Production Efficiency Research Articles

Tandem Proton Transfer in Carboxylated Supramolecular Polymer for Highly Efficient Overall Photosynthesis of Hydrogen Peroxide

Proton supply is as critical as O2 activation for artificial photosynthesis of H2O2 via two‐electron oxygen reduction reaction (2e‐ ORR). However, proton release via water dissociation is frequently hindered because of the sluggish water oxidation reaction (WOR), extremely limiting the efficiency of photocatalytic H2O2 production. To tackle this challenge, carboxyl‐enriched supramolecular polymer (perylene tetracarboxylic acid ‐ PTCA) is elaborately prepared by molecular self‐assembly for overall photosynthesis of H2O2. Interestingly, the interconversion between carboxyl as Brønsted acid and its conjugated base realizes rapid proton circulation. Through this efficient tandem proton transfer process, the spatial effect of photocatalytic reduction and oxidation reaction is greatly enhanced with reduced reaction barrier. This significantly facilitates 2e‐ photocatalytic ORR to synthesize H2O2 and in the meanwhile promotes 4e‐ photocatalytic WOR to evolve O2. Consequently, the as‐developed PTCA exhibits a remarkable H2O2 yield of 185.6 μM h‐1 in pure water and air atmosphere under visible light illumination. More impressively, an appreciable H2O2 yield of 78.6 μM h‐1 can be well maintained in an anaerobic system owing to in‐situ O2 generation by 4e‐ photocatalytic WOR. Our study presents a novel concept for artificial photosynthesis of H2O2 via constructing efficient proton transfer pathway to enable rapid proton circulation.

Bonding and fracture properties of SPI-CNTs/epoxy adhesive on SPI-CNTs deposited CFRP composites

Adhesive bonding is frequently used to connect CFRP structures due to its lightweight, easy implementation and high production efficiency. However, the bonding performance of adhesive is far from satisfactory as dimension and complexity of CFRP structures increase. In this paper, a new bonding strategy for CFRP structures via introducing soy protein isolate modified carbon nanotubes (SPI-CNTs) both in the epoxy resin adhesive and on the bonding parts' surface is proposed. Results showed that SPI can effectively improve CNTs' dispersion on the two areas, notably enhancing the bonding performance of the adhesive. When 0.3 wt% SPI-CNTs was added in the adhesive, its adhesive shear strength increased to 12.76 MPa, which was 72 % higher than the unmodified CNTs/epoxy adhesive. Based on this concentration, the SPI-CNTs was deposited uniformly on the surface of the CFRP adherends via bath sonication and resulted in a maximum shear strength of 15.59 MPa, which was 22.2 % greater than the untreated ones. Based on the above condition, the Mode I fracture toughness G1c and the Mixed-Mode I/II fracture toughness Gc could reach a maximum of 0.31 and 0.44 N/mm respectively, which were 117 % and 97 % higher than the pure epoxy adhesive. The present work shows a new pathway for the effective bonding of CFRP structural components used in the aerospace industry.

Mammary fat globules as a source of mRNA to model alterations in the expression of some milk component genes during lactation in bovines

BackgroundThe milk's nutritional value is determined by its constituents, including fat, protein, carbohydrates, and minerals. The mammary gland's ability to produce milk is controlled by a complex network of genes.Thereby, the fat, protein, and lactose synthesis must be boost in milk to increase milk production efficiency. This can be accomplished by fusing genetic advancements with proper management practices. Therefore, this study aimed to investigate the association between the Lipoprotein lipase (LPL), kappa casein CSN3, and Glucose transporter 1 (GLUT1) genes expression levels and such milk components as fat, protein, and lactose in different dairy breeds during different stages of lactation.MethodsTo achieve such a purpose, 94 milk samples were collected (72 samples from 36 multiparous black-white and red-white Holstein–Friesian (HF) cows and 22 milk samples from 11 Egyptian buffaloes) during the early and peak lactation stages. The milk samples were utilized for milk analysis and genes expressions analyses using non- invasive approach in obtaining milk fat globules (MFGs) as a source of Ribonucleic acid (RNA).ResultsLPL and CSN3 genes expressions levels were found to be significantly higher in Egyptian buffalo than Holstein–Friesian (HF) cows as well as fat and protein percentages. On the other hand, GLUT1 gene expression level was shown to be significantly higher during peak lactation than early lactation. Moreover, lactose % showed a significant difference in peak lactation phase compared to early lactation phase. Also, fat and protein percentages were significantly higher in early lactation period than peak lactation period but lactose% showed the opposite pattern of Egyptian buffalo.ConclusionTotal RNA can be successfully obtained from MFGs. The results suggest that these genes play a role in glucose absorption and lactose synthesis in bovine mammary epithelial cells during lactation. Also, these results provide light on the differential expression of these genes among distinct Holstein–Friesian cow breeds and Egyptian buffalo subspecies throughout various lactation phases.

