Electrolyte Temperature Research Articles

High Potential Electrochemical Synthesis of Thermally Reduced Graphene Nanomaterial

In this study, we provide electrochemical techniques for synthesizing thermally reduced graphene nanomaterial that have high potential, low defects, cost-effectiveness, and ecological sustainability. The electrochemical exfoliation is carried out by employing a 195 W DC (voltage = 60[Formula: see text]V and current = 3.25 A) power source at a maximum electrolyte temperature of about 92.5∘C within the aqueous suspension of 2[Formula: see text]M of sulfuric acid (H2SO[Formula: see text]. Thereafter, the synthesized nanomaterial was treated in the weak piranha [combination of sulfuric acid and hydrogen peroxide (H2O[Formula: see text]] solution using an electrochemical technique inside the water bath sonicator at 80∘C. X-ray diffraction (XRD) analysis shows the peak of diffraction to the (002) plane of the reduced graphene oxide (RGO) samples emerges at around 2[Formula: see text] and 26.56∘ with an interplanar distance of 3.40 Å and 3.54 Å. According to the XRD data, after the high-temperature thermal reduction phase, the structure of the crystals and interplanar separation were recovered. The size of the crystallite of RGO produced under H2SO4 conditions was discovered to be greater than the crystallite size of graphene oxide produced under piranha solution conditions. The Raman analysis results show that the degree of disorder of the graphene synthesized within the H2O2 was higher than in comparison to the graphene synthesized in H2SO4. Field emission scanning electron microscopy (FE-SEM) results show that graphene synthesized in the presence of H2O2 has a thin and porous microstructure in comparison to H2SO4 with no significant effect on the presence of the availability of the C/O ratio. The atomic force microscopy (AFM) analysis indicates that the surface roughness of the graphene synthesized in the H2O2 was higher than that of the H2SO4. The Fourier transform infrared spectroscopy (FT-IR spectroscopy) analytical results show that the majority of the functional groups have been eliminated within the samples.

Effect of 30˚C Electrolyte Temperature on The Sensitivity Cu/Ni

Given the necessity of cryogenic storage and monitoring cryogenic temperatures is equally important. This study aims to determine the resistance value and sensitivity of copper wire before and after electroplating at 30˚C electrolyte temperature as a low temperature sensor. The electrolyte solution consists of NiSO4 260 g, NiCl2 60 g, H3BO3 40 g and Aquades 1000 mL. Electroplating was carried out with an electrolyte temperature of 30˚C, electrode distance of 4 cm, voltage of 4.5 volts and plating time of 4 minutes. The plating results were analyzed to determine the resistance and sensitivity of the sensor at temperatures from 0 to -160˚C. The results showed that the resistance value of the Cu coil obtained RCu = (1.44 ± 0.00) ohm and the resistance of the Cu/Ni coil RCu / Ni = (1.50 ± 0.00) ohm. The resistance value on the Cu/Ni coil (after plating) is greater than the Cu coil (before plating). While the test results of sensor sensitivity show that Cu and Cu/Ni coils have properties as low temperature sensors. Sensor sensitivity increases after plating. The sensitivity value obtained by Cu coil is S(T) = -1E-06T + 6E-05 and Cu/Ni coil S(T) = -2E-06T + 2E-05. The projection sensitivity at a temperature of -200 ˚C obtained is 0.00046 V/˚C less than the Cu/Ni coil 0.00082 V/˚C. So nickel plating on copper coil at 30˚C electrolyte temperature has successfully improved the sensitivity value of the low-temperature sensor.

Electrochemical separation of tungsten from scrap cemented carbide WC in FLiNaK melt

Molten salt electrolysis is an innovative technology applied to recover tungsten from the scrap of cemented carbide, which enables the realization of energy saving and consumption reduction goals. Currently, numerous studies have focused on the molten salt electrolysis of chlorine salt systems, but still face challenges including low electrolysis efficiency and salt volatilization. Here, we propose to employ the FLiNaK molten salt system for recovering tungsten from the scrap cemented carbide and analyze the feasibility of the dissolution of WC occurring at the anode from the perspective of thermodynamics and electrochemical polarization curves. Moreover, the influence of electrolysis temperature on the dissolution of the anode is also investigated and the productions are identified as nano-flake tungsten powder by characterizing the cathode product using XRD, SEM, EDS, and XPS. A two-step reduction mechanism of W ions was analyzed by electrochemical means such as CV, SWV, etc., and the ionic groups stabilized by W6+ and W4+, and F− in the molten salts were deduced to be WF33+ and WF3+ by DFT simulation calculations. This work provides new guidance for the application of molten salt electrolysis in the recovery of tungsten from scrap cemented carbide.

