Efficient Single Photon Sources Research Articles

Programmable multiphoton quantum interference in a single spatial mode.

The interference of nonclassical states of light enables quantum-enhanced applications reaching from metrology to computation. Most commonly, the polarization or spatial location of single photons are used as addressable degrees of freedom for turning these applications into praxis. However, the scale-up for the processing of a large number of photons of these architectures is very resource-demanding due to the rapidly increasing number of components, such as optical elements, photon sources, and detectors. Here, we demonstrate a resource-efficient architecture for multiphoton processing based on time-bin encoding in a single spatial mode. We use an efficient quantum dot single-photon source and a fast programmable time-bin interferometer to observe the interference of up to eight photons in 16 modes, all recorded only with one detector, thus considerably reducing the physical overhead previously needed for achieving equivalent tasks. Our results can form the basis for a future universal photonics quantum processor operating in a single spatial mode.

Exceptionally strong coupling of defect emission in hexagonal boron nitride to stacking sequences

Van der Waals structures present a unique opportunity for tailoring material interfaces and integrating photonic functionalities. By precisely manipulating the twist angle and stacking sequences, it is possible to elegantly tune and functionalize the electronic and optical properties of layered van der Waals structures. Among these materials, two-dimensional hexagonal boron nitride (hBN) stands out for its remarkable optical properties and wide band gap, making it a promising host for solid state single photon emitters at room temperature. Previous investigations have demonstrated the observation of bright single photon emission in hBN across a wide range of wavelengths. In this study, we unveil an application of van der Waals technology in modulating their spectral shapes and brightness by carefully controlling the stacking sequences and polytypes. Our theoretical analysis reveals remarkably large variations in the Huang-Rhys factors–an indicator of the interaction between a defect and its surrounding lattice–reaching up to a factor of 3.3 for the same defect in different stacking sequences. We provide insights into the underlying mechanism behind these variations, shedding light on the design principles necessary to achieve rational and precise control of defect emission. This work paves the way for enhancing defect identification and facilitating the engineering of highly efficient single photon sources and qubits using van der Waals materials.

Single-Photon Emission from Organic Dye Molecules Adsorbed on a Quantum Dot via Energy Transfer.

Single-photon emissions from individual emitters are crucial in fundamental science and quantum information technologies. Multichromophoric systems, comprising multiple dyes, can exhibit single-photon emissions through efficient annihilation between the excited states; however, exploring this phenomenon in complex systems remains a challenge. In this study, we investigated the photon statistics of emissions from multiple perylene bisimide (PBI) dyes adsorbed onto the surface of CdSe/ZnS quantum dots (QDs). When multiple PBIs were simultaneously excited by both direct excitation and energy transfer from the QD, multiphoton emissions from the PBIs were observed. Conversely, when the QDs were selectively excited, multiple PBIs exhibiting single-photon emission through energy transfer from the QDs to the PBIs were found. These results highlight the intriguing interplay between multichromophoric systems and QDs, offering valuable insights into the development of efficient single-photon sources in quantum information technologies.

Xenon-plasma focused ion beam processing of photonic microstructures with GaAs-based quantum dots

So far, successful focused ion beam (FIB) based fabrication of photonic structures with quantum dots (QDs) has been limited to cases with above 1 µm thick cap, usually in a form of a distributed Bragg reflector of a vertical cavity, which simultaneously protects the active region from the destructive influence of the ion beam. Here, we propose optimized xenon-plasma FIB (Xe-PFIB) technology as a fast and cost-efficient solution alternative to the commonly used combination of electron beam lithography and etching. We demonstrate a 3D processing of GaAs-based photonic microstructures with InGaAs QDs emitting close to the telecom O-band for cylindrical mesas with different cap thicknesses (50-650 nm) obtained by using two approaches: (i) Xe-PFIB for both reducing the cap thickness as well as the in-plane microstructure size, and (ii) wet chemical etching for cap layer removal and subsequent Xe-PFIB for the in-plane milling. The latter appeared more efficient when judging by photoluminescence intensity. Utilizing an additional protecting layer of platinum or carbon was also tested. Eventually, we for the first time show successful FIB-based fabrication of photonic microstructures with bright emission from single QDs capped with only 200 nm layer, which indicates the prospects of this technology for processing of efficient QD-based single-photon sources for quantum communication.

