Electrical Insulation Performance Research Articles

Study on the Influence of Nanofiller Additives in Enhancing Electrical Insulation Performance and Thermal Properties of Biodegradable Oils for Electrical Insulation Applications

Study on the Influence of Nanofiller Additives in Enhancing Electrical Insulation Performance and Thermal Properties of Biodegradable Oils for Electrical Insulation Applications

Numerical Simulation of Galvanic Corrosion and Electrical Insulation for TC4/304 Galvanic Couple.

The galvanic corrosion and electrical insulation between TC4 Ti-alloy and 304 stainless steel coupled in pipe joints were investigated using the finite element method. The results obtained from polarization were applied as boundary conditions. The simulation incorporated secondary current distribution with chemical species transport and laminar flow. COMSOL modeling provided calculated values that showed good agreement with experimental measurements. The model was utilized to examine the influence of geometric and environmental factors, including insulation resistance, insulation distance, pipe diameter, temperature, and electrolyte concentration, on the galvanic corrosion process. The results indicated that electrical insulation performance significantly affects the corrosion process.

Effect and mechanism of phenyl content on the electrical insulation properties of silicone rubber

AbstractSilicone rubber is widely used in reinforced insulation of cable accessories due to its good electrical insulation and weather resistance. With the continuous improvement of high voltage transmission grade, higher requirements are put forward for the electrical insulation performance. The effect and mechanism of phenyl content on the electrical insulation properties of silicone rubber are investigated by the method of combination of experiments and molecular simulations. The experimental results show that the properties of silicone rubber are improved with the increase of phenyl content. Among them, the silicone rubber composite with phenyl content of 20 wt% has the best comprehensive performance. Compared with vinyl silicone rubber, the dielectric constant at 50 Hz decreases from 3.50 to 2.95, and the breakdown strength increases by 38.03%, from 56.59 to 78.11 kV/mm. In addition, the tensile strength and elongation at break are 5.44 MPa and 456%, respectively. The molecular simulation results show that with the increase of phenyl content, the glass transition temperature increases, the mean square displacement decreases, and the free volume decreases, which macroscopically leads to the change of electrical properties of the silicone rubber material. This work has a certain guiding significance for improving the electrical properties of silicone rubber for cable accessories.

Self-healing and degradable functionalization of EVA hot-melt adhesives based on disulfide bonds and polymer free radical copolymerization

This study aims to provide a new approach for the industrialization of self-healing adhesive or membrane materials. EVA hot melt adhesive has a market share of over 50 %, and it needs to be cured during use. It is a thermosetting resin that is difficult to recycle and reuse. In response to the defects mentioned above, we developed a self-healing and degradable EVA-based hot-melt adhesives (EDS) based on disulfide bonds and polymer free radical copolymerization. Specifically, we used divinyl disulfide as a crosslinking agent. Under the action of a peroxide initiator, disulfide and EVA formed a cross-linked network through free radical copolymerization. In the study, we characterized the Functionality and comprehensive performance of EDS using various testing methods such as FT-IR, DSC, and SEM. The research results indicate that EDS achieves self-healing and degradation by utilizing the rearrangement reaction of disulfide bonds under ultraviolet light and its reducibility under strong alkaline conditions. While maintaining the same electrical insulation performance, the barrier performance, thermal conductivity, aging resistance, and mechanical properties of EDS have all been improved. Meanwhile, we discussed the self-healing mechanism, curing kinetics, degradation mechanism, and aging mechanism of EDS.