Strategies for Effective Degradation of Methyl Orange Dye in Aqueous Solution via Electrochemical Treatment with Copper/Graphite Electrodes

This study investigated the electrochemical degradation of methyl orange dye (MO) in aqueous solution using copper/graphite electrodes as anode and cathode respectively. The process parameters such as electrolyte concentrations, current density, pH and temperature were analyzed. The results proved that copper/graphite electrodes were effective for MO degradation and the reaction followed the first-order kinetic model. The degradation efficiency decreased with increasing MO concentration and increased steadily with current density. The pH trend with degradation efficiency was pH 9 (98%) > pH 7 (96%) > pH 3 (77%) after 70 min of electrolysis time, which shows that the alkaline conditions favoured the degradation process. Fourier transform infrared spectroscopy (FTIR) and UV–Vis absorption spectroscopy confirmed the dye degradation process, with the formation of degradation intermediates. The FTIR results revealed that the oxidative degradation of MO may be initiated at the N=N azo bond, which was confirmed by quantum chemical modelling of the electronic structure parameters of MO.

Effect of Temperature of Citrate Electrolyte on Properties of Co–W Coatings

Effect of Temperature of Citrate Electrolyte on Properties of Co–W Coatings

Electrodeposition of Co-Mo Alloys and Its Applications in Electrochemical Sensing of Phosphate

Quantification of phosphate ions in water ecosystems is crucial for maintaining a healthy aquatic environment and optimizing aquaculture parameters. While cobalt (Co) thin film modified electrodes are widely used as phosphate sensors, their selectivity and stability often require improvements for on-site measurement. The present work addresses this challenge by introducing a novel phosphate sensing platform utilizing Cobalt-Molybdenum (Co-Mo) alloy film deposited on copper substrate. The developed Co-Mo thin film sensor exhibited a good thermal stability (up to 60 °C) and significantly improved the detection ranges (10−6 M to 10−2 M). The influence of electrolyte pH and temperature toward potentiometric sensing of phosphate were investigated and the conditions were optimized to improve the sensor sensitivity. The sensor showed a sensitivity of −56 mV.dec−1 with a good correlation coefficient (0.988). The detection limit was determined to be 0.987 μM and the relative standard deviation (RSD) was 1.3% (n = 3). The Co-Mo thin film sensor exhibited negligible interference even in the presence of 10-fold excess concentrations of common interfering analytes, demonstrating its robust performance in real-world environment. To validate the field practicality, the sensor’s performance was successfully tested in real shrimp culture water samples, demonstrating its compatibility with complex environmental matrices.

In English

The total reorganization energy of the system and its components, the solvent reorganization energy and the transformation energy of reactants (water clusters [(H2O)nOH]-), during electrocatalytic hydrogen evolution on binary alloys of molybdenum with iron subgroup metals (Fe, Co, Ni) in an alkaline medium (30 wt. % NaOH solution) have been calculated. The calculated values of the solvent reorganization energy and the reorganization energy of water clusters are in agreement with the Marcus – Dogonadze – Kuznetsov theory. The dependence of the total reorganization energy of the system, the solvent reorganization energy, and the reorganization energy of discharging species (water clusters) on the electrolyte temperature has been calculated. It was shown that the total reorganization energy of the system and the activation energy of the electron-transfer reaction of electrocatalytic hydrogen evolution (HER) on binary alloys of molybdenum with iron subgroup metals in an alcaline vedium (30 wt. % NaOH solution) decrease linearly with increasing electrolyte temperature in the following order: Fe-54 at. % Mo > Ni-54 at. % Mo > Co-52 at. % Mo. The temperature dependences of the water cluster discharge reorganization energy and the activation energy on binary molybdenum alloys are linear and intersect in the boiling point region of 30 wt. % NaOH solution 384.7 K. At this temperature, the electrode process is limited by the diffusion of regenerating water clusters to the electrode surface. The calculated diffusion activation energy Ad is 9.9 kJ·mol–1. The value of the system reorganization energy lt is 39.8 kJ·mol–1, which is consistent with the theory of Markus – Dogonadze – Kuznetsov. Electrocatalytic activity of binary alloys of molybdenum with iron subgroup m

