Efficient Generation Research Articles

Galvanostatic Electroshock Synthesis of Low Loading Au-Pt Nanoalloys onto Gas Diffusion Electrodes as Multifunctional Electrocatalysts for a Glycerol-Fed Electrolyzer.

Water electrolysis is increasingly considered a viable solution for meeting the world's growing energy demands and mitigating environmental issues. An inventive strategy to mitigate the energy requirements involves substituting the energy-intensive oxygen evolution reaction (OER) with biomass-derived glycerol electrooxidation. Nonetheless, the synthesis of electrocatalysts for controlling the selectivity towards added-value chemicals at the anode and efficient H2 generation at the cathode remains a critical bottleneck. Herein, we implemented a galvanostatic electroshock synthesis approach to control the reduction kinetics of Au(III) and Pt(IV) to grow ultra-low amount of gold-platinum alloys on a gas diffusion electrode (12-26 µgmetal cm‒2) for glycerol-fed hydroxide anion exchange membrane based electrolyzer. The symmetric GDE-Au100-xPtx||GDE-Au100-xPtx systems showed a notable improvement in electrolyzer performance (GDE-Au64Pt36 = 201 mA cm-2) as compared to monometallic versions (GDE-Au100Pt0 = 18 mA cm-2, GDE-Au0Pt100 = 81 mA cm-2). Chromatography (HPLC) analysis underscores the critical importance of bulk electrolysis methodology (galvanostatic vs potentiostatic) for the efficient conversion of glycerol into high-value-added products. Regarding the electrical energy required to produce 1 kg of H2 for such an electrolyzer fed at the anode with glycerol, our results confirm a drastic decrease by a factor of at least two compared with conventional water electrolysis.

Effects of Graphene Reinforcement on Static Bending, Free Vibration, and Torsion of Wind Turbine Blades.

Renewable energy markets, particularly wind energy, have experienced remarkable growth, predominantly driven by the urgent need for decarbonization in the face of accelerating global warming. As the wind energy sector expands and turbines increase in size, there is a growing demand for advanced composite materials that offer both high strength and low density. Among these materials, graphene stands out for its excellent mechanical properties and low density. Incorporating graphene reinforcement into wind turbine blades has the potential to enhance generation efficiency and reduce the construction costs of foundation structures. As a pilot study of graphene reinforcement on wind turbine blades, this study aims to investigate the variations of mechanical characteristics and weights between traditional fiberglass-based blades and those reinforced with graphene platelets (GPLs). A finite element model of the SNL 61.5 m horizontal wind turbine blade is used and validated by comparing the analysis results with those presented in the existing literature. Case studies are conducted to explore the effects of graphene reinforcement on wind turbine blades in terms of mechanical characteristics, such as free vibration, bending, and torsional deformation. Furthermore, the masses and fabrication costs are compared among fiberglass, CNTRC, and GPLRC-based wind turbine blades. Finally, the results obtained from this study demonstrate the effectiveness of graphene reinforcement on wind turbine blades in terms of both their mechanical performance and weight reduction.

Research on the design and optimal control of the power take-off (PTO) system for underwater eel-type power generators

Wave energy and ocean current energy are considered stable, reliable, and highly predictable renewable energy sources. The development of ocean current energy conversion technology is crucial in addressing power shortages. However, the low velocity of most ocean currents worldwide, typically less than 1.5 m/s, poses a challenge for traditional ocean current energy capture devices. Current estimations of power generation from underwater devices often significantly differ from actual results. This study presents an eel-type power generation device designed for underwater use, investigates the design and optimization of a hydraulic power take-off (PTO) system suitable for such devices, and examines key components of the hydraulic PTO system like variable hydraulic motors and generators. Analytical research was conducted to understand its operational characteristics, with a focus on components such as the accumulator, speed control valve, and energy storage flywheel. The article also delves into the hydrodynamic and energy conversion characteristics of the device under shallow water wave and current conditions, enhancing the hydraulic PTO system model and establishing an integrated calculation model for real-time data transmission during the calculation process. Through evaluations of pitch angle and power generation under varying sea conditions, the study explores the impact of hydraulic motor displacement and damping coefficient on the hydrodynamic and power generation characteristics of the device, further validated through sea trials. The study findings indicate a high level of parameter adaptation among the components of the hydraulic system. The addition of an accumulator to the system results in smoother output response curves, suggesting that the accumulator absorbs impacts and stabilizes the hydraulic power transmission system. The proposed comprehensive calculation method enables a more precise prediction of the performance of the eel power generation device in real marine environments, capturing its movement behavior and power generation characteristics. Adjusting the motor displacement or damping coefficient under specific conditions can optimize the total damping of the hydraulic PTO system for maximum power output. The optimal power point of the hydraulic power generation system varies for different sea conditions, with a potential power generation efficiency of up to 80.3% under certain circumstances.

