21.55%, while it was 83.45% for zeolite A. The leaching ability difference was also discussed combining with the characterization results. The fact that unit cell stayed the same before and after the regeneration treatment approved the efficacy of the regeneration method, which detached most of the ions while doing little change to both morphology and crystallinity of the zeolites. By evaluating the pH and conductivity changes, the leaching mechanisms by adsorption and ion exchange were further studied.

Simultaneous electrochemical removal of Microcystis aeruginosa and sulfamethoxazole and its ecologic impacts on Vallisneria spiralis

In this study, the simultaneous removal effects of electrochemical oxidation with boron-doped diamond anodes at different current densities were tested on Microcystis aeruginosa and sulfamethoxazole. Flow cytometry and non-invasive micro-test technology were applied to study the physiological states of M. aeruginosa and Vallisneria spiralis leaf cells. As the current density increased, the degradation effect of electrochemical oxidation on sulfamethoxazole and microcystin-LR increased and exceeded 60% within 6 h. In addition, population density of M. aeruginosa, fluorescence response of chlorophyll a, and cytoplasmic membrane integrity decreased, whereas the proportion of cells with excessive accumulation of intracellular reactive oxygen species (ROS) increased. The effect of electrochemical oxidation on the cell population of M. aeruginosa continued after the power was turned off. The physiological state of V. spiralis leaf cells was not severely affected at 10 mA/cm2 for 24 h. Higher current intensity and longer electrolysis time would induce apoptosis or necrosis. In order to achieve a higher target pollutant removal effect and simultaneously avoid damage to the lake ecosystem, the current intensity of the electrochemical oxidation device should not exceed 10 mA/cm2, and a single electrolysis treatment should range from 6 h to 24 h.

Study of Electrolysis Treatment of Persistent Organic Matter in Leachate

Study of Electrolysis Treatment of Persistent Organic Matter in Leachate

Підвищення абразивної зносостійкості алюмінієвих ливарних сплавів Al-Si АК-9 та АК-12 плазмо-електролітною обробкою

Aluminum casting alloys are used in machine-building, automobile, aviation, electrical and textile enterprises. However, aluminum alloys have low abrasive wear resistance, which significantly hinders their use in technological environments where abrasive particles are present. However, aluminum alloys have low abrasive wear resistance, which significantly hinders their use in technological environments where abrasive particles are present. The method of plasma electrolytic oxidation of plasma electrolyte treatment on aluminum alloys provides high hardness up to 2000 HV, low friction coefficient, high adhesion to the metal base, high environmental friendliness. However, this method does not allow the synthesis of oxide layers with high abrasive wear resistance on cast alloys - silumin. Plasma electrolyte treatment layers synthesized on the most widely used Al-Si foundry alloys have significant disadvantages: low rate of synthesis of the oxoceramic layer - 0.5 - 1 μm / min., Low thickness - up to 140 μm, low microhardness (700-1000 HV) and low abrasion resistance. Plasma electrolyte treatment layers were synthesized on the surface of 30x30 mm plates with a thickness of 4 mm from aluminum casting alloys AK-9 (9% Si) and AK-12 (12% Si) in electrolyte - 3 g / l KOH + 2 g / l Na2SiO3 (aqueous solution of liquid glass) without and with the addition to the electrolyte of 3 g / l of hydrogen peroxide H2O2, pulsed current at a frequency of 50 Hz in the cathode-anode mode at a ratio of currents (Ik / Ia) = 1 and a current density of 20 A / dm2. The thickness of the coatings after synthesis for 120 min was 120 -130 µm .. [4]. Metallographic studies were performed on a scanning electron microscope ZEISS EVO 40XVP with X-ray microanalysis system INCA Energy. The phase composition of the surface layers was investigated using a DRON-3M diffractometer in Cu-K radiation. Conclusions: 1. Plasma-electrolyte treatment of silumins AK-9 and AK-12 increases their microhardness up to 1000… 1300 HV, which causes an increase in their abrasive wear resistance by 14 ... 57 times. 2. Addition to the electrolyte of hydrogen peroxide H2O2 in the amount of 3% of the mass. increases the abrasive wear resistance of silumins after plasma electrolyte treatment by another 30 ... 70%. This is due to the increase in the content of oxide phases αAl2O3, γAl2O3 and the decrease in the content of the silicate phase of sillimanite - Al2O3 • SiO2 in the coating structure.

