Potential Effect Research Articles

Speciation and formation constants of aqueous lanthanum (III) chloride complexes from 5 to 80 °C by Raman spectroscopy

Lanthanum chloride solutions were studied both computationally and by polarized Raman spectroscopy to determine the aqueous species present and their equilibrium constants. Four species were predicted from Gaussian 16 computations using density functional theory: La(H2O)9 3+, LaCl(H2O)8 2+, LaCl2(H2O)6 2+, and LaCl3(H2O)4 0. Both LaCl(H2O)8 2+ and LaCl2(H2O)6 + were identified in the reduced isotropic solvent-subtracted Raman spectra from their La–Cl vibrational bands at 234 and 221 cm−1, respectively. The spectra did not change significantly with temperature from 5 to 80 °C, and the Raman bands for each species could not be fitted with sufficient accuracy to determine the scattering coefficients directly from the experimental data. Instead, the computed scattering coefficients from Gaussian 16 (B3LYP with the Los Alamos National Laboratory 2-double-zeta effective core potential and 6-311+G(d,p) basis set) were to be used to obtain the equilibrium concentrations of LaCl(H2O)8 2+ and LaCl2(H2O)6 +, from which the concentration of La(H2O)9 3+ was determined. The concentration dependent formation quotients were fitted with the specific ion interaction (SIT) activity coefficient model to determine the stepwise formation constants K0, 1 and K1, 2, from 5 to 80 °C. Both K0, 1 and K1, 2 showed minor increases with temperature.

Dual effect of string cloud and dark matter halos on particle motions, shadows and epicyclic oscillations around Schwarzschild black holes

In this work, we study the particle dynamics, shadows and quasi-periodic oscillations around the Schwarzschild black hole with three different dark matter halos and string cloud parameters. The motion of particles is considered with the string cloud parameter α and investigated for massive and massless particles. The photon orbits and inner stable circular orbits of these black holes are obtained from the effective potential. The black hole shadows are calculated using three different dark matter halos. The shadow radius of these black holes increases compared to a pure Schwarzschild black hole for different values of the string cloud parameter. Further, quasi-periodic oscillations are also discussed in the current analysis. Our study examines how the radial profiles of orbital and radial harmonic oscillation frequencies change with the string cloud parameter. This study examines the major properties of test particle's quasi-periodic oscillations near stable circular orbits in the black hole equatorial plane. Our findings indicate that observational tests for black holes influenced by dark matter halos and cloud strings are also feasible and viable.

Second resonance of the Higgs field: motivations, experimental signals, unitarity constraints

Perturbative calculations predict that the effective potential of the Standard Model should have a new minimum, well beyond the Planck scale, which is much deeper than the electroweak vacuum. So far, most authors have accepted the metastability scenario in a cosmological perspective which is needed to explain why the theory remains trapped in our electroweak vacuum but requires to control the properties of matter in the extreme conditions of the early universe. As an alternative, one can consider the completely different idea of a non-perturbative effective potential that, as at the beginning of the Standard Model, is restricted to the pure Φ4\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$\\Phi ^4$$\\end{document} sector but is consistent with the indications of the now existing analytical and numerical studies, namely “triviality” and a description of SSB as weak first-order phase transition. In this approach, the electroweak vacuum is now the lowest energy state because, besides the state with mass mh=125\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$m_h=125$$\\end{document} GeV, defined by the quadratic shape of the potential at its minimum, there is a second much larger mass scale (MH)Theor∼690(30)\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$(M_H)^\ extrm{Theor} \\sim 690(30)$$\\end{document} GeV associated with the zero-point energy determining the potential depth. Despite its large mass, the heavier state would couple to longitudinal Ws with the same typical strength as the low-mass state at 125 GeV and thus represent a relatively narrow resonance mainly produced at LHC by gluon-gluon fusion. Therefore, it is interesting that, in the LHC data, one can find combined indications of a new resonance of mass (MH)comb∼685(10)\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$(M_H)^\ extrm{comb} \\sim 685 (10)$$\\end{document} GeV, with a statistical significance which is far from negligible. Since this non-negligible evidence could become an important new discovery with forthcoming data, we outline further refinements of the theoretical predictions, that could be obtained by implementing unitarity constraints, in the presence of fermion and gauge fields, with the type of coupled-channel calculations nowadays used in meson spectroscopy.