Synergistic approach: Photocatalytic hydrogen generation for curcumin hydrogenation

Sn1-xFexO2 (x = 0, 0.1, 0.2 & 0.3) nanomaterials were successfully synthesized by co-precipitation technique and characterized by XRD, FTIR, SEM-EDAX, TG/DSC, etc. XPS revealed the presence of Fe+3 & Sn+4 ions in the SnO2 crystal lattice. Insertion of Fe shifts the absorption of SnO2 to the visible region. These synthesized nanomaterials show efficiency for hydrogen generation and degradation of organic dyes in the presence of visible light. The water splitting was performed under different conditions. A maximum hydrogen production rate of 12.8 mmol g−1h−1 was observed for Sn0.8Fe0.2O2 with glucose as a sacrificial agent. The photogenerated H2 finds application in hydrogenation of curcumin to tetrahydrocurcumin.

Enhancing heat transfer efficiency and entropy generation minimization in Micro-Channel Heat Sinks through pillar spacing and diameter optimization

Micro-Channel Heat Sinks (MCHSs) have several applications and notable efficiency in the cooling of electronic devices. In the present work, Micro-Channel Heat Sinks (MCHSs) with different number of inserted pillars are investigated extensively in the purpose of improving the efficiency of microstructures insertion in MCHS. A Computational Fluid Dynamics (CFD) analysis was carried out in ANSYS Fluent 19.0. The study focused on a single micro-channel, with simulations performed for Reynolds number ranging from 300 to 740. Effects of both the spacing between the pillars and their diameter was discussed, pillar spacing ranging from 2.5 to 97.5 times the pillar diameter (with pillar numbers from 5 to 150), and a pillar diameter ranging from 2/8 to 5/8 times the channel width (Wch). These two parameters have shown a serious impact on thermal, thermo-hydraulic performance and entropy generation of the MCHS. Heat transfer was augmented up to four-fold by inserting pillars into the MCHS. The highest Nusselt number was achieved with configuration P75 with a relative spacing around 5.2 (Ss=5.2×Dp), while the highest performance enhancement coefficient (PEC) was obtained for the 3/8×Wch diameter of configuration P50. Proposed insertion criterions enhance Nusselt number and PEC of MCHS with inserted pillars and provides design parameters for any further use of pillars in MCHS.

Sustainable lignocellulosic-based sponge with Janus salt-tolerant structure for efficient solar steam generation

Sustainable lignocellulosic-based sponge with Janus salt-tolerant structure for efficient solar steam generation

Electricity generation via metal oxide-air moist interaction

Harvesting electricity from ambient moisture and water droplets through the innovative technology of hydrovoltaics has lately gained attraction as it only requires water molecules' intrinsic energy and is applicable in different weather conditions. We present a device prototype for electricity generation from air humidity. The study investigates the complex interplay of water-solid interactions, focusing on band gap differences of n-type and p-type couple metal oxides and their performance in electricity generation. The research develops Moist-Electric Generators (MEGs) using ZnO as an n-type metal oxide with various p-type metal oxides (MnOx, CuO, and CoOx) on carbon paper substrates. Among these, the ZnO/CoOx MEG exhibits superior performance, producing an open circuit voltage of nearly 0.5 V, a current of around 9.5 µA for more than 7 days, with an areal and maximum power density of 1.48 µWcm2- and 4.5 µWcm2- at 95 % RH. Detailed characterization techniques, including XRD, XPS, and SEM, confirm the successful synthesis of ZnO and CoOx electrodes. The study demonstrates the sensitivity of the ZnO/CoOx MEG to changes in relative humidity and investigates its long-term stability. The results highlight the significance of water dissociation and minor redox processes for efficient energy generation, paving the way for advanced applications in renewable energy technologies.