Improved Corona Resistance of Epoxy Resin for Gas‐Insulated Equipment in Nitrogen Gas by Direct Fluorination

Direct fluorination has demonstrated efficacy in modulating the surface electrical properties of epoxy insulators and preventing surface charge accumulation. Comparative corona treatments were conducted on both surface fluorinated (modified) epoxy samples and untreated (virgin/original) samples using a modified electrode setup in a nitrogen (N2) atmosphere. The purpose was to evaluate the resistance of the modified epoxy surface layer against corona discharge. The results of ATR‐IR analysis and SEM surface and cross‐sectional imaging indicate that corona treatment did not alter the chemical composition of the fluorinated sample or the thickness of the fluorinated layer. Based on assessments of potential decay and water contact angle measurements, the surface conductivity of the modified sample was decreased by corona treatment. The wettability of fluorinated sample remained unchanged after corona treatment, and no soluble degradation products were produced. Conversely, the surface conductivity of the virgin sample exhibited an increase following corona treatment, accompanied by the formation of soluble degradation products. These results confirm that direct fluorination improves the epoxy insulator's discharge resistance in N2 and provides technical support for enhancing the electrical performance of epoxy insulators in gas insulated equipment. © 2024 Institute of Electrical Engineers of Japan and Wiley Periodicals LLC.

Electrical resistivity of cement-based materials through ion conduction mechanisms for enhancing resilient infrastructures

Cement-based materials (CBM) in humid environments, influenced by their inherent defects and the presence of pore solution, exhibit poor electrical insulation performance. Low electrical resistivity of cement-based materials poses a threat to the safety of resilient infrastructures, shortens the lifespan of materials, and increases the costs of maintenance and repair. In this work, we first elucidate two primary mechanisms for enhancing electrical resistivity: (1) inhibition of ion electromigration and (2) disruption of conduction paths. We then systematically summarize and discuss 16 potential methods for improving their electrical resistivity based on these mechanisms. It is indicated that among these 16 methods, early carbonation curing, the addition of high-activity mineral admixtures, and surface hydrophobic modification are particularly effective approaches. The combination of two or more methods can simultaneously exert their functions, thus maximizing the overall effectiveness. Future work is outlined with the aim of meeting the growing demand for cement-based materials with high electrical resistivity in the construction of resilient infrastructures.

Preparation and performance study of a new solvent-free insulation coating for low-voltage busbar

Abstract This study focuses on low-voltage busbar insulation and is committed to developing a new solvent-free insulation coating. A coating formula with specific properties was successfully synthesized by screening and optimizing various raw materials. A comprehensive and in-depth testing and analysis were conducted on the developed coatings’ physical properties, electrical insulation performance, heat resistance, and chemical corrosion resistance. The results show that the new solvent-free insulation coating has excellent heat resistance, corrosion resistance, and mechanical strength while maintaining good insulation performance. Compared with traditional insulation coatings, its solvent-free properties effectively reduce the emission of volatile organic compounds, meeting environmental requirements. This study provides a more efficient, reliable, and environmentally friendly solution for the insulation protection of the low-voltage busbar, which has significant practical application value and broad market prospects.

Simulation and Experimental Analysis of Electrical Characterization of Cap-Pin Glass Insulator under Uniform and Non-Uniform Pollution Layers

This paper deals with the analysis of the electrical performance of the glass cap-pin insulator under pollution conditions. The experiments are conducted in accordance with the IEC 60815 standard using artificial pollution (a distilled water mixture with NaCl). Several levels of applied voltage are used to evaluate the impact of both uniform and non-uniform pollution. For the same conditions, simulations are carried out using the COMSOL Multiphysics environment. Of interest, Leakage current waveforms are extracted from the current density and compared to those obtained from experiments. A proposed process, which aims to predict the effectiveness of the simulation in selecting appropriate parameters, geometry, boundaries etc., is investigated, where the findings are closely match the real model. Therefore, the electric field distribution on the insulator surface is presented, and 3D representations are considered for better visualizing the influence of the pollution on the insulating system. Accordingly, arcing discharges are characterized by high levels of electric field stress for uniform pollution, and dry-band arcing is simulated to correspond perfectly with laboratory findings for non-uniform pollution. Finally, this paper provides valuable insights into the electrical stress on the insulator under the effect of pollution conditions.

