Filtering Effect Research Articles

A ratiometric fluorescence sensor with different responsive modes based on carbon dots-embedded Tb-MOFs for the determination of norfloxacin and levofloxacin

Norfloxacin (NOR) and levofloxacin (LEV) are the two most frequently used fluoroquinolones (FQs) in clinic. Their residues seriously endanger the ecosystem and human health. Due to their similarity in structure and properties, it is urgent to develop an efficient and sensitive strategy for detection and differentiation. Herein, we synthesized a novel ratiometric fluorescent sensor for the first time by combining N, S co-doped carbon dots (CDs) and the precursors of Tb-MOFs through a facile one-pot method. The introduction of CDs effectively facilitated the energy transfer between Tb3+ and FQs, overcoming the limitation that single Tb-MOFs could not identify similar antibiotics. Specifically, the presence of NOR resulted in reverse signal response through the inner filter effect and antenna effect. The synergistic effect of these two mechanisms contributed to achieving signal amplification accompanied by a distinguishable color transition. The limit of detection (LOD) was 0.036 μM. Different from NOR, the addition of LEV reduced the electron density of the system, weakened the coordination ability of Tb3+ with LEV, and induced a single signal response with Tb3+ fluorescence intensity as a reference signal (LOD = 0.383 μM). Furthermore, the method proved to be rapid and visual, allowing for the straightforward analysis of FQs residues in water, food matrices, and biological samples with satisfactory precision. By integrating N, S-CDs@Tb-MOFs with flexible substrates, the paper-based sensor facilitated the visual quantitative determination of FQs by reading RGB values. The developed sensor presents a promising strategy for the identification and real-time monitoring of antibiotics.

Rainwater-borne H2O2 accelerates roxarsone degradation and reduces bioavailability of arsenic in paddy rice soils

Contamination of rice by arsenic represents a significant human health risk. Roxarsone -bearing poultry manure is a major pollution source of arsenic to paddy soils. A mesocosm experiment plus a laboratory experiment was conducted to reveal the role of rainwater-borne H2O2 in the degradation of roxarsone in paddy rice soils. While roxarsone could be degraded via chemical oxidation by Fenton reaction-derived hydroxyl radical, microbially mediated decomposition was the major mechanism. The input of H2O2 into the paddy soils created a higher redox potential, which favored certain roxarsone-degrading and As(III)-oxidizing bacterial strains and disfavored certain As(V)-reducing bacterial strains. This was likely to be responsible for the enhanced roxarsone degradation and transformation of As(III) to As(V). Fenton-like reaction also tended to enhance the formation of Fe plaque on the root surface, which acted as a filter to retain As. The dominance of As(V) in porewater, combined with the filtering effect of Fe plaque significantly reduced the uptake of inorganic As by the rice plants and consequently its accumulation in the rice grains. The findings have implications for developing management strategies to minimize the negative impacts from the application of roxarsone-containing manure for fertilization of paddy rice soils.

Tracing Magnetic Fields with the Gradient Technique: Spatial Filtering Effect and Use of Interferometers

Probing magnetic fields in astrophysical environments is both important and challenging. The Gradient Technique (GT) is a new tool for tracing magnetic fields, rooted in the properties of magnetohydrodynamic (MHD) turbulence and turbulent magnetic reconnection. In this work, we examine the performance of GT when applied to synthetic synchrotron emission and spectroscopic data obtained from sub-Alfvénic and trans-Alfvénic MHD simulations. We demonstrate the improved accuracy of GT in tracing magnetic fields in the absence of low spatial frequencies. Additionally, we apply a low-spatial-frequency filter to a diffuse neutral hydrogen region selected from the GALFA-H i survey. Our results show an increased alignment between the magnetic fields inferred from GT and the Planck 353 GHz polarization measurements.