P-794 Unraveling the function of GATA2 and GATA3 in mouse blastocyst formation via CRISPR/Cas9 gene editing

Abstract Study question What is the effect of the CRISPR/Cas9 mediated knock-out (KO) of Gata2 and Gata3 on mouse preimplantation development/blastocyst formation? Summary answer Efficient generation of Gata3/Gata2 KO mouse embryos was achieved. Gata3 and Gata2 KO embryos could form blastocysts, suggesting a possible dispensability for blastocyst formation. What is known already GATA2 and GATA3 are important trophectoderm markers in mouse and human embryos. Prior studies, involving RNAi knockdown or conditional KO of Gata3, demonstrated high rates of morula arrest of Gata3-/- embryos, indicating its essential role in blastocyst formation. However, conflicting results showed embryonic lethality in Gata3-/- embryos only at 11-12 dpf. Besides, conditional KO of Gata2 suggested its dispensability in blastocyst formation, as Gata2-/- embryos could form blastocysts. It is of interest to validate these findings and potential functional redundancy between GATA2 and GATA3 in mouse embryos, by generating CRISPR/Cas9-mediated single and double KOs of Gata2 and Gata3. Study design, size, duration Upon assessment of the on-/ off-target effects of CRISPR/Cas9 components in mouse embryonic stem cells (mESC), CRISPR/Cas9 ribonucleoprotein (RNP) complexes were electroporated in mouse zygotes. Suitable control groups (non-targeted and scrambled targeted (inactive crRNA)) were incorporated. Embryos were genotyped by next generation sequencing (NGS), to assess the effect of gene KO on embryo morphology. Additionally, the expression pattern of Gata2 and Gata3 was examined in wild type and CRISPR/Cas9 targeted embryos, with immunofluorescent staining (IFS). Participants/materials, setting, methods Following CRISPR/Cas9 mediated targeting of Gata2 and Gata3, mouse embryos were cultured and morphologically monitored until day 4.5, alongside relevant control groups (scrambled, media control). Subsequently, DNA was extracted, and embryos were genotyped by PCR amplification of the region surrounding the target site, followed by NGS. IFS of mouse embryos at different developmental stages (E2.5, E3.0, E3.5 and E4.5) was performed to assess expression patterns and localization of both Gata2 and Gata3 throughout development. Main results and the role of chance Following the design of two gRNAs targeting either Gata2 or Gata3, on-target editing efficiency was tested in mESCs. The selected Gata2-targeting design resulted in a frameshift efficiency of 75%, whereas the Gata3-targeting design resulted in a frameshift efficiency of 78%. No off-target effects were observed in Gata2 and Gata3 targeted mESCs when examining in silico predicted off-target sites through PCR and NGS. Furthermore, 51% of Gata3 targeted and 41% of Gata2 targeted mouse embryos contained frameshift mutations in all cells. Notably, the majority of Gata3-/- (93%, n = 22) and Gata2-/- (94%, n = 16) embryos developed to blastocysts, similar to media control and scrambled groups. No statistically significant difference between Gata3-/- (n = 24, p = 0.326) and Gata2-/- (n = 17, p = 0.978) embryo morphology and scrambled (n = 96) embryo morphology was detected. IFS of control embryos (n = 16) showed that nuclear expression of GATA2 precedes nuclear expression of GATA3, indicating that GATA2 might control the expression of Gata3. Following IFS of Gata3 targeted embryos (n = 4), no nuclear signal for both GATA2 and GATA3 was observed, indicating that GATA3 could regulate the expression of Gata2. Furthermore, we created 100% double KO mouse embryos for Gata2 and Gata3 in two ways, enabling comprehensive exploration of functional redundancy in future studies. Limitations, reasons for caution Mosaicism (>1 genotype present in one embryo), off-target effects and chromosomal arrangements pose challenges regarding CRISPR/Cas9 germline genome editing. Zygote-stage delivery of RNP complexes is used to address mosaicism, and off-target effects are screened in mESCs via NGS. Future efforts aim to increase the sample sizes for stronger support. Wider implications of the findings Our goal is to identify the molecular pathways underlying unsuccessful implantation in mouse and human embryos. Utilizing CRISPR/Cas9 to generate KO embryos enhances our understanding of key molecular mechanisms, potentially shedding light on pregnancy failure due to failure of trophectoderm specification, formation or maintenance. Trial registration number not applicable

