Effect Of Thermo-mechanical Cycling Research Articles

Effect of Thermo-mechanical Cycling on Fracture Resistance of Different CAD/CAM Crowns: An In Vitro Study.

To evaluate the effect of thermo-mechanical cycling (TMC) on fracture resistance of different computer-aided design/computer-aided manufacture (CAD/CAM) crowns. A total of 42 CAD/CAM crowns were fabricated on epoxy resin maxillary first premolar teeth and divided into three groups (n = 14) according to the material used: IPS e.max CAD (Ivoclar Vivadent) lithium disilicate (LD), Vita ENAMIC (VE) (VITA Zahnfabrik), Tetric CAD (Ivoclar Vivadent). Also, each group was subdivided into two equal subgroups according to TMC (n = 7). Subgroups (O) without TMC and subgroup (W) with TMC (5-55°C, 30 second, 75,000 cycles). All samples in each group were cemented with a universal bond (Tetric N bond universal) and adhesive resin cement (Variolink Esthetic DC) (Ivoclar Vivadent). Subsequently, the samples were loaded to failure in a universal testing machine at a crosshead speed of 1 mm/min, and the fracture pattern and the fracture resistance in each group were recorded. Fracture resistance was analyzed by one-way analysis of variance (ANOVA) test, followed by Tukey's post hoc test for pairwise comparison. Fracture resistance showed a significant difference between the tested groups before and after TMC; IPS e.max CAD has the highest value (1233.35 ± 97.72, 1165.73 ± 199.54 N) followed by Tetric CAD (927.62 ± 42.5, 992.04 ± 53.46 N) and Vita ENAMIC has lowest value (506.49 ± 74.24, 354.69 ± 90.36 N). Thermo-mechanical cycling affected the fracture resistance of both polymer-based CAD/CAM crowns. For dental practitioners, both IPS e.max CAD and Tetric CAD can be used clinically for posterior teeth, providing satisfactory results and resistance to fracture. How to cite this article: Elmokadem MI, Haggag KM, Mohamed HR. Effect of Thermo-mechanical Cycling on Fracture Resistance of Different CAD/CAM Crowns: An In Vitro Study. J Contemp Dent Pract 2024;25(1):29-34.

Effect of Thermomechanical Cycling on Martensitic Transformation and Shape Memory Effect in 304 Austenitic Steel

To improve the shape memory effect (SME) of 304 austenitic steel effectively and efficiently, thermomechanical cycling, comprising deformation at room temperature and annealing, was applied. The influences of cycle number and annealing temperature on the SME and microstructures in 304 austenitic steel were investigated by light microscope (LM), X-ray diffraction (XRD), and transmission electron microscope (TEM). The shape recovery ratio was remarkably improved from 16% to 40% after two thermomechanical cycles. The optimum annealing temperature was 833 K in the process of thermomechanical cycling. The improved SME by thermomechanical cycling was mainly related to stress-induced ε martensite rather than stress-induced α’ martensite. The reason is that thermomechanical cycling can not only promote the occurrence of the stress-induced γ→ε martensitic transformation, but also suppress the subsequently stress-induced ε→α′ transformation.

Effect of thermo-mechanical cycling and chlorhexidine on the bond strength of universal adhesive system to dentin

ObjectivesThis study evaluated the influence of thermo-mechanical cycling (TMC) on the bond strength (BS) of a universal adhesive system (UAS - Adper Single Bond Universal, 3M ESPE) to dentin treated or not with 0.2% chlorhexidine (CHX). MethodsEighty human molars were flattened until reach the dentin and separated into 4 groups according to the bonding protocol: ENR Group: 37% phosphoric acid + 3-step etch-and-rinse adhesive system (ENR); UAS Group: UAS in self-etch mode; ENR + CHX Group: 37% phosphoric acid + CHX + ENR; UAS + CHX Group: CHX + UAS in self-etch mode. After treatments, teeth were restored (Filtek Z350, 3M ESPE). Samples (n = 10) were submitted to aging process: stored in distilled water at 37°C/30 days or TMC (ERIOS - 98N/1.6Hz + thermal cycling 5/37/55 °C - 1,200,000 cycles). Specimens were sectioned into sticks (1.0 mm2) and submitted to the microtensile test (Mechanical Test Machine - 0.5 mm/min). Fracture patterns and hybrid layer integrity were analyzed under Stereomicroscope and Scanning Electron Microscopy (SEM). ResultsThe BS results (3-way ANOVA, Bonferroni's test, α = 5%) showed that groups treated with CHX presented higher BS values than control groups; significant in all cases (p < .05), except for ENR submitted to TMC (p > .05). When CHX was applied and samples were cycled, UAS revealed higher BS (p < .05) than ENR. After TMC, cohesive fractures increased for UAS, regardless of CHX application. SEM analysis demonstrated different hybridization patterns for the adhesive systems tested. ConclusionThe performance of the universal adhesive system used in self-etch mode was better than that of the 3-step etch-and-rinse adhesive system. Clinical significanceUniversal adhesive systems have been developed in order to simplify the dentin hybridization protocol. It is important to determine the longevity of the adhesive interface using these bonding materials after chewing.

