In recent years, advancement in material technology and a better understanding of material propertiescoupled with the quest for bio-compactible materials has driven research towards valorisation of agro-waste like empty palm fruit bunch (EPFB). Elaesis guineensis was a potential source of biomass and was classified as an environmental pollutant and disposal burden. In this study, the valorisation of Elaesis guineensis and its thermal responsiveness as lignin for use as a filler in polymer composites are examined. Lignin from EPFB was extracted via acid hydrolysis, using Di ethyl ether ((C2H5)2O) and HCl as the pretreatment solvent. The thermal stability, crystallinity, heat flow, chemical composition, and functional group of the extracted lignin were studied for treated and untreated EPFB samples using techniques like; Fourier Transform Infrared Spectroscopy (FTIR), Thermogravimetric Analysis (TGA), X- ray diffrraction (XRD), X-Ray Fluorescence Spectroscopy (XRF) and Differential Scanning Calorimetry (DSC). The percent yield of 23% obtained in this work is within the range specified in literature (20.1-23.8%) using sodium hydroxide(NaOH) and calcium hydroxide (Ca (OH)2) for alkali treatment. Results of the FTIR analysis of all samples in reference to the wave numbers of lignin are in good agreement with those stated in the literature. The stretching patterns alsoindicate the presence of compounds like phenols, hydroxides, and methyl groups, which are characteristics of lignin compounds. By comparing with the cellulose standard available in the database of the XRD system, two main peaks were observed from the XRD patterns at 2θ = 22.3 and 2θ = 26.7 representing peak 002 for hemicellulose and 011 for lignin, respectively corresponding to the amorphous region of hemicellulose and lignin while peaks I002 represent the crystalline region of cellulose. From the study, it was inferred that the thermal stability of extracted lignin with a Tg of 400C is higher compared to the samples treated with di ethyl ether and untreated EPFB having a Tg of 200C. The extracted lignin has a maximum decomposition temperature of 400oC, which makes it suitable as a filler in polymer composites.