Boosting Interfacial Electron Transfer and CO2 Enrichment on ZIF-8/ZnTe for Selective Photoelectrochemical Reduction of CO2 to CO.

Artificial photosynthesis is an effective way of converting CO2 into fuel and high value-added chemicals. However, the sluggish interfacial electron transfer and adsorption of CO2 at the catalyst surface strongly hamper the activity and selectivity of CO2 reduction. Here, we report a photocathode attaching zeolitic imidazolate framework-8 (ZIF-8) onto a ZnTe surface to mimic an aquatic leaf featuring stoma and chlorophyll for efficient photoelectrochemical conversion of CO2 into CO. ZIF-8 possessing high CO2 adsorption capacity and diffusivity has been selected to enrich CO2 into nanocages and provide a large number of catalytic active sites. ZnTe with high light-absorption capacity serves as a light-absorbing layer. CO2 molecules are collected in large nanocages of ZIF-8 and delivered to the ZnTe surface. As evidenced by scanning electrochemical microscopy, the interface can effectively boost interfacial electron transfer kinetics. The ZIF-8/ZnTe photocathode with unsaturated Zn-Nx sites exhibits a high Faradaic efficiency for CO production of 92.9% and a large photocurrent of 6.67 mA·cm-2 at -2.48 V (vs Fc/Fc+) in a nonaqueous electrolyte at AM 1.5G solar irradiation (100 mW·cm-2).

Adoption of Precision Agriculture Technologies among Farmers: A Comprehensive Review

Precision agriculture (PA) technologies have spearheaded a revolution in contemporary farming practices, ushering in an era of sustainability, efficiency, and data-driven agricultural production. This comprehensive examination aims to delve deeply into the intricate dynamics surrounding the adoption of precision agriculture technologies among farmers, synthesizing existing literature, identifying key determinants, barriers, and implications. The adoption of precision agriculture technologies is influenced by a myriad of factors spanning socio-economic, institutional, technological, psychological, and attitudinal dimensions. Socio-economic factors such as farm size, income level, access to credit, and demographic characteristics are pivotal in shaping farmers' decisions to adopt PA technologies. Institutional factors, including government policies, extension services, market structures, and support networks, also wield significant influence over adoption patterns. Technological considerations, such as the complexity, compatibility, and perceived benefits of precision agriculture technologies, impact farmers' adoption decisions. Moreover, psychological factors such as risk perception, innovativeness, and attitudes towards change contribute to shaping farmers' willingness to embrace new technologies. The adoption of precision agriculture technologies holds immense promise for enhancing farm productivity, sustainability, and profitability. By enabling precise management of inputs such as water, fertilizers, pesticides, and seeds, PA technologies help optimize resource use, minimize environmental impact, and maximize yield potential. Furthermore, the integration of advanced data analytics, remote sensing, and IoT (Internet of Things) devices facilitates real-time monitoring, decision-making, and predictive analytics, empowering farmers with actionable insights for improved farm management. However, despite the compelling benefits, the adoption of precision agriculture technologies faces several barriers and challenges. High initial investment costs, limited access to capital, inadequate infrastructure, and technical knowledge gaps pose significant hurdles for farmers, particularly those operating in resource-constrained settings. Concerns regarding data privacy, security, and ownership also contribute to farmers' apprehensions about adopting PA technologies, raising questions about data governance and regulatory frameworks. To overcome these barriers and promote the widespread adoption of precision agriculture technologies, concerted efforts are needed from various stakeholders. Farmer education and training programs play a crucial role in enhancing digital literacy, technical skills, and awareness about the potential benefits of PA technologies. Government policies and incentives, including subsidies, grants, and tax incentives, can help alleviate financial barriers and incentivize adoption. Moreover, collaboration between researchers, industry stakeholders, and policymakers is essential to drive technological innovation, develop user-friendly solutions, and address emerging challenges. Investments in infrastructure, such as rural broadband connectivity and sensor networks, are also imperative to ensure the seamless integration and scalability of precision agriculture technologies across diverse farming landscapes.

