The propagation characteristics of dust acoustic solitary waves (DASWs) in dusty plasmas with the effects of polarization force and superthermal ions are studied. First, the polarization force induced by superthermal ions is obtained. It is shown that the superthermality of background ions affect the Debye screening of dust grains as well as the polarization force significantly. Then for small amplitude solitary waves, the KdV equation is obtained by applying the reductive perturbation technique. And for the arbitrary amplitude solitary waves, the Sagdeev potential method is employed and the Sagdeev potential is analyzed. In both case, the effects of the polarization force associated the ions’ superthermality on the characteristic of the DASWs are analyzed.