Electrochemical Performance Of Cell Research Articles

Unveiling the key role of metal coordination mode and ligand's side groups on the performance of deep-red light-emitting electrochemical cell

Three novel deep-red to near-infrared (DR to NIR) emitters based on mononuclear and dinuclear ruthenium(II) complexes with bulky structures were presented herein. For the first time, the unusual effects of metal coordination mode on the electroluminescence properties of a binuclear emitter were investigated. Unexpectedly, the mononuclear complexes showed superior performance in deep-red light-emitting electrochemical cells (DR-LEC) compared to the dinuclear complex. Likewise, substituting various ancillary ligands improved the radiance and lifetime of devices by 2.5 and 1.5 times, respectively. To the best of our knowledge, the obtained efficiency is among the best reported to date for DR-LECs based on ruthenium polypyridyl complexes.

Demystifying ionic and electronic transport in prominent oxide ion and proton conducting ceramic electrolytes: Ce0.8Sm0.2O2 and BaCe0.7Zr0.1Y0.1Yb0.1O3-δ

ABSTRACT The development and performance of ceramic electrochemical cells (CECs) depend critically on choosing ceramic electrolytes with optimal ionic and electronic transport properties. In this study, we compare the structural, morphological, and transport characteristics of two representative ceramic electrolytes, oxide ion conducting Ce0.8Sm0.2O2 (SDC) and proton conducting BaCe0.7Zr0.1Y0.1Yb0.1O3-δ (BCZYYb). We demonstrate that SDC exhibits higher bulk conductivity but lower open-circuit voltage due to its higher electron density and larger crystallite size. In contrast, BCZYYb possesses higher proton conduction, lower activation energy (0.35–0.38 eV), and higher open-circuit voltage due to its lower electron density and smaller crystallite size with more grain boundaries. BCZYYb shows enhanced proton conductivity in humidified atmospheres due to the hydration of oxygen vacancies, making it more suitable for low-temperature CEC applications. These insights into ceramic electrolyte conduction mechanisms and microstructure-property relationships can guide the optimization of CECs for energy applications.

Unveiling the role of electrolyte to promote enhanced proton storage stability in WO3 for energy storage

In the present work, we systematically investigate the phenomenon of electrochemical proton storage in WO3 and subsequently demonstrate a strategy for enhancing the cycle life for proton storage. It was carried out in three different electrolytes medium based on H3PO4, H2SO4 and HCl. It was found that although H3PO4 can promote better cycling stability and high rate capability than HCl and H2SO4, there still persists an issue in achieving large number of charge/discharge cycles. The typical proton storage capacitance of WO3 in 3.75 M H3PO4 is estimated to be around 288–346 F g−1 at a current rate of 0.5 A g−1 over 30 cycles. The cycling stability could, however, be significantly improved by the utilization of gel electrolyte which is basically a mixture of H3PO4 and polyvinyl alcohol (PVA) of different concentrations. For example, the estimated proton storage capacitance is around 287 F g−1 in 3.75 M H3PO4-PVA gel electrolyte (1:8 wt %) over 100 cycles at a current density of 0.5 A g−1. On the basis of the improved proton storage stability in the gel electrolyte, the electrochemical performance of a proton storage full cell with WO3 and V10O24.12H2O as electrodes is also illustrated. Another important revelation is the drastic reduction of the self-discharge rate of the full cell in the gel electrolyte in comparison to pristine aqueous medium electrolyte.

Investigating the Performance and Safety of Li-Ion Cylindrical Cells Using Acoustic Emission and Machine Learning Analysis

Acoustic emission (AE) is a low-cost, non-invasive, and accessible diagnostic technique that uses a piezoelectric sensor to detect ultrasonic elastic waves generated by the rapid release of energy from a localised source. Despite the ubiquity of the cylindrical cell format, AE techniques applied to this cell type are rare in literature due to the complexity of acoustic wave propagation in cylindrical architectures alongside the challenges associated with sensor coupling. Here, we correlate the electrochemical performance of cells with their AE response, examining the differences during pristine and aged cell cycling. AE data was obtained and used to train various supervised binary classifiers in a supervised setting, differentiating pristine from aged cells. The highest accuracy was achieved by a deep neural network model. Unsupervised machine learning (ML) models, combining dimensionality reduction techniques with clustering, were also developed to group AE signals according to their form. The groups were then related to battery degradation phenomena such as electrode cracking, gas formation, and electrode expansion. There is the potential to integrate this novel ML-driven approach for widespread cylindrical cell testing in both academic and commercial settings to help improve the safety and performance of lithium-ion batteries.

