Effluent Plume Research Articles

Turbiditic, clay‐rich event beds in fjord‐marine deposits caused by landslides in emerging clay deposits – palaeoenvironmental interpretation and role for submarine mass‐wasting

AbstractDistinct, clay‐rich beds are common in fjord‐marine deposits in Trondheimsfjorden near the outlet of the Nidelva River. Their characteristic light‐grey colour makes the beds easily distinguishable from the surrounding brownish, bioturbated, muddy fjord sediments. The clay‐rich beds commonly display a clear stratification in clay, silt and very fine sand. The beds are interpreted as originating primarily from large quick‐clay landslides upstream along the Nidelva River. Such events resulted in a sudden increase in the supply of fines to the fjord from disintegrating landslide debris and heavily loaded effluent plumes, possibly favouring hyperpycnal flow. Typical beds can be divided into a clay‐rich lower section, reflecting an initial surge with high concentrations of suspended mud, and a sandier upper section reflecting pulses of higher energy. This development can be explained, for example, by a lowering in the supply of mud, an increasing activity of deltaic sediment gravity flows due to a higher availability of sandy sediments in the landslide‐affected river, and by flooding and/or breaching of landslide dams. The typical, stratified beds are interpreted as the result of one quick‐clay landslide, whereas exceptionally thick, less organized, stratified beds are possibly the result of several large and/or complex landslides. Radiocarbon dating of mollusc shells has helped to establish a chronology for major terrestrial landslides in the area. The frequency of landslides increases towards the end of the Holocene. This is explained by a progressively deeper incision of rivers during glacioisostatic rebound, possibly combined with a change to a wetter climate. The marine core record displays deformation structures and hiati representing submarine mass‐wasting events, and supports the evidence that the clay‐rich beds are weak layers in the fjord‐marine stratigraphy. The inherent weakness of these layers may be explained by their composition, immature texture, loose fabric and contrasting permeabilities in the deposits. Slide‐prone layers similar to the clay‐rich beds described here may be found in other comparable fjord‐marginal settings and are considered to be of importance for geohazard assessments.

Tracing the influence of sewage discharge on coastal bays of Southern Vancouver Island (BC, Canada) using sedimentary records of phytoplankton

The impact of sewage and stormwater effluents on phytoplankton is investigated by comparing organic-walled dinoflagellate cyst abundance and diversity from 38 surface sediment samples, flanking southern Vancouver Island. Site locations include those directly adjacent to wastewater outfall at Clover and Macaulay Points and Saanich Peninsula, as well as from a variety of near-shore environments with differing tidal flow influences. Excellently preserved dinoflagellate cyst assemblages have been recovered and 36 cyst taxa were identified. Local assemblages are characterized by a high relative proportion (average 56%) of cysts produced by heterotrophic dinoflagellates, which is typical for regions of high primary production. Relative proportional increases of cysts from heterotrophic species with particular increases of Polykrikos kofoidii/schwartzii and Dubridinium species, known to reflect areas affected by eutrophication, occur directly adjacent to all three sewage outfalls, as well as in the more stagnant waters of Esquimalt and Victoria Harbours and at the mouth of Cadboro Bay. Further effects of an anthropogenic effluent can be seen in the relatively higher concentrations of organic carbon and the diatom production proxy, biogenic opal. Results from this study clearly indicate a much larger impact zone than predicted by a sewage effluent plume model or trends found in monitored benthic biota and sediment chemistry that evidence primary outfall affects <800 m eastward of Macaulay Point and about 200 m eastward of the Clover Point. Enhanced production of cysts from potentially toxic Alexandrium species is also observed near locations of sewage outfalls.

Nitrogen control through decentralized wastewater treatment: Process performance and alternative management strategies