Effect of thermo-mechanical cycling on the shear bond strength of porcelain to milled and cast cobalt-chromium alloys

Statement of problem: Most of the failures in metal-ceramic restorations occurs at the interface between the two materials. For long term clinical performance, these restorations should have adequate bond strength between metal and ceramic. Few data is available in regards to the metal-ceramic bond strength of Cobalt Chromium (Co-Cr) alloys fabricated by computer aided designing design/computer aided manufacturing CAD/CAM technology.Purpose of the study: The purpose of this in vitro study was to explore the influence of Co-Cr fabrication techniques on shear bond strength of porcelain to milled and cast Co-Cr alloys and to evaluate failure mode with & without thermo-mechanical cycling.Materials & Methods: A total of 20 disc samples (10 mm diameter x 4 mm thickness) were fabricated of Co-Cr alloy and divided into two groups (10 discs each) according to their fabrication technique: Group I: fabricated by CAD/CAM milling and Group II: fabricated by conventional casting. Then porcelain build up for all discs (10 mm diameter x 2mm thickness) was done using feldspathic porcelain. Each group was subdivided according to discs’ exposure to thermo-mechanical cycling into two sub-groups (5 discs each). Sub-group A : without thermo-mechanical cycling and Sub-group B: with thermo-mechanical cycling. All the disc samples were subjected to the shear bond strength (SBS) test and the failure mode was investigated under digital microscope at 40 X. Data were statistically analyzed using Independent sample t-test and Two-way ANOVA test (P ≤ 0.05).Results: The results showed that the fabrication techniques were statistically insignificantly affecting the SBS of both CAD/CAM milled and conventional casting groups. Regarding the thermo-mechanical cycling, the CAD/CAM milled and conventional casting groups without thermo-mechanical cycling showed a statistically significantly higher SBS than those with thermo-mechanical cycling. Failure mode was mixed type for all disc samples.Conclusions: Fabrication technique of Co-Cr alloy had no significant effect on SBS. Thermo-mechanical cycling of milled and cast Co-Cr samples significantly affecting SBS with the superiority of the non-thermo-mechanical cycled samples. All the tested samples showed SBS values within the clinically acceptable levels. CAD/ CAM fabricated Co -Cr may be considered a promising alternative to conventional cast Co-Cr for metal ceramic prosthesis in terms of SBS.

Thermomechanical cyclic stability of porous NiTi shape memory alloy

It is known that shape memory and phase transition response of NiTi shape memory alloy (SMA) is dependent on mechanical or thermal background, and the presence of phases such as B2(NiTi), B19'(NiTi), Ni4Ti3, Ni3Ti2 and NiTi2. The volume fraction of metastable Ni4Ti3 phase in NiTi matrix can be easily changed by heat treatments. Both Ni4Ti3 phases and Ni ingredient affect the phase transition kinetics and the shape memory response. This work deals with the effect of thermomechanical cycling on the shape memory response of a porous Ni50.8Ti49.2 SMA, which is homogenized at 1050°C and aged at 800°C, afterwards slow cooled. Full recoverable shape memory response and cyclic stability were achieved during thermomechanical cycling under a compressive stress of 5MPa.

Effect of thermo-mechanical cycling on the microstructure and toughness in the weld CGHAZ of a novel high strength low carbon steel

We have studied the microstructural evolution in the simulated coarse grain heat affected zone (CGHAZ) of novel low carbon microalloyed steel with yield strength of 1000MPa using electron microscopy, while the crystallographic characteristics were studied by electron backscatter diffraction (EBSD). The deterioration in low temperature toughness after the simulated welding cycle was attributed to the formation of coarse blocky M–A constituent. However, the lower bainite microstructure of the matrix was beneficial for low temperature impact toughness because of similarity in the crystal structure of variants of lath martensite, which were present in high proportion at the high angle grain boundaries. A high fraction of small M–A constituent also influenced impact toughness.

