Effective Cation Exchange Capacity Research Articles

Kinetics of soil re-acidification under no-tillage system

The rate and amount of Al3+ released from re-solubilization of the Al-containing polymers and minerals due to the increase in proton activity in the soil solution in subtropical regions is scarce in the literature. The objective of the present study was to track the Al3+ reappearance following its neutralization during the switch from a conventional tillage system to a no-till (NT) system. For this purpose, we evaluated a long-term lime experiment under NT on a subtropical Ultisol. The treatments included varying lime rates, with different historic of lime reapplication. Soil samples were taken at the 0–5, 5–10, and 10–15 cm depth in 1988, 1994, 1995, 1996, 2001, 2003, 2006, 2012, and 2022. The re-solubilization of Al-containing soil polymers and minerals in the 0–15 cm soil layer proceeds slowly in the first 10 years; afterwards, the rate and amount of Al3+ released increased. However, regardless of the lime treatment, the soil never returns its natural acidic state, even after 34 years of the first liming operation. A decrease in the intensity of reappearance of exchangeable Al3+ in the soil profile is clearly observed, compared to the treatment without reapplication of surface lime. We have observed that it takes 7–9 years for 10% of the effective cation exchange capacity to be occupied by Al3+ if limestone is not reapplied on the soil surface; if underdoses are reapplied this level can be maintained for 13–15 years. Furthermore, if larger and more frequent lime doses are used, a low Al3+ saturation (<10%) can be maintained permanently. These findings emphasize the importance of an appropriate liming process at the start of NT, followed with surface limestone reapplication, to ensure a very low Al3+ saturation over a long period of time in the 0–15 cm soil layer.

Soil organic carbon and nutrient characteristics of Anogeissus groves in old Opara forest reserve, Nigeria.

Forest-savanna transition zones of West Africa are uniquely characterized by forest groves, forest patches, or forest islands, the importance of which for sustainable resource management and their potential for carbon sequestration and nutrient cycling is often underrated. Our study conducted a comparative analysis of the soil organic carbon and nutrient characteristics of the Anogeissus groves in the old Opara forest reserve and their adjoining arable lands. We established 30 sampling frames of 100m × 100m plots with 15 frames per land use type. For each sampling frame, six observation points were randomly selected, and composite soil samples were collected at soil depths of 0-20cm and 20-50cm per observation point. Our results showed Anogeissus groves and their adjoining arable lands to exist on similar landscapes while the groves have enriched soil morphological characteristics (e.g., soil color), higher soil organic carbon (SOC), and better nutrient characteristics. There were strong positive relationships between SOC, effective cation exchange capacity, total nitrogen, calcium, magnesium and calcium, zinc, electrical conductivity, and copper. The significant soil organic matter accumulation in the groves accounts for the overall improved soil characteristics over the adjoining arable lands. Preserving the groves and similar Africanecosystems may be important in climate regulation, resources and biodiversity conservation, and ethnopharmacology for rural communities. Thus, a question arises: should more land be set aside for ecological conservation or for agricultural productivity?

ASSESSMENT OF SOIL PHYSICOCHEMICAL PROPERTIES AND TOTAL PETROLEUM HYDROCARBON OF A THREE-DECADE-OLD POLLUTED SITE AT EVBAREKE, BENIN CITY

Monitoring of polluted sites require their assessment for effective management and environmental protection. This study assessed the soil properties including heavy metals (Fe, Zn, Mn, Cu, Cr, Pb, Cd and Ni) and total petroleum hydrocarbon (TPH) of a three-decade-old automobile workshop in Benin City. Top soil samples collected from outside the workshop and a control were analyzed using standard laboratory methods and their mean values were compared with critical limits for interpreting soil fertility as well as pollution status. The results showed that the texture of the polluted soil was unchanged but the pH has been modified from strongly to slightly acidic. Relatively slightly higher concentrations of the measured fertility parameters of the polluted site were not substantial for the very low organic C, N and Mg as well as the low for Ca, Na and EC because their ratings were not different from those of the control unlike the high ratings for K and P compared to medium and low in the control, respectively. Concentration of EA of the polluted soil was rated low as the control while effective CEC (cmol/kg) was low for the polluted (6.42) site compared to very low (4.80) of the control. Higher concentrations (mg/kg) of heavy metals in polluted soil were &lt; their DPR target values, except Cd (5.1) which exceeded its limit (0.8). Increased concentration (mg/kg) of TPH from 0.22 to 825 was &lt; its target value of 1,000. Decontamination of Cd from site should be carried out to avoid ill health of workers. &#x0D;