Circular motion and QPOs near black holes in Kalb–Ramond gravity

General relativity (GR) theory modifications include different scalar, vector, and tensor fields with non-minimal gravitational coupling. Kalb–Ramond (KR) gravity is a modified theory formulated based on the presence of the bosonic field. One astrophysical way to test gravity is by studying the motion of test particles in the spacetime of black holes (BHs) using observational data. In the present work, we aimed to test KR gravity through theoretical studies of epicyclic frequencies of particle oscillations using quasi-periodic oscillation (QPO) frequency data from microquasars. First, we derive equations of motion and analyze the effective potential for circular orbits. Also, we studied the energy and angular momentum of particles corresponding to circular orbits. In addition, we analyze the stability of circular orbits. It is shown that the radius of the innermost stable circular orbits is inversely proportional to the KR parameter. We are also interested in how the energy and angular momentum of test particles at ISCO behave around the KR BHs. We found that the Keplerian frequency for the test particles in KR gravity is the same as that in GR. Finally, we study the QPOs by applying epicyclic oscillations in the relativistic precession (RP), warped disc (WD), and epicyclic resonance (ER) models. We also analyze QPO orbits in the resonance cases of upper and lower frequencies 3:2, 4:3, and 5:4 in the QPO as mentioned above models. We obtain constraints on the KR gravity parameter and BH mass using a Monte Carlo Markov Chain simulation in the multidimensional parameter space for the microquasars GRO J1655-40 & XTE J1550-564, M82 X-1, and Sgr A*.

Bifurcation and spectral instability of asymptotic quasinormal modes in the modified Pöschl-Teller effective potential

Bifurcation and spectral instability of asymptotic quasinormal modes in the modified Pöschl-Teller effective potential

Relativistic two-fluid hydrodynamics with quantized vorticity from the nonlinear Klein-Gordon equation

Abstract We consider a relativistic two-fluid model of superfluidity, in which the superfluid is described by an order parameter that is a complex scalar field satisfying the nonlinear Klein-Gordon equation (NLKG). The coupling to the normal fluid is introduced via a covariant current-current interaction, which results in the addition of an effective potential, whose imaginary part describes particle transfer between superfluid and normal fluid. Quantized vorticity arises in a class of singular solutions and the related vortex dynamics is incorporated in the modified NLKG, facilitating numerical analysis which is usually very complicated in the phenomenology of vortex filaments. The dual transformation to a string theory description (Kalb-Ramond) of quantum vorticity, the Magnus force and the mutual friction between quantized vortices and normal fluid are also studied.

Predicting possible molecular states of nucleons with Ξc , Ξc* , and Ξc′

In the framework of a one-boson-exchange model, we carry out a comprehensive investigation of the ΞcN/ΛcΣ/Ξc′N/ΣcΛ/Ξc*N/Σc*Λ/ΣcΣ/Σc*Σ interactions. We consider the S−D-wave mixing effects and the coupled-channel effects to derive the relevant effective potentials. Our results can predict several possible charm-strange deuteronlike Ξc(′,*)N hexaquarks, the Ξc′N molecules with I(IP)=0(0+), 0(1+), 1(1+), the Ξc*N molecules with 0(1+), 0(2+), 1(2+), and the coupled ΞcN/Ξc′N/Ξc*N/ΣcΣ/Σc*Σ molecule with 0(1+). We expect the experiments to search for our predictions of the Ξc(′,*)N bound states. Published by the American Physical Society 2024

Circular motion of a charged particle on the inner surface of a frictionless cone under the influence of an electric field due to an electric dipole

A common problem provided in elementary physics textbooks is the analysis of the circular motion of a point-like particle affected by a gravitational field on the frictionless inner surface of an inverted cone. In this research, we study the motion of a charged particle on the same surface subject to an electric field generated by an electric dipole placed at the bottom of the cone. We study negatively and positively charged particles and analyse the dynamics of both. We calculate the physical quantities such as speed, angular velocity, angular momentum, and mechanical energy. Furthermore, we determine all possible distances travelled by the particles measured from the dipole. We also discuss the stability of the circular orbit using the effective potential. Finally, we consider the particle’s motion on a generic surface formed by the revolution of the curve ρz around the vertical axis. We determine the differential equation of ρz , in which the kinematic variables including speed v, angular velocity ω, and angular momentum L are constant.