Ultrafine TaOx/CB Oxygen Reduction Electrocatalyst Operating in Both Acidic and Alkaline Media

The high activity of non-platinum electrocatalysts for oxygen reduction reaction (ORR) in alkaline media is necessary for applications in energy conversion devices such as fuel cells and metal-air batteries. Herein, we present the electrocatalytic activity of TaOx/carbon black (CB) nanoparticles for the ORR in an alkaline atmosphere as well as in an acidic electrolyte. Ultrafine TaOx nanoparticles 1–2 nm in size and uniformly dispersed on CB supports were prepared by potentiostatic electrodeposition in a nonaqueous electrolyte and subsequent annealing treatment in an H2 flow. The TaOx/CB nanoparticles largely catalyzed the ORR with an onset potential of 1.03 VRHE in an O2-saturated 0.1 M KOH solution comparable to that of a commercial Pt/CB catalyst. ORR activity was also observed in 0.1 M H2SO4 solution. According to the rotating ring disk electrode measurement results, the oxide nanoparticles partly produced H2O2 during the ORR in 0.1 M KOH, and the ORR process was dominated by both the two- and four-electron reductions of oxygen in a diffusion-limited potential region. The Tafel slope of −120 mV dec−1 in low and high current densities revealed the surface stability of the oxide nanoparticles during the ORR. Therefore, these results demonstrated that the TaOx/CB nanoparticles were electroactive for the ORR in both acidic and alkaline electrolytes.

FABRICATION AND WEAR BEHAVIOR OF PEC/N HARDENED LAYER ON PURE IRON

In this paper, the antifriction carbonitriding (PEC/N) layers were prepared on pure iron by cathodic plasma electrolytic treatment (PET) in glycerin and carbamide aqueous solution under 360[Formula: see text]V for 1, 3 and 10[Formula: see text]min. Influence of discharge time on morphology, structure, surface roughness and microhardness of PEC/N layer was analyzed. The tribological performance of the PEC/N layer, growth mechanism and diffusion process during PEC/N treatment was investigated. The thickness of the PEC/N layer grew to 48[Formula: see text][Formula: see text]m for 10[Formula: see text]min treatment and the growth of the saturation layer met the parabolic law. The highest microhardness of the surface was up to 811 HV, which was 5 times of that of iron substrate. The PEC/N layer consisted of [Formula: see text]-Fe, Fe[Formula: see text]N, Fe4N, Fe3C, Fe5C2 phases and a little FeO phase. The wear rate of the PEC/N layer reduced by five-sixes comparing with the iron substrate and the surface of the wear track was much smoother. The temperature close to the surface during PEC/N fitted by the tested temperature values inside the sample was 801∘C (1074[Formula: see text]K), and the combination diffusion rate of C and N into pure iron during PET at 360[Formula: see text]V reached [Formula: see text][Formula: see text]m2/s. The electron temperature fluctuates between 3000[Formula: see text]K and 8000[Formula: see text]K. The antifriction PEC/N layer displayed a very good wear resistance and the higher diffusion rate makes plasma electrolytic carbonitriding a very effective technique for surface modification of pure iron.