Fluvial avulsions influence soil fertility in the Pantanal wetlands (Brazil)

River avulsions drive important changes in the Pantanal wetlands, owing to their role in the hydro-sedimentology of the region. Although relevant to numerous ecosystem services, few studies have analyzed the influence of river avulsions on soil fertility in the Pantanal. Here, we use the largest ongoing avulsion in the Taquari River (Caronal region) to evaluate the effects on soil fertility, considering two factors: avulsion stage (1) and aquatic-terrestrial succession (2). Since both factors are influenced by macrophyte abundance, an incident map was created through tasseled cap indices from Sentinel 2 images to guide sampling efforts in flooded soils. The mapped area was split into two zones of alluvial processes, the first from the apex of the Caronal lobe corresponding to the Taquari River megafan (TRM), and the second as the distal Paraguay River floodplain (PRF). Soil macro- and micronutrient levels were evaluated from 42 surface samples (0–0.2 m) distributed across the two alluvial process zones. The macrophyte map's overall accuracy (OA) was analyzed by a confusion matrix using the Sentinel 2 imagery. Finally, we used Random Forest regressions to determine the influence of response variables on soil attributes, including tassel indices, distance from the Caronal crevasse, macrophyte density, and an existing soil fertility map. The macrophyte map obtained an OA of 93 %. Some parameters such as pH (r = −0.62; R2 = 0.57), effective cation exchange capacity (r = −0.49; R2 = 0.79), Mn (r = −0.71; R2 = 0.6), Zn (r = −0.69; R2 = 0.54), and base saturation (r = −0.7; R2 = 0.93) were influenced by the distance or level of maturation of the avulsion stage in the TRM. Our scattering of soil collections was insufficient to test the terrestrialization hypothesis (2). The study results show that river channel avulsions influence the accumulation of mineral and organic nutrients in tropical floodplain soils, which has implications for fertility and biodiversity.

EFFECTS OF TEA (CAMELLIA SINENSIS) CULTIVATION ON SOIL QUALITY IN THE LAM DONG, VIETNAM

The objectives of the study were to assess soil quality and its relationship to the sustainability of tea cultivation in the Lam Dong, Vietnam. Overall soil quality declined with increasing age of the tea plantations as evidenced by decreases in soil OC, total N, K and S, available P and K, mean weight diameter of aggregates. As well, total P, bulk density and mechanical resistance increased with increasing cultivation intensity. Because these soil properties were sensitive to cultivation effects, they were considered to be good indicators of soil quality. Soil properties that were less sensitive to change, and limited as soil quality indicators included texture, clay mineralogy and sesquioxides, and effective cation exchange capacity. Soil quality changes were greatest during the first 10 years of cultivation and were generally greatest in the surface 0- to 40-cm of soil. Soil and crop management factors were considered to be the most important factors affecting soil quality. Decreases in long-term crop yields were found to correspond with decreases in soil quality. In terms of crop productivity, the most important soil quality indicators (based on a multiple regression analysis) were OC, available P, total K and PAWC. Economic analysis of the yield and production cost data indicated that, under current conditions, tea cultivation in the Lam Dong province is sustainable for periods of about 20 years. Thus, measured values of soil quality indicators in the 20-yr tea soils were considered to represent the "critical levels" for economic sustainability of tea cultivation.

Nitrogen enrichment does not adversely affect exchangeable bases in rainfed urban arable soils of Kumasi, a tropical West African city