Smart heat management flexible cellulose films with enhanced thermal conductivity via assembling graphene and boron nitride nanosheets

Smart materials with high thermal conductivity are expected to have greatly application potential in thermal management for future electronic equipment. However, actual applications often require multifunctional properties of materials, such as high thermal conductivity (TC), good mechanical properties, and suitable electrical insulation performance. It is still a challenge to obtain such polymer composites with good comprehensive properties. Herein, the rational assembly of two-dimensional (2D) nanofillers of boron nitride nanosheets (BNNS) and graphene nanosheets (GNs) in nanofibrillated cellulose matrix is reported. The film shows 53.76 W m−1 K−1 of TC and 87.88 MPa of tensile strength. Meanwhile, the flexible film has the ability of response deformation by sensing the environmental temperature, which is promising for soft materials with excellent heat dissipation.

Unification of thermal conductivity, electrical insulation, and electromagnetic shielding: A bulk thermal conductive polymer from solid waste

In the context of the ongoing advancements in high-performance chips, heat dissipation, and electromagnetic shielding within electrical and electronic equipment are becoming increasingly intricate. Plastics have garnered widespread usage in electrical and electronic equipment as prevalent framework materials. However, the challenge persists in achieving a unification of electromagnetic interference (EMI) shielding, thermal conductivity (TC), and electrical insulation performance for plastics. Herein, we capitalize on the styrene–butadiene–styrene (SBS) copolymer to integrate the merits of polymers and magnetic minerals. Utilizing pyrrhotite (Pyr) tailings and waste polystyrene (PS) as raw materials, a formable block material denoted as PS-S@SBS/Pyr has been formulated. This material exhibits commendable performance in terms of TC, electrical insulation, and EMI shielding performance concurrently. The bidirectional bridging effect of SBS effectively reduces the interfacial thermal resistance between PS and Pyr. The TC of PS-S@SBS/Pyr can reach a maximum of 1.36 W/m‧K with a resistivity greater than 108 Ω‧m. Moreover, PS-S@SBS/Pyr consistently demonstrates a stable EMI shielding effectiveness of 33.1 dB within the 8–12 GHz frequency range, with absorption shielding predominating as the underlying mechanism. This green preparation method makes efficient utilization of two main solid wastes while increasing the added value of the material.

Enhanced interface electrical insulation of aramid‐reinforced resin composites via iron phthalocyanine self‐assembled structures on the surface of aramid

AbstractAramid fiber‐reinforced epoxy resin composites (AFRP) are the main components of electrical equipment such as GIS insulated tie rods, but the poor interfacial bonding between aramid fibers (AF) and epoxy resin (EP) results in a degradation of the material's insulating properties. In this paper, iron phthalocyanine (FePc) molecules are introduced on the AF surface, and the π‐π interaction effect between the metal phthalocyanine rings is used as a driving force to guide the spontaneous assembly of FePc into a three‐dimensional microstructure, and the effect of microstructures with different FePc contents on the insulating properties of AFRP interfaces is investigated. Combining a series of test simulation methods such as surface potential attenuation test, electric tree test, interlayer shear test, and molecular dynamics simulation, reveals the enhancement mechanism of the electrical insulation performance of the interface. The results show that FePc at four contents has an enhancement effect on the flashover voltage along the AF and the breakdown voltage at the AFRP interface, with a maximum enhancement of 25.63% for the flashover voltage and 232.23% for the breakdown voltage.Highlights Self‐assembled three‐dimensional structures on aramid surfaces were constructed via iron phthalocyanine molecules. The effects of self‐assembled structures on physicochemical properties are compared. Modifications substantially increase the breakdown voltage and flashover voltage. The mechanism of microstructure on interface breakdown voltage enhancement is revealed. The overall effect of multiple factors on insulation properties is analyzed.