Safety enhanced novel polymer electrolytes for lithium-ion battery: Anomalous output performance with long term cycling stability by doping and polymer blending

Electrolyte with better safety and stability are the primary concern in the present lithium-ion battery (LIB) technology. Herein, a unique polymer blend electrolyte of polyvinylidene difluoride (PVdF)/poly (acrylonitrile butadiene styrene) (ABS) (75: 25) is fabricated by the non-solvent induced phase inversion method. The structural, morphological, and electrochemical performance of the PVdF/ABS blend is enhanced by incorporating the silica nanoparticles as the ceramic filler by the in-situ method. The gel polymer electrolyte (GPE) constitutes 6 wt % of in-situ synthesised silica in PVdF/ABS blend (PASI-06) exhibits better microporous structure with 80 % porosity. The thermal shrinkage, thermogravimetric analysis (TGA) and flammability test safeguards the exceptional thermal stability of the polymer membrane in LIBs. The polymer membrane activated in the liquid electrolyte (1 M LiPF6 in EC:EMC:DMC (1: 1: 1 v/v)) reveals an electrolyte uptake of 400 %, high electrolyte retention (0.82) and a room temperature ionic conductivity of 5.7 mS cm−1. The better oxidative stability exhibited by the PASI-06 (4.5 V) ensures its applicability with high voltage cathodes. Moreover, the electrochemical performance of the coin cell constitutes of Li/GPE/LFP able to exhibits an initial discharge capacity of 143 mAh g−1 and retained a capacity of 115 mAh g−1 even after 200 cycles at 0.1 C-rate at 25 °C. The long term cycling stability evaluated over 500 cycles at 1 C shows that the cell can exhibit an initial discharge capacity 120 mAh g−1 with 77 % capacity retention over 500 cycles that corresponds to 99 % of coulombic efficiency. These excellent performances exhibited by the PASI-06 GPE guarantee its applicability in thermally stable LIBs with better safety and reliability.

A novel efficient three-stage electrochemical pre-lithiation method for the amorphous carbon negative electrodes of lithium-ion capacitors

Electrochemical pre-lithiation stands as a practical and widely adopted technique for precisely controlling the degree of pre-lithiation, but the process is usually time-consuming. Herein, we introduce a novel three-stage electrochemical pre-lithiation method, comprising an initial stage of a high current density, a second stage of a low current density, and an additional stage of constant voltage to ensure the complete formation of solid electrolyte interphase (SEI) on the amorphous carbons: soft carbon (SC) and hard carbon (HC). Lithium-ion capacitors (LICs) are configured with the pre-lithiated SC or HC as the negative electrode and activated carbon as the positive electrode to assess the efficacy and adaptability of this three-stage pre-lithiation approach. Our findings demonstrate that this method can reduce the pre-lithiation time from 1114 to 604 min for SC, and from 1913 to 1080 min for HC, achieving nearly 46 % and 44 % decreases, respectively. Furthermore, the three-stage pre-lithiation method can simultaneously increase reversible Li-ion storage capacity within the same operating potential window, thereby enhancing the electrochemical performance of the LIC cells. Specifically, the LIC cell employing the three-stage pre-lithiated SC exhibits an energy density of 96.5 Wh kg-1 at 0.15 kW kg-1 and 76.5 Wh kg-1 at 5.98 kW kg-1. These cells demonstrate remarkable reversibility, retaining 89.6 % charge capacity after 10,000 cycles. Similarly, the LIC with the three-stage pre-lithiated HC achieves even higher energy densities of 105.3 Wh kg-1 at 0.15 kW kg-1 and 86.42 Wh kg-1 at 5.98 kW kg-1 with a retention of 85.2 % after 5000 cycles. The successful implementation and validation of this three-stage pre-lithiation method pave the way for further development of LICs.

Electrolyte Engineering via Fluorinated Siloxane Solvent for Achieving High-Performance Lithium-Metal Batteries.