The prospects of zero energy building as an alternative to the conventional building system in Bangladesh (A review)

Energy consumption in commercial and residential buildings worldwide accounts for about one-third of the world’s energy and one-quarter of greenhouse gas emissions. If current trends continue, by 2025, buildings worldwide will be the largest consumers of global energy, using as much power as the transportation and industrial sectors combined. Recent studies have found that improving energy efficiency in buildings is the least costly way to reduce a large quantity of carbon emissions. By changing energy management practices and instituting technologies that enhance energy efficiency, building owners and managers can reduce energy consumption by up to 35%. However, energy efficiency efforts in buildings alone cannot address future demand for more energy by this sector. To achieve breakthrough solutions to this problem, it is evident that a coordinated effort in a whole-building systems approach that emphasizes the necessity of integrating renewable on-site or distributed generation and energy efficiency is required to design the buildings of the future. Several International Energy Agency (IEA) countries have adopted a vision of so-called ‘net zero energy buildings’ (NetZEBs) as the long-term goal of their energy policies. This NetZEB is very new in Bangladesh and it started building green buildings which will lead to NetZEB shortly. However, Bangladesh has to comply with the IEA and must accept the zero-energy building concept.

The prospects of zero energy building as an alternative to the conventional building system in Bangladesh (A review)

Energy consumption in commercial and residential buildings worldwide accounts for about one-third of the world’s energy and one-quarter of greenhouse gas emissions. If current trends continue, by 2025, buildings worldwide will be the largest consumers of global energy, using as much power as the transportation and industrial sectors combined. Recent studies have found that improving energy efficiency in buildings is the least costly way to reduce a large quantity of carbon emissions. By changing energy management practices and instituting technologies that enhance energy efficiency, building owners and managers can reduce energy consumption by up to 35%. However, energy efficiency efforts in buildings alone cannot address future demand for more energy by this sector. To achieve breakthrough solutions to this problem, it is evident that a coordinated effort in a whole-building systems approach that emphasizes the necessity of integrating renewable on-site or distributed generation and energy efficiency is required to design the buildings of the future. Several International Energy Agency (IEA) countries have adopted a vision of so-called ‘net zero energy buildings’ (NetZEBs) as the long-term goal of their energy policies. This NetZEB is very new in Bangladesh and it started building green buildings which will lead to NetZEB shortly. However, Bangladesh has to comply with the IEA and must accept the zero-energy building concept.

Heme utilization by the enterococci

Abstract Heme consists of a tetrapyrrole ring ligating an iron ion and has important roles in biological systems. While well known as the oxygen binding molecule within hemoglobin of mammals, heme is also cofactor for several enzymes and a major iron source for bacteria within the host. The enterococci are a diverse group of Gram-positive bacteria that exist primarily within the gastrointestinal tract of animals. However, some species within this genus can transform into formidable opportunistic pathogens, largely owing to their extraordinary adaptability to hostile environments. Although enterococci cannot synthesize heme nor depend on heme to grow, several species within the genus encode proteins that utilize heme as a cofactor, which appears to increase their fitness and ability to thrive in challenging environments. This includes more efficient energy generation via aerobic respiration and protection from reactive oxygen species. Here, we review the significance of heme to enterococci, primarily the major human pathogen Enterococcus faecalis, use bioinformatics to assess the prevalence of hemoproteins throughout the genus, and highlight recent studies that underscore the central role of the heme-E. faecalis relationship in host-pathogen dynamics and interspecies bacterial interactions.

Efficient Anti-Icing of a Stable PFA Coating for Wind Power Turbine Blades.

