Electrical Surface Charge Density Research Articles

A Simulation study of the output characteristics of freestanding Triboelectric nanogenerators with interdigitated electrodes for self-powered sensing application

Diverse forms of mechanical energy are available in environmental routine activities. These energy forms can be harvested, measured and converted to produce electricity at nanogenerator (NG) and micro-scale levels based on the phenomenon of triboelectrification. These motivate this work to develop a self-powered sensing device to detect and monitor static and dynamic processes associated with mechanical activities. The significance is to study the output characteristics of freestanding mode triboelectric nanogenerator (TENG) with multiple units of metal and dielectric electrodes. The integrated modeling environment of COMSOL Multiphysics software was employed for the simulation study of the proposed TENG. The system output responses considered for analysis includes, open circuit electric potential and short circuit surface charge density. For the open circuit, the electric potential was achieved at maximum value of 10kV, while for short circuit surface charge density, the electric potential was achieved at maximum value of 27 Cm-2. The study results revealed that the input parameter of contact displacement of electrodes is proportional to the output electrical potential of the system. Hence, the efficiency of TENG can be deployed for energy harvesting and sensing of mechanical variables.

The mechanism of EP/SiC coating modulated DC flashover characteristics of epoxy composites in SF6/N2 mixtures

Surface flashover is an inevitable insulation issue for basin-type insulators in gas-insulated switchgears/lines, which significantly challenges the reliability of the electrical power systems. Previous studies have indicated that polymer/semiconductor-filler composite coatings effectively improve the insulation properties; however, the influence mechanism of the coating materials on flashover has not been demonstrated from a molecular perspective. In this work, epoxy/silicon-carbide (EP/SiC) composites were coated onto an EP substrate. The energy-level structure, surface trap, surface charging, and DC flashover voltage in SF6/N2 were calculated and characterized, and the process by which the tailored molecular energy level influences surface charge transport and flashover characteristics was elucidated. The incorporating of SiC particles reduced the width of the bandgap and introduced shallow traps, which improved carrier mobility and surface conductivity. Quantitative analysis of charge transport indicated that the improved carrier mobility and reduced surface trap level accelerated the surface charge dissipation. This reduced the tangential electrical field distortion and surface charge density and further impeded gas ionization. When the SiC concentration was 15 wt%, the flashover performance improved by 20.88%. This study describes the mechanism by which the EP/SiC coating regulates the surface charge distribution to improve the surface flashover performance by establishing a relationship among the microscopic molecular energy-level structures, mesoscopic charge transport, and macroscopic discharge phenomena.

A sharp immersed method for electrohydrodynamic flows accompanied by charge evaporation

AbstractThis article presents a sharp immersed method for simulating electrohydrodynamic (EHD) flows that involve charge evaporation. This well‐known multi‐scale, multi‐physics problem is widely used in various fields, including industry and medicine. The method adopts a fully sharp model, where surface tension and Maxwell stress are treated as surface forces and free charges are concentrated on the zero thickness liquid‐vacuum interface. Incorporating charge evaporation imposes strict restrictions on the time‐step, as the rate of evaporation sharply increases with surface evolution. To overcome this challenge, an iterative algorithm that couples the electric field and surface charge density is proposed to obtain accurate results, even with significantly large time‐steps. To mitigate the numerical residuals near the interface, which may introduce parasitic flows and cause numerical instability, an immersed interface method‐based iterative projection method for the Navier–Stokes equations is proposed, in which a traction boundary condition involving multiple surface forces is imposed on the sharp interface. Numerical experiments were carried out, and the results show that the method is splitting‐error‐free and stable. The sharp immersed method is applied to simulate the electric‐induced deformation of an ionic liquid drop with charge evaporation. The results indicate that charge evaporation can suppress the sharp development of Taylor cones at the ends of the drops. These findings have significant implications for the design and optimization of EHD systems in various applications.

Nanoscale Topography of Anodic TiO2 Nanostructures Is Crucial for Cell-Surface Interactions.