Electric field simulation in the electrochemical machining of a thin-walled part cavity

The article is aimed at simulating an electric field in the interelectrode gap during the electrochemical machining of a thin-walled part cavity for aerospace equipment. The study involved simulating the process of electrochemical cavity machining at a constant voltage in a steady-state mode in the COMSOL Multiphysics environment. The simulation was carried out for the scheme of electrochemical machining with a movable cathode and vertical and horizontal feeding to the workpiece surface undergoing machining while maintaining a constant interelectrode gap. The following simulation conditions were adopted: 12Cr18Ni10Ti stainless steel as the material of the cathode tube; AlMg6 aluminum alloy as the material of the thin-walled part; NaNO3 solution as the electrolyte. When simulating the electric field in the interelectrode gap, the heat exchange process was taken into account. The simulation of the electric field in the electrochemical cavity machining of a thin-walled part yielded a macro that allows the process simulation to be adapted to different input process conditions. As a result of the simulation, the following distribution patterns were obtained: current density in the cathode, potentials, electric field in the interelectrode gap and adjacent area, and process temperature of electrochemical machining. The simulation results show that the electric field lines are directed toward the cathode from the workpiece periphery. This means that anodic dissolution of material occurs in a given region, which characterizes the law concerning the distribution of potentials in an electrochemical cell. The temperature distribution pattern obtained in the simulation revealed that a temperature increase in the machining zone is insignificant. An increase in electrolyte temperature is shown to result in a proportional increase in wall temperature. Thus, the conducted study provides a theoretical insight into the examined process.

Enhanced photoelectrochemical water splitting via 3D flow field structure: Unveiling the decisive role of interfacial mass transfer

The efficiency of photoelectrochemical water splitting is not only related to the electrode material, but also influenced by the mass transport at the electrode surface. Here, we design a novel photoelectrochemical water splitting reactor, which generates a turbulent flow (0–145 mL/min) at the electrode/electrolyte interface. It was revealed that the reactor has a significant effect on the electrolyte flow, and the flow rate on the photocurrent density was more significant during the transition period of the flow state and the high flow rate. The 3D flow field structure improved the water splitting reaction of TiO2 photoelectrode by 130% at the flow rate of 130 mL/min, and consequently, the TiO2 exhibited a photocurrent density of 0.142 mA·cm−2 at 1.23 V versus the reversible hydrogen electrode. Then we changed the temperature (20–90 °C) of the electrolyte, and electrochemical impedance spectra results indicated that the ion transport impedance decreased with increasing electrolyte temperature in the experimental range. The photocurrent density increased by about 2.2 times at 90 °C compared to that at 20 °C. This work provided insights of the structure design on the photoelectrode/electrolyte interface in solar water splitting and revealed the non-negligible effect of interfacial mass transport in photoelectrochemical performance.

Electrochemical CO2 conversion in eutectic Li-Ba and Li-Ca carbonate mixtures

Here, the impact of electrolyte selection and electrolysis temperature on carbon morphology, energy consumption, and voltage efficiency in molten Li2CO3-BaCO3 and Li2CO3-CaCO3 electrolytes during 90 min 10 A constant current electrolysis are investigated. The scarcity of experimental investigations into these binary electrolytes, coupled with a lack of systematic investigation of temperature effects, necessitates further examination. The comprehensive analysis of the produced carbon reveals that both electrolyte composition and temperature influence carbon morphology. At lower temperatures the effect of electrolyte composition to the morphology is a more significant. The type and amount of metallic impurities mixed with the carbon vary depending on the electrolyte composition and electrolysis temperatures. The results from Li2CO3-CaCO3 electrolyte show more promising compared to results from Li2CO3-BaCO3 electrolyte in terms of product quality. Regarding electrolysis power and voltage efficiency, Li2CO3-CaCO3 proves equal or superior to other electrolytes, depending on temperature. Heat generation occurs in all the experiments, which emphasizes the importance maintaining a constant electrolysis temperature in industrial processes to manage heat generation effectively.

Electrode Surface Heating with Organic Films Improves CO2 Reduction Kinetics on Copper.

