Ultradispersed copper-bearing powders have been produced by the method of electrochemical cathode reduction from water-isopropanol solutions of copper dichloride. The dimensional and morphological properties of the obtained compounds have been studied using the procedure of atomic-power microscopy. It is shown that the introduction of isopropyl alcohol additions into the aqueous electrolyte composition causes a change of both the dimensional and qualitative features of the powders. The isopropyl alcohol admixture shifts the ratio between the components entering into the composition of the copper-bearing powders towards a greater content of copper oxide (I).