AbstractIn this research, the degradation of a polymer blend in the presence of nanoparticles by considering the effect of nanoparticles on the degradation was investigated using emulsion models and fractional Zener model for the first time. Poly(lactic acid)/poly(caprolactone)/zinc oxide nanocomposite blends were prepared using the melt mixing method. Interface complex shear modulus for the neat polymer blend and its nanocomposites were calculated using emulsion models in a range of frequencies. All competing factors imposing elasticity on the systems, including the solid‐like behavior and degradation catalytic activity of ZnO nanoparticles in the presence of polyesters, were considered. After comparing the interface complex shear modulus of samples, it was revealed that the negative elastic impact of ZnO (degradation role) governs the viscoelastic behavior of these systems. Accordingly, the samples containing ZnO nanoparticles exhibited low elasticity, which was attributed to overcoming the degradation role of ZnO compared with the hydrodynamic interaction of ZnO nanoparticles. Additionally, the results obtained from the fractional Zener model were in good harmony with the emulsion model analysis.
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