Decentralized or onsite wastewater treatment (OWT) systems have long been implicated in being a major source of N inputs to surface and ground waters and numerous regulatory bodies have promulgated strict total N (TN) effluent standards in N-sensitive areas. These standards, however, most of which have effluent limitations of <10 mg/L TN, were generally developed without data on treatment performance and attainable compliance levels of operating OWTs designed to remove N. This paper reviews OWT technologies that rely on preanoxic or postanoxic denitrification, or simultaneous nitrification–denitrification, and frequently include compact, mechanized components. TN effluent data from 20 OWTs in 3 long-term N removal demonstration projects in Florida, Oregon, and New Zealand are analyzed and compared with the performance of 15 centralized N removal treatment plants from the US and Canada. A reliability and stability analysis shows that only one of the 20 OWTs approaches the reliability and stability of centralized plants, and can comply with a <10 mg/L TN effluent standard with a 99% probability; all of the remaining 19 OWTs have a <50% probability of compliance. The lower reliability of OWTs, many of which are energy-intensive, scaled-down models of centralized plants, is due to the inherent variability of decentralized wastewater characteristics and the challenges of operationally controlling N removal processes at the level of residences. However, the small footprint (required land area) of these compact designs offers important opportunities for retrofitting OWTs on small lots, in shoreline developments where land is at a premium and where communities wish to foster and sustain compact, village developments that reflect “smart growth” strategies. Other approaches to decentralized N management emphasizing passive, robust, ecologically engineered designs are reviewed and include natural wastewater treatment systems such as single pass sand filters with denitrifying bioreactors, which performed better than any other OWT technology; shallow trenches and drip irrigation for denitrification or plant N uptake in the carbon-rich root zone; denitrification beds/layers installed down gradient from effluent plumes; and the consideration of watershed N sinks in estimating the risks of N loading to receiving waters. These alternative approaches require further research and development, but can offer alternatives or additional treatment to mechanized OWTs. More comparative studies of long-term operation of OWTs under field conditions in other parts of the world are needed to further quantify performance capabilities.

A multi-objective genetic algorithm applied to autonomous underwater vehicles for sewage outfall plume dispersion observations

This work presents a multi-objective genetic algorithm to solve route planning problem for multiple autonomous underwater vehicles (AUVs) for interdisciplinary coastal research. AUVs are mobile unmanned platforms that carry their own energy and are able to move themselves in the water without intervention from an external operator. Using AUVs one can provide high-quality measurements of physical properties of effluent plumes in a very effective manner under real oceanic conditions. The AUV's route planning problem is a combinatorial optimization problem, where the vehicles must travel through a three-dimensional irregular space with all dimensions known. Therefore, minimization of the total travel distance while considering the maximum number of water samples is the main objective. Besides the AUV kinematics restrictions other considerations must be taken into account to the problem, like the ocean currents. The practical applications of this approach are the environmental monitoring missions which typically require the sampling of a volume of water with non-trivial geometry for which parallel line sweeping might be a costly solution. Some real-life test problems and related solutions are presented.

Rapid dispersal of a hydrothermal plume by turbulent mixing

The water column imprint of the hydrothermal plume observed at the Nibelungen field (8°18 ′S 13°30 ′W) is highly variable in space and time. The off-axis location of the site, along the southern boundary of a non-transform ridge offset at the joint between two segments of the southern Mid-Atlantic Ridge, is characterized by complex, rugged topography, and thus favorable for the generation of internal tides, subsequent internal wave breaking, and associated vertical mixing in the water column. We have used towed transects and vertical profiles of stratification, turbidity, and direct current measurements to investigate the strength of turbulent mixing in the vicinity of the vent site and the adjacent rift valley, and its temporal and spatial variability in relation to the plume dispersal. Turbulent diffusivities K ρ were calculated from temperature inversions via Thorpe scales. Heightened mixing (compared to open ocean values) was observed in the whole rift valley within an order of K ρ around 10 −3 m 2 s −1. The mixing close to the vent site was even more elevated, with an average of K ρ = 4 × 10 − 2 m 2 s − 1 . The mixing, as well as the flow field, exhibited a strong tidal cycle, with strong currents and mixing at the non-buoyant plume level during ebb flow. Periods of strong mixing were associated with increased internal wave activity and frequent occurrence of turbulent overturns. Additional effects of mixing on plume dispersal include bifurcation of the particle plume, likely as a result of the interplay between the modulated mixing strength and current speed, as well as high frequency internal waves in the effluent plume layer, possibly triggered by the buoyant plume via nonlinear interaction with the elevated background turbulence or penetrative convection.

Detection of anthropogenic gadolinium in the Brisbane River plume in Moreton Bay, Queensland, Australia

Wastewater effluent is known to contain macro and micropollutants, which may be deleterious to environmental health. One such class of micropollutants is chelated gadolinium, which are used as MRI contrast agents. As these MRI contrast agents can be assumed to behave conservatively during estuarine mixing, it is possible to calculate how much wastewater is represented in any particular sample. In this study, the percentage contribution of wastewater at specific locations in Moreton Bay, Qld, were determined by calculating the additional anthropogenic gadolinium contribution to the total rare earth element concentrations. Wastewater contributions were measured at concentrations as low as 0.2%, demonstrating the applicability of this technique for wastewater effluent plume mapping.

