Effect Of Surface Functionalization Research Articles

Effect of MWCNTs surface functionalization on the characterization of PVA/MWCNTs nanocomposites

The present study aims to put forward the role of surface functionalization of multi-walled carbon nanotubes (MWCNTs) on the enhancement thermal and hydrophilicity properties of new nanocomposite based poly(vinyl alcohol)/surface functionalized MWCNTs (PVA/MWCNTs), prepared by a facile phase inversion process. In this study, the fabrication of PVA/MWCNTs nanocomposites is carried out using functionalized MWCNTs (f-MWCNTs) with different functional groups (–OH, –COOH, –NH2). The structural, morphological, thermal, hydrophilicity and physico-chemical properties of PVA/MWCNTs nanocomposites are characterized by XRD, FE-SEM, FT-IR, TGA and contact angle measurement. The FT-IR results confirm the formation of a hydrogen bond between MWCNTs and PVA chain. XRD analysis indicates an improvement in the crystallinity of the PVA/MWCNTs nanocomposite. TGA results reveal that the PVA/f-MWCNTs nanocomposites show higher thermal stability than pure PVA. It is revealed that PVA/MWCNTs nanocomposites based functionalized MWCNTs remarkably increase the degradation temperature, and thus enhancing the thermal properties. The highest weight loss (30.7 wt%) and degradation temperature (520 °C) values are obtained with PVA/f-MWCNTs(0.5 wt%). The contact angle measurement confirms that the hydrophobic properties of pure PVA became hydrophilic because of the functional groups of MWCNTs. The hydrophilicity of PVA/MWCNTs nanocomposites is increased with the increase in wt% of MWCNTs embedded in the nanocomposite.

Chinese architecture inspired smart roof tile integrating radiation cooling, water harvesting, and energy recycling

The development of new materials for resource and energy recycling has emerged as a primary focus in addressing global energy and environmental sustainability challenges. Inspired by traditional Chinese architecture, a smart roof tile (SRT) is scientifically designed, which incorporates hierarchical micro-nanostructured polyethylene/silica/barium sulfate composites (IH-PSB), semiconductor power generation modules, and LED chips. Leveraging the combined effects of surface and interface functionalities, the IH-PSB demonstrates exceptional sub-ambient cooling capabilities, resulting in its surface and bottom temperature being 5.4 °C and 12.1 °C lower than the ambient temperature, respectively. Additionally, the precisely controlled heterogeneous wettability, with a contact angle of approximately 151° and a roll-off angle of around 32°, allows the IH-PSB to efficiently condense moisture and transport droplets. Benefiting from the excellent radiation cooling performance and precisely controlled heterogeneous wettability, the IH-PSB exhibits remarkable passive sub-dewpoint cooling efficiency coupled with efficient water harvesting performance. During a one-month outdoor experiment, the IH-PSB operated stably and continuously without any electrical input, maintaining a mass flux ranging from ∼23.2–50.0 g m−2 h−1. Interestingly, the SRT system efficiently harnesses waste heat generated by the LEDs while simultaneously regulating their temperature effectively. The development and utilization of the SRT offer a sustainable, energy-efficient, and forward-thinking solution that addresses global water scarcity and energy crises.

Effects of Different Surface Functionalizations of Silica Nanoparticles on Mesenchymal Stem Cells.

