Organic solvents are commonly used in industrial manufacturing processes, resulting in large quantities of volatile organic compounds (VOCs) emitted from effluent wastewater treatment facilities. This work presents a novel stainless steel simulator designed for developing a model that estimates VOC emission rates from a quiescent water surface in an open/unaerated basin. The target pollutants were aqueous VOCs: alcohols (ethanol and iso-propanol) and methyl ethyl ketone. Two aromatic hydrocarbons, toluene and benzene, were also used and each mixed with ethanol. A formula, based on penetration theory and the concept of mass balance, was devised for simulating emission rates (N), with the following variables: wind velocity (W) above the air–water interface with a power number of β, the VOC concentration (C g*) at equilibrium with aqueous concentration (C L), and the emitted concentration (C g). Restated, N = kW β A s(C g* − C g), where k and β denote dimensionless constants, which were solved herein, and A s represents the emission surface area. From the proposed formula, three parameters (C L, water temperature, and W) were controlled during each simulation test to derive k and β values. To assess the feasibility of the simulation procedures for real water with multiple VOC compositions, a large open neutralization basin was used to measure the VOC emission rate. Comparing the calculated results, respectively using the proposed formula and emission model Water 8 developed by the U.S. EPA in 1985, confirmed that the proposed simulation method was a feasible alternative to Water 8.