Highly stable and pure single-photon emission with 250 ps optical coherence times in InP colloidal quantum dots.

Quantum photonic technologies such as quantum communication, sensing or computation require efficient, stable and pure single-photon sources. Epitaxial quantum dots (QDs) have been made capable of on-demand photon generation with high purity, indistinguishability and brightness, although they require precise fabrication and face challenges in scalability. By contrast, colloidal QDs are batch synthesized in solution but typically have broader linewidths, low single-photon purities and unstable emission. Here we demonstrate spectrally stable, pure and narrow-linewidth single-photon emission from InP/ZnSe/ZnS colloidal QDs. Using photon correlation Fourier spectroscopy, we observe single-dot linewidths as narrow as ~5 µeV at 4 K, giving a lower-bounded optical coherence time, T2, of ~250 ps. These dots exhibit minimal spectral diffusion on timescales of microseconds to minutes, and narrow linewidths are maintained on timescales up to 50 ms, orders of magnitude longer than other colloidal systems. Moreover, these InP/ZnSe/ZnS dots have single-photon purities g(2)(τ = 0) of 0.077-0.086 in the absence of spectral filtering. This work demonstrates the potential of heavy-metal-free InP-based QDs as spectrally stable sources of single photons.

A tip-enhanced quantum emitter with integrated TiO2 slot waveguides in the optical regime

We study the coupling between a nanoscopic dielectric slot waveguide and a metallic-tip-enhanced dipole quantum emitter and search for optimal emission and guiding of photons along a titanium dioxide photonic waveguide. Finite element calculations are used to characterize the mode properties of the waveguide over a range of parameters and predict the efficiency of emission guidance along the waveguide. We show how the effective quantum yield is dependent on the waveguide parameters as well as the dipole position and orientation and show that the integrated system can reach a maximum quantum yield of more than 30% along each direction of the waveguide. By placing the dipole emitter near the apex of a silver nanotip situated above or inside the slot waveguide to increase the overall emission rate, we also enable the capability of controlling the emitter–waveguide​ coupling in situ. We numerically compute the excitation and radiation fields and find that despite a reduction in the quantum yield, a 35-fold increase in the overall emission rate can be obtained due to very large field enhancement factors of up to 4000 at the location of the dipole. By using alternative materials for the tip, this tip-enhanced-waveguide approach has the potential of further increasing the guided photon emission rate. With the possibility of controlling emitter–waveguide coupling in situ, this tip-enhanced emitter configuration provides an alternative approach for the realization of an efficient single-photon source.

Highly efficient and indistinguishable single-photon sources via phonon-decoupled two-color excitation

Single-photon sources with near-unity efficiency and indistinguishability play a major role in the development of quantum technologies. However, on-demand excitation of the emitter imposes substantial limitations to the source performance. Here, we show that coherent two-color pumping allows for population inversion arbitrarily close to unity in bulk quantum dots thanks to a decoupling effect between the emitter and its phonon bath. Driving a micropillar single-photon source with this scheme, we calculate very high photon emission into the cavity mode (0.95 photons per pulse) together with excellent indistinguishability (0.975) in a realistic configuration, thereby removing the limitations imposed by the excitation scheme on single-photon source engineering.

Efficient room-temperature molecular single-photon sources for quantum key distribution.

Quantum key distribution (QKD) allows the distribution of cryptographic keys between multiple users in an information-theoretic secure way, exploiting quantum physics. While current QKD systems are mainly based on attenuated laser pulses, deterministic single-photon sources could give concrete advantages in terms of secret key rate (SKR) and security owing to the negligible probability of multi-photon events. Here, we introduce and demonstrate a proof-of-concept QKD system exploiting a molecule-based single-photon source operating at room temperature and emitting at 785 nm. With an estimated maximum SKR of 0.5 Mbps, our solution paves the way for room-temperature single-photon sources for quantum communication protocols.

