Abstract The effects of doped Sbon the formation of superconducting phases in [Bi0.8(Pb1-xSbx)0.2]2Sr2 Ca2Cu2.8Oy are investigated for x in the range of 0 to 0.5. Electrical resistivity measurements, powder X-ray diffraction and differential thermal analyses are performed. The coexistence of Pb and Sb is likely to cause a partially-melted state at a relatively low temperature of ≈840°C. The superconducting phase with 110 K transition temperature may rapidly grow in the partially-melted state. For x=0.2, samples showing zero resistivity at temperatures above 100 K can be obtained by sintering at 860°C for a period much shorter than that required for sintering samples without Sb.