Superhydrophobic coatings are increasingly recognized as a promising approach to enhancing power generation efficiency and prolonging the operational lifespan of wind turbines. In this research, a durable superhydrophobic perfluoroalkoxy alkane (PFA) coating was developed and specifically designed for spray application onto the surface of wind turbine blades. The PFA coating features a micronano hierarchical structure, exhibiting a high water contact angle of 167.0° and a low sliding angle of 1.7°. The optimal PFA coating exhibits stability and maintains a superhydrophobic performance during mechanical and chemical tests. The findings of this study establish a positive association between the surface energy of the coating and its effectiveness in anti-icing. The delayed icing time for the PFA-coated surface is 46.83 times longer than that of an uncoated surface, and the ice adhesion strength is only 1.875 kPa. Additionally, the PFA coating demonstrates remarkably high ice suppression efficiencies of 94.7 and 99.5% in anti-icing experiments at ambient temperatures of -6 and -10 °C, respectively. It is anticipated that this stable superhydrophobic PFA coating will be a candidate for anti-icing applications in wind turbine blades.

Defect detection of photovoltaic modules based on improved VarifocalNet

Detecting and replacing defective photovoltaic modules is essential as they directly impact power generation efficiency. Many current deep learning-based methods for detecting defects in photovoltaic modules focus solely on either detection speed or accuracy, which limits their practical application. To address this issue, an improved VarifocalNet has been proposed to enhance both the detection speed and accuracy of defective photovoltaic modules. Firstly, a new bottleneck module is designed to replace the first bottleneck module of the last stage convolution group in the backbone. This new module includes both standard convolution and dilated convolution, enabling an increase in network depth and receptive field without reducing the output feature map size. This improvement can help to enhance the accuracy of defect detection for photovoltaic modules. Secondly, another bottleneck module is also designed and used to replace the original bottleneck module used in the fourth stage convolution group of the backbone. This new module has smaller parameters than the original bottleneck module, which is useful to improve the defect detection speed of the photovoltaic module. Thirdly, a feature interactor is designed in the detection head to enhance feature expression in the classification branch. This helps improve detection accuracy. Besides, an improved intersection over union is proposed and introduced into the loss function to measure the difference between the predicted and ground truth boxes. This is useful for improving defect detection accuracy. Compared to other methods, the proposed method has the highest detection accuracy. Additionally, it also has a faster detection speed than other methods except for the DDH-YOLOv5 method and the improved YOLOv7 method.

Covalent Organic Framework Catalyzed Amide Synthesis Directly from Alcohol Under Red Light Excitation

The dehydrogenative coupling of alcohols and amines to form amide bonds is typically catalysed by homogeneous transition metal catalysts at high temperatures ranging from 130‐140 °C. In our pursuit of an efficient and recyclable photocatalyst capable of conducting this transformation at room temperature, we report herein a COF‐mediated dehydrogenative synthesis. The TTT‐DHTD COF was strategically designed to incorporate a high density of functional units, specifically dithiophenedione, to trap photogenerated electrons and effectively facilitate hydrogen atom abstraction reactions. The photoactive TTT‐DHTD COF, synthesized using solvothermal methods showed high crystallinity and moderate surface area, providing an ideal platform for heterogeneous amide synthesis. Light absorption by the COF across the entire visible range, narrow band gap, and valence band position make it well‐suited for the efficient generation of excitons necessary for targeted dehydrogenation. Utilizing red light irradiation and employing extremely low loading of the COF, we have successfully prepared a wide range of amides, including challenging secondary amides, in good to excellent yields. The substrate's functional group tolerance, very mild reaction conditions, and the catalyst's significant recyclability represent substantial advancements over prior methodologies.

High-Performance Aqueous Zinc-Organic Battery with a Photo-Responsive Covalent Organic Framework Cathode.