Device-Independent Quantum Secure Direct Communication with Single-Photon Sources

Quantum secure direct communication (QSDC) can directly transmit secrete messages through a quantum channel. Device-independent (DI) QSDC can guarantee the communication security relying only on the observation of the Bell-inequality violation, but not on any detailed description or trust of the inner workings of users' devices. In the paper, we propose a DI-QSDC protocol with practical highly efficient single-photon sources. The communication parties construct the entanglement channel from single photons by adopting the heralded architecture, which makes the message-leakage rate independent of the photon-transmission loss. The secure communication distance and the practical communication efficiency of the current DI-QSDC protocol are about 6 times and 600 times of those in the original DI-QSDC protocol. Combining with the entanglement purification, the parties can construct the nearly perfect entanglement channel and completely eliminate the message leakage. This DI-QSDC protocol may have useful applications in the future quantum communication field.

Efficient Single-Photon Sources Based on Chlorine-Doped ZnSe Nanopillars with Growth Controlled Emission Energy.

Isolated impurity states in epitaxially grown semiconductor systems possess important radiative features such as distinct wavelength emission with a very short radiative lifetime and low inhomogeneous broadening, which make them promising for the generation of indistinguishable single photons. In this study, we investigate chlorine-doped ZnSe/ZnMgSe quantum well (QW) nanopillar (NP) structures as a highly efficient solid-state single-photon source operating at cryogenic temperatures. We show that single photons are generated due to the radiative recombination of excitons bound to neutral Cl atoms in ZnSe QW and the energy of the emitted photon can be tuned from about 2.85 down to 2.82 eV with ZnSe well width increase from 2.7 to 4.7 nm. Following the developed advanced technology, we fabricate NPs with a diameter of about 250 nm using a combination of dry and wet-chemical etching of epitaxially grown ZnSe/ZnMgSe QW structures. The remaining resist mask serves as a spherical- or cylindrical-shaped solid immersion lens on top of NPs and leads to the emission intensity enhancement by up to an order of magnitude in comparison to the pillars without any lenses. NPs with spherical-shaped lenses show the highest emission intensity values. The clear photon-antibunching effect is confirmed by the measured value of the second-order correlation function at a zero time delay of 0.14. The developed single-photon sources are suitable for integration into scalable photonic circuits.

Tuning of silicon nitride micro-cavities by controlled nanolayer deposition

Integration of single-photon emitters (SPEs) with resonant photonic structures is a promising approach for realizing compact and efficient single-photon sources for quantum communications, computing, and sensing. Efficient interaction between the SPE and the photonic cavity requires that the cavity's resonance matches the SPE’s emission line. Here we demonstrate a new method for tuning silicon nitride (Si3N4) microring cavities via controlled deposition of the cladding layers. Guided by numerical simulations, we deposit silicon dioxide (SiO2) nanolayers onto Si3N4 ridge structures in steps of 50 nm. We show tuning of the cavity resonance exceeding a free spectral range (FSR) of 3.5 nm without degradation of the quality-factor (Q-factor) of the cavity. We then complement this method with localized laser heating for fine-tuning of the cavity. Finally, we verify that the cladding deposition does not alter the position and spectral properties of nanoparticles placed on the cavity, which suggests that our method can be useful for integrating SPEs with photonic structures.

Front Cover: Free‐Space Quantum Key Distribution with Single Photons from Defects in Hexagonal Boron Nitride (Adv. Quantum Technol. 9/2022)

Quantum key distribution (QKD) is one of the most mature applications of single photon sources. The cover image shows on demand generation of single photons and their subsequent polarization encoding to prepare flying qubits in QKD. In article number 2200059, Çağlar Samaner and colleagues implement an isolated defect in hexagonal boron nitride (hBN) as the efficient single photon source and control their polarization by an electro-optic modulator to demonstrate free-space B92 based QKD. These results suggest that optically active defects in hBN have a great potential for applications within quantum information technologies including practical QKD systems.

