In the present paper a newly developed particle mass spectrometer (PMS) is described which allows determination of the mass of charged ultrafine particles or large molecules. It combines different physical principles: a molecular beam technique to generate a particle beam, an electrical deflection and filter system which classifies the particles due to their kinetic energy and velocity in the beam, and a detection system for the charged particles. From all three, the probability density distribution of m p z · e (i.e. the particle mass per number of charges) can directly be determined. These characteristics form the basis of a mass spectrometer suitable for particles in the mass range 10 −21 g ⩽ m p ⩽ 10 −18 g (600 amu ⩽ m p ⩽ 600,000 amu). The PMS was tested to measure the particle mass distribution in a sooting low pressure premixed flame as well as in an aerosol containing silver particles.
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