Bandwidth modulation and pulse characterization of passively Q-switched erbium-doped fiber laser

We demonstrate the modulation of laser bandwidth by utilizing an ultranarrow tunable bandpass filter (UNTBF) in a passively Q-switched erbium-doped fiber laser. The passive Q-switch mechanism is enabled by using carbon nanotubes as saturable absorber at a Q-switched threshold of 35.5 mW. Based on spectral filtering effect introduced by the UNTBF, the 3 dB laser bandwidth can be tuned from 0.016 nm to 0.478 nm at a fixed pump power of 75.9 mW. The corresponding pulse behavior for each different bandwidth is characterized, and the results reveals that the pulse width can be as well tuned from 7.8 to 2.6 μs against the laser bandwidth, which agrees with the rule of time-bandwidth product. Correspondingly, the pulse repetition rate and the pulse energy vary from 16.23 kHz to 26.16 kHz and from 0.67 to 1.03 μJ respectively across the laser bandwidth. Further investigation of the pulse performance is performed against the pump power increment up to 107.2 mW. To the best of our knowledge, this is the first demonstration of spectrum bandwidth modulation in a passively Q-switched fiber laser, which can be useful for fully exploiting the possibilities of Q-switched pulse applications.

Tile roof inspired structure optimization on radial wood to fabricate oil-water separation function

Cross wood was usually selected to fabricate oil-water separation function. However, the cross wood is easy to be deformed after chemical delignification. Therefore, structure optimization via drilling holes on radial wood along with nano Cu(OH)2/CuCl modification overcame the bottleneck defect of dimensional instability, and simultaneously fabricated oil-water separation function. The oil absorption capacity of modified wood increases with the number and depth of drilled holes, reaching a maximum of 3.7 g/g toward dichloromethane. The modified radial wood demonstrated exceptional filtration effectiveness toward dichloromethane/chloroform-water mixtures and exhibited superior photocatalytic degradation capabilities against methylene blue, malachite green, and direct blue 151 dyes. Additionally, the modified radial wood displayed favorable recycle ability for both oil-water separation and photocatalytic degradation. Thus, a facile, cost-effective and environmental friendly strategy proposed in this work has potential to enhance the practical application of wood based oil-water separation materials.

Portable and Visual Detection of Cytochrome c with Graphene Quantum Dots–Filter Paper Composite

As a significant biomarker during the apoptosis process, cytochrome c (Cyt c) is considered as a critical component in the inherent apoptotic pathway, but the simple and portable detection still remains challengeable. In this work, a portable and visual sensing platform for Cyt c was developed based upon the fluorescence quenching of graphene quantum dots (GQDs), which could be finished within a few seconds. Herein, the absorption spectrum of Cyt c matched the emission spectrum of GQDs well, which could cause the fluorescence quenching of GQDs via the inner filter effect (IFE) in the range of 1–50 μg/mL with the limit of detection as low as 0.1 μg/mL. Furthermore, the intracellular Cyt c was imaged to observe the apoptosis process of cancer cells induced by staurosporine. To achieve the portable and visual detection of Cyt c, GQDs were deposited on the filter paper to form the solid platform, which displayed a gradual fluorescence quenching when different concentrations of Cyt c were present. Compared to the conventional methods, the proposed assay is low-cost, fast, portable, and visual, which will be useful for the investigation of mitochondrial dysfunction and apoptotic cell death.

Long-Range Imaging of Alpha Emitters Using Radioluminescence in Open Environments: Daytime and Night-Time Applications.

Alpha emitters like plutonium pose severe health risks when ingested, damaging DNA and potentially causing cancer. Traditional detection methods require proximity within millimeters of the contamination source, presenting safety risks and operational inefficiencies. Long-range detection through alpha radioluminescence (RL) offers a promising alternative. However, most of the previous experiments have been carried out under controlled conditions that preclude the overwhelming effect of ambient light. This study demonstrates the successful detection of a 3 MBq alpha emitter in an open environment using a compact alpha camera. This camera incorporates a deep-cooled CCD and a low f-number lens system designed to minimize the blue shift effects of filters. Night-time imaging was achieved with a dual-filter system using a sandwich filter assembly centered at 337 nm and 343 nm for capturing alpha RL and subtracting background light, respectively. At night, the alpha source was detected from 1 m away within one minute, and the lowest detection limit can be calculated as 75 kBq. The system was also evaluated under simulated urban lighting conditions. For daytime imaging, a stack of tilted 276 nm short pass filters minimized sunlight interference, enabling the detection of the alpha source at 70 cm within 10 min under indirect sunlight. This research highlights the viability of long-range optical detection of alpha emitters for environmental monitoring in real-world settings.