Urbanisation induces nitrogen (N) enrichment in tropical soils. This enhances soil acidification, leading in turn to a decrease in effective cation exchange capacity (CECe) and base saturation (BSe). Here, we investigated if and how these effects of urbanisation-induced N inputs affect the soils of tropical urban agroecosystems. Our aim was to quantify the impact of urbanisation intensity (UI) on total N (TN) contents and stocks, and to detect possible adverse N effects on soil pH, CECe, and exchangeable bases in rainfed urban arable soils of Kumasi, a tropical city in Ghana, West Africa. We analysed 618 topsoil samples (0–10 cm) from arable fields within the urban perimeter, categorised into four classes forming a gradient from low to high UI. For baseline comparison, 9 samples each from both rural arable fields and an urban forest were included. Urban arable soils generally had higher TN levels than their rural counterparts. Among the urban arable soils however, TN levels decreased with increasing UI, possibly as crop production and related N export through harvest intensified. Conversely, increasing UI correlated with increased levels of exchangeable Ca2+, K+, and Na+. No adverse N effect on soil pH, CECe, and BSe was detected. This could be explained with the strong TN-SOC relationship (R2 ≥ 0.9), and an increasingly strong relationship between exchangeable bases and TN and SOC (R2 = 0.5–0.8) with increasing UI. These relationships suggested a major common source of TN, SOC, and exchangeable bases. As the soils are neither chemically fertilised nor limed, these findings supported earlier studies that this source is provided by dumped biodegradable household waste, charred matter, ash, and construction materials. We concluded that soil N enrichment through these materials in Kumasi is accompanied by abundant bases in the same materials, which overcompensate any theoretic acidification. Our findings imply that not only can the fertility of tropical urban arable soils in cities like Kumasi be maintained, but also that the crops and ground water may not be at risk from the mobilisation of trace elements and heavy metals due to the hindered soil acidification.

Comparative analysis and prediction of cation exchange capacity via summation: influence of biochar type and nutrient ratios

IntroductionEnhancing soil cation exchange capacity (CEC) is of paramount importance for sustainable agriculture and ecosystem health. This study investigated the pivotal role of biochar in altering soil CEC and challenges conventional assumptions about universal effects of biochar application.MethodsContrasting biochar types, one with a low ash content of 4.4% (switchgrass-derived biochar, SGB) and the other with a high ash content of 45.9% (poultry litter-derived biochar, PLB) were used. Two experiments treated with increasing biochar application rates were conducted: one without plants and the other grown with ryegrass. Effective CEC (summation method) was determined by two extraction methods: Mehlich-3 (M3) and ammonium acetate (AA).Results and discussionThe SGB decreased CEC by 27% on average (from both experiments) from the lowest to the highest rate of biochar application, while the PLB significantly increased CEC by 91%. This highlights the critical role of biochar properties in influencing CEC dynamics. In the second experiment, ryegrass cultivation revealed the greater importance of the calcium and magnesium/potassium ratio ([Ca+Mg]/K) in the soil CEC than CEC only for plant growth in biochar-amended soils. The ratios for optimum ryegrass production ranged from 82‒86 (M3) and 69‒74 (AA), which was translated to 88:11:1 Ca:Mg:K percent base saturation ratios. Moreover, predictive models for estimation of soil CEC after biochar application were successfully developed based on initial soil and biochar CEC. However, M3 was more reliable than AA for such predictions mainly because it was more successful in predicting nutrient availability from biochar. These models offer a promising tool for informed soil management decisions.ConclusionThis research emphasizes the importance of biochar feedstock, elucidates nutrient ratio effects on plant growth, and provides a practical means to anticipate soil CEC changes post-biochar application.

Influence of soil nutrients on net primary productivity in post-mining forests in the Colombian Pacific

ABSTRACT Tropical forests have the highest rates of net primary productivity (NPP) in terrestrial ecosystems and, therefore, may contribute significantly to the mitigation of global climate change. Although NPP is influenced by soil fertility, and recently, in some regions, mining activity in forest ecosystems has intensified. Little is known about how soils determine the restoration of NPP in forests degraded by mining. We evaluated the influence of soil nutrients on wood NPP of post-mining forests in the biogeographic Chocó region (Colombia), with emphasis on the effects of nitrogen (N) and phosphorus (P) limitations in post-mining forests under successional stages of 12-15 or 30-35 years. For this, permanent plots were established in secondary post-mining forests in Jigualito (Colombian Pacific), the wood NPP (accumulated and current) was evaluated, and it was related to soil properties such as organic matter (OM), acidity, Al, total N, available P, magnesium (Mg), potassium (K), calcium (Ca), and texture. An accumulated wood NPP of 0.72 t ha -1 yr -1 was recorded in post-mining forests 12-15 years old. Meanwhile, in post-mining forests of 30-35 years, the accumulated wood NPP was 6.52 t ha -1 yr -1 . The current wood NPP was 4.25 t ha -1 yr -1 in post-mining forests with 30-35 years of recovery. Accumulated NPP positively correlated with soil OM, total N, Ca, Mg, and effective cation exchange capacity–ECEC in post-mining forests. In post-mining forests, a slow recovery of the wood NPP was denoted in the first years. Soil nutrients determined the wood NPP, and a multiple limitation of nutrients with the succession was observed, which corroborates the need to restore the degraded ecosystem in the region.