How Cells Stay Together: A Mechanism for Maintenance of a Robust Cluster Explored by Local and Non-local Continuum Models.

Formation of organs and specialized tissues in embryonic development requires migration of cells to specific targets. In some instances, such cells migrate as a robust cluster. We here explore a recent local approximation of non-local continuum models by Falcó et al. (SIAM J Appl Math 84:17-42, 2023). We apply their theoretical results by specifying biologically-based cell-cell interactions, showing how such cell communication results in an effective attraction-repulsion Morse potential. We then explore the clustering instability, the existence and size of the cluster, and its stability. For attractant-repellent chemotaxis, we derive an explicit condition on cell and chemical properties that guarantee the existence of robust clusters. We also extend their work by investigating the accuracy of the local approximation relative to the full non-local model.

Improved Topical Delivery of Sorafenib-Meglumine Antimoniate: Elastic Nano-Liposomal Formulation for the Treatment of Cutaneous Leishmaniasis

Background: Cutaneous leishmaniasis (CL) is a widespread parasitic disease with significant health and social impacts. Current systemic treatments have severe side effects, highlighting the need for effective topical alternatives.Objective: This study aimed to develop and evaluate the effectiveness of sorafenib (SF) and meglumine antimoniate (MM) dual-loaded transferosomes (TRs) for topical treatment of CL.Methods: TRs were prepared using a thin film hydration method and incorporated into a carbopol gel. The formulations were characterized for vesicle size, zeta potential, entrapment efficiency, and deformability index. In vivo and ex vivo skin permeation studies were conducted, along with anti-leishmanial efficacy testing on an intramacrophage amastigote model using BALB/c mice.Results: The TRs exhibited a vesicle size of 186.1 ± 65.89 nm, zeta potential of -27.9 mV, and entrapment efficiency of 71.7 ± 3.9% for MM and 78.6 ± 4.2% for SF. Ex vivo studies showed enhanced skin permeation with cumulative permeation of 327.6 ± 29.4 µg/cm² for MM and 291.6 ± 28.3 µg/cm² for SF. In vivo results indicated a significant reduction in lesion size (0.1 ± 0.12 mm) and parasite load (2.7 ± 0.3 log scale).Conclusion: The MM-SF dual-loaded TRs demonstrated effective topical delivery and therapeutic potential for CL, providing a promising alternative to systemic treatments.

Improved thermal resummation for multi-field potentials

The resummation of large thermal corrections to the effective potential is mandatory for the accurate prediction of phase transitions. We discuss the accuracy of different prescriptions to perform this resummation at the one- and two-loop level and point out conceptual issues that appear when using a high-temperature expansion at the two-loop level. Moreover, we show how a particular prescription called partial dressing, which does not rely on a high-temperature expansion, consistently avoids these issues. We introduce a novel technique to apply this resummation method to the case of multiple mixing fields. Our approach significantly extends the range of applicability of the partial dressing prescription, making it suitable for phenomenological studies of beyond the Standard Model extensions of the Higgs sector.

Greybody factor of uncharged black hole in symmetric teleparallel gravity

In this study, we investigate the greybody factor of a (3+1)-dimensional black hole solution in the context of alternative f(Q) gravity with minimum scalar field coupling. We obtain the radial equation by applying the Klein–Gordon equation and transforming it into a Schrodinger wave equation using the tortoise coordinate. This transformation enables us to determine the effective potential and its graphical behavior for different values of the coupling constant and relevant physical parameters. We obtain two solutions for the radial equation corresponding to the event and cosmological horizons. To determine the greybody factor and its behavior, we combine these two solutions in the intermediate regime. The greybody factor increases with an increase in radius and coupling constant. This indicates that in alternative gravity, the larger black hole will die sooner as compared to cosmic gravity.