Physicochemical properties of nanoparticles, such as particle size, surface charge, and particle shape, have a significant impact on cell activities. However, the effects of surface functionalization of nanoparticles with small chemical groups on stem cell behavior and function remain understudied. Herein, we incorporated different chemical functional groups (amino, DETA, hydroxyl, phosphate, and sulfonate with charges of +9.5, + 21.7, -14.1, -25.6, and -37.7, respectively) to the surface of inorganic silica nanoparticles. To trace their effects on mesenchymal stem cells (MSCs) of rat bone marrow, these functionalized silica nanoparticles were used to encapsulate Rhodamine B fluorophore dye. We found that surface functionalization with positively charged and short-chain chemical groups facilitates cell internalization and retention of nanoparticles in MSCs. The endocytic pathway differed among functionalized nanoparticles when tested with ion-channel inhibitors. Negatively charged nanoparticles mainly use lysosomal exocytosis to exit cells, while positively charged nanoparticles can undergo endosomal escape to avoid scavenging. The cytotoxic profiles of these functionalized silica nanoparticles are still within acceptable limits and tolerable. They exerted subtle effects on the actin cytoskeleton and migration ability. Last, phosphate-functionalized nanoparticles upregulate osteogenesis-related genes and induce osteoblast-like morphology, implying that it can direct MSCs lineage specification for bone tissue engineering. Our study provides insights into the rational design of biomaterials for effective drug delivery and regenerative medicine.

Cotransport of nanoplastics and plastic additive bisphenol AF (BPAF) in unsaturated hyporheic zone: Coupling effects of surface functionalization and protein corona

The ecological risk of combined pollution from microplastics (MPs) and associated contaminants usually depends on their interactions and environmental behavior, which was also disturbed by varying surface modifications of MPs. In this study, the significance of surface functionalization and protein-corona on the cotransport of nanoplastics (NPs; 100 nm) and the related additive bisphenol AF (BPAF) was examined in simulated unsaturated hyporheic zone (quartz sand; 250–425 μm). The electronegative bovine serum albumin (BSA) and electropositive trypsin were chosen as representative proteins, while pristine (PNPs), amino-modified (ANPs), and carboxyl-modified NPs (CNPs) were representative NPs with different charges. The presence of BPAF inhibited the mobility of PNPs/CNPs, but enhanced the release of ANPs in hyporheic zone, which was mainly related to their hydrophobicity changes and electrostatic interactions. Meanwhile, the NPs with high mobility and strong affinity to BPAF became effective carriers, promoting the cotransport of BPAF by 16.4 %–26.4 %. The formation of protein-coronas altered the mobility of NPs alone and their cotransport with BPAF, exhibiting a coupling effect with functional groups. BSA-corona promoted the transport of PNPs/CNPs, but this promoting effect was weakened by the presence of BPAF via increasing particle aggregation and hydrophobicity. Inversely, trypsin-corona aggravated the deposition of PNPs/CNPs, but competition deposition sites and increased energy barrier caused by coexisting BPAF reversed this effect, facilitating the cotransport of trypsin-PNPs/CNPs in hyporheic zone. However, BPAF and protein-coronas synergistically promoted the mobility of ANPs, owing to competition deposition sites and decreased electrostatic attraction. Although all of the NPs with two protein-coronas reduced dissolved BPAF in the effluents via providing deposition sites, the cotransport of total BPAF was improved by the NPs with high mobility (BSA-PNPs/CNPs) or high affinity to BPAF (BSA/trypsin-ANPs). However, the trypsin-PNPs/CNPs inhibited the transport of BPAF due to their weak mobility and adsorption with BPAF. The results provide new insights into the role of varying surface modifications on NPs in the vertical cotransport of NPs and associated contaminants in unsaturated hyporheic zone.

Dielectric, transparent, thermally stable and mechanically robust bionanocomposite films based on chitosan and modified cellulose nanocrystals

AbstractThe growing demand for electronics necessitates the development of novel environmentally responsible materials. A potential approach involves incorporating renewable and sustainable materials with mechanical and electrical properties while ensuring environmentally friendly disposal. Herein, this study reports the dielectric properties of chitosan (CS) reinforced with cellulose nanocrystals (CN) extracted from post‐harvest tomato plant residue. The resulting bionanocomposite material demonstrated remarkable characteristics, including dielectricity, transparency, thermal stability, and mechanical robustness. Additionally, the effect of high‐loading fillers (5 and 10 wt %) on the final properties of the material is investigated, as well as the effect of surface functionality of the CNs. The results showed that both the high‐loading fillers and the surface functionality of the CNs had a significant impact on the properties of the nanocomposite material. The bionanocomposite materials produced in this study hold great potential as an eco‐friendly substitute for conventional electronic materials and beyond. Its dielectric, transparent, thermally stable, and mechanically robust properties render it well‐suited for diverse applications.Highlights The phosphorylated groups insured high Crl (%) and high interface between the filler and matrix. High interface and crystallinity enhanced the mechanical characteristics. Low crystallinity increases the dielectric constant, case of 5% CNS. Filler’ type can tailor and optimize the energy dissipation up to tan δ = 0.5 for 5% CNP. Detection of Warburg impedance proves the interface polarization presence.