Cover crop management systems improves soil quality and mitigate water erosion in tropical olive orchards

The production of olive trees in shallow soils in hillslopes requires adequate soil and water conservation systems. In this context, soil use and management besides vegetation cover contributes to better soil quality and the sustainability of the olive cultivation system. Thus, the objective was to determine the physical and chemical properties that are indicative of soil quality in areas of Dystrudepts, under different soil cover management systems in olive cultivation in tropical region. Olive tree culture field experiment was established in 2015, where soil was sampled over three years (2016, 2017 and 2021). The effect of five cover management systems were compared for each agricultural year, namely BS: bare soil in 2015/2016, 2016/2017 and 2017/2021; OBS: olive trees on bare soil in 2015/2016, 2016/2017 and 2017/2021; OSV: olive trees intercropped with mowed spontaneous vegetation in 2015/2016, 2016/2017 and 2017/2021; OJB: olive trees intercropped with jack beans (Canavalia ensiformis L.) in 2015/2016 and 2016/2017, and olive trees crowned intercropped with mowed spontaneous vegetation in 2017/2021; OMI: olive trees intercropped with millet (Pennisetum glaucum L.) in 2015/2016, olive trees intercropped with sunn hemp (Crotalaria juncea L.) in 2015/2017 and olive trees with spontaneous vegetations treated with herbicide (Roundup) in 2017/2021. The soil quality indices (SQI) proved to be sensitive to variations in different types of soil management from the second year of assessment, regarding water erosion. OSV and OJB showed the highest SQI, while OBS showed the lowest values. The SQI demonstrated an inverse correlation with soil and water losses starting from the second year of assessment. This highlights its efficacy in assessment the effects of adopted management on soil quality in the context of water erosion. Moreover, it reinforces the importance of vegetation cover in maintaining soil fertility, resulting in increase of soil organic matter and improving the structuring of Dystrudepts. The attributes that most correlated with the SQI were soil organic matter, effective cation exchange capacity, sum of bases, geometric mean diameter of aggregates, pH and unsaturated soil hydraulic conductivity. These attributes collectively provide valuable insights into soil health and water erosion susceptibility within the olive tree production system.

Machine learning-based soil quality assessment for enhancing environmental monitoring in iron ore mining-impacted ecosystems

In November 2015, a catastrophic rupture of the Fundão dam in Mariana (Brazil), resulted in extensive socio-economic and environmental repercussions that persist to this day. In response, several reforestation programs were initiated to remediate the impacted regions. However, accurately assessing soil health in these areas is a complex endeavor. This study employs machine learning techniques to predict soil quality indicators that effectively differentiate between the stages of recovery in these areas. For this, a comprehensive set of soil parameters, encompassing 3 biological, 16 chemical, and 3 physical parameters, were evaluated for samples exposed to mining tailings and those unaffected, totaling 81 and 6 samples, respectively, which were evaluated over 2 years. The most robust model was the decision tree with a restriction of fewer levels to simplify the tree structure. In this model, Cation Exchange Capacity (CEC), Microbial Biomass Carbon (MBC), Base Saturation (BS), and Effective Cation Exchange Capacity (eCEC) emerged as the most pivotal factors influencing model fitting. This model achieved an accuracy score of 92% during training and 93% during testing for determining stages of recovery. The model developed in this study has the potential to revolutionize the monitoring efforts conducted by regulatory agencies in these regions. By reducing the number of parameters that necessitate evaluation, this enhanced efficiency promises to expedite recovery monitoring, simultaneously enhancing cost-effectiveness while upholding the analytical rigor of assessments.