Advanced solvent is of important significance to develop an excellent electrolyte that simultaneously maintains a high ionic conductivity, wide electrochemical window, and good compatibility with electrodes for high-performance lithium-metal batteries (LMBs). To realize a stable electrode/electrolyte interface and a uniform lithium (Li) deposition process, an optimal fluorinated siloxane (3,3,3-trifluoropropyltrimethoxysilane, TFTMS) is proposed as a cosolvent with 1,2-dimethoxyethane (DME) and highly antioxidative fluoroethylene carbonate (FEC) to formulate a Li-metal compatibility electrolyte. The TFTMS-based electrolyte presents high oxidization stability, high Li+ conductivity, and high Li+ transfer number, contributing to the accelerated reaction kinetics, homogeneous Li deposition behavior, and stable interfacial chemistry. Therefore, high Li stripping/plating reversibility (∼99%) and stable cycling (1400 h) are achieved in the TFTMS-based electrolyte, giving rise to the excellent electrochemical performance of practical Li-metal full cells. Moreover, an industrial 4 Ah NCM811|Gr pouch cell with the TFTMS-based electrolyte is demonstrated to display similar cycling performance with the commercial carbonate electrolyte in 120 cycles at 1 C. This work offers an approach toward high-performance LMBs through rational electrolyte design with fluorinated siloxane solvent.

Enhancing the Performance of Light-Emitting Electrochemical Cells by Incorporating Quantum Dots

Enhancing the Performance of Light-Emitting Electrochemical Cells by Incorporating Quantum Dots

On the structural evolution of pristine P2-type Na0.67Ni0.33Mn0.67O2 for symmetric full cell application

P2 type Na0.67Ni0.33Mn0.67O2 (NNMO) is a widely studied layered oxide cathode material for sodium-ion batteries (SIBs) because of its high capacity (160 mAhg-1 practically achieved) and broad voltage window (2–4.5 V). The redox activity in NNMO is shown by both Ni2+ and Mn4+ ions, making it a prospective symmetric SIB electrode material. The average working potential of the symmetric full cell is less due to the limited average working voltages of both the redoxes in a half cell between 2 V and 4.5 V, resulting in poor energy density. Herein, we report the feasibility of the NNMO symmetric full cell by widening the operational voltage window of NNMO. The electrochemical performance of NNMO half cells between 0.01 V and 4 V and the structural evolution during cycling are mapped by ex-situ XRD. Na0.44MnO2-like tunnel-type structure (Pbam) with high Na+ content (>0.90) exists at potentials close to the Mn3+/4+ redox reaction during cycling. The phase change was relatively reversible, implying that the NNMO anode works at such low voltages without the hazard of severe capacity losses. The symmetric full cell made using NNMO cycled between 0.01 V and 3 V and, at C/10 rate, delivered a capacity of ∼68 mAhg−1.

Suppressing Structure Delamination for Enhanced Electrochemical Performance of Solid Oxide Cells.

Reversible solid oxide cells (rSOCs) have significant potential as efficient energy conversion and storage systems. Nevertheless, the practical application of their conventional air electrodes, such as La0.8Sr0.2MnO3-δ (LSM), Ba0.5Sr0.5Co0.8Fe0.2O3-δ (BSCF), and PrBa0.8Ca0.2Co2O5+δ (PBCC), remains unsatisfactory due to interface delamination during prolonged electrochemical operation. Using micro-focusing X-ray absorption spectroscopy (µ-XAS), a decrease (increase) in the co-valence state from the electrode surface to the electrode/electrolyte interface is observed, leading to the above delamination. Utilizing the one-pot method to incorporate an oxygen-vacancy-enriched CeO2 electrode into these air electrodes, the uniform distribution of the Co valence state is observed, alleviating the structural delamination. PBCC-CeO2 electrodes exhibited a degradation rate of 0.095mVh-1 at 650°C during a nearly 500-h test as compared with 0.907mVh-1 observed during the 135-h test for PBCC. Additionally, a remarkable increase in electrolysis current density from 636 to 934mAcm-2 under 1.3V and a maximum power density from 912 to 989mWcm-2 upon incorporating CeO2 into PBCC is also observed. BSCF-CeO2 and LSM-CeO2 also show enhanced electrochemical performance and prolonged stability as compared to BSCF and LSM. This work offers a strategy to mitigate the structural delamination of conventional electrodes to boost the performance of rSOCs.