Behavioural toxicity of organic chemical contaminants in fish: application to ecological risk assessments (ERAs)

Chemical pollutants rarely attain acutely lethal concentrations in nature; thus the majority of their effects are expected to be sublethal. Estimation of the likelihood of effects from exposures to sublethal concentrations of contaminants in effluent plumes downstream of point sources poses a challenge when conducting ecological risk assessments (ERAs). This is an issue for regulatory agencies worldwide. This paper reviews the importance and availability of information on behavioural toxicity and identifies opportunities for its inclusion in ERAs. One of the major advantages of using data on behavioural effects is that they are more sensitive indicators of potential for impacts on survival in the field than are measures of lethality. Indications from available data for fish suggest that behavioural effects of organic contaminants often occur at concentrations 1 to 2 orders of magnitude lower than those found to elicit mortality. As a result, it is believed that the use of data on behavioural toxicity in ERAs could benefit the assessment process a great deal, allowing for the consideration of more ecologically significant and protective hazard and exposure scenarios.

Monitoring the greater San Pedro Bay region using autonomous underwater gliders during fall of 2006

Glider surveys of the greater San Pedro Bay region in the Southern California Bight during the fall of 2006 demonstrated the utility of autonomous underwater gliders in a coastal region with complex flow and significant anthropogenic inputs. Three Spray gliders repeatedly surveyed between Santa Catalina Island and the coast of Southern California collecting profiles of temperature, salinity, and chlorophyll fluorescence and estimates of vertically averaged currents. These observations provided context for shelf transport studies during the Huntington Beach 2006 experiment and showed the transition from summer to winter conditions. Vertically averaged currents were predominantly poleward following topography with horizontal scales of approximately 20 km. The gliders surveyed a small cyclonic eddy near Santa Catalina Island and provided a unique view of the structure of the eddy. Nitrate concentration within the euphotic zone was estimated to be 19% greater within the eddy and led to significantly elevated chlorophyll concentrations at the subsurface maximum. Glider observations of salinity reliably detected the distinctly fresh signature of the effluent plume from an ocean outfall near Huntington Beach, California. The salinity anomaly caused by the plume was used to track the spread of the plume as it was advected poleward and away from the coast while remaining subsurface.

Acoustic methods for water mass delineation in coastal marine ecosystems

Acoustical methods play an important role in the in the study of nutrient sources for coral reef ecosystems in the south Florida coastal ocean. Many nutrients released into the coastal ocean are released in distinct water masses such as inlet discharge plumes, wastewater outfall discharge plumes, and hurricane-induced re-suspensions. Using water column acoustic backscatter profiles, obtained via either ship-borne instrumentation or in-situ instrumentation, multidimensional images of nutrient bearing water masses are derived. Said images are of assistance in the design of chemical and biological sampling efforts. Examples of water mass imaging will be presented as well as the use of such images in the design of water quality sampling programs. Using a combination of acoustic backscatter, Doppler current profilers, nutrient (nitrate, nitrite, silica, phosphate, ammonia) samples and microbiological (fecal, protozoa, viruses) samples, flux estimates of said quantities may be made for inlet discharges. Results will be presented for a south Florida inlet having an average net seaward discharge of approximately 200 million gallons per day. Selected acoustic images of treated waste water effluent plumes will be presented and compared with plume spatial distributions inferred from conservative plume tracer studies.

