Although the green light emission of Tb3+ ions can be effectively improved by utilizing energy transfer from Eu2+ to Tb3+ ions, obtaining phosphors with high quantum efficiency remains a major problem. Here, we have achieved a novel apatite-type structure Ca4La(PO4)3O (CLPO) containing Eu2+ and Tb3+ ions. The CLPO:Eu2+ is capable of being effectively excited by near-ultraviolet light and emits blue light at about 460 nm. Energy transfer from the Eu2+ to Tb3+ ions in CLPO:Eu2+,Tb3+ can be readily constructed by utilizing the energy transfer from Eu2+ to Tb3+ ions. The optimized phosphor CLPO:0.02Eu2+,0.7Tb3+ has a high internal quantum efficiency of 96.6% and an external quantum efficiency of 64.7%. CLPO:0.02Eu2+,0.7Tb3+ and commercially available blue and red phosphors were coupled with a 365 nm chip package to form WLEDs, which presented a good Ra value (89.9) and correlated color temperature (3808 K). Our work provides an avenue to realize novel and efficient green phosphors by selecting suitable hosts and constructing efficient energy transfer.
Read full abstract