Enhancing LSCF-based air electrode durability: Insights into sulfur poisoning and air purification

The electrochemical performance of perovskite-type air electrodes in solid oxide cells is strongly affected by a trace amount of SO2 as the air impurity. The present work aims to study air purification efficiency in suppressing the degradation rate for the LSCF-GDC air electrode while operating under different SO2 concentrations. For this purpose, the electrochemical performance of symmetrical cells was evaluated using impedance spectra measured over 320 h and compared with intrinsic electrode degradation in synthetic air. Accordingly, the intrinsic degradation rate was measured at 0.05 mΩ cm2 h−1 while exposing the cell to synthetic air containing 10 and 100 ppb SO2, causing a severe increase to 0.17 and 0.30 mΩ cm2 h−1, respectively. Nevertheless, the calculated degradation rate under purified air containing 100 ppb SO2 was similar to the LSCF-GDC intrinsic degradation rate, representing the high practicality of filter material to adsorb SO2 species. Interpreting the impedance spectra using a distribution of relaxation times (DRT) and a complex nonlinear least squares fit (CNLS) revealed that the intrinsic degradation mechanisms were the limitation of dissociative surface adsorption of oxygen and charge transfer to the adsorbed oxygen. At the same time, inhibition of the O2 adsorption caused by the deposition of SrO, SO32−, and SrSO4 phases and increasing surface diffusion resistance for the adsorbed oxygen atoms were the rate-determining steps in SO2-containing synthetic air. Lastly, the effective suppression of degradation rate by gas purification indicates an extensive use of filter material to extend the lifespan of SOCs.

Factors Governing the Presodiation Degree of Hard Carbon Anode for Sodium Ion Batteries

This study explores the improvement of sodium-ion batteries by presodiating hard carbon anodes, with the goal of reducing initial capacity loss and enhancing the overall electrochemical performance of full cells. Using Na-biphenyl for presodiation and exploring its effects under various conditions—such as electrolyte composition and electrode loading—alongside two different cathode configurations (Na-stoichiometry Na3V2(PO4)3 and Na-deficient Na0.44MnO2), we seek to elevate the overall electrochemical performance of sodium-ion batteries. Our findings reveal the significance of finely tuning presodiation conditions leading to significant improvements in both initial Coulombic Efficiency and the cycling stability of full cells. Furthermore, a comparative analysis of the solid electrolyte interface formed through both chemical and electrochemical presodiation methods reveals significant similarities in impedance characteristics. This research provides valuable insights into the impact of presodiation on hard carbon anodes, offering a pathway to enhance the practical application of presodiation technology for sodium-ion batteries.

Regulating ionic transport and interface chemistry via high-dielectric BaTiO3 porous scaffolds for aqueous Zn-ion batteries

Rechargeable aqueous Zn-ion batteries (AZIBs) are gaining considerable attention as alternatives to Li-ion batteries owing to their excellent safety, high energy density, low cost, and environmental friendliness. However, their Zn anodes suffer from severe dendritic growth, the hydrogen evolution reaction (HER), and corrosion, which limit the commercialization of AZIBs. To address this challenge, we designed a solution involving the development of a high-dielectric hydrophobic BaTiO3 (BTO) porous scaffold layer that is strategically applied to the Zn surface. This BTO layer effectively impedes the dendritic growth of Zn. The distinct polarizability of the BTO layer actively diminishes the electric-field gradient, thereby minimizing the interaction between the H2O molecules and the Zn surface. This phenomenon helps suppress dendritic growth, thus ensuring the uniform deposition of Zn and preventing the HER. The electrochemical performance of a symmetric cell containing the Zn@BTO electrode exhibits low-voltage polarization and stable charge–discharge performance for up to 500 h. In addition, a full-cell AZIB containing a high-capacity α-MnO2 cathode and Zn@BTO anode exhibits good rate capability and a long life of up to 500 cycles. This study demonstrates the development of a cost-effective dendrite-free Zn anode integrated with a highly dielectric hydrophobic BTO porous scaffold layer as a stable Zn–electrolyte interface layer for high-performance AZIBs.

Ru-Ce0.7Zr0.3O2-δ as an Anode Catalyst for the Internal Reforming of Dimethyl Ether in Solid Oxide Fuel Cells.

