Effect Of Natural Aging Research Articles

Polyester Microplastic Mitigated NH3 Volatilization from a Rice–Wheat Rotation System: Does Particle Size or Natural Aging Effect Matter?

Polyester Microplastic Mitigated NH₃ Volatilization from a Rice–Wheat Rotation System: Does Particle Size or Natural Aging Effect Matter?

Effect of Cold Rolling on Cluster(1) Dissolvability during Artificial Aging and Formability during Natural Aging in Al-0.6Mg-1.0Si-0.5Cu Alloy

Natural aging after solution treatment has a negative effect on the precipitation strengthening of Al–Mg–Si alloys since Cluster(1) formed at a room temperature cannot be dissolved or transformed into precipitates during artificial aging at 170 °C. In this study, cold rolling is focused on as an alternative solution to pre-aging, which is a conventional method to prevent Cluster(1) formation. It is known that excess vacancies are necessary for cluster formation. Cold rolling suppresses cluster formation because excess vacancies disappear at dislocations introduced by cold rolling. In addition, it is expected that cold rolling accelerates the precipitation behavior because the diffusion of solute atoms is promoted by introduced lattice defects. The transition of Cluster(1) was evaluated by Micro Vickers hardness tests, tensile tests, electrical conductivity measurements and differential scanning calorimetry analyses. Results showed the negative effect of natural aging was almost suppressed in 10% cold-rolled samples and completely suppressed in 30% cold-rolled samples since Cluster(1) dissolved during artificial aging at 170 °C due to lowering of the temperature of Cluster(1) dissolution by cold rolling. It was found that the precipitation in cold-rolled samples was accelerated since the hardness peak of 10% cold-rolled samples appeared earlier than T6 and pre-aged samples.

Mechanism for the Inhibition of the Negative Natural Aging Effect in a Si-Rich Al-Mg-Si Alloy

Mechanism for the Inhibition of the Negative Natural Aging Effect in a Si-Rich Al-Mg-Si Alloy

Impact of natural and artificial ageing on the properties of multilayer external wall thermal insulation systems

Multilayer external wall thermal insulation systems are widely used in new constructions and for the retrofitting of building façades. Despite the increasing use as constructive solution, significant anomalies have been frequently identified on these systems only few years after their application, raising questions on their long-term durability. This paper focuses on the effects of one-year natural ageing and artificial ageing through hygrothermal cycles (heat/rain and heat/cold) on the water performance (capillary water absorption and drying kinetics), bio-susceptibility (mould development) and surface properties (colour, gloss, and roughness) of four multilayer external wall thermal insulation systems (three ETICS and a thermal rendering system). Results showed a significant loss of surface hydrophobicity after ageing. Considering the 24 h water absorption results, an increase up to 73% and 432% was obtained for the naturally and artificially aged systems, respectively, and when compared to the reference unaged systems. The drying kinetics was affected by ageing, with increases of the drying resistance ranging between 47% and 122% after artificial ageing. Traces of mould growth were observed on the artificially aged systems; however, no growth was detected on either the unaged or the one-year naturally aged systems. Substantial colour change for all systems after ageing was observed, confirming aesthetic alteration. Results contribute towards the development of implemented artificial ageing protocols, as well as for the delivery of multilayer thermal systems with enhanced performance and durability.

Effect of natural and artificial ageing on steel mechanical properties and fracture toughness

The operating conditions of welded structures of shipbuilding steels, including operation at northern latitudes, determine high requirements for their quality. Materials used for such structures should guarantee stable mechanical properties, good processability during hull fabrication and serviceability at subzero temperatures. Strain aging is due to the thermodynamic non-equilibrium of steel structure in its initial state and gradual transition to the equilibrium state provided the diffusion mobility of interstitial atoms is sufficient. In unfavorable conditions, this can lead to the degradation of properties during processing (cold straightening, bending, welding), operation or long-term storage. The paper studies the probability of natural and artificial ageing processes in steels of different chemical compositions due to bulk diffusion and carbon dislocation core diffusion (dislocation pipe diffusion). The effect of strain ageing on mechanical properties and the CTOD parameter value has been examined.