Testing Biochar’s Ability to Moderate Extremely Acidic Soils in Tea-Growing Areas

Biochar as a by-product of the carbonization of biomass has an inherent potential to modify acidic soils due to its alkaline nature. To explore the mechanism and effectiveness of biochar, a case study was conducted on severely acidic soils from six fields under tea cultivation in a subtropical zone, comparing rice husk biochars, in three rates (B5, B10, B15 t ha−1), and CaCO3 as conventional liming practice. The results showed increases in pH of 71.5%, 52.7%, 30.6%, and 29.7% in B15, B10, B5, and CaCO3-treated soils compared to the control. On average, B15 and B10 treatments resulted in the highest organic matter with 12.3% and 9.7%, respectively. B15, B10, B5, and CaCO3 caused increases of 196.6%, 173.4%, 129.7%, and 100.9% in base saturation compared to the control, respectively. Also, after the application of B15, B10, and B5 treatments, the effective cation exchange capacity increased by 191.4%, 112.1%, and 39.5%; however, the application of CaCO3 resulted in a 20.1% decrease. Overall, applying biochar on acidic soils provides adequate negative charges due to its well-extended specific surface area and pore volume, which cause the absorption of additional Al+, resulting in ameliorating soil pH. The application of proper biochar could notably be more effective in improving acidic soils than conventional practices such as the overuse of CaCO3. In this regard, evaluating various biochars in terms of feedstock, pyrolysis conditions, and modification scenarios merits in-depth research in future studies.

Quantitative analysis of soil degradation in response to land use change in the Guinea savanna zone of Ghana

Soil degradation (SD) poses a significant challenge to tropical agricultural production systems due to its role in depleting soil nutrients. Recently, SD has threatened population growth by causing hunger and poverty among smallholder farmers in the Guinea savanna agro-ecological zone of Ghana. However, SD cannot be directly measured. Instead, assessment and modelling efforts rely on biological and physico-chemical indicators. This study sought to: (i) select a minimum dataset (MDS) using a multivariate statistical technique; (ii) identify SD processes, and evaluate the extent of degradation; and (iii) suggest strategies to monitor SD in the study area. Soil samples were collected using the Land Degradation Surveillance Framework (LDSF), specifically designed for sub-plot level (1000 m2) sampling. This scheme aligns well with the typical farm structure of smallholder farmers (<10 acres). Soil samples, taken from a depth of 0–20 cm, were analyzed to assess their physico-chemical properties. Principal component analysis (PCA) identified seven key SD processes: soil texture, pH, organic carbon (OC), total nitrogen (TN), available phosphorus (Av. P), base saturation (BS) and Effective Cation Exchange Capacity (ECEC). These identified processes lead to the loss of OC, deterioration of soil texture, reduction in soil nutrients, and increased soil acidity. There was a strong positive correlation (r = 0.70, p<0.05) between soil physical and chemical properties. PC1 explained 26.86% of the total variance, followed by PC2 at 15.31%, PC3 at 12.46%, and PC4 at 9.98%. Also, PC5, PC6, and PC7 accounted for 8.49%, 7.25% and 1.42% of the variance, respectively. The land-use systems we identified significantly affected the concentration of soil nutrients (p<0.001). In our computed Composite Soil Degradation Index (CSDI), CEC emerged as the most significant SD indicator with a weight of 0.328, followed by Si:CL ratio at 0.187. The results indicate that soil management activities should focus on increasing organic matter. Soil nutrient depletion primarily occurs through several processes. Land clearing and burning of organic materials during land preparation are primary causes. Furthermore, a total crop removal during harvest, inadequate manure application, and subsequent leaching and erosion aggravates SD, leading to nutrient-depleted soils. We conclude that the loss of nutrients, specifically CEC, OC, Ex. K and Av. P is the primary contributor to chemical SD. Therefore, implementing integrated soil fertility management (ISFM) strategies, such as applying organic (e.g., animal-based manures, green manure, crop residues, compost) and inorganic fertilizers (e.g., NPK + micronutrients) is crucial for increasing soil nutrient availability, enhancing SOM content, and promoting carbon sequestration in these farming systems. This study establishes a baseline for comparing and evaluating the effectiveness of land management interventions at the landscape level in northern Ghana. Consequently, soil nutrient management should be tailored to site-specific conditions, focusing on increasing the efficiency of N, P, K and micronutrient uptake by plants. Adopting such site-specific management strategies could significantly contribute to the sustainable intensification of agricultural production systems in the Guinea Savanna agro-ecological zone of Ghana.

