Efficient Solar Concentrators Research Articles

Procedure for thermal performance evaluation of steam generating point-focus solar concentrators

Solar energy can be used for substitution of the depleting fossil fuels in thermal applications and electricity generation through thermal route. For medium and high temperature applications, solar concentrators are required. Proper sizing and selection of concentrator for any thermal application calls for characterization of the concentrator at the required operating temperature. There are few procedures reported in literature for testing and evaluating solar concentrator performance which are based on sensible heating of the working fluid. One of the limitations of these procedures is requirement of precise operating conditions during testing. A test procedure for characterization of point-focus steam generating solar concentrators based on latent heating at different operating temperatures is proposed. The proposed procedure uses the phase change characteristic of water at constant temperature to measure the thermal performance. This procedure can be used to estimate thermal efficiency of solar concentrator at different operating temperatures above 100 °C. This procedure was used to estimate the efficiency of a point-focus solar concentrator having 25 m2 aperture area at 161 °C (equivalent to 5.4 bar (g)). The efficiency was estimated as 47 ± 3.5%. The test procedure can be used for field evaluation of existing systems also with minimum amount of instrumentation and controls.

Thermodynamic efficiency of solar concentrators

The optical thermodynamic efficiency is a comprehensive metric that takes into account all loss mechanisms associated with transferring flux from the source to the target phase space, which may include losses due to inadequate design, non-ideal materials, fabrication errors, and less than maximal concentration. We discuss consequences of Fermat's principle of geometrical optics and review étendue dilution and optical loss mechanisms associated with nonimaging concentrators. We develop an expression for the optical thermodynamic efficiency which combines the first and second laws of thermodynamics. As such, this metric is a gold standard for evaluating the performance of nonimaging concentrators. We provide examples illustrating the use of this new metric for concentrating photovoltaic systems for solar power applications, and in particular show how skewness mismatch limits the attainable optical thermodynamic efficiency.

Optical efficiency of solar concentrators by a reverse optical path method

A method for the optical characterization of a solar concentrator, based on the reverse illumination by a Lambertian source and measurement of intensity of light projected on a far screen, has been developed. It is shown that the projected light intensity is simply correlated to the angle-resolved efficiency of a concentrator, conventionally obtained by a direct illumination procedure. The method has been applied by simulating simple reflective nonimaging and Fresnel lens concentrators.

Intramolecular Energy Transfer in Pyrene–Bodipy Molecular Dyads and Triads

Molecules bearing a 4,4-difluoro-8-(aryl)-1,3,5,7-tetramethyl-2,6-diethyl-4-bora-3a,4a-diaza-s-indacene (bodipy) core and 1-pyrenyl-1-phenyl-4-(1-ethynylpyrene), or 1-phenyl-4-[1-ethynyl-(6-ethynylpyrene)pyrene] units were constructed in a step-by-step procedure based on palladium(0)-promoted cross-coupling reactions with the required preconstructed modules. X-ray structures of single crystals reveal a twisted arrangement of the two chromophores. In one case, an almost perfect orthogonal arrangement is found. These dyes are strongly luminescent in solution and display rich electrochemistry in which all redox processes of the bodipy and pyrene fragments are clearly resolved. The absorption spectra indicate that the bodipy and pyrene chromophores are spectrally isolated, thereby inducing a large "virtual" Stokes shift. The latter is realised by efficient transfer of intramolecular excitation energy by the Förster dipole-dipole mechanism. The rate of energy transfer depends on the structure of the dual-dye system and decreases as the centre-to-centre separation increases. The energy transfer efficiency, however, exceeds 90 % in all cases. The linkage of two pyrene residues by an ethyne group leads to a decrease in the energy-transfer efficiency, with the two polycycles acting as a single chromophore. The directly linked bodipy-pyrene dual dye binds to DNA and operates as an efficient solar concentrator when dispersed in plastic.

Self absorption treatment for the luminescent solar concentrators

The effect of self absorption accompanying most dyes used as a luminescent solar concentrator in the form of rigid sheets was reduced, allowing for more efficient solar concentrators and hence high photovoltaic solar conversion. The treatment involved mixing dopant molecules of specific properties with the dyes before forming the rigid final shape. Dyes including Rhodamine 6G, Rhodamine B, Ruthenium bi byridyl and crystal violet were used while thionin molecules were utilized as the dopant. The study shows that the efficiency enhancement is a function of dopant concentration and sample thickness.

Dyes Boost Efficiency of Solar Concentrator

Dyes Boost Efficiency of Solar Concentrator