Effect of In addition on the precipitation behavior and mechanical property for Al-Mg-Si alloys

The impact of In addition on the precipitation behavior and properties for Al-Mg-Si alloys under different aging treatments was systematically studied by hardness measurements, atom probe tomography (APT), high angle annular dark field scanning transmission electron microscopy (HAADF-STEM) and density functional theory (DFT) calculations. We found that the In addition effectively suppresses the harmful effect of natural aging (NA), and improves the age hardening for the Al-Mg-Si alloy. Mg-Si-In clusters are formed in the early stage of aging caused by the incorporation of In atoms, which can facilitate the nucleation of the β" phase. During peak aging, In atoms distort the well-ordered structure of the β" and occupy the positions in the interface of the β", facilitating the transition of β" to post-β" (i.e., U2 and β′). During the following aging, In atoms are presented in two different configurations: forming In-rich particles and aggregation at the interfaces of β′. Most of the In-rich particles are formed at the edge of the β′ particles. The segregation of In atoms at the precipitate/matrix interface and the formation of In-rich particles can probably be attributed to the reduced strain energy of the β′ phase it brings about.

4 Day in dry immersion reproduces partially the aging effect on the arteries as observed during 6 month spaceflight or confinement

The objectives of this study were to determine whether 4 days of dry immersion (DI) induced similar arterial aging as spaceflight and to test the impact of thigh cuffs. Eighteen subjects underwent DI; nine wore thigh cuffs. Cardiac and arterial targets were assessed by ultrasound. No significant differences were found between the groups. The left ventricle volume, stroke volume (SV), and ejection fraction decreased with DI (p < 0.001). Carotid distensibility reduced (p < 0.05), carotid to femoral arterial tree became stiffer in 33% of the subjects, and femoral artery intima media thickness increased (p < 0.05). A reduction in plasma volume is likely to have caused the observed cardiac changes, whereas the arterial wall changes are probably best explained by hypokinesia and/or environmental stress. These changes are similar but lower in amplitude than those observed in spaceflight and mimic the natural aging effect on earth. The daytime-worn thigh cuffs had no acute or chronic impact on these arterial-focused measurements.

Evaluation of Recurrent Neural Network Models for Parkinson's Disease Classification Using Drawing Data.

Parkinson's disease is a disorder that affects the neurons in the human brain. The various symptoms include slowness of motor functions (bradykinesia), motor instability, speech impairment and in some cases, psychiatric effects such as hallucinations. Most of these, however, are also common side effects of natural aging. This makes an accurate diagnosis of Parkinson's disease a challenging task. Some breakthroughs have been made in recent years with the help of deep learning. This work aims at considering figure drawing data as a time series of coordinates, angles and pressure readings to train recurrent neural network models. In addition, the work compares two recurrent network models, Long Short-Term Memory and Echo State Networks, to explore the advantages and disadvantages of both architectures.

Human Cytomegalovirus Immediate Early Protein 2 Protein Causes Cognitive Disorder by Damaging Synaptic Plasticity in Human Cytomegalovirus-UL122-Tg Mice.

Human cytomegalovirus (HCMV) infection is very common in the human population all around the world. Although the majority of HCMV infections are asymptomatic, they can cause neurologic deficits. Previous studies have shown that immediate early protein 2 (IE2, also known as UL122) of HCMV is related with the cognitive disorder mechanism. Due to species isolation, a HCMV-infected animal model could not be established which meant a study into the long-term effects of IE2 on neural development could not be carried out. By establishing HCMV-UL122-Tg mice (UL122 mice), we explored the cognitive behavior and complexity of neuron changes in this transgenic UL122 mice that could consistently express IE2 protein at different ages (confirmed in both 6- and 12-month-old UL122 mice). In the Morris water maze, cognitive impairment was more pronounced in 12-month-old UL122 mice than in 6-month-old ones. At the same time, a decrease of the density of dendritic spines and branches in the hippocampal neurons of 12-month-old mice was observed. Moreover, long-term potentiation was showed to be impaired in 12-month-old UL122 mice. The expressions of several synaptic plasticity-regulated molecules were reduced in 12-month-old UL122 mice, including scaffold proteins postsynaptic density protein 95 (PSD95) and microtubule-associated protein 2 (MAP2). Binding the expression of IE2 was increased in 12-month-old mice compared with 6-month-old mice, and results of statistical analysis suggested that the cognitive damage was not caused by natural animal aging, which might exclude the effect of natural aging on cognitive impairment. All these results suggested that IE2 acted as a pathogenic regulator in damaging synaptic plasticity by downregulating the expression of plasticity-related proteins (PRPs), and this damage increased with aging.