Enzymatic Synthesis of Prebiotic Carbohydrates from Lactose: Integration of Osmotic Membrane Distillation with Batch Reactor System

AbstractThis study aimed to enhance galactooligosaccharide (GOS) yield by maintaining high lactose concentration levels using osmotic membrane distillation (OMD) throughout the synthesis. The main problem influencing GOS yield during transgalactosylation is the decrease of lactose concentration over extended reaction periods. By integrating OMD with a continuous stirred batch reactor, water was progressively removed from the reaction medium. Compared to a standard batch reactor, the OMD-integrated system not only increased GOS yield by a maximum of 20.1% but also reduced the time needed for equivalent lactose conversion about 15–90 min. This integration particularly boosted the formation of longer-chain GOS. A consistent GOS yield of 67% was achieved, with up to 28% lactose conversion, surpassing the non-integrated reactor’s performance. The proposed reactor design shows promise for enhancing GOS production efficiency while concurrently concentrating the reaction medium in a single step.

Fabrication of CdS NRs /MoS2@g-C3N4 nanotubes for efficient photoelectrochemical hydrogen production

Exploration of noble metal-free and highly efficient photoelectrocatalyst for hydrogen production attracts the attention of researchers. The graphitic carbon nitride nanotubes, cadmium sulfide nanorods (NRs) and molybedun disulfide, CdS NRs/MoS2@g-C3N4 nanotubes were synthesized via facile hydrothermal method for hydrogen production studies. The synthesized CdS NRs/MoS2@g-C3N4 nanotubes were studied for electrochemical hydrogen production applications. Structural data revealed that the synthesized composite materials attained crystallinity. Electrochemical investigations demonstrated the highest hydrogen production efficiency of CdS NRs/MoS2@g-C3N4 nanotubes as compared to the bare graphitic carbon nitride nanotubes. This seems that the modification of g-C3N4 NTs with MoS2 increased the photocatalytic efficiency of g-C3N4 NTs. The good efficiency of the CdS NRs/MoS2@g-C3N4 NTs is owing to a unique tubular structure, the presence of active sites, light reflection channel, nanotube composite heterostructure, electron-hole separation, better charge transfer and the synergistic effect. Moreover, it was observed that the tubular structure would be the best photoelectrocatalyst for hydrogen production achieving a geometric current density of 10 mAcm−2 at an overpotential of 0.81 V gives 144 mVdec−1 in 1 M KOH versus the RHE. These results may provide insights into constructing highly efficient photoelectrocatalysts by varying the structural morphology and heterojunction for hydrogen production.

Study on the Influence of Agricultural Scale Management Mode on Production Efficiency Based on Meta-Analysis

Agricultural scale management is an important means of improving agricultural production efficiency. To answer the controversy over whether different agricultural scale management models can improve production efficiency, this paper obtained 117,627 samples from 68 domestic and foreign literature and used meta-analysis to study the effects of land-scale operation (LSO) and service-scale operation (SSO) on agricultural production efficiency (APE). The moderators that affect the relationship between LSO, SSO, and APE are also examined. The research results show that (1) both LSO and SSO positively impact production efficiency, but LSO has a stronger impact. (2) The relationship between LSO and APE is positively regulated by the agricultural production and operation environment, characteristics of the agricultural location, degree of farmers’ participation, and types of APE, and negatively regulated by the research situation. (3) The relationship between SSO and APE is negatively regulated by APE types and data types. Therefore, the government should promote agricultural dual-scale operation according to the local conditions through the complementary advantages of LSO and SSO, so as to fully release the promotion potential of APE.

Thermal dynamics in deep shale reservoirs: Influences of the kerogen microstructural behavior on the gas adsorption/desorption capacity