Long-Term Organic Manure Retarding Soil Acidity in the Double-Cropping Rice Field of Southern China

ABSTRACT This paper investigates the effects of different long-term (36 years) fertilizer treatments on soil pH, exchangeable acids, exchangeable base cation and cation exchange capacity (CEC) at 0–10 cm and 10–20 cm soil layers in a double-cropping rice field. The following fertilizer treatments were included: chemical fertilizer (MF), rice straw and chemical fertilizer (RF), 30% organic manure and 70% chemical fertilizer (OM), and without any fertilizer input as a control (CK). This result indicated that soil pH at 0–10 cm layer with RF and OM treatments was higher than that of MF and CK treatments. Soil exchangeable acidity content at 0–10 cm and 10–20 cm layers with RF and OM treatments were decreased by 48.4%, 51.6% and 49.2%, 54.2%, compared with CK treatment, respectively. Soil exchangeable calcium (Ca2+), magnesium (Mg2+) and potassium (K+) contents at 0–10 cm and 10–20 cm layers in paddy field with OM and RF treatments were higher than that of CK treatment. Moreover, compared with CK treatment, soil exchangeable base ion content at 0–10 cm and 10–20 cm layers in paddy field with OM treatment were increased by 54.1% and 42.6%, respectively. Soil CEC and effective cation exchange capacity (ECEC) at 0–10 cm and 10–20 cm layers with OM and RF treatments were significantly higher than that of MF and CK treatments. In conclusion, our results indicated that long-term application of crop residue or organic manure can improve soil exchangeable base ion and exchangeable capacity contents, alleviate soil acidity in a double-cropping paddy field.

Exploring Genomics and Microbial Ecology: Analysis of Bidens pilosa L. Genetic Structure and Soil Microbiome Diversity by RAD-Seq and Metabarcoding.

Bidens pilosa L., native to South America and commonly used for medicinal purposes, has been understudied at molecular and genomic levels and in its relationship with soil microorganisms. In this study, restriction site-associated DNA markers (RADseq) techniques were implemented to analyze genetic diversity and population structure, and metabarcoding to examine microbial composition in soils from Palmira, Sibundoy, and Bogotá, Colombia. A total of 2,984,123 loci and 3485 single nucleotide polymorphisms (SNPs) were identified, revealing a genetic variation of 12% between populations and 88% within individuals, and distributing the population into three main genetic groups, FST = 0.115 (p < 0.001) and FIT = 0.013 (p > 0.05). In the soil analysis, significant correlations were found between effective cation exchange capacity (ECEC) and apparent density, soil texture, and levels of Mg and Fe, as well as negative correlations between ECEC and Mg, and Mg, Fe, and Ca. Proteobacteria and Ascomycota emerged as the predominant bacterial and fungal phyla, respectively. Analyses of alpha, beta, and multifactorial diversity highlight the influence of ecological and environmental factors on these microbial communities, revealing specific patterns of clustering and association between bacteria and fungi in the studied locations.

Soil electrical conductivity as a proxy for enhanced weathering in soils

To effectively monitor and verify carbon dioxide removal through enhanced weathering (EW), this study investigates the use of soil electrical conductivity (EC) and volumetric water content (θ) as proxies for alkalinity and dissolved inorganic carbon (DIC) in soil water. EC-θ sensors offer a cost-effective and straightforward alternative to traditional soil and water sampling methods. In a lab experiment, three different substrates were treated with NaHCO3 solutions to increase the alkalinity of the soil water and analyze the response. The combination of EC and θ to track the increase in carbonate alkalinity due to EW, and therefore CO2 consumption, is applicable for low cation exchange capacity (CEC) soil-substrates like the used quartz sand. However, the presence of organic material and pH-dependent CEC complicates the detection of clear weathering signals in soils. In organic-rich and clay-rich soils, only a high alkalinity addition has created a clear EC signal that could be distinguished from a non-alkaline baseline with purified water. Cation exchange experiments revealed that the used soil buffered alkalinity input and thereby might consume freshly generated alkalinity, initially mitigating CO2 uptake effects from EW application. Effective CEC changes with pH and pH buffering capacity by other pathways need to be considered when quantifying the CO2 sequestration potential by EW in soils. This should be estimated before the application of EW and should be part of the monitoring reporting and verification (MRV) strategy. Once the soil-effective CEC is raised, the weathering process might work differently in the long term.