Thermomechanical behavior and microstructural evolution of a Ni(Pd)-rich Ni24.3Ti49.7Pd26 high temperature shape memory alloy

The effect of thermomechanical cycling on a slightly Ni(Pd)-rich Ni24.3Ti49.7Pd26 (near stochiometric Ni–Ti basis with Pd replacing Ni) high temperature shape memory alloy was investigated. Aged tensile specimens (400°C/24h/furnace cooled) were subjected to constant-stress thermal cycling in conjunction with microstructural assessment via in situ neutron diffraction and transmission electron microscopy (TEM), before and after testing. It was shown that in spite of the slightly Ni(Pd)-rich composition and heat treatment used to precipitation harden the alloy, the material exhibited dimensional instabilities with residual strain accumulation reaching 1.5% over 10 thermomechanical cycles. This was attributed to insufficient strengthening of the material (insufficient volume fraction of precipitate phase) to prevent plasticity from occurring concomitant with the martensitic transformation. In situ neutron diffraction revealed the presence of retained martensite while cycling under 300MPa stress, which was also confirmed by transmission electron microscopy of post-cycled samples. Neutron diffraction analysis of the post-thermally-cycled samples under no-load revealed residual lattice strains in the martensite and austenite phases, remnant texture in the martensite phase, and peak broadening of the austenite phase. Texture developed in the martensite phase was composed mainly of those martensitic tensile variants observed during thermomechanical cycling. Presence of a high density of dislocations, deformation twins, and retained martensite was revealed in the austenite state via in-situ TEM in the post-cycled material, providing an explanation for the observed peak broadening in the neutron diffraction spectra. Despite the dimensional instabilities, this alloy exhibited a biased transformation strain on the order of 3% and a two-way shape memory effect (TWSME) strain of ∼2%, at relatively high actuation temperatures.

Effect of thermo-mechanical cycling on zirconium hydride reorientation studied in situ with synchrotron X-ray diffraction

The circumferential hydrides normally present in nuclear reactor fuel cladding after reactor exposure may dissolve during drying for dry storage and re-precipitate when cooled under load into a more radial orientation, which could embrittle the fuel cladding. It is necessary to study the rates and conditions under which hydride reorientation may happen in order to assess fuel integrity in dry storage. The objective of this work is to study the effect of applied stress and thermal cycling on the hydride morphology in cold-worked stress-relieved Zircaloy-4 by combining conventional metallography and in situ X-ray diffraction techniques. Metallography is used to study the evolution of hydride morphology after several thermo-mechanical cycles. In situ X-ray diffraction performed at the Advanced Photon Source synchrotron provides real-time information on the process of hydride dissolution and precipitation under stress during several thermal cycles. The detailed study of diffracted intensity , peak position and full-width at half-maximum provides information on precipitation kinetics, elastic strains and other characteristics of the hydride precipitation process . The results show that thermo-mechanical cycling significantly increases the radial hydride fraction as well as the hydride length and connectivity. The radial hydrides are observed to precipitate at a lower temperature than circumferential hydrides. Variations in the magnitude and range of hydride strains due to reorientation and cycling have also been observed. These results are discussed in light of existing models and experiments on hydride reorientation. The study of hydride elastic strains during precipitation shows marked differences between circumferential and radial hydrides, which can be used to investigate the reorientation process.

The effect of thermal and mechanical cycling on bond strength of a ceramic to nickel-chromium (Ni-Cr) and cobalt-chromium (Co-Cr) alloys

This study evaluates the effect of thermo-mechanical cycling (TMC) on the bond strength of a ceramic to three cobalt-chromium (Co-Cr) and two nickel-chromium (Ni-Cr) alloys. One hundred metal-ceramic specimens were prepared. While half of the specimens from each metal-ceramic combination (n = 10) were tested after storage in water at 37°C for 24 hours, the other half were subjected to TMC before testing. The bond strength was evaluated by the flexural strength test according to ISO 9693:1999 (E) recommendations. TMC decreased the bond strength of the tested metal-ceramic systems as compared to the water storage (control groups) (P=0.04). Although metal alloys were significantly different from each other in their bond strength with porcelain (P<0.001), the effect of TMC on the various metal-ceramic systems was not significantly different (P=0.99). It may be concluded that base metal-ceramic bond strength is affected by aging and the effect is relatively the same for all the tested porcelain-metal systems.