In shale gas extraction projects, an investigation into the mechanisms of energy/mass transfer associated with shale gas adsorption/desorption in organic matter (kerogen) microstructure under high temperature and stress condition is crucial for improving the efficiency of shale gas production. This study presents a coupling thermo-hydro-mechanical model based on an improved fractal method that could explain the microstructural evolution of the kerogen system and the resultant alterations during the gas adsorption/desorption process under varying thermal conduction, gas seepage, and stress conditions. The influence of porosity, diameter, and tortuosity on the abundance, length, and complexity of kerogen networks under coupled multi-field effects is evaluated. The significance of this study is it could address the following aspects quantitively: (1) the spatiotemporal evolution of kerogen fractal dimensions following various extraction timelines; (2) the influence of shale temperatures on kerogen structures; (3) the influence of the kerogen fractal dimension on the shale gas desorption capacity and production efficiency; and (4) under different temperatures, when the fractal dimension/tortuosity fractal dimension of kerogen changes due to extraction disturbances, the volumetric deformation induced by gas adsorption increases by a maximum of 26.1%/decreases by 28.1% and in the later stages of extraction, the maximum gas pressure decreases by 44.7%/increases by 47.1%. The proposed fractal method adeptly reveals shale gas desorption behaviors under multi-field coupling conditions from a microscopic perspective, which cannot be found in the literature.

Paper-based Microfluidic Devices for the Analysis of Various Pathogens from Diverse Samples

Abstract: In today’s era, detection of disease is utmost important for the management of disease. Early detection leads to early management of disease. Paper-based microfluidic devices are promising technologies that are cost-effective, portable and easy to use over conventional methods. In addition, paper-based microfluidics offers low reagent/sample volume, less response time and can be used in resource-limited settings. Researchers are highly fascinated by this technology as it has a lot of potential to convert into commercial monitoring devices. The present article covers the uses of paper-based microfluidic technology for the swift and sensitive detection of pathogens from diverse samples, viz. food, water and blood. In this comprehensive review, paper-based microfluidic devices are introduced, including the basic concepts, current status and applications, along with the discussion of the limitations of microfluidics for the detection of pathogens. Although paper-based microfluidic devices are being developed, their commercialization requires simplification of manufacturing processes, reduction in production costs as well as an increase in production efficiency. Nonetheless, the integration of artificial intelligence (AI) and the Internet of Things (IoT) like smartphones, digital cameras, webcam etc. with paper-associated diagnosis has transformed the point-of-care (POC) diagnostics.

Towards an electrochemically-based circular economy: Electro-refinery for valorizing phenolic wastewater

This study introduces an innovative approach to wastewater treatment that combines two electrochemical technologies: electrolysis and electrochemical separation facilitated by anionic exchange membranes. This integrated technology converts pollutants into carboxylates, which are valuable intermediates for further electrosynthesis and fuel production. The efficacy of this approach was demonstrated using synthetic wastewater containing phenol as a model pollutant, chosen for its well-documented characteristics that enable comparative analysis with previous studies. The treatment process utilized mixed metal oxides (MMO) anodes with a composition of Ti/(RuO2)0.8(Sb2O4)0.2 and a boron-doped diamond (BDD) anode. The investigation was structured to evaluate each component of the treatment system individually before examining their collective performance. Through a series of case studies, the research not only confirmed the feasibility of this innovative technology but also highlighted the need for further study on the optimization of operational parameters and electrode materials. Comparative analysis revealed that MMO anodes outperformed BDD anodes, achieving maximum carboxylate transport rates of 138.7 mmol m−2h−1. The efficiency of carboxylate separation from the solution where they were generated reached up to 54.6 mmol kWh−1, while the maximum overall production efficiency was 8.77 mmol kWh−1. The study further determined that current density significantly affects both the production rate and the extent of mineralization, identifying optimal densities of 100 mA cm−2 and 30 mA cm−2 for the electrolyzer and electroseparator units, respectively. This work provides valuable insights for the optimization of this promising wastewater treatment technology, with potential applications in various industries.

Protonated Z-scheme CdS-covalent organic framework heterojunction with highly efficient photocatalytic hydrogen evolution

The low efficiency of photocatalytic hydrogen production from water is mainly suffer from limited light absorption, charge separation and water delivery to the active centers. Herein, an inorganic–organic Z-scheme heterojunction (CdS-COF-Ni) is constructed by in-situ growth of CdS nanosheets on the porphyrin-based covalent organic framework with nickel ions (COF-Ni) in the porphyrin centers. A built-in electric field is formed at the interface, which accelerates the separation and transfer of photogenerated charges. Moreover, through the surface protonation treatment in ascorbic acid (AC) solution, the hydrophilicity of the obtained composite is obviously increased and facilitates the transport of water molecules to the photocatalytic centers. Under the synergistic effect of the interfacial interaction and surface protonation treatment, the photocatalytic hydrogen production rate is optimized to be 18.23 mmol h−1 g−1 without adding any cocatalysts, which is 21 times that of CdS. After a series of photoelectrochemical measurements, in situ X-ray photoelectron spectroscopy (XPS) analysis, and density functional theory (DFT) calculations, it is found that the photocatalytic charge transfer pathway conforms to the Z-scheme mechanism, which not only greatly accelerates the separation and transfer of photogenerated charges, but also retains a high reduction capacity for water splitting. This work offers a good strategy for constructing highly efficient organic–inorganic heterojunctions for water splitting.