Intelligent measurement method of transition resistance of insulation fasteners in urban rail transit system based on SSA-optimized algorithm

Rail-to-earth transition resistance characterizes the amplitude of stray current leakage in urban rail transit system using electric traction, which is critical for evaluating failure risk of metal infrastructures caused by electrochemical corrosion. However, detection method commonly used in the field exhibit measurement errors resulting from the limitation of measuring principle and measuring distance, which will seriously affect the accuracy of electrical insulation performance evaluation of the whole system. In view of this, this paper proposes a data-driven method for accurately measuring rail-to-earth transition resistance in urban rail transit system based on CDEGS-based simulation and SSA-optimized algorithm. CDEGS model was built to construct database for machine learning of SSA-RF network structure. SSA algorithm was used in the measurement model to optimize the topology of the random forest (RF) structure. Proposed ensemble in this paper was proved to conduct transition resistance regression with a mean relative accuracy rate of 98.85 %. Results of sensitivity analysis indicate that proposed measurement method shows acceptable robustness, which allows the algorithm parameters to fluctuate within a certain range when applied in the field. Besides, in the case of uniform and non-uniform insulation degradation, the proposed method shows good performance in assessing insulation performance. This provides a feasible foundation for future applications of the proposed method in failure risk evaluation of buried infrastructures.

Simultaneous improvements in energy density and thermal conductivity of PAN polymer nanocomposites enabled by core-shell structure BZCT@BNNS nanofibers

If the heat generated by electronic devices in high-power applications cannot be dissipated in a timely manner, it will not only affect the use of the equipment but also reduce its service life. Therefore, there is an urgent need to develop thin films of dielectric nanocomposites with high thermal conductivity, high energy storage, and excellent flexibility and electrical insulation performance. In this study, we reported the successful preparation of BZCT nanofibers (BZCT NFs) and core-shell structures BZCT@BNNS nanofibers using electrospinning and coaxial electrospinning techniques, respectively, and there were used to composite with polyacrylonitrile (PAN) polymer matrix to prepare BZCT NFs/PAN and BZCT@BNNS/PAN dielectric nanocomposites thin film. Research has found that when the shell thickness of BNNS is 15 nm and BZCT@BNNS (15 nm) volume fraction is 20 vol%, the comprehensive performance of the dielectric nanocomposites is the best, with thermal conductivity and energy storage performance of 3.36 W m−1K−1 and 12.23 J/cm3, respectively. Therefore, the nanocomposites thin film can be used as a potential high-performance dielectric material for thermal management applications in high-power density electronic devices.

Nano-BN and nano-cellulose synergistically enhanced the mechanical, thermal, and insulating properties of cellulose insulating paper

The complex and demanding environments of high humidity, heat, altitude, and intricate electric fields necessitate higher standards for the mechanical, thermal stability, and electric insulation properties of insulating paper. However, a single nanomaterial alone struggles to enhance overall performance. Hence, we propose employing two-phase nanomaterials with distinct dimensions to synergistically enhance the performance of cellulose insulation paper. Accordingly, “simulation design directly guided experimental research” was utilized in constructing nano-BN/nanocellulose/cellulose (nano-BN/NFC/cellulose) models through molecular dynamics simulation, and its mechanical parameters, dielectric properties, thermal stability, and so on were simulated and calculated. Based on simulation results, suitable proportions of nano-BN/NFC/cellulose insulating paper were prepared. Nano-BN and NFC synergistically enhance the mechanical properties of insulating paper. The nano-BN, CNF, and cellulose are arranged layer by layer under the action of gravity, allowing the fillers to overlap diagonally along the plane, synergistically forming a thermally conductive network conducive to heat transfer. Additionally, a strong interfacial effect is formed between the three-phase materials, reducing the overall structure's polarization effect and charge accumulation, and synergistically enhancing electrical insulation performance. The 12%nano-BN/NFC/cellulose (P12) exhibits optimal overall performance and is expected to be used in power equipment operating in special environments with high humidity and heat.