Effect of thermo-mechanical cycling on the flexural strength of ceramics

Effect of thermo-mechanical cycling on the flexural strength of ceramics

Microstructure and Phase Identification of Tertiary Oxide Scale on Steel by EBSD

Oxide scales growing during hot rolling of steel represent an industrial and environmental problem. Tertiary oxide, which starts to form before entering the finishing stands, remains on the steel surface until the end of the process, affecting the final surface quality and the response to downstream processing. Characterizing scale layers and the scale/steel interface in terms of phase morphology, texture, grain structure and chemical composition is fundamental for a better understanding of their behaviour and the effect of thermomechanical cycles on the material response to further processing. Thin tertiary scale layers have been grown on ULC steel under controlled conditions in a laboratory device adequately positioned in a compression-testing machine, immediately before plane strain deformation. After heating under a protective atmosphere (nitrogen), the samples have been oxidized in air at 1050°C for a short oxidation time. Immediately after this controlled oxidation, some of the samples were subjected to plane strain compression (PSC) inside the experimental device, in order to simulate the finishing hot rolling process. Direct observations of oxide scale layers are impossible. The EBSD technique has been identified as a powerful tool that can be used to reveal the microstructure within the oxide scale and to distinguish between its constitutive phases, based on their distinct crystal lattices. The texture of the deformed oxide scales, originally grown on ULC steel, was determined in a SEM using the EBSD technique. This will help to achieve a better understanding of their complex deformation behaviour. Because the substrate deformation affects the oxide layer, orientation relationships between scale layer and substrate were measured and the crystallographic orientation between undeformed and deformed areas was determined. Strongly textured wustite grains with a clearly pronounced columnar structure were observed after oxidation at 1050°C. The detailed EBSD study reveals that the oxide layer is able to accommodate a significant amount of deformation.

Effects of thermomechanical cycling on the shape memory behavior and transformation temperatures of a Ni50.2Ti49.8 alloy

The effects of thermomechanical cycling on the shape memory behavior and transformation temperatures of a Ni50.2Ti49.8 alloy under a constant applied stress of 300 MPa were investigated. It is believed that thermomechanical cycling induces defects such as dislocations, which evidently affect the shape memory behavior and transformation temperatures. The recovery strain decreases with increasing number of thermomechanical cycles, whereas the irreversible plastic strain increases, especially in the initial few cycles. The stored elastic strain energy has an important influence on transformation temperatures, the A s σ decreases and the M s σ increases with increasing number of thermomechanical cycles. The recovery strain, irreversible plastic strain, A s σ and M s σ reach a saturation value after several cycles.

Effect of thermo-mechanical cycles on the physico-chemical properties of poly(lactic acid)

Polylactic acid (PLA) has now become an economically viable commodity plastic in many industries. This raises the question of recyclability of industrial production waste and some packaging wastes as well. The evolution of rheological and mechanical properties of polymer with the number of recycling cycles up to seven was investigated. For PLA, only the tensile modulus remains constant with the thermo-mechanical cycles. In contrast, stress and strain at break, rheological factors and the modulus and hardness probed by nanoindentation decrease for PLA. This dramatic effect is ascribed to a large decrease in the molecular weight due to several different complex degradation processes which are discussed. The effect of two stabilizers is also assessed.

Effects of thermo-mechanical cycling on the strain response of Ni–Ti–Cu shape memory alloy wire actuator

The present paper deals with the strain response of Ni–Ti–Cu shape memory alloy (SMA) wire actuators on thermo-mechanical cycling (TMC). The characteristics of the actuators such as austenite (hot shape) remnant deformation and recovery strain undergo changes upon TMC. These changes are significant in the initial few cycles and the properties of SMA tend to reach a steady state on further cycling. It is believed that TMC induces defects in the microstructure and stabilizes the martensite/austenite phase. These in turn result in continuous change in strain response with the progress of TMC. It has been shown that for a stable strain response, the wire actuators need to be subjected to TMC at a higher stress than the working stress prior to application. Experiments were also conducted in order to minimize the number of TMC required for achieving stable strain response.