Preparation and performance evaluation of heat resistant and salt resistant anionic fluid loss reducer for water‐based drilling fluid

AbstractIn this investigation, a new micro‐crosslinked anionic polymer resistant to elevated temperature and high salinity, PKDASN, was synthesized using 3‐chloropropyltriethoxysilane (KMB703), N, N‐Dimethylacrylamide (DMAM), 2‐acrylamido‐2‐methylpropanesulfonic acid (AMPS), N‐vinyl caprolactam (NVCL), and sodium (4‐vinyl phenyl)methanesulfonate (SVM) employing free radical polymerization in a water‐based solution. The structure of PKDASN was analyzed using Fourier‐transform infrared spectroscopy, nuclear magnetic resonance spectroscopy, and X‐ray photoelectron spectroscopy, while its microstructure was analyzed using scanning electron microscopy. Thermogravimetric analysis showed that the pyrolysis temperature of PKDASN was above 294°C. Adding KMB703 enables the polymer to form a dense and stable spatial network. This intensified polymer network could interact with bentonite via intermolecular force and Coulomb force and form a dual grid structure, which presents impressive stability and control of filtration in saltwater. This is mainly achieved through creating a “silane coupling layer” on the particle surface by KMB703, which facilitates the crosslinking and aggregation of the polymer, thereby reinforcing the polymer's framework. This implies that under high‐temperature conditions of 230°C, 3 wt% PKDASN can improve the filtration effectiveness of drilling fluids and exhibit resistance to 15 wt% NaCl contamination. American Petroleum Institute filtration(FLAPI) and High temperature and high pressure filtration(FLHTHP) values were 4.6 and 23.0 mL, respectively. Therefore, this investigation provides a novel approach to utilizing the designated silane agent for the advancement of filtration loss additives in drilling fluids resistant to elevated temperature and high salinity.

Cellulose-based fluorescent chemosensor with controllable sensitivity for Fe3+ detection

Polymer-based sensors, particularly those derived from renewable polymers, are gaining attention for their superior properties compared to organic small molecules. However, their complex preparation and poor, uncontrollable sensitivity have hindered further development. Herein, cellulose-based polymer photoluminescence (PL) chemosensors were fabricated using a straightforward and adjustable strategy. Specifically, water-soluble cellulose acetoacetate (CAA) was used as the substance for the in-situ synthesis of 1,4-dihydropyridine (DHPs) fluorescent rings on cellulose chains via a catalyst-free, room-temperature Hantzsch reaction. Benefiting from the synergetic through-space conjugation of DHPs rings and semi-rigid cellulose chains with heteroatoms, the sensors exhibit bright and stable PL properties. Based on this performance, the cellulose-based sensor excels in the specific recognition of Fe3+ in aqueous systems, showing exceptional selectivity, stability, and anti-interference performance due to the synergy between the inner filter effect (IFE) and intramolecular charge transfer (ICT). Theoretical calculations confirm the role of the extended π-conjugated structure at the DHPs-4 position in modulating the sensor sensitivity, achieving a low limit of detection (LOD) of 0.48 μM. Furthermore, the versatility of the Hantzsch reaction shows the potential of this strategy for developing a new generation of biomass-based polymer portable sensors for real-time and on-site detection.

Centrifugated lateral flow assay strips based on dual-emission carbon dots modified with europium ions for ratiometric determination and on-site discrimination of tetracyclines in environment

Due to the serious detrimental impact on human health, antibiotic pollution particularly tetracyclines residues has become a serious problem. Herein, a multiple response fluorescent probe consisted of dual-emission carbon dots and Eu3+ (D-CDs@Eu3+) is designed for the determination and discrimination of tetracyclines (TCs). Specifically, the carboxyl and amidogen group of dual-emission carbon dots (D-CDs) can coordinate with Eu3+ to form the D-CDs@Eu3+. Upon adding TCs, the fluorescence intensities of D-CDs at 405 nm and 495 nm are quenched due to inner filter effect (IFE) and the localization of fluorescence resonance energy transfer (L-FRET) between the D-CDs@Eu3+ and TC. Simultaneously, the D-CDs@Eu3+ may chelate with TCs to enhance the occurrence of antenna effect, while the characteristic peaks of Eu3+ at 590 nm and 615 nm are enhanced. On these bases, the TCs detection is achieved with low detection limits from 46.7 to 72.0 nM. Additionally, through the distinct efficiencies of L-FRET, the discrimination of TCs is achieved. Moreover, a novel centrifugated lateral flow assay strips (CLFASs) device is developed by integrating the D-CDs@Eu3+, lateral flow assay strips and smartphone using RGB variations for TCs detection, achieving remarkable recoveries (98.6–103.7 %) in real samples. Therefore, this CLFASs device provides a reliable approach for the TCs detection, demonstrating potential applications.