Giant bake hardening response of multi-scale precipitation strengthened Al-Mg-Si-Cu-Zn alloy via pre-aging treatments

A high-performance Al-1.20Mg-1.60Si-0.20Cu-3.00Zn (wt%) alloy was designed based on the concept of high degree alloying with the main element content exceeding the range found for the 6xxx aluminum alloys. Using the optimized pre-aging (160 °C-6 min) treatment, compared to the 6016 and 6111 alloys, both the plasticity (T4P) and strength (BH) of the alloy were improved. In particular, the bake hardening response was as high as 180.2 MPa, which was more than 2 times higher than those of the 6016 and 6111 alloys. The enhanced performance of the alloy was attributed to micron/nanoscale multi-particle strengthening effects and optimized deformation heat treatments. The micro-scale phases were Mg2Si and Al(Fe,Mn)Si, and the nano-scale phases were GP zones and β"phases. Precipitation kinetics calculations, microstructure quantitative statistics, and strengthening contribution ratio analysis showed that the optimized pre-aging treatment effectively suppresses the negative natural aging effect, reduces the β "phase activation energy, and increases the mean diameter and number density of the GP zones (β"-nuclei) prior to paint baking and the β" phase number density after paint baking, thus improving the effectiveness of the paint baking treatment.

Bimodal 1H Double Quantum Build-Up Curves by Fourier and Laplace-like Transforms on Aged Cross-Linked Natural Rubber.

The 1H DQ Fourier and Laplace-like spectra for a series of cross-linked natural rubber (NR) samples naturally aged during six years are presented and characterized. The DQ build-up curves of these samples present two peaks which cannot be described by classical functions. The DQ Fourier spectra can be obtained after a numeric procedure which introduces a correction time which depends less on the chosen approximation, spin-½ and isolated CH2 and CH3 functional groups. The DQ Fourier spectra are well described by the distributions of the residual dipolar coupling correlated with the distribution of the end-to-end vector of the polymer network, and with the second and fourth van Vleck moments. The deconvolution of DQ Fourier spectra with a sum of four Gaussian variates show that the center and the width of Gaussian functions increase linearly with the increase in the cross-link density. The Laplace-like spectra for the natural aged NR DQ build-up curves are presented. The centers of four Gaussian distributions obtained via both methods are consistent. The differences between the Fourier and Laplace-like spectra consist mainly of the spectral resolution in the favor of Laplace-like spectra. The last one was used to discuss the effect of natural aging for cross-linked NR.

Conducted EMI susceptibility analysis of a COTS processor as function of thermal cycling and overvoltage stresses

As technology evolves, processors are increasingly used in critical applications while the operating environment has become more unfavorable, with greater electromagnetic interference (EMI) detrimental to the proper functioning of the component. In this context, EMI represents one of the most critical problems for assessing the reliability and robustness of electronic systems, worsening when associated with the natural aging effect of circuits. This paper investigates the electromagnetic susceptibility (EMS) of a Cortex-M4 processor to conducted EMI in the power supply lines as function of accelerated aging. The component's reliability assessment was performed according to the IEC 61000-4-4 and IEC 61000-4-6 standards as function of the accelerated aging by means of stress combination of temperature variations and overvoltage. Test results demonstrated an increased processor susceptibility to conducted EMI after accelerated aging process. In this context, after aging it was observed a 13,166% increase in the number of observed faults, while current consumption raised by 5.63%.

Long-term immobilization of soil metalloids under simulated aging: Experimental and modeling approach

Aging is an inevitable natural process, leading to faded performances of soil amendments. Understanding long-term aging features is crucial for the risk management of contaminated soil. In this study, a novel quantitative aging method, namely, the “soil coin” method, was developed, which can simulate the effects of natural aging on metal(loid) immobilization performances. To better depict the aging features, two models on the basis of conditional probability-induced failure were developed. To effectively immobilize soil arsenic (As) and antimony (Sb), magnesium (Mg) and iron (Fe) oxides were simultaneously introduced to either fresh or pre-oxidized biochar via a facile method. Although post-application aging is harmful, pre-aging (i.e., pre-oxidation using H2O2) in turn served as an effective means to introduce more metal oxides, thereby rendering better short-term and long-term effectiveness for metalloid immobilization. Experimental and modeling approaches suggested that precipitation accounted for long-term immobilization, while a constant aging rate is the key feature for a promising soil amendment. It is suggested that to further calibrate this method and better understand the immobilization performances in the long run, more evidence from the field is needed.

