In order to reduce irreversible loss and recover expansion work for improving automotive thermal system performance, this study experimentally evaluated the performances and characteristics of a CO2 ejector-expansion (EJE) heat pump system for electric vehicles under typical cooling and heating operating modes, examined the adaptability of the EJE system with a fixed-dimension ejector, and compared the EJE system with the basic-regenerative (REG) and vapor-injection (INJ) systems in the − 30 °C to 50 °C range. The results show that the increasing electronic expansion valve (EXV) opening leads to an increasing entrainment ratio and a decreasing lift ratio in both two modes. The maximum COP is 2.00 at 35 °C/27 °C (out-cabin/in-cabin air temperature) and 1.85 at 0 °C/20 °C. The COP improvement reaches a maximum of 21.6 % and 31.0 % at the ejector design temperature of 45 °C, compared to the REG and INJ systems, respectively. However, the heating performance of the ejector designed at a high temperature significantly decreases as the ambient temperature goes down. At − 30 °C/20 °C, the EJE system performs worse with a COP degradation of 6.1 % compared to the REG system.