A risk evaluation method for human-machine interaction in emergencies based on multiple mental models-driven situation assessment

In the process of human-machine interaction (HMI) under abnormal situations, situation assessment (SAS) is a critical component as incorrect SAS can feed into inappropriate actions and cause severe accidents. Therefore, it is essential to model SAS for HMI risk evaluation. During emergency situations, SAS is predominantly affected by time pressure. However, current researches focus on deliberative SAS with sufficient time and have limitations in quantifying the time pressure effect on SAS during emergencies. This paper proposes a risk evaluation method for HMI in emergencies by quantitatively modeling the time pressure effect on SAS under the recognition-primed decision (RPD) model framework. Firstly, SAS process is characterized as identifying the first plausible cause of an abnormal phenomenon driven by multiple Bayesian network-based mental models, and a simulation algorithm for SAS process is proposed to evaluate HMI risk. Secondly, two effects of time pressure on SAS activities, i.e., filtration effect on information perception and impair effect on knowledge retrieval, are quantified based on the Saliency-Effort-Expectancy-Value (SEEV) model and the Adaptive Control of Thought-Rational (ACT-R) theory. Finally, this method is applied to a Boeing 737-31S accident with high time pressure and results demonstrate the effectiveness of the method.

Cellulose-based yellow-green emitting carbon dots with large Stokes shift as effective “turn off-on” fluorescence platforms for Cr (VI) and AA dual efficacy detection

BackgroundHexavalent chromium (Cr (VI)) is highly carcinogenic to humans. Ascorbic acid (AA) deficiency can be hazardous to health. And the dual-effect fluorescence detection of them is an important research topic. Carbon dots (CDs) based on cellulose are excellent candidates for the fluorescence probes due to their low cost and environmental friendliness. But most of them exhibit shortwave emission, small Stokes shift and poor fluorescence performance, all of which limit their use. Therefore, there is an urgent need for cellulose CDs with longer emission wavelengths and larger Stokes shifts in dual-effect fluorescence detection of Cr (VI) and AA. ResultsUnder optimal conditions (180 °C, 12 h), we prepared cellulose-based nitrogen-doped carbon dots (N-CDs) by a simple one-step hydrothermal process, which display longer emission wavelengths (ex: 370 nm, em: 510 nm), larger Stokes shifts (140 nm) and high fluorescence quantum yield (QY: 19.27 %). The continuous “turn-off” and “turn-off-on” fluorescence detection platforms were constructed based on the internal filtering effect (IFE) between Cr6+ and N-CDs, and Cr6+ reduced to Cr3+ by AA at pH = 6. The platform has been successfully simultaneous detect Cr (VI) and AA with a wide range of 0.01–40 μM and 0.1–100 μM. And the lowest limits of detection (LOD) are 0.0303 μM and 0.072 μM, respectively. In the presence of some other metals, non-metal ions and water-soluble acids in the fruits, this fluorescent platform can demonstrate a high level of interference immunity. Significance and noveltyThis represents the first yellow-green cellulose-based N-CDs with large Stokes shift for dual-effect detection of Cr (VI) and AA in real water samples and fresh fruits. The fluorescence detection platform has the advantage of low volume detection. Less than 2 mL of sample is required for testing and results are available in <5 min. This method is rare and supply a novel idea for the quantitative monitoring of Cr (VI) and AA.

LCL filter design and experimental response analysis for a SiC inverter

In this paper, an LCL filter for a 20-kW SiC power inverter with a 25 kHz switching frequency is proposed and assessed. The transfer function without neglecting the network effect is considered. The optimal value of the damping resistor is evaluated to minimize losses while maintaining power quality and device stability. Finally, the harmonic content produced by the SiC inverter is experimentally measured to verify the effectiveness of the LCL filter.