Effect of natural aging on relaxation behavior and mechanical property of a La-based bulk metallic glass

Natural aging, which is the spontaneous temporal evolution of meta-stable systems, is a great task in amorphous materials. In this work, La62Al14(Cu5/6Ag1/6)14(Ni1/2Co1/2)10 BMGs with the same master alloy was prepared 8 years ago and at present. The effect of natural aging on the relaxation behavior and mechanical property of the La-based BMG was studied. Experimental results based on dynamic mechanical analysis and differential scanning calorimetry showed that natural aging for 8 years caused the atomic configuration to relax from a meta-stable state to a relatively more stable state, and the crystallization characteristic was also affected by natural aging. The results of compression testing indicated that the plasticity of the La-based BMG would be reduced, as a result of structural relaxation caused by natural aging.

Natural Aging Effect of Al-20Zn-3Cu Alloy on Mechanical Properties and Its Relation to Microstructural Change

We investigate the effect of the natural age-hardening response of the Al-20Zn-3Cu alloy with natural aging times up to 12 months. The ultimate tensile strength of the Al-20Zn-3Cu alloy is drastically enhanced from 308 to 320 MPa after 2 months and from 320 to 346 MPa after 9 months. Then, natural age hardening becomes saturated after 9 months. A microstructural investigation reveals that the natural age-hardening mechanism is mainly induced by the diffusion of the Zn element. First, a rapid decrease in the volume fraction of the eutectoid lamellae (α-Al+η-Zn) is observed at the early stage of natural aging, leading to an increase in the tensile strength. This originates from the relatively high diffusivity of Zn due to its low melting temperature. Then, the diffusion of Zn into the Al matrix induces clusters of solute atoms that enhance the growth rate of the nanoprecipitates formed in the Al matrix. As a consequence, the tensile strength of the natural-aged Al-20Zn-3Cu alloy increases drastically after 9 months, whereas the ductility is significantly degraded.

Effects of natural aging on the surface compositions and optical properties of thermochromic vanadium oxide films

We experimentally investigate the long-term atmospheric durability of thermochromic vanadium oxide (VOX) films. The VOX films were deposited on glass substrates by reactive direct current magnetron sputtering and were then in-situ annealed at the preparation temperature ≤350 °C. The X-ray photoelectron spectroscopy (XPS) was applied to investigate the surface compositions of the natural aged films, while the optical properties of the films were characterized by the spectrophotometer and spectroscopic ellipsometry. The XPS results reveal that the oxygen-deficient VOX (X < 2.5) components possessing remarkable chemical changes is preferred to react with the O2 and H2O in the air and become high oxidation state compounds. However, it is worth to note that the optical properties of the films shows extra-low variation performance (e.g. linear increasing rate of transmittance ~0.00448% per day @ λ = 600 nm). The aging mechanism of the VOX films in air was interpreted in terms of the interface aging and the diffusion-reaction aging on basis of the above experimental results. This study would provide valuable experience of the natural aging of VOX films.

Use of Sediqualsoft® to Determine the Toxicity of Cigarette Butts to Marine Species: A Weather Simulation Test

Cigarette butts (CBs) are among the dominant constituents of marine and beach litter. Few studies have been conducted, and the environmental effects of CBs on marine species are still poorly understood. This study aims to evaluate the ecotoxicological effects on marine organisms of both classic and electronic CBs. Three representative species of different trophic levels in marine ecosystems (Aliivibrio fischeri, bacteria; Phaeodactylum tricornutum, algae, primary producers; Paracentrotus lividus, echinoderms, consumers) were tested. The effects of natural ageing of CBs due to exposure to atmospheric conditions (natural sunlight vs. simulated rain) and for different times (1 vs. 2 weeks) were evaluated. The results were weighted together to obtain a synthetic hazard level to the environment (Class of Hazard) from Sediqualsoft®. Classic CBs (CCBs) performed the worst and posed a mild to moderate risk compared to electronic CBs (absent Class of Hazard). Smoked classic CBs posed a higher environmental risk than unsmoked. The highest risk was produced by classic CBs after one week of exposure in dry weather. Echinoderms and the body size reduction in normo-formed (72 h) plutei were shown to be the more sensitive organism and endpoint, respectively. We recommend the use of Sediqualsoft® software for risk assessment studies of sediments contaminated with contaminants of various types, especially in conjunction with a weight of evidence approach (WOE).