Anodic titanium dioxide (TiO2) nanostructures, i.e., obtained by electrochemical anodization, have excellent control over the nanoscale morphology and have been extensively investigated in biomedical applications owing to their sub-100 nm nanoscale topography range and beneficial effects on biocompatibility and cell interactions. Herein, we obtain TiO2 nanopores (NPs) and nanotubes (NTs) with similar morphologies, namely, 15 nm diameter and 500 nm length, and investigate their characteristics and impact on stem cell adhesion. We show that the transition of TiO2 NPs to NTs occurs via a pore/wall splitting mechanism and the removal of the fluoride-rich layer. Furthermore, in contrast to the case of NPs, we observe increased cell adhesion and proliferation on nanotubes. The enhanced mesenchymal stem cell adhesion/proliferation seems to be related to a 3-fold increase in activated integrin clustering, as confirmed by immunogold labeling with β1 integrin antibody on the nanostructured layers. Moreover, computations of the electric field and surface charge density show increased values at the inner and outer sharp edges of the top surfaces of the NTs, which in turn can influence cell adhesion by increasing the bridging interactions mediated by proteins and molecules in the environment. Collectively, our results indicate that the nanoscale surface architecture of the lateral spacing topography can greatly influence stem cell adhesion on substrates for biomedical applications.

THE EFFECT OF PARGILINE, SPERMINE AND THEIR COMBINATIONS ON ANDROGEN-DEPENDENT AND ANDROGEN-INDEPENDENT HUMAN PROSTATE CANCER CELLS in vitro

Summary. A series of studies on enhancing the cytotoxic effect of spermine on human prostate cells by affecting the enzymes of its metabolism has been continued. Aim: to investigate effects of pargyline, spermine and their combinations the survival, ζ-potential and surface charge and cytomorphological properties of human prostate cancer cells in culture. Object and methods: studies were conducted on cell cultures: differentiated androgen-dependent LNCaP cell line and low-differentiated androgen-independent DU-145 cell line. Cell survival was determined in the trypan blue assay. The effect of the investigated compounds, both individually and in combination, on the viability and proliferative activity of cells was assessed by the colorimetric method – by staining living cells with a solution of crystal violet in methanol. Biophysical parameters (ζ-potential and surface electric charge density) were determined according to the method cellular microelectrophoresis. Cytomorphological characteristics were studied on preparations of cells grown on coverslips, fixed and stained with hematoxylin and eosin (magnification 1000×). Results: for LNCaP cells, the IC50 of pargyline was 2.2 mM, and the IC50 of spermine was 1.5 mM. For DU-145 cells, the IC50 of pargyline was 2.35 mM, the IC50 of spermine was 5.0 mM. According to biophysical indicators, spermine caused an inversion of the sign of the electric charge in cells of the LNCaP line. Pargyline did not exert such an effect, the charge remained negative, demonstrating an inverse dependence on its concentration. The combination of pargyline and spermine increased the cytotoxic effect of spermine on LNCaP cells, but did not affect the value of their ζ-potential and surface charge density, the positive sign of which, caused by the effect of spermine, was preserved. At the same time, pargyline completely eliminated spermine-induced inversion of the sign of the total surface charge of DU-145 cells, returning it to the normal negative values. Conclusions: it is shown that the differentiated androgen-dependent cells of the LNCaP line with the combined use of pargyline and spermine demonstrated an enhancement of the cytotoxic effect of spermine. At the same time, low-differentiated cells of the DU-145 line, which do not have androgen receptors, were more resistant to the effects of both pargyline and pargyline in combination with spermine. Pargyline also reversed spermine-induced inversion of the sign of the total surface charge of DU-145 cells, returning it to normal negative values. Cytomorphological changes that occurred under the influence of both pargyline alone and in its combination with spermine demonstrate mainly the apoptotic pathway of cell death in the androgen-independent DU-145 line, while in the androgen-dependent LNCaP line, a smaller proportion of cells were in a state of apoptosis.