Enhancing efficiency in ethanol production from high solid corn stover: Insights into enzymatic hydrolysis parameters and cellulase recovery

BackgroundThe simultaneous saccharification and co-fermentation (SSCF) at high solid loading is an effective approach to improve the economic feasibility of bioethanol. MethodsIn this study, the high-solid SSCF of superfine grinding corn stover was treated with cheap and readily available deionized water (DW) instead of sodium citrate buffer solution (SCBS). Additionally, the evaluation of temperature, enzyme loading, solid loading, and cellulose recovery were carried out to determine their impact on ethanol production. Significant FindingsThe results of the analysis indicated that replacing SCBS with DW had negligible effects on the SSCF of ethanol and byproducts (acetic acid and glycerol). The ethanol yield increased by 18 % at 35 °C compared to the yield at 30 °C. As enzyme loading increased, more cellulose active sites in corn stover were bound by cellulase, which increased the ethanol yield by improving the efficiency of enzymatic hydrolysis. The SSCF process didn't incorporate any buffer, resulting in an even higher ethanol titer (55.42 g/L). Furthermore, the cellulase productivity increased by 71 % after recovery, compared to the non-recovery. The results indicated that the optimized SSCF process is a potential technique for producing bioethanol on a commercial level because it improves the production efficiency while keeping costs low.

Study on biogas production from pig manure wastewater by microbial electrosynthesis at sub-psychrophilic conditions

In colder regions, relatively low temperatures results in low microbial activity and low biogas production in anaerobic digestion. This study investigated if microbial electrosynthesis system (MES) can enhance biogas production from pig manure wastewater under sub-psychrophilic conditions (20 °C). Results showed that the applied voltage of MES (0.4V and 0.8V) significantly increased the biogas production and COD removal rate. Biogas production and COD removal rate increased most when the voltage reached 0.8V (34.77%, 26.67%), and decreased when the voltage was 1.2V. Low voltage (≤ 0.8V) did not significantly alter the microbial structure, but higher voltage (1.2V) resulted in a significant decrease in Clostridium and Methanosarcina. Coenzyme F420, NADH, as indicators for methanogenic efficiency, showed the highest fluorescence intensity at 0.8V and decreased at 1.2V. Results indicated that the improvement of gas production was mainly due to the improvement of key enzymes rather than the shift of microbial structure. The information provided will be useful to improve the efficiency of biogas production.

Sustainable conversion of carbon dioxide to high-value antioxidant astaxanthin through microbial electrosynthesis-assisted microalgae cultivation

Microbial electrosynthesis (MES) effectively converts carbon dioxide (CO2) to short carboxylic acids but has lower efficiency for higher molecular value-added products. This study used a two-stage process integrating MES with microalgae cultivation to convert CO2 into a value-added chemical—astaxanthin, a xanthophyll carotenoid with strong antioxidant activity. In the first stage, MESs featuring platinum-coated anodes and carbonaceous cathodes were employed to bioelectrochemically convert CO2 to volatile fatty acids (VFAs). In the second stage, microalgal cultivation for sustainable astaxanthin production was conducted using a VFA-containing MES effluent. In the MES operation, a newly designed cathode with alternating layers of carbon felt (CF) and reticulated vitreous carbon (RVC) significantly improved hydrodynamics and bacterial attachment. Consequently, the CF/RVC composite cathode produced 7.68g/L VFAs from CO2, with the highest production rate of 1225mg/L/day and the highest coulombic efficiency of 94.15% at 2.8V. Feeding acetate-containing catholyte effluent demonstrated faster growth of microalgae and astaxanthin accumulation compared to autotrophic culture, indicating synergistic integration of MES and microalgae for capturing value from CO2. Among tested microalgae strains, Haematococcus pluvialis most efficiently accumulated astaxanthin up to 12.95mg/L as cultured with MES effluent. Successful CO2-to-astaxanthin conversion using MES and microalgae can contribute to resolving unprecedented environmental challenges attributed to the excess emission of CO2.

