Compared to surfaces machined by electrical discharge machining (EDM), surfaces machined by electrochemical machining (ECM) tend to show smoother surface finish. Heat-affected zone is generated on the EDMed surface, but not on the ECMed surfaces. Hence, the previous study aimed to finish wire-EDMed surfaces with wire-ECM, using the same machine. A bipolar pulse current with positive pulse duration of 100 µs and negative pulse duration of 150 µs resulted in mirror like surface finish for stainless steel (SUS304). However, previous research showed low surface quality for cold tool steel SKD11 with wire-ECM finishing. This is because the precipitate of chromium carbide was preferentially corroded. Hence, in this study, surface quality of SKD11 finished with various positive pulse duty factor was investigated. As a result, it was found that the surface can be machined uniformly when the duty factor is 30%. Whereas the chromium carbide was less machined and protruded when the duty factor was lower, and it was machined faster than the other metallic structure and resulted in pit corrosion when the duty factor was higher than 30%.