Management of the electrode surface temperature is an understudied aspect of (photo)electrode reactor design for complex reactions, such as CO2 reduction. In this work, we study the impact of local electrode heating on electrochemical reduction of CO2 reduction. Using the ferri/ferrocyanide open circuit voltage as a reporter of the effective reaction temperature, we reveal how the interplay of surface heating and convective cooling presents an opportunity for cooptimizing mass transport and thermal assistance of electrochemical reactions, where we focus on reduction of CO2 to carbon-coupled (C2+) products. The introduction of an organic coating on the electrode surface facilitates well-behaved electrode kinetics with near-ambient bulk electrolyte temperature. This approach helps to probe the fundamentals of thermal effects in electrochemical reactions, as demonstrated through Bayesian inference of Tafel kinetic parameters from a suite of high throughput experiments, which reveal a decrease in overpotential for C2+ products by 0.1 V on polycrystalline copper via 60 °C surface heating.

Elucidating the Complex Oxidation Behavior of Aqueous H3PO3 on Pt Electrodes via In Situ Tender X-ray Absorption Near-Edge Structure Spectroscopy at the P K-Edge.

In situ tender X-ray absorption near-edge structure (XANES) spectroscopy at the P K-edge was utilized to investigate the oxidation mechanism of aqueous H3PO3 on Pt electrodes under various conditions relevant to high-temperature polymer electrolyte membrane fuel cell (HT-PEMFC) applications. XANES and electrochemical analysis were conducted under different tender X-ray irradiation doses, revealing that intense radiation induces the oxidation of aqueous H3PO3 via H2O yielding H3PO4 and H2. A broadly applicable experimental procedure was successfully developed to suppress these undesirable radiation-induced effects, enabling a more accurate determination of the aqueous H3PO3 oxidation mechanism. In situ XANES studies of aqueous 5 mol dm-3 H3PO3 on electrodes with varying Pt availability and surface roughness reveal that Pt catalyzes the oxidation of aqueous H3PO3 to H3PO4. This oxidation is enhanced upon applying a positive potential to the Pt electrode or raising the electrolyte temperature, the latter being corroborated by complementary ion-exchange chromatography measurements. Notably, all of these oxidation processes involve reactions with H2O, as further supported by XANES measurements of aqueous H3PO3 of different concentrations, showing a more pronounced oxidation in electrolytes with a higher H2O content. The significant role of water in the oxidation of H3PO3 to H3PO4 supports the reaction mechanisms proposed for various chemical processes observed in this work and provides valuable insights into potential strategies to mitigate Pt catalyst poisoning by H3PO3 during HT-PEMFC operation.

The study on the shortcut approach for cooperative disposal of arsenic-rich copper dust and waste acid to prepare high-purity copper

The copper dust derived from the double-flash copper smelting process contains high level of arsenic with almost zero positive potential impurities. This study explores a new process for the preparation of high-purity copper through selective leaching of arsenic-rich copper dust with waste acid-purification-electrodeposition. Furthermore, the study also explores the causes and solutions for recurrent occurrence of excessive Hg impurity content. The results indicate that, the high-purity copper that meets standard 6 N (China) requirements and exhibits smooth surface, dense crystallization, and uniform color can be obtained under the optimal conditions of 200 A/m2 current density, electrolyte sulfuric acid concentration of 120 g/L, additive dosage of 120 g/t·Cu, electrolysis temperature of 50 °C, electrode spacing of 45 mm, endpoint Cu2+ concentration of 30.50 g/L, with C1 used as active adsorbent to purify the electrolyte. The current efficiency can be up to 99.65 %, with average tank voltage of 1.87 V and electrical energy consumption of 1582.93 kW h/t⋅Cu. There will be good environmental and economic benefits with this process of co-disposal and high-value recovery of arsenic-rich copper dust and waste acid.

Electrocoagulation treatment of sugarcane vinasse: Operating parameters and cost analysis by response surface methodology

The production of ethanol biofuel using sugarcane as substrate generates vinasse as the main wastewater from the fermentation–distillation process. The Brazilian legislation allows the use of vinasse for fertigation in limited volumes, and the remaining effluent must be treated prior to its reuse or discharge into the environment. The study aimed to evaluate the electrocoagulation (EC) technique as an alternative treatment process for raw sugarcane vinasse. The effects of the electrode gap (1–3 cm), applied electric charge (0–39000 C/L), current density (2.2–20 mA/cm2), and stirrer speed (0–680 rpm) were evaluated in a batch electrolytic reactor with aluminum electrodes. The evaluation results revealed that dissolved solids were removed and the pH increased during electrolysis in all experimental conditions, which suggested that EC was suitable for the pH neutralization of vinasse without the requirement of salt addition. An electrode gap of 1 cm and a current density of 2.2 mA/cm2 resulted in the lowest electric energy consumption (11.0 kW h/m3) and the lowest increment in the electrolyte temperature (9.5 °C). High vinasse clarification was achieved under the optimal operating conditions of 1 cm electrode gap, 31,000 C/L applied electric charge, 6.1 mA/cm2 current density, and 430 rpm stirrer speed, with 13.5 kW h/m3 and 2.88 kg Al/m3 of consumption. The treatment cost was calculated to be 6.95 US$/m3, from which the electrode dissolution was determined to be 75%. The sludge settling velocity was 0.14 cm/min, which suggested poor sedimentability, possibly due to bubble gas adsorption on the surface of the formed flocs. Results of the proposed operational parameters indicate that EC can be used as a pre-treatment of vinasse, adapting the main sugarcane processing wastewater biotechnological use.