Soil organic carbon stocks and fertility in smallholder indigenous agroforestry systems of the North-Eastern mountains, Tanzania

Soil organic carbon and soil fertility are critical components of soil health and play a significant role in sustaining agricultural productivity. Indigenous agroforestry practices have been identified as an interesting avenue to sequester carbon and enhance soil fertility in tropical smallholder farms. However, that potential remains poorly quantified. To better understand the dynamics of soil organic carbon stocks and fertility, this study evaluated and compared 4 different smallholder indigenous agroforestry systems (i.e., Kihamba, Ginger, Miraba, and Mixed spices) in the northeastern volcanic and block mountains of Tanzania. Specifically, we compared old and young agroforestry systems in terms of soil organic carbon stocks and soil fertility (proxied by effective cation exchange capacity (eCEC)). In each agroforestry system, a network of old and young tree farm plots were selected for soil sampling at different depths and physico-chemical parameters were analyzed (soil organic carbon, texture, bulk density, pH-H2O, and eCEC). Our findings showed that there was no significant difference between young and old agroforestry systems in terms of soil organic carbon stocks, except in the Kihamba system on the slopes of Kilimanjaro. The highest soil carbon sequestering potential was found in the old Kihamba (located on Nitisols) compared to other systems on Acrisols. Young agroforestry in Ginger and Miraba appeared to have a higher capacity to sequester soil carbon than Mixed spices. Regarding eCEC levels, there was a significant difference between old and young agroforestry systems in both the Kihamba and Miraba system. At the 0–10 cm depth, the highest eCEC levels were found in young agroforestry for Kihamba, Miraba, and Mixed spices. Our results implied that specific management and restoration strategies should focus on optimizing soil fertility and carbon sequestration potential of agroforestry systems in the South Pare and Usambara Mountains characterized by low-fertility Acrisols.

Evaluation of land use impact on soil quality in Samaru College of Agriculture, Northern Guinea Savanna, Nigeria

Abstract Land use changes influence soil quality, which is of fundamental importance in sustainable crop production and environmental management. This study evaluated land use impact on soil quality at Samaru College of Agriculture farm, Ahmadu Bello University, Zaria, Nigeria. The land use types were Tomato/Pepper, Grapevine/Fluted pumpkin, Mango/Orange, and Guava/Mango. A profile pit was dug in each land unit. Soil samples were collected from genetic horizons, prepared, and analysed in the laboratory using standard methods. Sand, silt, and clay differed significantly (p &lt; 0.05) among the land uses. The soil texture varied from clay loam to clay. Bulk density (BD) was significantly (p &lt; 0.05) higher under Mango/Orange and Guava/Mango than other land use types. The soil reaction (pH) ranged from 5.0 to 5.8 and was strongly to moderately acidic. Soil organic carbon was low (&lt; 10 g/kg), total nitrogen values of 0.19 – 0.24 g/kg were low, and available phosphorus values of 1.8 – 27.4 mg/kg were rated low to high across the land use types. Soils under the Grapevine/Fluted pumpkin land use type were significantly higher in organic carbon, exchangeable potassium, sodium, and effective cation exchange capacity than the other land use types. Soil quality under Grapevine/Fluted pumpkin was rated best (80 %), whereas soil quality under Tomato/Pepper land use type was the worst (40 %). The soils were low-to-high in quality and had a higher potential to support crop production if management practices that encourage the build-up of nutrients in the soil system were adopted. The application of manure, liming materials, and phosphorus-based fertilisers is advocated.

Tetracycline adsorption/desorption by raw and activated Tunisian clays

Clay-based adsorbents have applications in environmental remediation, particularly in the removal of emerging pollutants such as antibiotics. Taking that into account, we studied the adsorption/desorption process of tetracycline (TC) using three raw and acid- or base-activated clays (AM, HJ1 and HJ2) collected, respectively, from Aleg (Mazzouna), El Haria (Jebess, Maknessy), and Chouabine (Jebess, Maknessy) formations, located in the Maknessy-Mazzouna basin, center-western of Tunisia. The main physicochemical properties of the clays were determined using standard procedures, where the studied clays presented a basic pH (8.39–9.08) and a high electrical conductivity (446–495 dS m−1). Their organic matter contents were also high (14–20%), as well as the values of the effective cation exchange capacity (80.65–97.45 cmolckg−1). In the exchange complex, the predominant cations were Na and Ca, in the case of clays HJ1 and AM, while Mg and Ca were dominant in the HJ2 clay. The sorption experimental setup consisted in performing batch tests, using 0.5 g of each clay sample, adding the selected TC concentrations, then carrying out quantification of the antibiotic by means of HPL-UV equipment. Raw clays showed high adsorption potential for TC (close to 100%) and very low desorption (generally less than 5%). This high adsorption capacity was also present in the clays after being activated with acid or base, allowing them to adsorb TC in a rather irreversible way for a wide range of pH (3.3–10) and electrical conductivity values (3.03–495 dS m−1). Adsorption experimental data were studied as regards their fitting to the Freundlich, Langmuir, Linear and Sips isotherms, being the Sips model the most appropriate to explain the adsorption of TC in these clays (natural or activated). These results could help to improve the overall knowledge on the application of new low-cost methods, using clay based adsorbents, to reduce risks due to emerging pollutants (and specifically TC) affecting the environment.