Directional radiation enhancement of nanowire quantum dots based on line-array plasmonic antenna coupling

The integration of a single III-V semiconductor quantum dot with a plasmonic nanoantenna as a means toward efficient single-photon sources (SPEs) is limited due to its weak, wide-angle emission, and low emission rate. These limitations can be overcome by designing a unique linear array of plasmonic antenna structures coupled to nanowire-based quantum dot (NWQD) emitters. A linear array of a coupled device composed of multiple plasmonic antennas at an optimum distance from the quantum dot emitter can be designed to enhance the directionality and the spontaneous emission rate of an integrated single-photon emitter. Finite element modeling has been used to design these compact structures with high quantum efficiencies and directionality of single-photon emission while retaining the advantages of NWQDs. The Purcell enhancement factor of these structures approaches 66.1 and 145.8, respectively. Compared to a single NWQD of the same diameter, the fluorescence was enhanced by 1054 and 2916 times. The predicted collection efficiencies approach 85% (numerical aperture, NA = 0.5 ) and 80% ( NA = 0.5 ), respectively. Unlike single-photon emitters based on bulky conventional optics, this is a unique nanophotonic single-emission photon source based on a line-array configuration that uses a surface plasmon-enhanced design with minimum dissipation. The designs presented in this work will facilitate the development of SPEs with potential integration with semiconductor optoelectronics.

Bright single-photon sources in the telecom band by deterministically coupling single quantum dots to a hybrid circular Bragg resonator

High-performance solid-state quantum sources in the telecom band are of paramount importance for long-distance quantum communications and the quantum Internet by taking advantage of a low-loss optical fiber network. Here, we demonstrate bright telecom-wavelength single-photon sources based on In(Ga)As/GaAs quantum dots (QDs) deterministically coupled to hybrid circular Bragg resonators (h-CBRs) by using a wide-field fluorescence imaging technique. The QD emissions are redshifted toward the telecom O-band by using an ultra-low InAs growth rate and an InGaAs strain reducing layer. Single-photon emissions under both continuous wave (CW) and pulsed operations are demonstrated, showing high brightness with count rates of 1.14 MHz and 0.34 MHz under saturation powers and single-photon purities of g ( 2 ) ( 0 ) = 0.11 ± 0.02 (CW) and g ( 2 ) ( 0 ) = 0.087 ± 0.003 (pulsed) at low excitation powers. A Purcell factor of 4.2 with a collection efficiency of 11.2 % ± 1 % at the first lens is extracted, suggesting efficient coupling between the QD and h-CBR. Our work contributes to the development of highly efficient single-photon sources in the telecom band for fiber-based quantum communication and future distributed quantum networks.

Tailoring the Emission Wavelength of Color Centers in Hexagonal Boron Nitride for Quantum Applications.

Optical quantum technologies promise to revolutionize today’s information processing and sensors. Crucial to many quantum applications are efficient sources of pure single photons. For a quantum emitter to be used in such application, or for different quantum systems to be coupled to each other, the optical emission wavelength of the quantum emitter needs to be tailored. Here, we use density functional theory to calculate and manipulate the transition energy of fluorescent defects in the two-dimensional material hexagonal boron nitride. Our calculations feature the HSE06 functional which allows us to accurately predict the electronic band structures of 267 different defects. Moreover, using strain-tuning we can tailor the optical transition energy of suitable quantum emitters to match precisely that of quantum technology applications. We therefore not only provide a guide to make emitters for a specific application, but also have a promising pathway of tailoring quantum emitters that can couple to other solid-state qubit systems such as color centers in diamond.

Selective Control of Eu3+ Radiative Emission by Hyperbolic Metamaterials.

In recent years the quest for novel materials possessing peculiar abilities of manipulating light at the nanoscale has been significantly boosted due to the strict demands of advanced nanophotonics and quantum technologies. In this framework radiative decay engineering of quantum emitters is of paramount importance for developing efficient single-photon sources or nanolasers. Hyperbolic metamaterials stand out among the best cutting-edge candidates for photoluminescence control owing to their potentially unlimited photonic density of states and their ability to sustain high-k modes that allow us to strongly enhance the radiative decay rate of quantum light emitters. The aim of the present paper is to show how Au/ hyperbolic multilayers can be used to selectively control the photoluminescence of coupled emitters. We point out an enhancement of the transitions when they are in the hyperbolic regime of the metamaterials and a significant alteration of the ED and MD branching ratios by changing the emitter–metamaterial distance.

