A plausible solution to the current energy crisis is the development of cost-effective and inherently secure methods for accelerating the sustainable production of value-added compounds from biomass. In this study, we have developed a highly efficient catalytic system for the conversion of fructose into 2,5-diformylfuran (DFF) using tetracationic ionic liquids with dual Brønsted acid sites and four bromide ion sites. The presence of Brønsted acid sites promotes the production of 5-hydroxymethylfurfural (HMF), while the bromide anions react to form a DFF, which undergoes further transformation via the Kornblum mechanism. Under optimized conditions, a remarkable DFF yield of 99.6 % was attained in dimethyl sulfoxide (DMSO) at 140 °C for 6 h. Moreover, the catalyst exhibited excellent stability and reusability, indicating its potential for industrial application in the synthesis of DFF from fructose. With the help of this effort, Br- anion may be able to throw some light on the oxidation of HMF to DFF. Overall, this study highlights the promising application of tetracationic ionic liquid catalyst systems, showcasing the potential for the efficient utilization of renewable biomass resources and the synthesis of high-value-added compounds.