DETECTION OF GASEOUS EFFLUENTS FROM AIRBORNE LWIR HYPERSPECTRAL IMAGERY USING PHYSICS-BASED SIGNATURES

Detection of gaseous effluent plumes from airborne platforms provides a unique challenge to the remote sensing community. The measured signatures are a complicated combination of phenomenology including effects of the atmosphere, spectral characteristics of the background material under the plume, temperature contrast between the gas and the surface, and the concentration of the gas. All of these quantities vary spatially further complicating the detection problem. In complex scenes simple estimation of a “residual” spectrum may not be possible due to the variability in the scene background. A common detection scheme uses a matched filter formalism to compare laboratory-measured gas absorption spectra with measured pixel radiances. This methodology can not account for the variable signature strengths due to concentration path length and temperature contrast, nor does it take into account measured signatures that are observed in both absorption and emission in the same scene. We have developed a physics-based, forward model to predict in-scene signatures covering a wide range in gas / surface properties. This target space is reduced to a set of basis vectors using a geometrical model of the space. Corresponding background basis vectors are derived to describe the non-plume pixels in the image. A Generalized Likelihood Ratio Test is then used to discriminate between plume and non-plume pixels. Several species can be tested for iteratively. The algorithm is applied to airborne LWIR hyperspectral imagery collected by the Airborne Hyperspectral Imager (AHI) over a chemical facility with some ground truth. When compared to results from a clutter matched filter the physics-based signature approach shows significantly improved performance for the data set considered here.

Dissolved Oxygen Downstream of an Effluent Outfall in an Ice-Covered River: Natural and Artificial Aeration

In ice-covered rivers, dissolved oxygen (DO) might fall below critical levels for aquatic biota in the absence of surface aeration, combined with low winter flow conditions and reduced photosynthesis rates. Open-water zones, however, can be created downstream of a diffuser by warm effluent discharges, resulting in an increase in surface aeration. In this study, we modeled the behavior of the effluent plume and the resulting open-water lead development in the Athabasca River, Alberta, Canada downstream of a pulp mill diffuser. The DO was found to increase by 0.26 mg∕L due to surface aeration of an open-water lead of 6.07 km . We also evaluated oxygen injection into the effluent pipeline to increase the DO in the river. At an injection rate of 3,500 and 5,000 lb∕day of liquid oxygen, the DO was increased by 0.16 and 0.21 mg∕L , which corresponded to an absorption efficiency of about 50%. The artificial aeration technique evaluated here appears to be an effective alternative to increase DO levels in ice-cove...

Simulations of Dye Releases off the Coast of New Jersey: Development and Validation of an Ocean Outfall Mixing Model

A kinematic mixing model has been developed to predict far field effluent distributions for ocean discharges. The model allows for complex outfall configurations and time varying discharge rates to be simulated. The model can use field observations or the output from a proven near field mixing model as input to this far field mixing model. The model uses observed or simulated horizontal currents at one location to advect the effluent plume and a scale-dependent “diffusion velocity” submodel to account for horizontal diffusive processes. To collect data to calibrate and verify the model, long-term continuous dye release experiments were conducted at two New Jersey ocean outfalls. Based upon the results of the dye release experiments, appropriate values for the diffusion velocity were determined for each outfall. Simulations using these diffusion velocities provided reasonable predictions of plume width and of average dye concentration at each transect for each outfall. This work demonstrates that an Euleri...

Electrical Conductivity of a Failed Septic System Soil Absorption Field

Locating existing septic systems and determining the extent of soil contamination after septic system failure can be destructive, time consuming, and a nuisance to homeowners. The objective of this study was to determine the effectiveness of noninvasive electromagnetic induction (EMI) for locating a failed septic system in fine‐textured glacial‐till‐derived soils. Components of a failed septic system were located with a push probe, georeferenced with a theodolite, and surveyed with a dual receiver EMI sensor (DUALEM‐2) in December 2001 (wet soil moisture condition) and July 2002 (dry soil moisture condition). Three transects located perpendicular to the soil absorption field trenches were sampled to a depth of 1.2 m and used to ground reference the EMI survey. Near‐surface (1‐m depth) apparent conductivity (ECa) was significantly correlated to unweighted average electrical conductivity from soil saturated paste extracts (ECsat; r = 0.79). The ECa below the soil absorption field was higher than the surrounding native soil under both dry and wet soil moisture conditions. Individual soil absorption trenches had a higher ECa than background ECa under both soil moisture conditions. A higher ECa pattern that was apparent in December 2001 associated with discharge of wastewater at shallow depths was not evident in July 2002 after the system had been abandoned for 6 mo. While more research is warranted, results from this study suggest that electromagnetic induction is a promising technique to identify the location of septic system components, failed septic systems, and their associated effluent plumes.