The development of direct dimethyl ether (DME) solid oxide fuel cells (SOFCs) has several drawbacks, due to the low catalytic activity and carbon deposition of conventional Ni-zirconia-based anodes. In the present study, the insertion of 2.0 wt.% Ru-Ce0.7Zr0.3O2-δ (ruthenium-zirconium-doped ceria, Ru-CZO) as an anode catalyst layer (ACL) is proposed to be a promising solution. For this purpose, the CZO powder was prepared by the sol-gel synthesis method, and subsequently, nanoparticles of Ru (1.0-2.0 wt.%) were synthesized by the impregnation method and calcination. The catalyst powder was characterized by BET-specific surface area, X-ray diffraction (XRD), field emission scanning electron microscopy with an energy-dispersive spectroscopy detector (FESEM-EDS), and transmission electron microscopy (TEM) techniques. Afterward, the catalytic activity of Ru-CZO catalyst was studied using DME partial oxidation. Finally, button anode-supported SOFCs with Ru-CZO ACL were prepared, depositing Ru-CZO onto the anode support and using an annealing process. The effect of ACL on the electrochemical performance of cells was investigated under a DME and air mixture at 750 °C. The results showed a high dispersion of Ru in the CZO solid solution, which provided a complete DME conversion and high yields of H2 and CO at 750 °C. As a result, 2.0 wt.% Ru-CZO ACL enhanced the cell performance by more than 20% at 750 °C. The post-test analysis of cells with ACL proved a remarkable resistance of Ru-CZO ACL to carbon deposition compared to the reference cell, evidencing the potential application of Ru-CZO as a catalyst as well as an ACL for direct DME SOFCs.

Structural Effects of 3D Inkjet-Printed Ni(O)-YSZ Pillared Electrodes on Performances of Solid Oxide Electrochemical Reactors.

Increasing densities of reaction sites for gaseous reactants in solid oxide electrochemical reactors (SOERs), is a key strategy for achieving enhanced performance in either fuel cell or electrolysis modes. Fabrication of 3D structured components in SOERs can enhance those densities of reaction sites, which is achieved by 3D inkjet printing with high reproducibility, having developed inks with appropriate properties. First, the effects of pillar geometries on SOER performances are predicted through numerical simulations, enabling subsequent 3D printing to focus on the more effective geometries. Herein, the study reports the results of experimental validation of those predictions by evaluating the electrochemical performances of cells with various heights of 3D inkjet-printed Ni(O)- yttria stabilized zirconia (YSZ) pillars and YSZ pillars. Those measurements prove that increasing pillar heights generally increases SOER peak power densities in fuel cell mode and increased current densities at the thermoneutral potential (1.285V) in steam electrolysis mode, as predicted by simulations. With increasing pillar heights, more limitations in performance enhancement are found with YSZ electrolyte pillars than with Ni-YSZ pillars, again as predicted by simulations. The subsequent microstructural analysis of Ni-YSZ pillars proves the suitability of the Ni(O)-YSZ composite particle ink formulation and the reliability of 3D printing.

Enhancing room temperature performance of solid-state lithium cell via a facile solid electrolyte-cathode interface design

Herein, we report the enhanced electrochemical performance of a solid-state cell realized through an engineered solid electrolyte-cathode interface via a simple casting technique. The ceramic-in-polymer solid electrolyte sample with 15 wt% NASICON-type Li1·2Sn0·9Zr0·9Al0·2(PO4)3 ceramic filler in a P(VDF-HFP) matrix (CPSE15) showed the highest room temperature conductivity of ∼1.1 × 10−4 S cm−1 and lithium-ion transference number of ∼0.60. The symmetric Li|CPSE15|Li cell showed a consistent voltage profile with an over-potential of ∼45 mV for 750 h at a current density of 0.1 mA cm−2. CPSE15 slurry was directly cast onto the LiFePO4 (LFP) cathode layer using a doctor-blade coating method to obtain a cathode-electrolyte assembly. Subsequently, a full cell fabricated using this assembly and lithium metal delivered an initial discharge capacity of ∼157 mAh g−1 at 0.2C. Further, the cell exhibited ∼90 mAh g−1 discharge capacity at 1C and sustained 500 charge-discharge cycles at room temperature. The engineered interface in cathode-electrolyte assembly enabled this cell to outperform its conventionally fabricated counterpart with a stacked LFP cathode sheet and freestanding CPSE15 electrolyte membrane, which was attributed to a lower interfacial resistance (∼51%) of the former.