Synergetic Effect of Microporosity, Composition, and Surface Functionality of Nanoporous Activated Carbon: An Interface for CO2 Capture and Supercapacitor Applications

Synergetic Effect of Microporosity, Composition, and Surface Functionality of Nanoporous Activated Carbon: An Interface for CO₂ Capture and Supercapacitor Applications

Ultraviolet shielding composites of different cellulose/aramid nanofibers

In order to improve the UV shielding properties of cellulose nanofibers (CNF), aramid nanofibers (ANF) are used as additives. For composite preparation, three distinct CNFs are used in this work: ionic liquid mediated hydrolyzed (ILCNF), high-speed mechanically sheared (MCNF), and TEMPO-mediated oxidized (TCNF) to identify the effect of surface functionality and morphology on the composite properties. The performance of the prepared composites is compared by evaluating their UV shielding and mechanical properties. Due to the maximum (7.9 nm) and minimum (3.5 nm) average fibre diameters, respectively, pristine MCNF had minimum transparency and TCNF had maximum transparency. 5 wt% ANF - TCNF composite had maximum UV-250 and UV-300 nm shielding ratios of 74.6 and 93.7%, respectively. For the same composite, an enhancement in tensile strength of 117% is also noted. According to these findings, TCNF composite with 5% ANF has excellent UV shielding, superior transparency in the visible light region, and outstanding mechanical strength.

Synergistic effects of melamine functionalized graphene oxide and imidazolium ionic liquid on the tribological performance and thermal stability of polyalphaolefin based hybrid nanolubricants

Tribological and thermophysical characteristics of a new hybrid nanolubricant that incorporates melamine functionalized graphene oxide (mGO) and imidazolium cation based ionic liquid (IL) in a polyalphaolefin (PAO-6) base oil have been investigated. Different formulations of nanolubricants with 0.05 wt%, 0.1 wt% nanosheets and 1 wt% ionic liquid were studied to examine the synergistic effects of surface functionalization and ionic liquid addition on the antifriction and antiwear properties of the PAO-6 base oil. Thermal stability studies involved Thermogravimetric analysis to analyze the oxidation onset and decomposition temperature of different formulatons at varying weight concentrations of nanoadditives. Anti-friction performance was quantified by the coefficient of friction (COF) reduction compared to neat lubricant. The highest reduction in COF was observed for 0.05 wt% mGO + 1 wt% IL with an outstanding 73.33% reduction followed by 0.05 wt% mGO and 0.05 wt% GO with 73% and 67% reduction respectively. Post-wear analysis of the wear scars was performed using 3D optical profiler, SEM micrographs, EDX elemental composition and Raman spectra. The highest reduction in wear depth was observed in the case of PAO-6 + 0.05% mGO with a value of 46.3% followed by a 39.9% reduction in the case of PAO-6 + 0.05% GO. The morphologies of samples containing both ionic liquid and nanosheets exhibited a much smoother surface with the absence of deep grooves and pits which was attributed to the formation of a strongly bonded tribofilm owing to the chemical interactions between ionic liquid capped nanosheets and metal substrate. Strong interfacial interactions also induced a significant increase in the thermal stability of the nanofluids. The maximum shift observed in the oxidation onset temperature compared to neat PAO-6 was 68◦C while the decomposition temperature increased by 61◦C. Due to their excellent friction, wear, and thermal properties, these hybrid nanofluids could be applied in various highly demanding industrial sectors such as automotive, machining operations, aerospace, thermal power plants and micro/nano-electromechanical systems.