Sewage outfall plume dispersion observations with an Autonomous Underwater Vehicle

This work represents one of the first successful applications of Autonomous Underwater Vehicles (AUVs) for interdisciplinary coastal research. A monitoring mission to study the shape and estimate the initial dilution of the S. Jacinto sewage outfall plume using an AUV was performed on July 2002. An efficient sampling strategy enabling greater improvements in spatial and temporal range of detection demonstrated that the sewage effluent plume can be clearly traced using naturally occurring tracers in the wastewater. The outfall plume was found at the surface highly influenced by the weak stratification and low currents. Dilution varying with distance downstream was estimated from the plume rise over the outfall diffuser until a nearly constant value of 130:1, 60 m from the diffuser, indicating the near field end. Our results demonstrate that AUVs can provide high-quality measurements of physical properties of effluent plumes in a very effective manner and valuable considerations about the initial mixing processes under real oceanic conditions can be further investigated.

Initial stages of effluent plume development, Kinloch water treatment plant (WTP), Kinloch, Taupo, New Zealand

Studies of groundwater following changes to the wastewater treatment plant and disposal field at Kinloch (Taupo area, New Zealand) showed increases in chloride (Cl) after 5 months, followed by increased calcium (Ca) and magnesium (Mg) concentrations arising as a result of cation exchange with sodium (Na) and potassium (K). Sodium (Na) and potassium (K) showed only small increases after 12 months of initial discharge, while phosphorus (P) was still being totally adsorbed by ion exchange in the aquifer.

Field Evaluation of Mixing Length and Attenuation of Nutrients and Fecal Coliform in a Wastewater Effluent Plume

We present an alternative method to dye tracer studies for mapping wastewater effluent plumes in rivers. A case study of a wastewater treatment effluent plume that was mapped in two different months (October and April) showed good resolution in determining where the plume reached the opposite river bank, the degree of mixing in a given river reach, and where the river was fully mixed with respect to the plume. Both electrical conductivity and chloride were useful in mapping domestic wastewater effluent plume mixing. Mixing lengths obtained by field mapping were consistent with previous studies. Electrical conductivity field readings facilitated real-time plume delineation and sampling locations, and identified a non-point source plume during the mapping exercise. The apparent difference in dispersion of the plume between to the two mapping dates (despite similar upstream river discharge) suggests that the calibration of a water quality model based on a single dye test may be inadequate. The river distributions of effluent nutrients and fecal coliform were also mapped. Nutrient attenuation rates were faster than that of the chloride tracer, indicating processes other than mixing occur. Substantial differences were observed in nutrient and fecal coliform distributions between the two mapping dates.

An Integrated Case Study for Evaluating the Impacts of an Oil Refinery Effluent on Aquatic Biota in the Delaware River: Bivalve Bioavailability Studies

ABSTRACT The objectives of this study were to (1) determine the bioavailability of polycyclic aromatic hydrocarbons (PAHs) and other non-polar organics in resident brackish water clams (Rangia cuneata) at selected sites near an oil refinery; (2) determine if the tissue burdens were causing adverse effects to the clams, and (3) evaluate potential seasonal variations from reproduction in clams taken from the same beds in the spring and fall. Clams were evaluated from three beds located in the refinery discharge plume (near-field stations), three beds located up river outside of the Refinery effluent plume (north far-field), and three beds down river (south far-field) of the Refinery plume. Total PAH concentrations in the tissues of the near-field clams were significantly higher than in the clams located at the far-field stations in both the spring and fall. Total PAH concentrations of the near-field clams were significantly higher in the spring than the fall. No difference was found in total PAHs in the spring or fall in the far-field clams. Total pesticide and total PCB concentrations were significantly higher in the spring than the fall at all stations. The highest concentrations of both pesticides and PCBs were found at the north far-field stations. A tissue residue concentration analysis and three theoretical approaches for estimating detrimental effects to clams in both the near- and far-field suggested that no adverse effects should occur from total PAHs, total pesticides, or total PCBs. Some uncertainty, however, was associated with the theoretical approaches. An estimate of clam density in each clam bed showed that Rangia were growing and reproducing at all stations.