Remittance Inflow, Investment, and Economic Growth in Africa amidst COVID-19 Pandemic

Africa has fared well in the aspect of remittance receipts in recent years; however, the region recorded a decline in remittances amid the COVID-19 pandemic which constrained the circular flow of income significantly and ultimately economic growth. In view of this, this study investigates the economic effects of remittance inflows and investment on economic growth in Africa amid COVID-19 pandemic using a panel of 48 economies and estimated with pooled OLS and two-step system GMM. The study employed two distinct approaches for estimation; pre-COVID-19 (2010–2019) and amid COVID-19 (2010–2023). The results indicate that the behavior of remittances, investment and economic growth in Africa is not significantly different between pre-COVID-19 and amid COVID-19. That is, remittances remain a significant economic growth catalyst in Africa whereas investment is not (though with growth effect potential). Overall, the study concludes that African economic policy stakeholders and other relevant policy authorities should sustain the current remittance and labor policy frameworks with possible fine-tuning where applicable while doubling their investment efforts especially in productive sectors of the economy.

The cosmological constant problem and the effective potential of a gravity-coupled scalar

We consider a quantum scalar field in a classical (Euclidean) De Sitter background, whose radius is fixed dynamically by Einstein’s equations. In the case of a free scalar, it has been shown by Becker and Reuter that if one regulates the quantum effective action by putting a cutoff N on the modes of the quantum field, the radius is driven dynamically to infinity when N tends to infinity. We show that this result holds also in the case of a self-interacting scalar, both in the symmetric and broken-symmetry phase. Furthermore, when the gravitational background is put on shell, the quantum corrections to the mass and quartic self-coupling are found to be finite.

Comparison of optimized effective potential with inverse Kohn-Sham method for Hartree-Fock exchange energy.

The inverse Kohn-Sham (inv-KS) density-functional theory for the electron density of the Hartree-Fock (HF) wave function was revisited within the context of the optimized effective potential (HF-OEP). First, we clarify the relationship between the inv-KS and the HF-OEP within the framework of the potential-functional theory. The similarities and the differences of the approaches are then discussed on the basis of their methodological details, which motivates comparisons of the wave function provided by each method. Next, the real-space grid implementations of the inv-KS and the HF-OEP are addressed for the comparisons. The total HF energies EHF[{φiinv-KS}] for the wave functions φiinv-KS on the effective potentials optimized by the inv-KS are computed for a set of small molecules. It is found that the mean absolute deviation (MAD) of EHF[{φiinv-KS}] from the HF energy is clearly smaller than the MAD of EHF[{φiOEP}], demonstrating that the inv-KS is advantageous in constructing the detailed structure of the exchange potential υx as compared with the HF-OEP. The inv-KS method is also applied to an ortho-benzyne radical known as a strongly correlated polyatomic molecule. It is revealed that the spin populations on the atomic sites computed by the UHF calculation can be faithfully reproduced by the wave functions on the inv-KS potential.

A novel radial air-breathing proton exchange membrane fuel cell for miniaturized applications with effective stacking potentials

Increasing volumetric power density in fuel cells can be accomplished by increasing its compactness or output power. This is very crucial for miniaturized applications due to constraints in available spaces. In this study, a three-dimensional, multiphase, and non-isothermal computational fluid dynamics (CFD) tool is used to develop a novel radial air-breathing (AB) PEM fuel cell for miniaturized applications, which has unique stack-ability feature. The noted cell can accommodate multiply higher active area in cathode electrode with respect to planar and tubular AB designs. Increasing the cathode side active area, the electrode with the highest sources of losses for the kinetics of reactions in proton exchange membrane (PEM) fuel cells, has shown to play a significant role in performance enhancement of radial AB cells. For instance, at 0.4 Acm−2 the radial AB PEM fuel cell, can deliver 27.9 % and 10 % more power than the earlier planar and tubular AB ones, respectively. The stack-ability of AB fuel cells usually face severe challenges due to non-uniform air supply to the cells, resulting in imbalance of the cells output power. As opposed to tubular and planar AB cells, one unique feature for the present radial AB stack design is its attack-ability that ensures adequate and uniform supply of air/oxygen to all cells.

Prediction of the dark fermion mass using multicritical-point principle

This paper proposes a method to determine the effective potential using the multicritical-point principle (MPP) under the additional scalar field. The MPP is applied to the model in which a singlet dark fermion and a singlet real scalar field are added to the Standard Model (SM) to predict the dark fermion mass. As a result, the dark fermion mass is predicted to be about 901–972 GeV.