Reversible Surface Engineering of Cellulose Elementary Fibrils: From Ultralong Nanocelluloses to Advanced Cellulosic Materials.

Cellulose nanofibrils (CNFs) are supramolecular assemblies of cellulose chains that provide outstanding mechanical support and structural functions for cellulosic organisms. However, traditional chemical pretreatments and mechanical defibrillation of natural cellulose produce irreversible surface functionalization and adverse effects of morphology of the CNFs, respectively, which limit the utilization of CNFs in nanoassembly and surface functionalization. Herein, this work presents a facile and energetically efficient surface engineering strategy to completely exfoliate cellulose elementary fibrils from various bioresources, which provides CNFs with ultrahigh aspect ratios (≈1400) and reversible surface. During the mild process of swelling and esterification, the crystallinity and the morphology of the elementary fibrils are retained, resulting in high yields (98%) with low energy consumption (12.4kJ g-1). In particular, on the CNF surface, the surface hydroxyl groups are restored by removal of the carboxyl moieties via saponification, which offers a significant opportunity for reconstitution of stronger hydrogen bonding interfaces. Therefore, the resultant CNFs can be used as sustainable building blocks for construction of multidimensional advanced cellulosic materials, e.g., 1D filaments, 2D films, and 3D aerogels. The proposed surface engineering strategy provides a new platform for fully utilizing the characteristics of the cellulose elementary fibrils in the development of high-performance cellulosic materials.

P-n Junction catalysis in action: Boosting norfloxacin photodegradation with ZIF-67-based Co3O4 wrapped in MoS2 with surface functionalized graphene quantum-dot

The primary challenge in photocatalytic application is to address the inefficiency in exploiting the photo-induced charge carriers. The dynamic behaviors of photogenerated carriers can be controlled through an internal electric field by building a p-n heterojunction. In this respect, p-n heterojunctions constructed from zeolitic imidazolate frameworks (ZIFs) with further surface functionalization are uniquely active and can increase the charge separation due to a favorable band structure. Thus, the present work demonstrates the preparation of an excellent visible-light absorbing photocatalyst based on a Co3O4 from ZIF-67 wrapped with MoS2 and functionalized with graphene quantum dots (GQDs), which is evaluated for the photodegradation of norfloxacin. Under visible light irradiation, the as-designed GQDs-functionalized MoS2@Co3O4 p-n heterojunction photocatalyst outperforms the individual MoS2 and Co3O4 semiconductors. The remarkable degradation efficiency is mostly due to the formation of a p-n heterojunction between MoS2 and the ZIF-67-based Co3O4. The photocatalytic mechanism of the as-designed system is deduced from reactive species trapping studies. This study sheds light on the design of a photocatalytic system based on ZIF-67, and on the effect of surface functionalization, thereby expanding the potential practical application of these materials in the field of environmental remediation.

Investigation on the physicochemical properties of poly (ethylene-co-vinyl acetate)/mesoporous silica nanocomposites: Effects of content and surface functionalization

In this study, poly (ethylene-co-vinyl acetate)/mesoporous silica EVA/SBA-15 nanocomposites, containing 0.5, 1.5, and 2.5 wt% of unfunctionalized and functionalized SBA-15 were prepared by melt blending in an internal mixer. Mesoporous silica was synthesized through the sol-gel method and modified by hexadecyltrimethoxysilane (HDTMS). Several characterizations were performed; including Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), mechanical properties, dynamic mechanical analysis (DMA), and dielectric study to characterize the physicochemical properties of elaborated materials. The results revealed the successful synthesis and functionalization of mesoporous silica, as confirmed by the FTIR and SEM. The crystallinity of the nanocomposites decreased and the elastic modulus increased with the incorporation of the mesoporous silica. Measurement of tensile properties shows that the tensile strength of the nanocomposite content of 1.5 wt% F-SBA-15 is 17.2% is higher as compared to pure EVA. DMA analysis validates the improvement in mechanical properties of the EVA/SBA-15 samples. SEM images displayed well-dispersed F-SBA-15 nanoparticles and enhanced interfacial adhesion between the phases. TGA indicates the enhancement of the thermal stability of nanocomposites as compared with the pure EVA matrix. The surface functionalization presented an approach to preparing nanocomposites with enhanced thermal stability and a low dielectric constant.

