Charge Electric Potential Research Articles

Clapeyron equations and fitting formula of the coexistence curve in the extended phase space of charged AdS black holes

In this paper, we first review the equal area laws and Clapeyron equations in the extended phase space of the charged anti-de Sitter black holes. With different fixed parameters, the Maxwell's equal area law holds not only in the pressure-thermodynamic volume oscillatory line, but also in the charge-electric potential and temperature-entropy oscillatory lines. The conventional Clapeyron equation is generalized and two extra equations are found. Moreover, we show that the coexistence curve of the small and large charged black holes is charge independent in the reduced parameter space for any dimension of spacetime. The highly accurate fitting formula for the coexistence curve is also presented. Using this fitting formula of the coexistence curve, we find that the Clapeyron equations are highly consistent with the calculated values. The fitting formula is also very useful for further study on the thermodynamic property of the system varying along the coexistence curve.

Electro-osmotic flow through a two-dimensional screen-pump filter

The electro-osmotic flow driven by a screen pump, composed of a line array of evenly spaced identical rectangular solid blocks, is investigated under the Debye-Hückel approximation. The geometry of the screen pump is determined by the spacing and aspect ratio of the solid blocks. A constant surface zeta potential is assumed on the block surface. The method of eigenfunction series expansion is applied to solve analytically for the applied electric field, electric charge potential in the fluid, and flow field. Because of the low Reynolds number, Stokes equations are applied for the flow. The analytic result is first confirmed by comparing with the exact solution of the electro-osmotic flow in an infinite channel. Then different geometries of the screen pump and the effect of the electrokinetic width are computed for their influence on the flow rate. Recirculating eddies and reversing flow are found even though the applied electric driving field is unidirectional.