The residual microstructure of 304 stainless steel has been examined by transmission electron microscopy following shock loading to pressures of 150, 250 and 350 kbar at a constant pulse duration of 2 μsec, and 0.5, 1.0 and 6.0 μsec at a constant pressure of 250 kbar. These observations were compared with those for the same material cold-rolled to reductions in thickness of 15, 30 and 35%. Deformation twins were observed in all deformed samples. The twin volume densities increased for increasing shock pressure at constant pulse duration, and for constant pressure for pulse durations of up to 2 μsec α′-martensite was observed as trace microstructure at 2 μsec (250 kbar) while at 6 μsec the volume percent of α′-martensite was observed to be roughly 5%. α′-Martensite in the cold-rolled samples was observed to increase steadily in volume percent with increasing reduction by rolling. Residual microhardness was also observed to increase steadily with increased reduction by rolling, while residual microhardness increased with pulse-duration at 250 kbar of up to 1μsec, then decreased to a hardness plateau between 2 and 6 μsec. The residual deformation twin structure in all samples is shown to consist of fault bundles composed of a varying composition of stacking faults, ϵ-phase and twins, with a small contribution of ϵ-phase in shock-loaded microstructures, except at 6 μsec (250 kbar). The results confirm the formation of α′-martensite within these fault bundles and at intersecting twin faults in both the shock-loaded and cold-rolled 304 stainless steel.
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