Functional groups effect on the toxicity of modified ZIF-90 to Photobacterium phosphoreum

Zeolitic imidazolate framework (ZIF) is of wide interest in biomedical applications due to its extraordinary properties such as high storage capacity, functionality and favorable biocompatibility. However, more comprehensive safety assessments are still essential before ZIF is broadly used in biomedicine. Using the characteristic that aldehyde groups on the surface of ZIF-90 can be modified with other functional groups, a series of ZIF-90s modified with different functional groups (oxime group, carboxyl group, amino group and sulfhydryl group) were synthesized to investigate the effect of functionalization on the toxicity of ZIF-90. ZIF-90 series showed concentration-dependent toxic effects on Photobacterium phosphoreum T3 and the functionalized ZIF-90s are more toxic than pristine ZIF-90, with the ZIF-90 modified with amino group (ZIF-90-NH2) showing the strongest toxicity (IC50 = 23.06 mg/L). Based on the results of the cellular assay and stability exploration, we concluded that corresponding imidazole-ligand release and the property of positively charged are responsible for the elevated toxicity of ZIF-90-NH2. Cell membrane damage, oxidative damage and luminescence damage are the main contributors to the toxic effects of ZIF-90 series. This study explored the effect of surface functionalization on the toxicity of ZIF and proposed mechanistic clues for the safety application of ZIF.

Synergistic effects of PVDF membrane surface functionalization with polydopamine and titanium dioxide for enhanced oil/water separation and photocatalytic behavior

This study investigates the surface modification of poly(vinylidene fluoride) (PVDF) membranes using polydopamine (PDA) and titanium dioxide (TiO2) for effective separation of oily compounds and self-cleaning photocatalytic behavior. The aim was to improve the antifouling properties of the membrane, which was modified by varied PDA and TiO2 concentrations and evaluated regarding the water permeance, total organic carbon (TOC) rejection, and photocatalytic degradation activity. The results demonstrated considerable improvements in the membrane's antifouling properties, achieving a water permeance of 781 kg h−1 bar−1 m−2, TOC rejection of 87%, and methylene blue photocatalytic degradation of 97%, using dopamine (DA) and TiO2 concentration of 0.92 g L−1 and 1.4% (w/w), respectively, and a solution agitation speed of 106 rpm. Additionally, flux recovery reached 86% after the photocatalytic self-cleaning process, indicating that TiO2 improved the membrane's antifouling properties. These findings highlight the potential of PDA and TiO2 as effective surface modifiers for enhancing oil/water separation, reducing fouling, and promoting self-cleaning effect in photocatalytic PVDF membranes. This study’s outcomes provide valuable insights for developing efficient and sustainable membrane-based separation processes for oily wastewater treatment applications.

Effect of surface functionalization on DNA sequencing using MXene-based nanopores.

As one of the most promising types of label-free nanopores has great potential for DNA sequencing via fast detection of different DNA bases. As one of the most promising types of label-free nanopores, two-dimensional nanopore materials have been developed over the past two decades. However, how to detect different DNA bases efficiently and accurately is still a challenging problem. In the present work, the translocation of four homogeneous DNA strands (i.e., poly(A)20, poly(C)20, poly(G)20, and poly(T)20) through two-dimensional transition-metal carbide (MXene) membrane nanopores with different surface terminal groups is investigated via all-atom molecular dynamics simulations. Interestingly, it is found that the four types of bases can be distinguished by different ion currents and dwell times when they are transported through the Ti3C2(OH)2 nanopore. This is mainly attributed to the different orientation and position distributions of the bases, the hydrogen bonding inside the MXene nanopore, and the interaction of the ssDNA with the nanopore. The present study enhances the understanding of the interaction between DNA strands and MXene nanopores with different functional groups, which may provide useful guidelines for the design of MXene-based devices for DNA sequencing in the future.