A processable high thermal conductivity epoxy composites with multi-scale particles for high-frequency electrical insulation

The solid-state transformer (SST) in the renewable energy grid is developing in the way of high voltage and high frequency, which often results in a sharp increase in heat production of the equipment and accelerates the failure of the insulating materials. Epoxy resin (EPR) is commonly used as an insulation material for SST due to its excellent electrical insulating properties, processing performance (viscosity), and low price. However, the thermal conductivity of EPR is only about 0.2 W/(m·K), which leads to poor insulating performance under high frequency and temperature. To enhance thermal conductivity, a substantial quantity of highly thermally conductive particles is incorporated into the EPR, accompanied by a severe increase in electrical insulation defects and viscosity. This study utilized a multi-scale particle-filled approach to investigate the thermal conductivity, processing characteristics, and high-frequency electrical insulation performance of composites. The composite, filled with 25 µm BN and 5 µm SiO2 particles, enhances thermal conductivity to 0.732 W/(m·K) and demonstrates superior electrical insulating properties at both 10 kHz and 20 kHz bipolar square waves (with an increase of 131.76% and 163.97% in relative EPR, respectively), as well as good processability. Meanwhile, it is found that the dielectric loss, thermal conductivity, and electric field distribution of the composite are the main factors affecting the electrical insulating properties from 10 to 20 kHz under high voltage.Graphical

Electrical insulation and dielectric properties of aramid fiber reinforced epoxy composites under mechanical stress

In this work, an in-situ testing platform that could simultaneously apply high voltage (HV) and mechanical stress has been established. The dielectric properties evolution of aramid fiber reinforced composite (AFRC) under different tensile stresses is investigated systematically. The results show that there is a significant influence on the electrical insulation performance of AFRC, when the applied tensile stress reaches 45 % of the ultimate tensile stress (UTS). Elevated tensile stress will induce interface strain concentration inside composites under this condition, which is prone to cause local damage and defects, consequently enhancing charge accumulation under HV. As the tensile stress continues to increase, it is observed that the absorbed charge around defects increases by 49.4 % under 60 % UTS, accompanied by a discernible decline in the partial discharge inception voltage (PDIV) by 46.9 %. With the increase of absorbed charge, the localized intense electric field is formed, thereby fostering partial discharge and breakdown failure. Therefore, it is important to pay more attention to the evolution of dielectric properties of AFRC under mechanical stress in the design and assessment of aramid-based insulation rods. © 2014 xxxxxxxx. Hosting by Elsevier B.V. All rights reserved.

Epoxy fiber derived all‐polymer films for high performance electrostatic energy storage dielectrics

Dielectric films with high discharged energy density are highly desired in electrical and electronic systems. Adding inorganic nanoparticles, especially for 1D inorganic fillers, in polymer films is recognized as one of the most effective methods to improve the electric breakdown strength, which is a key parameter of energy storage. However, 1D inorganic fillers added into thin films will undoubtedly introduce many defects and reduce the electric insulation performance. Herein, homogeneous epoxy fiber derived all‐polymer films were fabricated by electrospinning, laminating, and curing in sequence. The existing 1D structure of the epoxy films significantly enhanced the dielectric constant and electric breakdown strength, resulting in a very high enhancement of 2.7 times the discharged energy storage density at 25 °C, up to 9.6 J/cm3. Assisted by the simulation analysis, the enhanced dipole polarization and reduced current density are found to be the main reasons for the improved energy storage performances. Preparing all‐polymer films with fiber structure has proved to be an effective way to find advanced energy storage dielectric films.This article is protected by copyright. All rights reserved.