Soil δ15N spatial distribution is primarily shaped by climatic patterns in the semiarid Caatinga, Northeast Brazil

Soil nitrogen isotopic composition (δ15Nsoil) is an invaluable tool as it integrates nitrogen (N) transformations in soils. In addition to serving as a baseline to understand the N cycle, spatial representations of δ15Nsoil across landscapes (or isoscapes) is a multi-purpose tool useful to investigate, for example, plant-microbe interactions, animal migration and forensics. We investigate the climatic and edaphic controls of δ15Nsoil utilising data from 29 geographical locations sampled across the semiarid Brazilian Caatinga biome. The sampling covered a mean annual precipitation (PA) gradient ranging from 0.51 to 1.36 m a−1 and eight soil types originating from three different geological origins. Our data show that the combination of higher aridity and lower seasonality (ψ) leads to higher values of δ15Nsoil. Moreover, soil total carbon had a positive relationship with δ15Nsoil, appearing within the best-supported models according to the information-theoretic approach undertaken here. The contribution to the plant communities by the Fabaceae trees expressed as their basal area was not related to δ15Nsoil values, suggesting that the magnitude of biological N fixation in the Caatinga is not large enough to be reflected in the soil. In addition, considering PA in a categorical fashion, i.e., ‘high’ (> 0.8 m a−1) and ‘low’ PA (< 0.8 m a−1), we found that, within the wetter category, δ15Nsoil was positively related to several soil properties (i.e., clay content, effective cation exchange capacity, exchangeable calcium, silt content, pHH2O, total phosphorus and sum of bases) and negatively related to sand content. Our study provides new insights into the functioning of semiarid ecosystems from a pedo-isotopic perspective and contributes to the overall understanding of the N cycle in the Caatinga region, with the potential to support the development of new conceptualisation of biogeochemical process and testing of global models that simulate N and C cycles.

Investigation into the Chemical Characteristics of Soils near Sinkholes Situated in Anambra State, Nigeria

In this comprehensive study, we delve into the chemical properties of soil in the proximity of sinkholes located in Anambra state of Nigeria. Three distinct sinkhole sites were selected for examination: Awka site 1 (6.2232°N and 7.0824°E), Awka site 2 (6.2220°N and 7.0819°E), and Agulu (6.0941°N and 7.0203°E). For a comprehensive analysis, 24 soil samples were meticulously collected and subjected to thorough analysis. These samples comprised of 15 specimens obtained from the immediate vicinity of the sinkholes, while 9 samples were procured from locations situated at least 2 kilometers away from the sinkhole sites. The study focused on investigating various parameters, namely pH levels, Organic Carbon (OC) content, Organic Matter (OM) content, Aluminum (Al) levels, Hydrogen (H) levels, Total Nitrogen (TN) content, Magnesium (Mg) levels, Potassium (K) levels, Sodium (Na) levels, Calcium (Ca) levels, Effective Cation Exchange Capacity (ECEC), Base Saturation, and soil texture. The obtained results revealed that the study areas predominantly exhibited a sandy composition with a notably low clay content. Furthermore, the analysis indicated low hydrogen values, while sodium levels were observed to be relatively high. Consequently, certain areas, particularly those situated farther away from the sinkhole site, exhibited a reduced amount of exchangeable bases and effective cation exchange capacity. This phenomenon potentially resulted in leaching and dispersion within the soil, leading to inadequate water infiltration and subsequent run-off. Notably, this process may have contributed to the formation of tunnel erosion, ultimately resulting in the emergence of sinkholes.