This paper introduces a directional coupler for partial discharge (PD) measurements in gas-insulated substations (GIS). The sensor comprises a combination of magnetic and electric couplers, effectively segregating forward and backward pulses to enhance PD charge estimation and defect location. The sensor's design was supported with finite element method simulations and measurements conducted in a transverse electromagnetic test bench. Comparative analyses were performed against independent magnetic and electric couplers. The charge estimation and the directional coupler's directivity were evaluated in both the test bench and a full-scale GIS with different PD defects. Initially, the combined magnetic and the electric couplers exhibited undesired interactions, prompting corrective measures. Subsequent adjustments included changes to the electric coupler material and modifications to the magnetic coupler construction. The resulting high-voltage directional coupler performed better than the separated couplers in a GIS with discontinuities. This partial discharge sensor emerges as a candidate for future SF6-free alternative GIS.