Evaluation of tribotechnical properties of modified surfaces after plasma electrolytic treatment

The article considers the study of the effect of plasma electrolytic processing on the tribotechnical characteristics of medium-carbon steel. Friction tests were carried out in dry friction mode. Electron microscope and profilometer were used to study the friction tracks. For a comprehensive assessment of the quality of the modified surface layer, the Kragelsky-Kombalov complex parameter was calculated. It was found that plasma electrolytic treatment leads to a decrease in the coefficient of friction and weight wear in comparison with hardened and untreated steel. It has been determined that the mechanism of wear of samples after plasma electrolytic treatment is fatigue wear at boundary friction and plastic contact.

Features of anodic plasma electrolytic treatment of an ultra-light alloy of the Mg-Li system in an aqueous electrolyte

The possibility of plasma electrolytic treatment of an alloy of the Mg-Li system in an aqueous solution of ammonium chloride, ammonium nitrate and boric acid has been studied. The specific features of the process in the voltage range from 10 to 600 V are determined. The current-voltage and voltage-temperature characteristics during alloy processing are shown, as well as the effect of the processing time on the temperature of the samples. Plasma electrolytic boronitriding of the alloy can be carried out to study the efficiency of the technology at avoltage of 240 V, which corresponds to a sample temperature of 300 ± 10 °C.

Investigation of electrolysis-related modification of graphene films in biosensors

In this work, the modification of the surface parameters of graphene chips after electrolysis treatment in a NaClO4 aqueous solution has been studied. Two electrolysis modes have been analysed. In the first one, a negative potential (-0.2 V) is applied to the graphene chips, while in the second one the potential is positive (0.8 V). Investigation using a number of techniques including atomic force microscopy, Kelvin probe force microscopy, Raman spectroscopy, measurements of current-voltage characteristics and low-frequency noise has shown that the electrolysis mode with application of a positive potential on graphene chips decreases the 1/f noise and allows one to obtain a uniform surface potential distribution while leaving the graphene structure undamaged. The results of this study help to understand the efficiency and reproducibility of the procedure for electrolysis treatment of graphene chips.

Significance of plasma electrolytic oxidation treatment on corrosion and sliding wear performances of selective laser melted AlSi10Mg alloy

In this investigation, Plasma Electrolytic Oxidation (PEO) process was used to prepare an alumina (Al 2 O 3 ) coating for corrosion and wear protection of a Selective Laser Melted (SLM) AlSi10Mg alloy radiator. The phase compositions, microstructures, mechanical properties, corrosion properties and wear resistance of the SLM AlSi10Mg alloy and the PEO coatings were investigated systematically. It was observed that the AlSi10Mg alloy prepared by SLM displayed a denser microstructure, finer grains and excellent mechanical properties with an average ultimate tensile strength of 402 MPa and an elongation of 9.9%. In addition, a double-layered coating with Al 2 O 3 as the top layer having a thickness of ~20 μm and a hardness of 1051HV 0.01 was realizable on the SLM AlSi10Mg alloy by PEO treatment. The corrosion current density and wear rate of the PEO Al 2 O 3 coatings were 5.7 and 279.3 times lower compared to the plain SLM AlSi10Mg alloy. The results indicate that the PEO treatment can significantly improve the wear and corrosion resistance of the AlSi10Mg alloy prepared by the SLM process. • AlSi10Mg alloy prepared by SLM exhibits dense microstructure and fine grain size. • AlSi10Mg alloy prepared by SLM process has excellent mechanical properties. • PEO film has dense outer layer and less dense inner one whose main phase is γ-Al 2 O 3. • PEO can provide excellent corrosion and wear protection for the SLM AlSi10Mg parts.