Tandem Proton Transfer in Carboxylated Supramolecular Polymer for Highly Efficient Overall Photosynthesis of Hydrogen Peroxide.

Proton supply is as critical as O2 activation for artificial photosynthesis of H2O2via two-electron oxygen reduction reaction (2e- ORR). However, proton release via water dissociation is frequently hindered because of the sluggish water oxidation reaction (WOR), extremely limiting the efficiency of photocatalytic H2O2 production. To tackle this challenge, carboxyl-enriched supramolecular polymer (perylene tetracarboxylic acid - PTCA) is elaborately prepared by molecular self-assembly for overall photosynthesis of H2O2. Interestingly, the interconversion between carboxyl as Brønsted acid and its conjugated base realizes rapid proton circulation. Through this efficient tandem proton transfer process, the spatial effect of photocatalytic reduction and oxidation reaction is greatly enhanced with reduced reaction barrier. This significantly facilitates 2e- photocatalytic ORR to synthesize H2O2 and in the meanwhile promotes 4e- photocatalytic WOR to evolve O2. Consequently, the as-developed PTCA exhibits a remarkable H2O2 yield of 185.6 μM h-1 in pure water and air atmosphere under visible light illumination. More impressively, an appreciable H2O2 yield of 78.6 μM h-1 can be well maintained in an anaerobic system owing to in-situ O2 generation by 4e- photocatalytic WOR. Our study presents a novel concept for artificial photosynthesis of H2O2 via constructing efficient proton transfer pathway to enable rapid proton circulation.

Integration of renewable energy sources in tandem with electrolysis: A technology review for green hydrogen production

The global shift toward sustainable energy solutions emphasises the urgent need to harness renewable sources for green hydrogen production, presenting a critical opportunity in the transition to a low-carbon economy. Despite its potential, integrating renewable energy with electrolysis to produce green hydrogen faces significant technological and economic challenges, particularly in achieving high efficiency and cost-effectiveness at scale. This review systematically examines the latest advancements in electrolysis technologies—alkaline, proton exchange membrane electrolysis cell (PEMEC), and solid oxide—and explores innovative grid integration and energy storage solutions that enhance the viability of green hydrogen. The study reveals enhanced performance metrics in electrolysis processes and identifies critical factors that influence the operational efficiency and sustainability of green hydrogen production. Key findings demonstrate the potential for substantial reductions in the cost and energy requirements of hydrogen production by optimising electrolyser design and operation. The insights from this research provide a foundational strategy for scaling up green hydrogen as a sustainable energy carrier, contributing to global efforts to reduce greenhouse gas emissions and advance toward carbon neutrality. The integration of these technologies could revolutionise energy systems worldwide, aligning with policy frameworks and market dynamics to foster broader adoption of green hydrogen.

A Systematic Review and Meta-Analysis of Factors Influencing Water Use Behaviour and the Efficiency of Agricultural Production in South Africa

Water use behaviour and efficiency are essential topics regarding water scarcity. Water is a life-sustaining resource used for various activities within the three primary sectors: agricultural, industrial, and domestic. Increasing competition among these sectors could affect the availability and sustainability of water use. The higher demand for agricultural-related commodities emphasizes the efficient and productive use of water. Still, to achieve this, the behaviour of consumers regarding water use needs to be changed. This systematic review paper aims to highlight the factors affecting water use behaviour and efficiency for agricultural production in South Africa. It further aims to determine how agricultural producers change their behaviour to improve their water use efficiency. The Preferred Reporting Items for Systematic Reviews and Meta-Analyses (PRISMA) criteria were used as a reporting framework and guidelines to identify the articles included in the review. The review only included articles focussing on agricultural water use behaviour and efficiency and articles written in English and excluded articles from web pages, blogs, magazines, etc. The databases used for the review were Google Scholar and Web of Science. The articles were reviewed by the five authors to avoid the risk of bias, along with the inclusion and exclusion criteria. The final review included 30 peer-reviewed articles. A word frequency table was developed using the NVivo 14 software to conduct a thematic analysis for the review. The main factors which played a role in the water use behaviour and efficiency of farmers were (i) climate and adaptation strategies, (ii) policy and water pricing, and (iii) agricultural production and management. Each category elaborated on how water use could be improved and the different measures adopted to incorporate sustainable farm water use. This could be a guideline for farmers, stakeholders, and policymakers to improve and enhance water use behaviour and efficiency in Sub-Saharan Africa, particularly South Africa. This could ultimately assist in efficiently using the water while enhancing sustainability within the agricultural sector and attaining Sustainable Development Goal (SDG) six, which is to increase water use efficiency. The limitation of this study was that it was only narrowed down to the geographical context of South Africa. This review was funded by the Water Research Commission (WRC) of South Africa (Project Number: C20222023-00798). This review was not registered.