Covalent organic framework (COF) materials, known for their robust porous character, sustainability, and abundance, have great potential as cathodes for aqueous Zn-ion batteries (ZIBs). However, their application is hindered by low reversible capacity and discharge voltage. Herein, a donor-acceptor configuration COF (NT-COF) is utilized as the cathode for ZIBs. The cell exhibits a high discharge voltage plateau of ≈1.4V and a discharge capacity of 214 mAh g-1 at 0.2 A g-1 when utilizing the Mn2+ electrolyte additive in the ZnSO4 electrolyte. A synergistic combination mechanism is proposed, involving the deposition/dissolution reactions of Zn4SO4(OH)6·4H2O and the co-(de)insertion reactions of H+ and SO4 2- in NT-COF. Meanwhile, the NT-COF with a donor-acceptor configuration facilitates efficient generation and separation of electron-hole pairs upon light exposure, thereby enhancing electrochemical reactions within the battery. This leads to a reduction in charging voltage and internal overvoltage, ultimately minimizing electricity consumption. Under ambient weather conditions, the cell exhibits an average discharge capacity of 430 mAh g-1 on sunny days and maintains consistent cycling stability for a duration of 200 cycles (≈19 days) at 0.2 A g-1. This research inspires the advancement of Zn-organic batteries for high-energy-density aqueous electrochemical energy storage systems or photo-electrochemical batteries.

PVA/cellulose hydrogel with asymmetric distribution of MoS2 for highly efficient solar-driven interfacial evaporation and electricity generation

Population growth and economic globalization have exacerbated freshwater shortages and energy crises, and solar-driven interfacial evaporation (SDIE) offers a promising solution due to its environmental friendliness, accessibility, and sustainability. However, the highly efficient cogeneration of freshwater and electricity using the SDIE process is a challenge. Herein, a PVA/cellulose hydrogel with asymmetric distribution of MoS2 is proposed as a highly efficient SDIE system to overcome the bottleneck in the cogeneration of freshwater and electricity. By applying material genome engineering and microstructure regulation to improve light harvesting, energy efficiency, evaporation performance, and vapor escape. The evaporation rate of the PVA/cellulose evaporator could reach 3.23 kg m−2 h−1 when desalinating 3.5 wt% seawater under 1 sun and remained basically stable during the long-term continuous evaporation. In addition to desalination, the prepared evaporator also has a potential application in the cyclic utilization of the industrial and domestic wastewater. The synergistic effect of the electron double layer effect and the seawater battery principle produces a high output voltage of 0.714 V. Meanwhile, the optimized solar evaporator demonstrates good mechanical properties, salt resistance, environmental adaptability, and carbon emission economy. This work provides new insights into efficient seawater desalination and power generation, and inspires further research on multifunctional solar-driven interfacial evaporation systems to effectively address water scarcity and energy crises.

Multi-criteria decision analysis and experimental study on heat pipe thermoelectric generator for waste heat recovery

In the realm of heat conversion and utilization, gravity heat pipes have garnered significant attention due to their exceptional heat conduction efficiency. As a strategy to effectively enhance the efficiency of thermoelectric generator (TEG) systems through shallow geothermal heat recovery, optimizing the performance of gravity heat pipes holds significant implications for their widespread application in the field of sustainable energy. Experimental evaluations comprehensively assessed the performance of a 6 m gravity heat pipe within a temperature difference power generation system, employing multi-criteria decision-making to test thermal performance, efficiency, reliability, stability, and working fluid studies. The study demonstrates that the heat transfer efficiency of gravity heat pipes is highest under film boiling conditions at 250 °C to 350 °C. By adjusting the inclination angle to 60° to 90° and the filling ratio to 30 %–60 %, the power generation efficiency can be improved to 9.71 %. With an increase in wind speed to 8 m/s, the cold end temperature decreases by 30 %, resulting in a peak power generation efficiency of up to 11.3 %. Additionally, CHIME connection methods reduce energy losses to 8.1 %, providing crucial scientific foundations for the design and optimization of temperature difference power generation systems. These findings not only elucidate the heat transfer mechanisms of gravity heat pipes but also offer technical guidance for efficient energy conversion in thermoelectric generator systems.