The role of electrolysis and enzymatic hydrolysis treatment in the enhancement of the electrochemical properties of 3D-printed carbon black/poly(lactic acid) structures

Additive manufacturing, also known as 3D printing, is beginning to play an unprecedented role in developing many applications for industrial or personalized products. The conductive composite structures require additional treatment to achieve an electroactive surface useful for electrochemical devices. In this paper, the surfaces of carbon black/poly(lactic acid) CB-PLA printouts were activated by electrolysis or enzymatic digestion with proteinase K, or a simultaneous combination of both. The proposed modification protocols allow the tailoring of electrochemically active surfaces and electron transfer kinetics determined by electrochemical techniques (CV, EIS) by [Fe(CN)6]4-/3- redox probe. X-ray photon spectroscopy and SEM imaging were applied to determine the delivered surface chemistry. CB-PLA hydrolysis under alkaline conditions and anodic polarization greatly impacted the charge transfer kinetics. The enzymatic hydrolysis of PLA with proteinase K led to highly efficient results, yet requires an unsatisfactory prolonged activation duration of 72 h, which can be efficiently reduced by electrolysis carried out in the presence of the enzyme. Our studies hint that the activation protocol originates from surface electropolymerization rather than a synergistic interaction between the electrolysis and enzymatic hydrolysis. The detailed mechanism of CB-PLA hydrolysis supported by electrolysis is a promising new route to achieve time-efficient and environmentally-friendly activation procedure.

Copper recovery from sludges generated in the electrolyte treatment plant of a pyrometallurgical complex

Electrolytic sludge is generated in the last stage of the electrolyte decontamination treatment plant in the manufacture of cathodic copper (> 99.99 % Cu). Currently, this sludge is recycled back to the process due to the high concentration of copper, although its recirculation involves a serious problem of arsenic accumulation in the industrial process. This negatively affects the quality of commercial copper. Therefore, the main focus of this study was the recovery of copper contained in the electrolyte sludge as copper (II) sulfate pentahydrate (CuSO4∙5H2O) for its return to the industrial process and/or commercialization. The remaining waste, which contains mainly As and other toxic chemical species, were eliminated in a controlled repository. To this end, an exhaustive characterization of the electrolytic sludge was performed to determine its chemical composition, mineral phases, and particle size. The main results indicated that the sludge was composed of very fine particles (~ 99 % < 100 μm), containing mostly Cu (~ 54 %) (Cu3As, Cu2O, Cu and CuSO4∙xH2O), As (~ 10 % as Cu3As) and S (~ 7 % as CuSO4∙xH2O). More than 90 % of the Cu contained in the sludge was recovered as very pure copper sulfate (≥ 99.5 %) by an evaporative crystallization process. In addition, around 70 % of the As was removed in the process as a solid (> 99 % in As2O3). The rest of pollutants remained in the final solution, which ultimately will be treated in the liquid effluent treatment plant. Therefore, valorization of the electrolytic sludge was achieved by copper recovery as CuSO4∙5H2O using evaporative crystallization; this process was an effective way for both recovering Cu and removing the As contained in the electrolytic sludge generated in the electrolyte treatment plant.

Electrochemically Engineered, Highly Energy-Efficient Conversion of Ethane to Ethylene and Hydrogen below 550 °C in a Protonic Ceramic Electrochemical Cell

Ethylene is one of the largest building blocks in the petrochemical industry, mainly produced by steam cracking of ethane derived from naphtha or shale gas at high temperatures (>800 °C). Despite its technical maturity and economic competitiveness, the thermal steam cracking of ethane is highly energy-intensive. Herein, an electrochemically engineered direct conversion process of ethane to produce hydrogen and ethylene using a planar protonic ceramic membrane reactor with a bi-functional three-dimensional catalytic electrode is reported, with a single-pass ethane conversion of 40% and ethylene yield of 26.7% at 550 °C. Compared with the industrial ethane steam cracking, this method saves process energy input by 45.1% and improves process energy efficiency by 50.6%, based on comprehensive process simulation using Aspen Plus software. Further, steam electrolysis treatment under the solid oxide electrolysis cell mode can regenerate the system’s catalytic performance and significantly alleviate catalytic degradation by 74%, demonstrating high techno-economic viability.

