Nowadays, internal combustion engine fuels need to shift from diesel and gasoline to clean fuels. As a low-carbon fuel, methane has attracted widespread attention. Diesel ignition of premixed methane is one of the measures to achieve effective application. However, limited by the equipment and the active reactivity of methane, there are few basic visualization studies on that, resulting in a lack of deep understanding of ignition and flame propagation processes. Therefore, this paper studies the diesel ignition and combustion characteristics of diesel-ignited methane and the promotion of 10 and 20% (volume fraction) hydrogen on combustion performance based on the rapid compression and expansion machine. The experimental results indicate that methane has a suppressive effect on the ignition of diesel. The combustion process can be mainly divided into the diesel ignition stage, the premixed combustion stage, and the fuel burnout stage. Blending 10% and 20% hydrogen has little effect on the diesel ignition stage, but has a relatively great impact on the premixed combustion stage. The flame propagation can be improved with hydrogen blending, but that is limited due to the effects of ignition and wall. The combustion duration can be shortened with hydrogen blending, mainly for the CA50-90, especially at a lower equivalence ratio. The combustion efficiency can be improved with hydrogen blending. Overall, the strategy of blending hydrogen is considered more suitable for large bore engines and the results can deepen the understanding of the combustion process of diesel-ignited methane/hydrogen/air mixtures and have value for the relevant engine development so that the energy shortage and environment pollution issues can be alleviated.