Understanding the synergistic improving adsorbed and catalytic activity of polysulfide by design of oxygen vacancies and Li+ lithiation/delithiation behavior in Titanium Oxide separator

The commercialization of lithium-sulfur (Li-S) battery is hindered by severe shuttle effect and sluggish electrochemical kinetics, which are induced by the high dissolution of intermediate lithium polysulfides (LiPSs) in cathode side. Here, we describe a strategy towards efficient adsorption and conversion of polysulfides by designing a functional TiO2-based separator. The enhanced overall electrochemical performance of cells is highly related to the synergistic effect of mutually transformational of TiO2 and LixTiO2 and the existence of oxygen vacancies (OVs). During the charging and discharging process of Li-S cell, the in-situ formation of LixTiO2 assigned to lithiation of anatase TiO2 plays a pivotal role in reversible adsorption and desorption of LiPSs. In addition, we also discussed the effect of OVs, which can act as active sites to accelerate electrochemical kinetics and exhibit stronger chemical interaction with LiPSs. The synergy of lithiation and delithiation process of TiO2 with OVs not only offers an effective pathway towards the improvement of LiPSs adsorption and catalytic performance but could also inspire new ideas on developing functional metal oxides modified separator for Li-S battery. We anticipate that this work will provide new avenues for Li-S battery commercialization.

0D-3D Superstructure of Biocarbon with FeCl3-Assisted for Electrochemical Symmetrical Supercapacitor

Biomass materials exhibit a diversity of macrostructures that can be derived or developed into various 0D-3D nanoscale structural designs with various different dimensions such as spherical, nanofiber, tubular, nanosheet, hierarchical, nanosphere, and honeycomb structures, when converted into activated carbon. This research converts oil palm empty fruit bunch fiber biomass into supercapacitor carbon material by optimizing the chemical activation process by varying the activating reagent. The active carbon conversion process includes precarbonization stages, chemical activation (KOH, FeCl3, and ZnCl2), carbonization, and physical activation. The resulting electrode was confirmed to have a morphology with a 0D to 3D structure (nanosphere, nanofiber and nanopore) due to the FeCl3 activator, so the resulting surface area was high (517.998 m/g). Biomass was successfully converted into carbon which was confirmed through through the resulting physical and electrochemical properties. The electrochemical performance of the sample supercapacitor cell was analyzed in a symmetric two-electrode system in 1 M H2SO4 electrolyte solution. The FeCl3-activated samples shows the highest specific capacitance of 256 F/g at a scan rate of 1 mV/s. In addition, oil palm empty fruit bunch fiber biomass is a potential raw material, as a carbon material for supercapacitor cells with high performance.

A novel platinum modified barium zirconate-based electrolyte for enhanced solid oxide fuel cell performance

Pt modified BaZr0.76Y0.2Ni0.04O3 (BZYN) is fabricated and characterized as a stable electrolyte for proton-conducting solid oxide fuel cell (H-SOFC). The utilization of X-ray diffraction method (XRD) and transmission electron microscopy (TEM) enables the identification of the presence of platinum (Pt) in both the crystal lattice sites and the grain interface. This occurrence contributes to a reduction in grain boundary resistance. Consequently, this phenomenon improves the conductivity of the electrolyte. The electrochemical performance of the single cell with Pt-modified BZY electrolyte is improved by the reduction of ohmic resistance and enhancement of ion migration. This signifies a noteworthy advancement in the creation of more efficient and durable proton-conducting SOFCs.

Effect of flow channel cross-section shape on the performance of proton exchange membrane electrolysis cell

To study the thermal and mass distribution in proton exchange membrane electrolytic cells (PEMEC), a two-phase numerical model of a single-channel electrolytic cell was established. The polarization performance and gas-heat distribution in a single-channel electrolytic cell under five different flow channel cross-sections (rectangle, trapezoid, inverted trapezoid, triangle, and circle) were studied. The findings indicate that the inverted trapezoidal flow channel’s gas buildup effect is rather severe in both the catalytic and diffusion layers. In the trapezoidal flow channel, the temperature of the proton exchange membrane region is lower, and the electrochemical performance of the rectangular flow channel electrolytic cell is the best, with an improvement rate of up to 11.47%. The electrochemical performance of the triangular and circular flow channels is the worst.