In Situ Analysis of the Effect of Ultrasonic Cavitation on Electrochemical Polishing of Additively Manufactured Metal Surfaces

Abstract The effects of a hybrid process that combines ultrasonic cavitation and electrochemical polishing on the electrochemical behavior and the resulting surface characteristics of additively manufactured 316-L stainless steel were investigated. In situ potentiodynamic scans and electrochemical impedance spectroscopy (EIS) were conducted to gain a fundamental understanding of the effect of ultrasonic cavitation on the electrochemical processes involved, considering the influence of electrolyte temperature at 60 and 70 °C. The potentiodynamic scans revealed that increasing the ultrasonic excitation amplitude from 20 to 80 µm at 20 µm intervals and temperature from 60 to 70 °C led to reduced polishing resistance, and elevated passivation current density at equivalent applied potentials, thus leading to an increased polishing rate. These findings are attributed to intensified cavitation near the material surface, which promoted anodic dissolution reactions and accelerated the polishing rate. In situ EIS measurements provided valuable information on the charge transfer resistance and double-layer capacitance and their influence on the hybrid process. Specifically, higher ultrasonic amplitudes and elevated temperatures contributed to enhanced electrical double-layer formation and ion adsorption, resulting in a faster rate of polishing, indicating the efficacy of the hybrid process. These findings enhance our understanding of the complex interactions between ultrasonic cavitation and electrochemical dissolution processes that occur during ultrasonic cavitation-assisted electrochemical polishing. The research provides valuable insights for optimizing the process and its potential application in the post-processing of metal additive manufactured parts.

High-performance cryo-temperature ionic thermoelectric liquid cell developed through a eutectic solvent strategy

Ionic thermoelectric (i-TE) liquid cells offer an environmentally friendly, cost effective, and easy-operation route to low-grade heat recovery. However, the lowest temperature is limited by the freezing temperature of the aqueous electrolyte. Applying a eutectic solvent strategy, we fabricate a high-performance cryo-temperature i-TE liquid cell. Formamide is used as a chaotic organic solvent that destroys the hydrogen bond network between water molecules, forming a deep eutectic solvent that enables the cell to operate near cryo temperatures (down to –35 °C). After synergistic optimization of the electrode and cell structure, the as-fabricated liquid i-TE cell with cold (–35 °C) and hot (70 °C) ends achieve a high power density (17.5 W m−2) and a large two-hour energy density (27 kJ m−2). In a prototype 25-cell module, the open-circuit voltage and short-circuit current are 6.9 V and 68 mA, respectively, and the maximum power is 131 mW. The anti-freezing ability and high output performance of the as-fabricated i-TE liquid cell system are requisites for applications in frigid regions.

Computational modelling and experimental investigation of micro-electrochemical discharge machining by controlling the electrolyte temperature

Glass vias are emerging as a favourable option for radiofrequency-based micro-electromechanical system packaging. For the micromachining of glass, electrochemical discharge machining (ECDM) could be the most suitable technique if issues pertaining to the process stability are addressed thoroughly. The electrolyte temperature has immense influence on the viscosity and conductivity of the electrolyte, which percolate the stability of the ECDM process. Therefore, this article investigates the effects of the electrolyte temperature and applied voltage on the performance characteristics of ECDM for the micromachining of borosilicate glass. The machining rate (MR) and hole overcut (HOC) of the machined microholes are considered as performance characteristics. A 3D thermal-based finite element model (FEM) was developed for the thermal analysis in the machining zone. In the thermal analysis, the heat flux by thermal discharge was assumed to have Gaussian distribution, and accordingly, temperature profiles in the thermal zone were analyzed by controlling the electrolyte temperature and voltage at various levels. Further processing of temperature profiles in the thermal zone was utilized in the estimation of MR and HOC. Electrostatic-based FEM was utilized to assess the intensity of the electric field in the proximity of the tool electrode to analyze the probable locations of thermal discharge and its impact on the geometrical characteristics of the machined microholes. The simulation outcomes were validated experimentally, and show good agreement. A field emission electron microscope with energy dispersive spectroscopy was used for the characterization of the machined surface to observe the effect of the electrolyte temperature.