Revisiting the effects of electrostatic forces on the lifting of sand particles in dust storms

We derived theoretical formulations for the fluid threshold of conducting and insulating sand particles under an imposed electric field. Our analysis reveals a non-monotonic dependency of the fluid threshold on particle diameter, imposed electric field, and surface charge density. For conducting particles, electrostatic forces lead to a reduction of the fluid threshold by up to 31%. In contrast, for negatively charged insulating particles, electrostatic forces enhance the fluid threshold by up to 76%. Unexpectedly, electrostatic forces either enhance or inhibit the fluid threshold by up to 30%, depending on the imposed electric field and surface charge density.

Optimization of insulators in ±550 kV HVDC GIS for offshore wind platform considering charge accumulation

High voltage direct current (HVDC) gas-insulated switchgear (GIS) plays a crucial role in developing far offshore wind power and attaining renewable energy and interconnection objectives. However, surface charge accumulation reduces the surface flashover voltage and restricts the development of DC GIS at the higher voltage. In this paper, the design criteria for a ± 550 kV DC insulator were proposed based on DC insulation testing. The influence of geometry on electric field and charge distribution of obtuse conical insulators, disk insulators, and conical insulators was systematically investigated. The results show that the threshold of the tangential electric field under the DC superimposed lighting impulse test for the ±550 kV DC insulator is 11.1 kV/mm. The simulation results indicate that the increasing inclination of the insulator enhances the normal electric field and surface charge density, while the increase in insulator size diminishes the tangential electric field dramatically. The obtuse conical insulator with an upper surface inclination angle of 30°, a lower surface included angle of 140°, and a diameter of 812.5 mm is ideal for ±550 kV DC GIS. The obtained results may provide guidance for the compact design of insulators and the development of DC GIS.

Electro-osmotic flow in different phosphorus nanochannels

The electrokinetic transport in a neutral system consists of an aqueous NaCl solution confined in a nanochannel with two similar parallel phosphorene walls and is investigated for different black, blue, red, and green phosphorene allotropes in the presence of an external electric field in the directions x (parallel to the walls roughness axis) and y (perpendicular to the walls roughness axis). The results show that irrespective of the electric field direction, the thickness of the Stern layer increases with the increase in the magnitude of the negative electric surface charge density (ESCD) on the nanochannel walls, and it also increases with the increase in the roughness ratio for different allotropes. Moreover, three different regimes of Debye–Hückel (DH), intermediate, and flow reversal appear as the absolute value of the negative ESCD on the walls grows. With the increase in the absolute value of the negative ESCD, in the DH regime, the flow velocity grows, then in the intermediate regime, it decreases, and finally, at sufficiently high ESCD, the flow reversal occurs. When the external electric field is applied in the y direction, the dynamics of the system are slower than that of the x direction; therefore, the flow reversal occurs at the smaller absolute values of the negative ESCD.

Precise control of CNT-DNA assembled nanomotor using oppositely charged dual nanopores.

Inspired by nature, nanomotors have been developed that have great potential in microfluidics and biomedical applications. The development of the rotary nanomotor, which is an important type of nanomotor, is an essential step towards intelligent nanomachines and nanorobots. Carbon nanotubes (CNTs) are a crucial component of rotary nanomotors because of their excellent mechanical properties and adaptability to the human body. Herein, we introduce a convenient manipulation method for controlling the rotation of a nanomotor assembled from CNT-DNA, which uses the electroosmosis effect within oppositely charged dual nanopores. The central components of this nanomotor consist of a double-walled carbon nanotube (DWCNT) and a circular single-stranded DNA (ssDNA), which acts as the driving element for the nanomotor. Selective ion transport through charged nanopores can generate a robust electroosmotic flow (EOF), which serves as the primary power for the movement of circular ssDNA. The tangential force on the ssDNA is transmitted via electrostatic adsorption to the outer surface of the CNT, known as the rotor, resulting in the rotation of the nanomotor. By simply adjusting the electric field and surface charge density of each nanopore, rotational variables including speed, output power and torque can be readily regulated in this work. This proof-of-concept research provides a promising foundation for the future development of the precise control of nanomotors.

