Manganese is an indispensable metal widely used in various fields. China ranks as the fourth-largest producer of manganese ore and the largest producer of electrolytic manganese metal (EMM). However, EMM production is linked to high energy consumption and pollution. This study conducts a life cycle assessment (LCA) of EMM production in the Manganese Triangle region of China to comprehensively evaluate its environmental impact. Results show that Human carcinogenic toxicity, mainly from electricity generation (65.3 %) and mining activities (24.4 %), is the most significant environmental impact. Chromium (VI) is identified as the predominant hazardous substance, contributing up to 91 % to Human carcinogenic toxicity. Endpoint results estimate that the production of 1 t of EMM results in 1.01E-02 DALY of harm to human health, 1.97E-05 species.yr of harm to the ecosystem, and $227.15 worth of resource depletion. Simulation scenarios demonstrate that replacing thermal power with hydropower can reduce environmental pollution by over 90 %. Finally, based on the findings, technical measures for promoting clean production of EMM were proposed.