Sedimentary processes on a Gilbert-type delta in Lake Llanquihue, southern Chile

A small Gilbert-type delta on the southern shore of Lake Llanquihue, southern Chile, was studied over a period of two months. Bottom samples were taken by scuba diving along a 10 x 10 m grid to determine the distribution of sedimentary facies. The wind direction, wave conditions, underwater current directions and the orientation of sedimentary structures were recorded on a daily basis. Observations made during fair-weather conditions indicate that neither waves nor currents have any significant effect on the bottom sediments, and that the only transport is produced by bivalves causing small avalanches on the steep delta slope. This probably prevents the oversteepening and large-scale slope collapse typical of many Gilbert deltas. Observations recorded from shore during one major storm, show an excellent agreement with wave theory and empirical predictions, indicating that storm waves can affect the whole delta front and slope. These waves break about 35 m from shore where there is a clear transition from clast-supported gravel on the inner delta front to matrix-supported gravel and gravelly sand on the outer front. The storm waves are able to transport cobbles up to 40 cm in diameter. During these events, strong lakeward-directed bottom currents enhanced by the effluent plume of the river, transport some of these clasts to the edge of the delta front, where they avalanche down to the foot of the delta. During the waning stages of the storm and shortly thereafter, dense, sediment-laden bottom currents discharged from the river mouth carry plant material down the delta slope and over the pro-delta, burying the cobbles just deposited. A single cycle of delta progradation should produce two coarsening-upward cycles, which might be confused in the rock record with two distinct phases of delta progradation.

On-board flow cytometric observation of picoplankton community structure in the East China Sea during the fall of different years

On-board flow cytometric determinations of picoplankton abundance (i.e. Synechococcus spp., Prochlorococcus spp., picoeukaryotes and also heterotrophic bacteria) were obtained in the East China Sea in fall of 2000 and 2003. The average abundances of Synechococcus, Prochlorococcus, picoeukaryotes and heterotrophic bacteria were 10 5, 10 5, 10 4 and 10 6 cells ml −1, respectively. Synechococcus, picoeukaryotes and heterotrophic bacteria were abundant at all the stations and presented higher concentration in the inner shelf where influences from the Changjiang effluent plumes and the coastal upwelling were evident, while Prochlorococcus was absent from the near-shore stations and became the dominant picophytoplankton population in offshore waters, where its abundance was comparable to that for heterotrophic bacteria. All picoplankton groups showed a reduction in cell number with depth, and a positive correlation with water temperature were observed, which reflected the importance of light and temperature on picoplankton growth. A negative relationship with salinity was found for heterotrophic bacteria along two sections across the East China Sea Shelf, and distribution of picoplankton was dominated by different water masses. The fixation could lead to loss in Prochlorococcus cell numbers within one month, and all the picoplankton numbers decreased dramatically after three months.

Assessing a Wastewater Discharge to the Subtropical Rio Grande Using Aerial Videography and In Situ Physicochemistry

The Rio Grande contributes approximately 97% of the water used in Texas' Lower Rio Grande Valley for consumption, crop irrigation, industry, support of riparian vegetation and wildlife and for recreation. Anthropogenic impacts on this international river have significantly degraded both the quantity and quality of its water. The objectives of this project were to assess the utility of multispectral aerial videography for assessing a point‐source wastewater discharge to the Rio Grande and to track the plume downstream to assess distribution and dilution of the contaminants over distance. An airborne 12‐band imaging system [11 visible and 1 near‐infrared (NIR) band] was used to collect videography of the study area while in situ physicochemical data were collected along three transects established across the river. Transect 1 was located at the discharge source, while transects 2 and 3 were located approximately one and two km downstream, respectively. Visual observations were used to divide each horizontal transect into plume, mixing and non‐plume zones. Each of the three zones was sampled along each transect. With the exception of the 820 nm NIR image band, all image bands recorded a higher light intensity (luminance) in the plume zone than in the mixing or non‐plume zones for all transects. Visible band results were associated with higher abiotic and biotic suspension concentrations in the effluent (plume) than in the river water. Video data correlated best with total chlorophyllous aggregates [ΣCA, (chlorophyll a + pheophytin a)], followed by total suspended solids (TSS), pheophytin a, total dissolved solids (TDS) and chlorophyll a concentrations. The 720 nm band demonstrated the best overall relationship with the selected parameters, followed by the 560 nm band, and then by the 700 mn band. No significant correlations were noted with any of the bands for total organic carbon (TOC) concentration. Correlations conducted for all transects indicated a significant relationship between plume luminosity and ΣCA, TSS, TDS and pheophytin a concentrations. Results indicated a significant potential for the use of multispectral narrowband visible imagery in conjunction with ground measurements (water physicochemistry) for rapid monitoring of environmental water chemistry. Development of imaging techniques to qualitatively estimate concentrations of certain constituents in impacted water columns without the need for in situ sampling may be possible.