Radiation synthesis and chemical modifications of p(AAm-co-AAc) hydrogel for improving their adsorptive removal of metal ions from polluted water

The research focuses on utilizing gamma irradiation to synthesize polyacrylic acid-co-polyacrylamide p(AAm-co-AAc) hydrogels. The effect of synthetic parameters on physicochemical features of p(AAm-co-AAc) hydrogls were examined, including acrylic acid (AAc): acrylamide (AAm) weight ratios, monomer concentration, and gamma irradiation dosage (kGy). At the optimum synthetic conditions (30 kGy and 75% AAc), different chemical modifications are explored to incorporate sulfonate, hydroxyl, carboxyl, cysteine, thiol, and amine functional groups within the bare hydrogel (Cpd 0) structure. Fourier-transform infrared spectroscopy (FTIR) and scanning electron microscopy (SEM) analyses confirmed the success development of functionalized hydrogels (namely Cpd 1 to 6) with three-dimensional porous structures. These modified hydrogels include Cpd 1, a sulfonated hydrogel through a sulfonation reaction; Cpd 2, modified via NaOH hydrolysis; Cpd 3, modified using thionyl chloride; Cpd 4, incorporating cysteine modification through reaction with cysteine; Cpd 5, with 4-(Dimethylamino) benzaldehyde; and Cpd 6, modified with 3,4-Dimethylbenzoic acid.The effect of hydrogel composition and surface functionalities on the swelling capacity and interactions with scale-forming/heavy metal ions (e.g., Ba2+, Sr2+, and Cu2+) was investigated in saline water solution (NaCl = 1000 mg/L). Batch adsorption studies reveal that all modified hydrogels exhibited higher removal efficiency for the three metal ions than unmodified p(AAm-co-AAc) hydrogel, validating the key role of surface functionalities in tailoring hydrogel affinity for metal ions adsorption. Amongst these, NaOH-treated hydrogel (Cpd 2) outperformed all other modified ones in the removal of Cu2+, Ba2+, and Sr2+ ions, with maximum capacities of 13.67, 36.4, and 27.31 mg/g, respectively. Based on adsorption isotherm and kinetic modeling, the adsorption process of the three metal ions onto all modified hydrogels better obeyed Freundlich isotherm and pseudo-first-order kinetic models. Thermodynamic studies also indicated that the adsorption behavior of Sr2+ ions can exhibit both exothermic and endothermic characteristics, depending on the nature of hydrogel surface chemistry. Conversely, the adsorption process of Cu2+ and Ba2+ ions onto all modified hydrogels is endothermic, suggesting favorable chemical adsorption mechanisms. These findings reveal that the specific adsorption performance of hydrogel is dependent on the type of modification and the targeted heavy metal ions. Based on the nature of hydrogel surface functionality, surface modifications can change the charge density, hydrophilicity, and overall chemical environment of the hydrogel, offering a versatile approach to optimize the adsorption affinity/selectivity of hydrogel's in removing scale-forming/heavy metals from water solutions.

Investigation of direct surface charge transfer of glutamic acids on 2D monolayer molybdenum disulfide and its sensing properties

2D transition metal dichalcogenides (TMDs) have attracted significant attention because of their potential in biomolecular sensing applications owing to their sensitive surface interactions with analytes. In particular, glutamic acid (GLU) as representative of amino acids (AAs) are considered not only basic metabolites in proteins and food, but also vital biomarkers of body status and diseases. In addition, monitoring GLU profiles appears to be a highly effective real-time and early diagnostic technique. In this study, a biomolecular GLU sensor that uses a 2D polycrystalline MoS2 as channel material, based on the effect of the direct surface charge transfer, was fabricated. As fundamental approach, the direct charge transfer of adsorbed GLU onto MoS2 was experimentally demonstrated for the first time. The sensor exhibited sensitive responses to GLU exposure, without any enzymes or receptors. In addition, the electrode-encapsulated MoS2 sensor showed comparably stable responses to the non-encapsulated MoS2 sensor. The results confirmed that the 2D TMDs such as polycrystalline MoS2 could be a viable platform for highly sensitive and stable biomolecular sensor applications based on direct surface interactions. In addition, this study can contribute to the extended researches such as the effect of surface functionalization by metal nanoparticles, and other types of AAs.