Practicality and Compatibility of Cd(II) Coordination Polymer as Luminescent Sensor in Selective and Sensitive Detection of 3‐Nitrotyrosine Biomarker

AbstractBased on the mixed ligands of 1,4‐bis(2,4,6‐tricarboxylpyrid‐5‐yl)benzene (H6BTPB) and 1,4‐bis(imidazol‐1‐yl)benzene (bib), a new cadmium(II) coordination polymer with the molecular formula of {[Cd(bib)(μ2‐H2O)(H2O)2](H4BTPB)0.5(bib)0.5}n (CdCP) was constructed under solvothermal condition, and displayed a 3D supramolecular structure expanded by the hydrogen bonds between the 1D [Cd(bib)(μ2‐H2O)(H2O)2]n ladder chain and the guests. Profiting from its superior stability and inherent luminescence, the prepared CdCP dispalyed great potential as a highly sensitive and selective luminescent sensor in trace detection of 3‐NT biomarker in both water and real bodily fluids through the luminescence quenching effects, with the Ksv and LODs being 2.408×105 M−1 and 30.3 nM in water, 2.230×105 M−1 and 44.7 nM in diluted urine, 2.249×105 M−1 and 43.9 nM in diluted serum, respectively. Subsequent mechanism studies indicated the synergistic effect of internal filtering effect, photo‐induced electron transfer, and fluorescence resonance energy transfer determining the luminescence quenching response of CdCP towards 3‐NT biomarker.

Progress of persulfate-based advanced oxidation process (PS-AOPs) coupled with ultrafiltration membrane to alleviate membrane fouling: A review

Membrane fouling significantly hampers the extensive deployment of ultrafiltration membranes in treating drinking water. To mitigate fouling and improve filtration effectiveness, advanced oxidation processes (AOPs) have been considered as a potent approach, particularly the activation of AOPs by persulfate (PS-AOPs). Establishing a membrane system based on PS-AOPs is a promising approach to addressing membrane fouling. This article reviews the homogeneous and heterogeneous activation methods of PS. Recent research on the degradation of sulfamethoxazole by various activation methods are summarized, their mechanisms are discussed, and their advantages and disadvantages are compared. The integration of PS-AOPs with UF membranes to control fouling is highlighted, with evidence showing a significant reduction in membrane fouling. The article emphasizes the improvements and limitations of the PS-AOPs coupled with membrane system, especially in heterogeneous systems. Heterogeneous catalysts are doped into membrane materials to form catalytic membranes that can not only participate in membrane filtration but also undergo advanced oxidation upon PS introduction. Finally, the article looks ahead to future research paths and challenges for the PS-AOPs coupled UF membrane system. Based on metal-carbon catalytic membranes, the exploration of materials suitable for activating persulfate is discussed to promote further development of the technology.

Ratiometric fluorescence probe based on carbon dots and p-phenylenediamine-derived nanoparticles for the sensitive detection of manganese ions.

A ratiometric fluorescence probe based on carbon quantum dots with 420nm emission (bCQDs) and a p-phenylenediamine-derived fluorescence probe with 550nm emission (yprobe) is constructed for the detection of Mn2+. The presence of Mn2+ results in the enhanced absorption band at 400nm of yprobe, and the fluorescence of yprobe is significantly enhanced based on the chelation-enhanced fluorescence mechanism. The fluorescence of bCQDs is then quenched based on the inner filtration effect. The ratio (I550/I420) linearly increases with the increase of Mn2+ concentration within 2.00 × 10-7-1.50 × 10-6M, and the limit of detection is 1.76 × 10-9M. Given the fluorescence color changing from blue to yellow, the visual sensing of Mn2+ is feasible based on bCQDs/yprobe coupled with RGB value analysis. The practicability of the proposed method has been verified in tap water, lake water, and sparkling water beverage, indicating that bCQDs/yprobe has promising application in Mn2+ monitoring.

Preparation of Double-Layer Composite Coffee Filtration Nonwovens.