Plasmonic Waveguides: Enhancing quantum electrodynamic phenomena at nanoscale

The emerging field of plasmonics can lead to enhanced light matter interactions at extremely nanoscale regions. Plasmonic (metallic) devices promise to efficiently control both classical and quantum properties of light. Plasmonic waveguides are usually used to excite confined electromagnetic modes at the nanoscale that can strongly interact with matter. The analysis of these nanowaveguides exhibits similarities with their low frequency microwave counterparts. In this article, we review ways to study plasmonic nanostructures coupled to quantum optical emitters from a classical electromagnetic perspective. These quantum emitters are mainly used to generate single photon quantum light that can be employed as a quantum bit or qubit in the envisioned quantum information technologies. We demonstrate different ways to enhance a diverse range of quantum electrodynamic phenomena based on plasmonic configurations by using the classical dyadic tensor Green function formalism. More specifically, spontaneous emission and superradiance are analyzed by using the Green function based field quantization. The exciting new field of quantum plasmonics will lead to a plethora of novel optical devices for communications and computing applications operating in the quantum realm, such as efficient single-photon sources, quantum sensors, and compact on-chip nanophotonic circuits.

Numerical optimization of single-mode fiber-coupled single-photon sources based on semiconductor quantum dots.

We perform extended numerical studies to maximize the overall photon coupling efficiency of fiber-coupled quantum dot single-photon sources emitting in the near-infrared and O-band and C-band. Using the finite element method, we optimize the photon extraction and fiber-coupling efficiency of quantum dot single-photon sources based on micromesas, microlenses, circular Bragg grating cavities and micropillars. The numerical simulations which consider the entire system consisting of the quantum dot source itself, the coupling lens, and the single-mode fiber, yield overall photon coupling efficiencies of up to 83%. Our work provides objectified comparability of different fiber-coupled single-photon sources and proposes optimized geometries for the realization of practical and highly efficient quantum dot single-photon sources.

Unity yield of deterministically positioned quantum dot single photon sources

We report on a platform for the production of single photon devices with a fabrication yield of 100%. The sources are based on InAsP quantum dots embedded within position-controlled bottom-up InP nanowires. Using optimized growth conditions, we produce large arrays of structures having highly uniform geometries. Collection efficiencies are as high as 83% and multiphoton emission probabilities as low as 0.6% with the distribution away from optimal values associated with the excitation of other charge complexes and re-excitation processes, respectively, inherent to the above-band excitation employed. Importantly, emission peak lineshapes have Lorentzian profiles indicating that linewidths are not limited by inhomogeneous broadening but rather pure dephasing, likely elastic carrier-phonon scattering due to a high phonon occupation. This work establishes nanowire-based devices as a viable route for the scalable fabrication of efficient single photon sources and provides a valuable resource for hybrid on-chip platforms currently being developed.

Optical properties of individual CdS/CdSe/CdS nanocrystals: spherical quantum wells as single-photon sources

We have synthesized CdS(1.3 nm)/CdSe(1.7 nm)/CdS(3.4 nm) spherical quantum wells (SQWs) with a diameter of 13 nm and demonstrated the first photon-antibunching from their emission, labelling them as single-photon sources. Antibunching survives even at high excitation intensities, ruling-out strong emission from the bi-exciton. For the largest intensities, antibunching coupled to spectral measurements reveal the signature of a blue-shifted emission, associated to an irreversible photo-aging effect. A statistical analysis over 26 SQWs demonstrates a moderate correlation between the energy of the main and the blue-shifted emission. Intensity-timetraces recorded on 28 single SQWs show weak blinking, with a median time spent in the bright state of 89%. Their emission decay reveals a complex dynamic with either three or four exponential components. We assigned three of them to the neutral and singly-charged excitons and the slowest to defect emission. While SQWs have been initially designed for laser-oriented applications, we demonstrate that they can serve as efficient single-photon sources.