Toward Exact Critical Exponents from the low-order loop expansion of the Effective Potential in Quantum Field Theory

The asymptotic strong-coupling behavior as well as the exact critical exponents from scalar field theory even for the simplest case of 1+1 dimensions have not been obtained yet. Hagen Kleinert has linked both critical exponents and strong coupling parameters to each other. He used a variational technique ( back to kleinert and Feynman) to extract accurate values for the strong coupling parameters from which he was able to extract precise critical exponents. In this work, we suggest a simple method of using the effective potential ( low order) to obtain exact values for the strong-coupling parameters for the ϕ4 scalar field theory in 0+1 and 1+1 space–time dimensions. For the 0+1 case, our results coincide with the well-known exact values already known from literature while for the 1+1 case we test the results by obtaining the corresponding exact critical exponent. As the effective potential is a well-established tool in quantum field theory, we expect that the results can be easily extended to the most important three dimensional case and then the dream of getting exact critical exponents is made possible.

Human Placenta Extract (HPH) Suppresses Inflammatory Responses in TNF-α/IFN-γ-Stimulated HaCaT Cells and a DNCB Atopic Dermatitis (AD)-Like Mouse Model.

Atopic dermatitis (AD), a chronic inflammatory disease, severely interferes with patient life. Human placenta extract (HPH; also known as human placenta hydrolysate) is a rich source of various bioactive substances and has widely been used to dampen inflammation, improve fatigue, exert anti-aging effects, and promote wound healing. However, information regarding HPH's incorporation in AD therapies is limited. Therefore, this study aimed to evaluate HPH's effective potential in treating AD using tumor necrosis factor (TNF)-α/interferon (IFN)-γ-stimulated human keratinocytes (HaCaT), immunized splenocytes, and a 2,4-dinitrochlorobenzene (DNCB)-induced AD mouse model. In TNF-α /IFN-γ-stimulated HaCaT cells, HPH markedly reduced the production of reactive oxygen species (ROS) and restored the expression of nuclear factor erythroid 2-related factor 2 (Nrf2), superoxide dismutase 1(SOD1), catalase, and filaggrin (FLG). HPH reduced interleukin (IL)-6; thymus- and activation-regulated chemokine (TARC); thymic stromal lymphopoietin (TSLP); and regulated upon activation, normal T cell expressed and presumably secreted (RANTES) levels and inhibited nuclear factor kappa B phosphorylation. Additionally, HPH suppressed the T helper 2 (Th2) immune response in immunized splenocytes. In the AD-like mouse model, it significantly mitigated the DNCB-induced elevation in infiltrating mast cells and macrophages, epidermal thickness, and AD symptoms. HPH also reduced TSLP levels and prevented FLG downregulation. Furthermore, it decreased the expression levels of IL-4, IL-5, IL-13, TARC, RANTES, and immunoglobulin E (IgE) in serum and AD-like skin lesion. Overall, our findings demonstrate that HPH effectively inhibits AD development and is a potentially useful therapeutic agent for AD-like skin disease.

Rearrangement of Proline Complexes with Zn2+: An Infrared Multiple Photon Dissociation and Theoretical Investigation.

Complexes of proline (Pro) cationized with Zn2+ and Cd2+ were examined by infrared multiple photon dissociation (IRMPD) action spectroscopy using light generated from a free electron laser. Complexes of intact Pro with CdCl+, CdCl+(Pro), a complex of (Zn+Pro-H)+ where a proton has been lost, as well as Zn+(Pro-H)(Pro) were formed by electrospray ionization. In order to identify the structures formed experimentally, the IRMPD spectra were compared to those calculated from optimized structures at the B3LYP/6-311+G(d,p) level for zinc complexes and B3LYP/def2-TZVP level with an effective core potential on cadmium for the CdCl+(Pro) system. For the latter complex, the main binding motif observed has a zwitterionic proline ligand structure, [CO2-]cc, where the metal binds to the two carboxylate oxygens. In contrast, for Zn+(Pro-H)(Pro), both ligands interact with zinc via a [N,CO-][N,CO] binding motif, where binding is observed at the carbonyl oxygens and nitrogens for both ligands, consistent with previous work. In both cases, contributions from different puckers of the proline ring may contribute. For (Zn+Pro-H)+, we identify that the structure is actually ZnH+(Pro-2H), in which the proline has been dehydrogenated and one of the hydrogens has migrated to form a covalent bond with Zn, which verifies a previous report relying on a single OH stretch band.