Effect of Natural Aging on Oak Wood Fire Resistance.

The paper deals with the assessment of the age of oak wood (0, 10, 40, 80 and 120 years) on its fire resistance. Chemical composition of wood (extractives, cellulose, holocellulose, lignin) was determined by wet chemistry methods and elementary analysis was performed according to ISO standards. From the fire-technical properties, the flame ignition and the spontaneous ignition temperature (including calculated activation energy) and mass burning rate were evaluated. The lignin content does not change, the content of extractives and cellulose is higher and the content of holocellulose decreases with the higher age of wood. The elementary analysis shows the lowest proportion content of nitrogen, sulfur, phosphor and the highest content of carbon in the oldest wood. Values of flame ignition and spontaneous ignition temperature for individual samples were very similar. The activation energy ranged from 42.4 kJ·mol−1 (120-year-old) to 50.7 kJ·mol−1 (40-year-old), and the burning rate varied from 0.2992%·s−1 (80-year-old) to 0.4965%·s−1 (10-year-old). The difference among the values of spontaneous ignition activation energy is clear evidence of higher resistance to initiation of older wood (40- and 80-year-old) in comparison with the younger oak wood (0- and 10-year-old). The oldest sample is the least thermally resistant due to the different chemical composition compared to the younger wood.

Effects of chemical and natural ageing on the release of potentially toxic metal additives in commercial PVC microplastics

Various chemical substances, such as potentially toxic trace metals, are used as plastic additives to improve the performance of polymers and extend the service life of plastic products. However, these added trace metals are likely released from plastic into the environment when the plastic becomes a pollutant, although the process is poorly understood. In this study, chemical ageing of commercial polyvinyl chloride (PVC) microplastics using hydrogen peroxide (H2O2) and natural ageing of PVC that had been added to an alkaline paddy soil were undertaken to evaluate the potential release of trace metals from PVC. Enhanced release of trace metals from PVC with the increasing H2O2 concentrations was observed, in which the released Pb was 1–2 orders of magnitude higher than other metals (p < 0.01). The released Cr, Ni, Pb, Cu, Zn, Cd and Mn accounted for 87.37%, 79.27%, 22.02%, 20.93%, 17.06%, 15.11%, and 11.02% of their total concentrations (0.28 ± 0.03, 0.08 ± 0.01, 13.67 ± 0.18, 1.07 ± 0.02, 2.20 ± 0.18, 0.05 ± 0.00 and 1.26 ± 0.08 mmol kg−1) in PVC after ageing with 30% H2O2, respectively. Compared with the control treatment without PVC addition, the concentrations of CaCl2-extractable Cu, Mn, Ni, Pb, and Zn in the soil treated with 5% PVC are significantly increased after incubation for 60 days (p < 0.01). In conclusion, chemical and natural ageing have the potential to lead to the release of Cu, Mn, Ni, Pb, and Zn from the commercial PVC into aquatic and terrestrial environments.

Effects of natural aging and pre-aging on the strength and electrical conductivity in Al-Mg-Si AA6201 conductor alloys

The effects of natural aging (NA), and its combination with pre-aging (PA), on the strength and electrical conductivity (EC) of drawn Al–Mg–Si AA6201 conductor alloys were studied. Natural aging had a negative impact on precipitation before the drawing process. However, wire drawing counteracted the detrimental influence of natural aging on precipitation hardening; after drawing and post-aging, the NA samples exhibited a better combination of strength and EC compared to those of the samples that did not undergo NA. Transmission electron microscopy results show that the NA samples exhibited a higher number density of precipitates in the drawn and post-aged conditions relative to those of the samples that did not undergo NA. The combination of natural aging and pre-aging followed by wire drawing and post-aging provided the highest strength (369 MPa) with an acceptable EC (53% IACS). The applied natural aging and pre-aging modified the strengthening contributions in AA6201 conductor alloys in favor of precipitation hardening. The relationship between strength and EC was analyzed in detail using strengthening models and Matthiessen's rule based on various microstructural features.