Content Size-Dependent Alginate Microcapsule Formation Using Centrifugation to Eliminate Empty Microcapsules for On-Chip Imaging Cell Sorter Application.

Alginate microcapsules are one of the attractive non-invasive platforms for handling individual cells and clusters, maintaining their isolation for further applications such as imaging cell sorter and single capsule qPCR. However, the conventional cell encapsulation techniques provide huge numbers of unnecessary empty homogeneous alginate microcapsules, which spend an excessive majority of the machine time on observations and analysis. Here, we developed a simple alginate cell encapsulation method to form content size-dependent alginate microcapsules to eliminate empty microcapsules using microcapillary centrifugation and filtration. Using this method, the formed calcium alginate microcapsules containing the HeLa cells were larger than 20m, and the other empty microcapsules were less than 3m under 4000 rpm centrifugation condition. We collected cell-containing alginate microcapsules by eliminating empty microcapsules from the microcapsule mixture with simple one-step filtration of a 20 m cell strainer. The electrical surface charge density and optical permeability of those cell-encapsulated alginate microcapsules were also evaluated. We found that the surface charge density of cell-encapsulated alginate microbeads is more than double that of cells, indicating that less voltage is required for electrical cell handling with thin alginate gel encapsulation of samples. The permeability of the alginate microcapsule was not improved by changing the reflective index of the medium buffer, such as adding alginate ester. However, the minimized thickness of the alginate gel envelope surrounding cells in the microcapsules did not degrade the detailed shapes of encapsulated cells. Those results confirmed the advantage of alginate encapsulation of cells with the centrifugation method as one of the desirable tools for imaging cell sorting applications.

Liquid-Polymer Contact Electrification: Modeling the Dependence of Surface Charges and ξ-Potential on pH and Added-Salt Concentration.

Here, a mathematical model is presented, which accounts for the dependence of the surface electrical charge density (σ) on pH and the concentration of added salts (Cs), generated when a water drop rolls or slides on the surface of a hydrophobic polymer, a process known as liquid-polymer contact electrification (LPCE). The same model was successfully applied to fit the isotherms of ξ-potential as a function of pH, reported in the literature by other authors for water-poly(tetrafluoroethylene) (PTFE) interfaces. Hence, the dependence of σ and ξ on pH was described using the same concept: acid-base equilibria at the water-polymer interface. Equilibrium constants were estimated by fitting experimental isotherms. The experimental results and the model are consistent with a number of 10-100 acid-base sites/μm2. The model predicts the increase of |σ| and |ξ| with pH in the range of 2-10 and the existence of a zero-charge point at pHzcp ≅ 3 for PTFE (independent of Cs). Excellent fits were obtained with Ka/Kb ∼ 9 × 107, where Ka and Kb are the respective acid and base equilibrium constants. On the other hand, the observed decrease in |σ| and |ξ| with Cs at fixed pH is quantitatively described by introducing an activity factor associated with the quenching of water activity by the salt ions at the polymer-water interface, with quenching constant Kq. Additionally, the quenching predicts a decrease in |σ| and |ξ| at extreme pH, where I > (1/Kq) (I: ionic strength), in agreement with literature reports.

Tracking electronic band alignment across 2D bridge-channel MoS2 during charge transport

Commanding charge carrier diffusion in semiconducting channels requires the precise and realistic experimental realization of electronic energy band alignments at the interfaces and within the channels. We have demonstrated a non-contact and direct way to accurately probe the energy band bending at nanoscale spatial precision on MoS2 flakes laid on gold electrodes by mapping the surface potential landscape at non-equilibrium conditions during carrier injection. By systematically varying the charge carrier injection, the contrast gradient in surface potential profiles is studied along the MoS2 channel. Corresponding interfacial parameters, such as surface electric field (ξ), built-in potential (Ψbi), and space charge density (σ), are experimentally determined.

Encoding Manipulation of DNA-Nanoparticle Assembled Nanorobot Using Independently Charged Array Nanopores.

