Mössbauer spectra of the amorphous metallic glass Fe 82P 11B 7 recorded at 80 K and 295 K reveal a linewidth asymmetry involving the three line pairs L i and L 7− i ( i = 1, 2, 3) of the six-line pattern. This asymmetry has been attributed to the negative correlation between the hyperfine magnetic field and the quadrupole interaction. The degree of linearity of this correlation, which is about 10(7)%, is found to be constant at 80 K and 295 K. A separate estimate of the widths of the hyperfine field, isomer shift and electric field gradient distribution along with the average values of the parameters in this metallic glass has been made at these two temperatures. An analysis of the intensity ratios of the asymmetric Gaussian lines of the Mössbauer spectra indicates that the canting angle of magnetic moment with respect to the ribbon plane changes from 19.9° to 24.8° when the temperature is lowered from 295 K to 80 K.