Quantum maximum power point tracking (QMPPT) for optimal solar energy extraction

Solar energy is key to achieving a more environmentally responsible future. One way to exploit it is to use semiconductor technology through solar panels to generate clean, sustainable, and controllable energy. However, the use of such solutions must be optimised by methods such as maximum power point tracking (MPPT) to extract the maximum available solar energy. Although MPPT algorithms have been widely used and improved, the use of newer approaches, such as quantum computing, appears to hold the promise of achieving new performance levels, particularly for real-time MPPT implementation. The goal of this work is to develop and test a quantum algorithm for the photovoltaic (PV) energy MPPT problem using quantum particle swarm optimisation. The performance of the classic and quantum MPPT algorithms was evaluated under three main operating conditions: normal, high-temperature, and partial shading conditions. This represents a variety of environmental scenarios that can affect the efficiency of solar power generation. According to the study's results, the classical algorithm recorded 0.15% more power than the quantum algorithm in normal operating conditions, and the quantum algorithm generated 3.33% more power in higher temperature tests and 0.89% more power in the partial shading test. Moreover, the quantum algorithm recorded lower duty cycles for the three tests. While the classical algorithm may have a slight edge in power output under normal operation conditions, the quantum algorithm indicates superior performance in challenging conditions and consistently reveals more promising overall efficiency.

Structure-performance relationship of SrTiO3/S@g-C3N4 nanocomposites for highly active hydrogen production via NaBH4 methanolysis

The catalytic performance of SrTiO3/S@g-C3N4 nanocomposite catalyst for hydrogen production from NaBH4 methanolysis was investigated. The X-ray diffraction (XRD), Attenuated Total Reflectance (ATR) spectroscopy, and scanning electron microscopy (SEM) analyses revealed the structure of the nanocomposite catalyst. The XRD spectrum of SrTiO3/S@g-C3N4 showed the presence of both SrTiO3 and S@g-C3N4 phases. ATR spectroscopy analysis proved the interaction between SrTiO3 and g-C3N4 that facilitates electron-hole separation and charge transfer. The ESEM images demonstrated that the SrTiO3/S@g-C3N4 sheets were broken up during growth. The surface area of SrTiO3/S@g-C3N4 was 195 m2/g, which is higher than that of pristine S@g-C3N4 (40 m2/g), while the BJH pore size of SrTiO3/S@g-C3N4 (1.6 nm) was lower than that of S@g-C3N4 (2.0 nm). The band gap of the nanocomposite catalyst was reduced from 2.71 to 2.67 eV after the incorporation of SrTiO3. The PL spectra showed a characteristic peak of S@g-C3N4 at 457 nm, which red-shifted the addition of SrTiO3. The catalyst SrTiO3/S@g-C3N4 achieved a promising hydrogen production rate of 8537 mL/g.min and a reaction activation energy of 19.20 kJ/mol. These findings show promise for catalytic performance and high efficiency in hydrogen generation from NaBH4 methanolysis.

Structure-performance relationship of SrTiO3/S@g-C3N4 nanocomposites for highly active hydrogen production via NaBH4 methanolysis

The catalytic performance of SrTiO3/S@g-C3N4 nanocomposite catalyst for hydrogen production from NaBH4 methanolysis was investigated. The X-ray diffraction (XRD), Attenuated Total Reflectance (ATR) spectroscopy, and scanning electron microscopy (SEM) analyses revealed the structure of the nanocomposite catalyst. The XRD spectrum of SrTiO3/S@g-C3N4 showed the presence of both SrTiO3 and S@g-C3N4 phases. ATR spectroscopy analysis proved the interaction between SrTiO3 and g-C3N4 that facilitates electron-hole separation and charge transfer. The ESEM images demonstrated that the SrTiO3/S@g-C3N4 sheets were broken up during growth. The surface area of SrTiO3/S@g-C3N4 was 195 m2/g, which is higher than that of pristine S@g-C3N4 (40 m2/g), while the BJH pore size of SrTiO3/S@g-C3N4 (1.6 nm) was lower than that of S@g-C3N4 (2.0 nm). The band gap of the nanocomposite catalyst was reduced from 2.71 to 2.67 eV after the incorporation of SrTiO3. The PL spectra showed a characteristic peak of S@g-C3N4 at 457 nm, which red-shifted the addition of SrTiO3. The catalyst SrTiO3/S@g-C3N4 achieved a promising hydrogen production rate of 8537 mL/g.min and a reaction activation energy of 19.20 kJ/mol. These findings show promise for catalytic performance and high efficiency in hydrogen generation from NaBH4 methanolysis.