An electroacoustic echo method for studying the high-frequency (HF) electrical and elastic properties of piezoelectric materials in a finely dispersed state is described. The characteristics and relaxation time of electroacoustic echo for natural and artificial quartz powders are determined. Natural one is represented by the following types: smoky quartz, citrine, amethyst, recrystallized, granular and columnar. It is shown that natural quartz (especially citrine), has a higher electromechanical coupling coefficient than artificial quartz. The amplitudes of HF electric field are determined, at which the saturation mode of the echo signals is observed.