Effect of Surface Chemistry on Macrocycle and Conducting Polymer Based-Carbon Composites

Redox-active carbon composite-based electrodes, especially nitrogen-based redox active materials, can provide high power and energy storage in electrochemical capacitors. These materials include porphyrin macrocycles which are found in nature and possess unique electronic and redox-active properties from their large π-conjugated systems [1], [2]. When compositing with carbon-based materials such as carbon nanotubes (CNTs), they have shown increased stability and long-term performance. Previous work using macrocyclic tetraphenyl porphyrin sulfonate (TPPS) in CNT-based composites demonstrated improved capacitive profiles, better interfacial kinetics, and charge retention introduced in capacitive electrodes [3], [4]. On the other hand, conducting polymers with π-conjugated backbones also enabled high charge storage when used in composites [5]. To further advance these capabilities, the effects and mechanisms of surface functionalities of carbon substrates need to be investigated. For example, the presence of carboxyl groups on CNTs has been shown to improve charge storage through favourable interfacial interactions in some conducting polymers [6], [7]. The challenge as highlighted in Figure 1 lies in understanding which redox-active species, e.g. macrocycle or conducting polymer, will favour certain surface functionalities based on the nature of their interactions. Thus, a systematic investigation to design and create desirable composites and interactions for high energy and power densities, and to extend to low-cost carbon sources including waste biomass-based activated carbons.In this work, we conducted a systematic study comparing the effect of several surface functionalities like carboxyl groups on TPPS macrocycles and on conducting polymer-based carbon composites to answer the question on why certain surface functionalities are favored for each species. Preliminary studies have shown presence of TPPS has increased the capacitive profiles, reaction kinetics and rate capabilities of CNT composites, exceeding the conducting polymer counterparts. But this capacitive increase can be further improved through surface modification. This study leveraged layer-by-layer deposition approaches to fabricate redox-active carbon composites, followed by electrochemical characterizations using cyclic voltammetry and electrochemical impedance spectroscopy. Surface morphology was studied using electron microscopy while surface functional groups were investigated using x-ray photoelectron spectroscopy. The findings from this study can be used to implement systematic surface modification for redox-active carbon composites to improve energy storage, towards a more sustainable future.

Effect of Surface Functionality on the Rheological and Self-Assembly Properties of Chitin and Chitosan Nanocrystals and Use in Biopolymer Films.

Chitin nanocrystals (ChNCs) are unique to all other bio-derived nanomaterials in one aspect: the inherent presence of a nitrogen moiety. By tuning the chemical functionality of this nanomaterial, and thus its charge and hydrogen bonding capacity, one can heavily impact its macroscopic properties such as its rheological and self-assembly characteristics. In this study, two types of ChNCs are made using acid hydrolysis (AH-ChNCs) and oxidative (OX-ChNCs) pathways, unto which deacetylation using a solvent-free procedure is utilized to create chitosan nanocrystals (ChsNCs) of varying degree of deacetylation (DDA). These nanocrystals were then studied for their rheological behavior and liquid crystalline ordering. It was found that with both deacetylation and carboxylation of ChNCs, viscosity continually increased with increasing concentrations from 2 to 8 wt %, contrary to AH-ChNC dispersions in the same range. Interestingly, increasing the amine content of ChNCs was not proportional to the storage modulus, where a peak saturation of amines provided the most stiffness. Conversely, while the introduction of carboxylation increased the elastic modulus of OX-ChNCs by an order of magnitude from that of AH-ChNCs, it was decreased by increasing DDA. Deacetylation and carboxylation both inhibited the formation of a chiral nematic phase. Finally, these series of nanocrystals were incorporated into biodegradable pectin-alginate films as a physical reinforcement, which showed increased tensile strength and Young's modulus values for the films incorporated with ChsNCs. Overall, this study is the first to investigate how surface functionalization of chitin-derived nanocrystals can affect their rheological and liquid crystalline properties and how it augments pectin/alginate films as a physical reinforcement nanofiller.