Growth performance, proximate composition and fatty acid profile of black soldier fly larvae reared on two grape pomace varieties

The black soldier fly (Hermetia illucens) is attracting increasing interest for its ability to convert low-value substrates into highly nutritious feed. This study aimed at evaluating grape pomace from two varieties (Becuet – B; Moscato – M) as rearing substrates for black soldier fly larvae (BSFL), focusing on the related effects on larval growth performance, proximate composition, and fatty acid profile. A total of six replicates per treatment, and 1 000 BSFL per replica, were used. Larval development was assessed by larvae weight, which was recorded eight times during the trial: the day after the beginning of the trial, and then on days 5, 8, 13, 15, 20, 22, and 27 (day in which the 30% of BSFL reached the prepupal stage). Production and waste reduction efficiency parameters, namely the growth rate, substrate reduction and substrate reduction index, were calculated. The two grape pomace varieties were analysed for their proximate composition and fatty acid profile; the same analyses were conducted on BSFL (30 larvae per replica) that were collected at the end of the trial (day 27). The growth rate of BSFL showed a higher value when the larvae were reared on B substrate (4.4 and 3.2 mg/day for B and M, respectively; P<0.01). The rearing substrate did not significantly affect the proximate composition of BSFL. The percentage of total lipids (TL) in M-fed BSFL was significantly higher than in B ones. Total saturated (P<0.001) and monounsaturated fatty acids (P<0.05) were significantly higher in M-fed BSFL, while an opposite trend was observed for total branched-chain (P<0.001) and total polyunsaturated fatty acids (P<0.001). Interestingly, some conjugated linoleic acid (CLA) isomers [i.e., C18:2 c9t11(+t7c9+t8c10) and t9t11] were detected in low amounts in both rearing substrates (total CLA equal to 0.085 and 0.16 g/100 g TL in B and M substrate, respectively). Some CLA isomers (i.e., C18:2 c9t11, t7c9, and t10c12) were also found in BSFL, reaching a total CLA concentration equal to 2.95 and 0.052 g/100 g of TL in B-fed and M-fed BSFL, respectively. This study demonstrates that winery by-products from different grape varieties can significantly affect the development and lipid composition of BSFL. The CLA biosynthesis potential of BSFL opens newsworthy perspectives for a new valorisation of winery by-products to produce full-fat black soldier fly meal and black soldier fly oil enriched in specific fatty acids of potential health-promoting interest.

Effects of air to fuel ratio on parameters of combustor used for gas turbine engines: Applications of turbojet, turbofan, turboprop and turboshaft

Combustors of gas turbine engines have generally the highest irreversibility due to the combustion process. Therefore, to observe influence of air to fuel ratio (AFR) on combustor performance is of high importance. In this study, thermodynamic laws are employed to separately determine adiabatic flame temperature (AFT), entropy production, exergy destruction and exergy efficiency of combustor for turbojet (TJ), turbofan (TF), turboprop (TP) and turboshaft (TS) where variables are AFR, combustor inlet temperature (CIT) and combustor pressure ratio (CPR). In this regard, the higher the AFR, the lower the adiabatic flame temperature, however the higher the entropy production for related combustor. Similarly, increasing AFR leads to raise exergy destruction, thereby lowering exergy efficiency. On the other hand, as CIT increases, exergy efficiency of the combustor improves whereas slight effects of CPR on the combustor metrics are observed. Namely, due to variation of AFR, exergy destruction of combustor changes between 0.512 MW and 0.825 MW for TJ, between 1.807 MW and 2.735 MW for TS, between 28.38 MW and 40.49 MW for TF and between 3.102 MW and 4.564 MW for TP. Moreover, exergy efficiency of combustor changes between 59% and 73% for TJ, between 70% and 77% for TS, between 78% and 81% for TF and between 75% and 79% for TP engine through the determined AFR and CIT ranges. These findings indicate that combustor of each gas turbine engine demonstrates different behavior according to the mentioned variables and exergy efficiency of combustor depends on finding the optimum points of combustor variables.