During the past decades, scientists have developed different kinds of nanorobots based on various driving principles to realize controlled manipulation of them for potential applications like medical diagnosis and directed cargo delivery. In order to design a nanorobot with advantages of simple operation and precise control that can enrich the familyof intelligent nanorobots, an encoding manipulation method is proposed to control the movement of a DNA-nanoparticle assembled nanorobot by combing electrophoresis and electroosmosis effect in independently charged array nanopores. The nanorobot is composed of one nanoparticle and one or two ssDNAs. ssDNAs act as the legs of the nanorobot. The selective ion transport through charged nanopores can induce cooperation and competition between the electroosmosis and electrophoresis, which is the main power to activate the nanorobot. Thus by simply switching the applied electric field and surface charge density of each nanopore which is defined as the encoded nanopore according to a predetermined strategy, the well-controlled encoding manipulation including capturing, releasing, jumping, and crawling of the nanorobot is realized in this work. The study is expected to realize its value in many interesting applications like drug delivery, nanosurgery, and so on in the near future.

Elucidation of Response Mechanism of a Potentiometric Sweetness Sensor with a Lipid/Polymer Membrane for Uncharged Sweeteners

Nowadays, the utilization of a taste sensor with lipid/polymer membranes is one of the most accurate and objective ways to evaluate the tastes of solutions. However, it has been difficult to evaluate uncharged sweet substances, such as sucrose, because the conventional taste sensor uses the potentiometric measurement, which is mainly based on changes in the surface electric charge density of the membrane. Previous studies have reported that a sweetness sensor called GL1 can evaluate the sweetness of sugars and sugar alcohols, and is commercially available for food, beverage, and pharmaceutical industries. However, the response mechanism of GL1 has not been fully elucidated. In this study, we focus on clarifying the effect of concentrations and types of metal ions in the conditioning solution on the response mechanism of the sweetness sensor GL1. Moreover, according to the different concentrations and types of metal ions in conditioning solutions, the complex formation and the hydrated radius were considered to influence the membrane potential measured in a reference solution and the sensor responses. The purpose of this study is to elucidate the response mechanism and improve the selectivity and sensitivity of the sweetness sensor.

Computational physics in action: the problem of a charged conducting toroid

We present a comprehensive numerical analysis of the peculiarities of the electric field, equipotential surfaces, capacitance, and surface charge density at different thickness of a charged conducting ring. First, we review the filamentary ring case and prove that, unlike a sphere, there is a non-zero electric force inside it. We find that at relatively large values of the ring thickness the electric field has a local maximum inside the hole of the toroid. We also show the existence of a region of space, where the electric field is substantially homogeneous.

Studying properties of corona electret based on compositions of polylactic acid and bentonite

The study focuses on the composites of polylactic acid and bentonite as well as corona electrets based on them. The paper explores rheological, electrical, physical and mechanical properties of the composites as well as the effect of corona charging on their properties. Differential scanning calorimetry was used to assess transition temperatures in the compositions. Surface potential, electric field strength and effective surface charge density were measured. Optimal performance was shown by the compositions of polylactic acid with 4% bentonite.

A large piezoelectric response in highly-aligned electrospun poly(vinylidene fluoride/trifluoroethylene) nanofiber webs for wearable energy harvesting

In this study, highly-aligned and molecularly oriented poly(vinylidene fluoride/trifluoroethylene) [P(VDF/TrFE)] nanofiber webs were fabricated and their piezoelectric response was investigated. Using systematic post-treatments under appropriate conditions, a significant enhancement of the piezoelectric response in the P(VDF/TrFE) nanofiber webs was observed for the first time. The high-quality nanofibers exhibited a large output voltage of 0.4 V. The short-circuit current of post-treated nanofibers was found to be 731.25 μA, which increased about 330 times and the surface electric charge density was found to be 0.64 nC cm−2, which was about 2.7 times higher than those of the as-spun nanofibers. The large enhancement of piezoelectric response of the nanofibers is attributed to the additional stretching, annealing and poling of the as-spun nanofibers under the appropriate post-treatment conditions. The results highlight the potential of the high-quality P(VDF/TrFE) nanofibers to be used as wearable piezoelectric energy harvesters and other flexible self-powered portable devices.