The Effectiveness of Partial Lid Margin Excision Including Hair Follicles in Diffuse Trichiasis and Distichiasis

Purpose: In the present study, we introduced and evaluated the effectiveness of partial lid margin excision including hair follicles in diffuse trichiasis and distichiasis. Methods: A retrospective review of medical records was performed on 21 eyelids of 14 patients with diffuse trichiasis and distichiasis. The patients had trichiasis of more than 1/3 of the eyelid margin and received lid margin excision including hair follicles at our hospital. The patients were followed up for more than 3 months after surgical correction. A telephone survey of the surgical outcomes, including recurrence and cosmetic satisfaction, was conducted for patients who were unable to visit the clinic. Success was defined as complete resolution of symptoms, no recurrence of abnormal cilia, and acceptable cosmesis. Results: The patients included five males (6 eyes) and nine females (15 eyes) with an average age of 61.9 years (range, 39.8-82.4 years). The surgical success rate was 90.5%. Two eyelids showed a recurrence of trichiasis requiring additional electrolysis treatment, and one eyelid exhibited skin pigmentation. Conclusions: For patients with diffuse trichiasis and distichiasis, partial lid margin excision including hair follicles showed excellent results with respect to resolving irritating symptoms, with minimal complications, low recurrence, and an easy procedure.

Effect of Gammulin supplementation during the first 24 d of life on health, growth, and first-lactation performance of Holstein cows

Development and health during calfhood are paramount for the success of dairy operations because they are associated with longevity and productivity later in life. Thus, provision of nutritional supplements has been explored as an alternative to improve growth of preweaned calves. Holstein calves (female = 472, male = 46) from 2 dairies located in the San Joaquin Valley were assigned randomly to receive 25 g/d of Gammulin (APC Inc.) from 2 to 24 d of age (GAM = 263) or to receive no supplementation (control = 255). Calves were fed a mixture of waste milk and milk replacer (3.79 L/d), and study personnel added the supplement to the bottles of calves in the GAM treatment daily. Study personnel monitored calves 6 d/wk and recorded starter intake, fecal score (1 = firm, 4 = watery), and attitude score (1 = alert and responsive, 4 = recumbent). Blood samples were collected (4, 7, 14, 26, 44, 56, and 68 d of age) to determine concentrations of total protein, glucose (n = 64), nonesterified fatty acids (n = 64), β-hydroxybutyrate (n = 171), and hematocrit (n = 518). Calves (n = 64) were treated with 0.5 mg of ovalbumin at 3, 21, and 42 d of age, and concentration of anti-ovalbumin IgG was measured. The percentage of polymorphonuclear leukocytes positive for phagocytosis and oxidative burst after the ex vivo exposure to an enteropathogenic Escherichia coli was evaluated (n = 64). We followed the female calves through the end of the first lactation or until they left the herd to evaluate the effect of treatment on first-lactation performance. Treatment did not affect metabolic and immune responses. During the supplementation (1 to 24 d of age), starter intake did not differ between treatments, but the GAM treatment reduced starter intake (638.5 ± 1.1 vs. 696.6 ± 1.1 g/d; mean ± standard error of the mean) from 25 to 60 d of age and average daily gain (798.8 ± 15.4 and 749.5 ± 15.2) from 23 to 60 d of age, resulting in reduced body weight at 60 d of age (68.4 ± 0.4 vs. 69.8 ± 0.5 kg). From 1 to 24 d of age, GAM treatment reduced the number of days calves had fecal score = 4 (ratio of number of days = 0.92; 95% confidence interval = 0.84-1.00) and it reduced the number of electrolyte treatments calves received (ratio of number of treatments = 0.92; 95% confidence interval = 0.85-0.99). Treatment did not affect the hazard of first calving and first-lactation 305-d milk yield, but the adjusted hazard ratio (0.82; 95% confidence interval = 0.65, 1.04) of pregnancy in the first lactation tended to be reduced for the GAM treatment. In the conditions of this experiment, supplementation with 25 g/d of GAM to the liquid feed from 2 to 24 d of age did not improve calfhood health and performance.