Transformation behavior in a thermomechanically cycled TiNiCu alloy

The effect of thermomechanical cycling under 150 MPa on the transformation behavior in a TiNi40Cu10 (at pct) alloy annealed at different temperatures was investigated using electrical resistivity measurements and differential scanning calorimetry (DSC). It was found that thermomechanical cycling to failure could increase or decrease the transformation temperature for specimens annealed below or above the recrystallization temperature, respectively, but there was no obvious change of the transformation temperature for specimens annealed at the recrystallization temperature. The DSC and electrical-resistance experiments show that the B2 ⇋ B19 and B19 ⇋ B19′ two-stage transformations occurred in cold-worked and thermomechanically cycled specimens and that the electrical-resistance change due to the B2 → B19 transformation is larger than that of annealed specimens.

Effects of thermomechanical cycling on lead and lead-free (SnPb and SnAgCu) surface mount solder joints

Accelerated reliability tests have been performed on leadless and leaded lead-free and lead containing SMT component assemblies. Results so far have shown that lead-free reflow soldering is a viable alternative for conventional lead based reflow soldering. The selected ternary eutectic solder alloy SnAg3.8Cu0.7 requires higher processing temperatures which could restrict the use of certain board and component types, but other than that no major modifications seem necessary. Although better SnAg3.8Cu0.7 bulk mechanical properties were obtained compared to the near eutectic lead bearing bulk solder properties, reflowed solder joints did not reflect this difference. In general, quite similar reliability results were obtained as found for the lead based solders. Dependent on board and component metallisations and use environment, the reliability of the lead-free solders could perform better or worse than the lead based solders. Temperature dependent aspects such as solderability and mechanical behaviour of the lead-free assemblies could play a role in this. Although microstructural differences can be seen between the lead-free and lead bearing solder joints, similar joint failure mechanisms occur. Resistor solder joint cracks propagate from underneath the component through either transgranular (lead-free) grains or along intergranular (lead) grain boundaries between lead-rich and tin-rich areas and into coarsened regions near the component terminations. Gullwing lead cracks were seen propagating from the heel fillet along the lead/solder interfacial intermetallic mostly (some cracks started in the heel fillet and propagated through the solder body dispersed with coarsened spherical Ag 3Sn intermetallic particles). Package design and leadframe material seem to play a more important role in the fatigue mechanism than the change in microstructure of the solder joint.

Residual stresses in titanium matrix composites (TMC) in thermomechanical cycling using matrix etching

A method based on matrix etching for measuring residual stresses in continuous fibre reinforced titanium matrix composites has been applied. Four types of Ti/SiC matrix composite (TMC) materials were investigated. Two sets of experiments were carried out for each TMC: the effect of increasing tensile stress from 100 to 600 MPa at room temperature on residual stress was investigated, and another set was done by cycling the stress up to 300 MPa at various temperatures (25–600°C). The effect of thermomechanical cycles (up to 4000 cycles) on residual stress was determined. The details of this residual stress measurement by matrix etching techniques, and errors easily caused by bad treatment and measurement including unetched matrix, fibre displacement and uneven reference plane, have also been discussed. A specific emphasis is placed on both fundamental and experimental aspects of the method for measuring residual stresses in continuous fibre reinforced titanium matrix composites, in particular on the relationship between residual stresses and experimental parameters (heating temperature, applied tensile stresses, and thermomechanical cycling).

Effect of thermomechanical cycling in an FeMnSiCrNi shape memory alloy

Previous studies on the effect of cycling in Fe-Mn-Si alloys have shown an increase in reversibility with increasing number of thermal cycles. In Fe-Mn-Si-Cr-Ni and Fe-Mn-Si-Co-Ni alloys, the shape recovery strain during thermomechanical cycling increased when the strain amplitude for each successive cycle is kept constant. Where the total strain (i.e., the sum of the transformation and permanent strain) is held constant, a small decrease in strain recovery with increasing number of cycles occurs. Nonetheless, an increase in reversibility with increasing number of thermomechanical cycles is a common feature for most studies. While previous studies have shown that training or thermomechanical transformation cycling may improve the shape recovery in these alloys, the mechanism is not still clear. Characterization of the transformation behavior during cycling is an important prerequisite for practical use of such alloys. In this paper the authors report microstructural changes during thermomechanical cycling of an Fe-Mn-Si-Cr-Ni shape memory alloy.