Vertically aligned and conformal BN-coated carbon fiber to achieve enhanced thermal conductivity and electrical insulation of a thermal interface material

Due to excellent thermal conductivity, high aspect ratio, and low density, mesophase pitch-based carbon fibers (MPCFs) are highly desired in electronic packaging. However, their thermal conductivity is hard to present in the polymer matrix because of the disordered stacking and low filling. Moreover, few researches are focused on the enhancement of the electrical insulation performance for MPCFs. Herein, we report vertically aligned and insulating boron nitride (BN) coated carbon fiber (CF) powders as significant fillers for polymer composites, endowing markedly improved thermal conductivity and electrical insulation. The high-quality BN coating layer on the surface of the CF is produced by a cooling precipitation method and high-temperature treatment with ingenious use of solubility properties, exhibiting a conformal, dense, and highly crystalline structure. This preparation method overcomes the limitations of coating thickness and particle agglomeration, resulting in a 31-fold enhancement of the electrical resistivity of the CF powders. After orientation treatment in a silicone rubber matrix, such CF@BN-filled pads exhibit good thermal conductivity, significantly improved insulation performance, and excellent mechanical properties. Among them, the optimized pad achieves a thermal conductivity of 12.06 W m−1 K−1, a volume resistivity of 50 × 108 Ω cm and a breakdown voltage of 3100 V mm−1, exceptional flexibility, and a favorable compression ratio (@45 psi) of 41.7 %. This work provides unique insights into constructing carbon fiber fillers as well as the preparation of high thermal conductivity composites, thereby expanding the application scenarios of carbon fiber powder in electronic packaging.

Atomically engineered Al-doped LaOCl for chlorine-ion batteries

LaOCl belongs to one kind of promising solid electrolyte for chlorine-ion batteries due to its excellent electric insulation performance and special layered structure. However, LaOCl still suffers from poor chlorine-ion conductivity. Then, we proposed microstructure modulation of LaOCl to solve this problem based on Al doping method. Firstly, we carried out first-principles and ab-initio molecular dynamics (AIMD) calculations to investigate the internal relation among structure stability, chlorine-ion conductivity and related physicochemical properties of Al doped LaOCl(La1-xAlxOCl). It is found that La0.75Al0.25OCl not only possesses most stable structure but also demonstrates the best ductility. Moreover, La0.75Al0.25OCl also possesses much lower chlorine-ion diffusion energy barrier than LaOCl(0.40 eV vs.0.78 eV) and its chlorine-ion conductivity goes as high as 5.4 × 10−3 S/cm at 300K. This is attributed to the optimal reconstruction of La–Cl coordination structure induced by Al dopant, which weakens the limiting effect of La–Cl bond as far as possible. Meanwhile,La0.75Al0.25OCl exhibits excellent electrical insulating property due to its wide band gap of 5.87 eV. In addition, La0.75Al0.25OCl exhibits wide electrochemical window with La and Al metal acted as anode materials, respectively (1.92–9.66 V for La and 0–7.74 V for Al). At this stage, La0.75Al0.25OCl solid electrolyte requires no chlorine-ion uptake and loss in the process of oxidation and reduction, indicating its excellent electrochemical stability.

Enhancement of thermal conductivity and insulation of silicone thermal interface material through surface modification and synergistic effects of nanofillers for thermal management of electronic devices

Thermal interface materials (TIMs) play an irreplaceable role in highly integrated microelectronic devices. In this work, the addition of acidified carbon nanotubes modified by 3-aminopropyl triethoxysilane (KH550) had an effective enhancement to the thermal conductivity, thermal stability, and electrical insulation performance of silicone grease. On this basis, multi-filled silicone grease composites with better thermal conductivity and electrical insulation were prepared by introducing zinc oxide (ZnO) and Graphene nanoflakes (GNFs). The thermal conductivity of silicone grease achieved 1.438 W m−1 K−1, while the volume resistivity still exceeded 1013 Ω·cm. Additionally, the study explored the impact of varying filler parameters, temperature, and contact pressure on the interface thermal contact resistance of silicone grease. The best performance silicone grease applied to the cooling of the high-power LED exhibited excellent heat dissipation. This work presented a reference for the design and development of low cost, high performance TIMs.