Newborns with Collodion Skin Disorders

Collodion Baby is a descriptive term for newborns with the entire surface of the body wrapped in a rigid yellowish membrane that resembles solid and translucent parchment paper. A rare disorder that often occurs in preterm babies with low birth weight. Collodion babies can have defects in protein and fat metabolism due to genetic mutations. Management with emollients, fluid and electrolyte balance and overcoming infection. Case Report : Reported newborn came to the emergency room of Soeselo Hospital referral from Puskesmas with Collodion Baby and low birth weight. Yellowish skin is obtained throughout the body such as translucent thick parchment, fissures with some erosion and ecropions in both eyes. The patient is placed in an incubator with a temperature of 30-32o C, emollient therapy, topical antibiotics on fissures and erosions, prophylactic antibiotics and antibiotic creams for ectropion. Discussion : Collodion baby is a condition at risk of serious complications including: risk of infection, hypernatremic dehydration, fluid and electrolyte imbalances and temperature instability caused by epidermal lipid disorders and protein homeostasis, resulting in increased transepidermal water loss (TEWL) caused by mutations in the transglutaminase 1-TGM1, ALOXE3 or ALOX12B, ABCA12, HIPAL4/ichthyin, ABHD5 genes responsible for epidermal homeostasis. Conclusion: Collodion Baby is a disorder with severe corneal damage. The importance of proper and comprehensive management with the aim of minimizing complications can reduce morbidity and mortality.

Hybrid battery energy storage for light electric vehicle — From lab to real life operation tests

The aim of the research presented in the paper is to improve the lifetime of lead-acid battery systems which are widely used in low-speed electric vehicles or utility vehicles, since the cycle life of lead-acid batteries is nonlinearly dependent on the depth of discharge and electrolyte temperature. The solution proposed here is to connect lead-acid batteries with a small lithium‑iron-phosphate battery using only a diode. This connection is simple and does not require the use of an actively controlled converter. The concept was tested at various levels of an experiment, from the initial calculation of cycle life improvement and simulation, through a laboratory experiment, all the way to operational environment tests. The results obtained confirmed the main assumptions of the study: decrease in the depth of discharge of lead-acid battery for the distance traveled of around 17 %—which would translate into a 30 % better cycle life according to the characteristics indicated by the producers—and decrease in the root mean square and maximum current values of lead-acid battery by around 40–50 % and 26 %, respectively. Range extension was also achieved in vehicles. The solution has been successfully introduced to the market and is now used in few light electric vehicles.

Growth mechanism, structure, stoichiometry and optical properties of electrochemically grown iron selenide and ferroselite thin films

In this present work, FeSe and FeSe2 thin films were deposited on ITO substrate at different electrolytic bath temperatures at 30 °C and 70 °C by using electrodeposition method. The growth mechanism was investigated via cyclic voltammetry with the potential window was found to be −1600 to 1600 mV versus SCE and the formation of well adherent film was found to be higher bath temperature. XRD result shows the deposited FeSe and FeSe2 films found to exhibit stoichiometric wurtzite and orthorhombic phases respectively. The microscopic observation shows, the uniform particle growth of FeSe and FeSe2 was found to be higher electrolytic bath temperature at 70 °C. The EDX analysis shows the deposited FeSe and FeSe2 films at higher temperature elemental is stoichiometric ratio. The determined bandgap values for FeSe (1.26 eV) and FeSe2 (1.07 eV) deposited at 70 °C. Also, we observed that the refractive indices (n) values was increased for the film deposited from 30 °C to 70 °C resulting, the estimated refractive indices (n) for FeSe and FeSe2 are 3.16 and 3.45 respectively. Furthermore the most significant optical parameters extinction coefficient (k), optical conductivity (σoptical), real (Ɛ1) and imaginary (Ɛ1) dielectric constants and dissipation factor (tan δ) are determined in order to investigate their usefulness in photovoltaic applications.