The coffee industry is developing rapidly in the world, and the use of coffee filtration nonwovens (CFNs) is becoming more and more extensive; however, there is a lack of standards and research for its production and trade, and the quality of related products on the market is uneven at present. Here, eight double-layer composite coffee filtration nonwovens (D-LCCFNs) were prepared by using 5 g/m2 and 10 g/m2 polypropylene (PP) melt-blown nonwovens (MNs), 20 g/m2 PP spunbonded nonwovens and 20 g/m2 viscose/ES fiber chemically bonded nonwovens, and the physical properties, morphology and the filtration effect of coffee and purified water for the prepared samples were tested. It was found that the surface density of the microfiber layer (MNs) in the D-LCCFNs was negatively correlated with the coffee filtration rate; when the microfiber layer in the D-LCCFNs was in direct contact with the coffee, the liquid started to drip later, and the filtration rate of the coffee was slower; the filtration rate of the samples with the viscose/ES chemically bonded nonwovens was very fast. However, the samples without viscose/ES fibers basically did not filter pure water much, but they could filter out the coffee liquid normally, and the samples' hydrophilicity increased significantly after filtering coffee.

Long-term stability of extra virgin olive oil: effects of filtration and refrigeration storage on the Kolovi variety.

The composition of extra virgin olive oil (EVOO) defines its sensory, nutritional, and human health benefits, and distinguishes it as a key component of the Mediterranean diet. Nevertheless, EVOO constituents are susceptible to degradation during processing and storage, which reduces the olive oil's quality and limits its shelf life. The present study investigated the effect of molecular filtration before storage and the effect of cool storage at 4 °C on the stability of 'Kolovi' EVOO, a variety originating from the Greek island of Lesvos, over a 24 month period. Storing EVOO at 4 °C positively affected free acidity, peroxide value, K268, fruity qualities, and concentrations of hydroxytyrosol, tyrosol, ligstroside aglycone, lutein, and squalene, in comparison with the control sample stored at room temperature, particularly after 1 year. Molecular filtration significantly affected the ratio of unsaturated fatty acids to saturated fatty acids (UFAs/SFAs). Optimal preservation of parameters such as acidity value and lutein content was achieved by combining molecular filtration with refrigeration. The present study recommends storing EVOO in the refrigerator for up to 18 months. Based on the regulatory limits of the quality characteristics of acidity, peroxide value, K232 value and fruity sensory attributes, the shelf-life of the protected geographical indication (PGI) 'Kolovi' EVOO can reach 2 years under cool storage (4 °C) and with molecular filtration before storage. © 2024 The Author(s). Journal of the Science of Food and Agriculture published by John Wiley & Sons Ltd on behalf of Society of Chemical Industry.

Delta opioid receptors engage multiple signaling cascades to differentially modulate prefrontal GABA release with input and target specificity.

Opioids regulate circuits associated with motivation and reward across the brain. Of the opioid receptor types, delta opioid receptors (DORs) appear to have a unique role in regulating the activity of circuits related to reward without a liability for abuse. In neocortex, DORs are expressed primarily in interneurons, including parvalbumin- and somatostatin-expressing interneurons that inhibit somatic and dendritic compartments of excitatory pyramidal cells, respectively. But how DORs regulate transmission from these key interneuron classes is unclear. We found that DORs regulate inhibition from these interneuron classes using different G-protein signaling pathways that both converge on presynaptic calcium channels, but regulate distinct aspects of calcium channel function. This imposes different temporal filtering effects, via short-term plasticity, that depend on how calcium channels are regulated. Thus, DORs engage differential signaling cascades to regulate inhibition depending on the postsynaptic target compartment, with different effects on synaptic information transfer in somatic and dendritic domains.

Green synthesis of soybean residue-based nitrogen-chlorine co-doped carbon dots based on deep eutectic solvents: Construction of a PNP fluorescence detection system under the IFE mechanism

How to manage the potential environmental pollution of waste biomass while realizing the resource utilization of the waste is a topic worthy of in-depth investigation. In this paper, after successfully preparing a deep eutectic solvents, we constructed N, Cl-CDs fluorescent probes with high fluorescence yield and biocompatibility by utilizing waste soybean residue as a cheap nitrogen-rich carbon-sourced biomass precursor. The results showed that the fluorescence quenching of N, Cl-CDs has a good linear relationship with the concentration of p-nitrophenol in the range of 0.1–60 μM, with the detection limit of 30 nM, and the fluorescence quenching mechanism was the inner filter effect. This paper demonstrates that the carbon dots fluorescence system has a superior prospect for the highly selective detection of p-nitrophenol, and provides a reliable basis for the future exploration of efficient and environmentally friendly carbon dots synthetic method as well as the economic recycling of waste.