Development of Taste Sensor to Detect Non-Charged Bitter Substances.

A taste sensor with lipid/polymer membranes is one of the devices that can evaluate taste objectively. However, the conventional taste sensor cannot measure non-charged bitter substances, such as caffeine contained in coffee, because the taste sensor uses the potentiometric measurement based mainly on change in surface electric charge density of the membrane. In this study, we aimed at the detection of typical non-charged bitter substances such as caffeine, theophylline and theobromine included in beverages and pharmaceutical products. The developed sensor is designed to detect the change in the membrane potential by using a kind of allosteric mechanism of breaking an intramolecular hydrogen bond between the carboxy group and hydroxy group of aromatic carboxylic acid (i.e., hydroxy-, dihydroxy-, and trihydroxybenzoic acids) when non-charged bitter substances are bound to the hydroxy group. As a result of surface modification by immersing the sensor electrode in a modification solution in which 2,6-dihydroxybenzoic acid was dissolved, it was confirmed that the sensor response increased with the concentration of caffeine as well as allied substances. The threshold and increase tendency were consistent with those of human senses. The detection mechanism is discussed by taking into account intramolecular and intermolecular hydrogen bonds, which cause allostery. These findings suggest that it is possible to evaluate bitterness caused by non-charged bitter substances objectively by using the taste sensor with allosteric mechanism.

In-Gel Isolation and Characterization of Large (and Other) Phages.

We review some aspects of the rapid isolation of, screening for and characterization of jumbo phages, i.e., phages that have dsDNA genomes longer than 200 Kb. The first aspect is that, as plaque-supporting gels become more concentrated, jumbo phage plaques become smaller. Dilute agarose gels are better than conventional agar gels for supporting plaques of both jumbo phages and, prospectively, the even larger (>520 Kb genome), not-yet-isolated mega-phages. Second, dilute agarose gels stimulate propagation of at least some jumbo phages. Third, in-plaque techniques exist for screening for both phage aggregation and high-in-magnitude, negative average electrical surface charge density. The latter is possibly correlated with high phage persistence in blood. Fourth, electron microscopy of a thin section of a phage plaque reveals phage type, size and some phage life cycle information. Fifth, in-gel propagation is an effective preparative technique for at least some jumbo phages. Sixth, centrifugation through sucrose density gradients is a relatively non-destructive jumbo phage purification technique. These basics have ramifications in the development of procedures for (1) use of jumbo phages for phage therapy of infectious disease, (2) exploration of genomic diversity and evolution and (3) obtaining accurate metagenomic analyses.

A discrete phase hybrid continuum-atomistic model for electrokinetics in nanofluidics

The ever-growing field of micro- and nanotechnology has a great deal of interest in simulating dynamic phenomena of multiscale systems. Hybrid approaches that produce a trade-off between accuracy and computational costs play a key role in this area. In this study, an improved hybrid continuum-atomistic model is proposed for the simulation of electroosmotic flows in nanochannels. The aqueous solvent phase is modeled by the continuum four-way coupled Navier-Stokes equations, while a Lagrangian approach is used for the ion transport. Different forces, including the drag, buoyancy, Brownian, electrostatic, and ion-ion/wall-ion collision, and torques, including the drag and collision, govern the motion of ion particles. The ion-ion/wall-ion collision is taken into account by a discrete phase model, and the electric field is derived by the Poisson-Boltzmann closure. Results of the model, such as the change in bulk velocity with surface electric charge density, are validated by several molecular dynamics simulations and experimental observations available in the literature. It is shown that the present hybrid model is capable of predicting the main features of the problem. Moreover, the significance of different forces and the other alternative for modeling the external electric field, i.e., the discrete Coulomb’s approach with the modified particle mesh Ewald boundary treatment, are also examined. The proposed model would be extremely useful for future studies on the electrokinetics in nanochannels, especially in more complex geometries where the molecular dynamics approaches are limited due to the computational costs.