Impact of Surface Functionalization and Deposition Method on Cu-BDC surMOF Formation, Morphology, Crystallinity, and Stability.

For direct integration into device architectures, surface-anchored metal-organic framework (surMOF) thin films are attractive systems for a wide variety of electronic, photonic, sensing, and gas storage applications. This research systematically investigates the effect of deposition method and surface functionalization on the film formation of a copper paddle-wheel-based surMOF. Solution-phase layer-by-layer (LBL) immersion and LBL spray deposition methods are employed to deposit copper benzene-1,4-dicarboxylate (Cu-BDC) on gold substrates functionalized with carboxyl- and hydroxyl-terminated alkanethiol self-assembled monolayers (SAMs). A difference in crystal orientation is observed by atomic force microscopy and X-ray diffractometry based on surface functionalization for films deposited by the LBL immersion method but not for spray-deposited films. Cu-BDC crystallites with a strong preferred orientation perpendicular to the substrate were observed for the films deposited by the LBL immersion method on carboxyl-terminated SAMs. These crystals could be removed upon testing adhesive properties, whereas all other Cu-BDC surMOF film structures demonstrated excellent adhesive properties. Additionally, film stability upon exposure to water or heat was investigated. Ellipsometric data provide insight into film formation elucidating 7 and 14 Å average thicknesses per deposition cycle for films deposited by the immersion method on 11-mercapto-1-undecanol (MUD) and 16-mercaptohexadecanoic acid (MHDA), respectively. In contrast, the films deposited by the spray method are thicker with the same average thickness per deposition cycle (21 Å) for both SAMs. While the spray method takes less time to grow thicker films, it produces similar crystallite structures, regardless of the surface functionalization. This research is fundamental to understanding the impact of deposition method and surface functionalization on surMOF film growth and to provide strategies for the preparation of high-quality surMOFs.

Theoretical study of catalytic performance of WN MXenes as cathodes for Li-O2 batteries: Effects of surface functionalization and atomic layers

Promising Li–O2 batteries suffer from high overpotentials of the oxygen evolution reaction (ηOER)/oxygen reduction reaction (ηORR) at cathodes during charging/discharging. Herein, the first-principles calculations were performed to investigate WN MXenes, including the pristine Wn+1Nn and oxygen − functionalized Wn+1NnO2 (n = 1, 2, and 3), as the potential cathode catalysts for Li − O2 batteries. Both Wn+1Nn and Wn+1NnO2 exhibit high electrical conductivity. Compared to the electrophilic W surfaces of Wn+1Nn, the nucleophilic O surfaces of Wn+1NnO2 can not only bind to Li of LixO2 to activate the Li − O bond, but also promote electron transfer to form Li+, which facilitates to the delithiation of LixO2 in the OER, thus lowering ηOER on Wn+1NnO2. Moreover, the O-functionalized surfaces can also reduce the adsorption energies of LixO2, thereby lowering ηORR and ηOER. On the other hand, reducing atomic layers of Wn+1Nn and Wn+1NnO2 can further lower ηORR and ηOER, because WN MXenes with fewer atomic layers have lower d-/p- band centers, which can weaken the adsorption of LixO2. The W2NO2 MXene not only has a high electrical conductivity but also exhibits ultra-low ORR, OER, and total overpotentials (0.12, 0.17, and 0.29 V), indicating it possesses an ultra-high catalytic performance as cathodes for Li-O2 batteries.