Effect Of Porosity Research Articles

Unveiling the porosity effect of superbase ionic liquid-modified carbon sorbents in CO2 capture from air

Direct air capture (DAC) of CO2 represents one of the most promising technologies to achieve negative carbon emissions. In this work, the superbase ionic liquids (ILs)-modified carbon substrates were developed for DAC of CO2 by harnessing the strong CO2 binding capability of IL and the ordered porous channels of the carbon supports. Detailed porosity analysis revealed that the IL with an aromatic cation and an oxygenate anion preferred to fill the micropores, and a thin layer was created on the surface of the mesopores. Strong π-π interaction between the IL layer and the carbon surface was disclosed by wide-angle X-ray scattering (WAXS) analysis, leading to enhanced thermal stability of the IL phase. For the same lL coating amount, the DAC of CO2 evaluation revealed that a larger mesopore size and pore volume in the carbon/IL composite materials led to higher CO2 uptake capacity by exposing more active sites to integrate CO2 from diluted sources. The thermodynamic analysis confirmed the critical role of IL coating in providing strong chemisorption sites and significantly improved selectivity to enrich the diluted CO2 from the air atmosphere. This work provides guidance on leveraging the scaffolds' surface properties and porosities of the scaffolds to optimize DAC of CO2 behavior.

Thermally-induced fracture in the oxide scale of T91 ferritic/martensitic steel after exposure to oxygen-saturated liquid lead–bismuth eutectic

Ensuring the continuity and stability of the oxide scale to separate T91 steel from lead-bismuth eutectic (LBE) is an effective method for limiting corrosion in the lead-based fast reactor system. In this study, we specifically investigated the impact of cooling thermal stress on the stability and damage of the oxide scales of T91 steel when exposed to oxygen-saturated liquid lead–bismuth eutectic at high temperatures. A corrosion test was conducted on T91 steels exposed to stagnant oxygen-saturated LBE at 500 °C. Experimental results indicated that oxide damage exists without any external force, including interface cracks and through-scale cracks perpendicular to the interface. We developed a three-layer peridynamic model of T91-(Fe,Cr)3O4-Fe3O4 to simulate the deformation and failure of oxides under a cooling process from high temperature to room temperature. The simulation results show that a temperature drop of about 200 °C from 500 °C can cause through-oxide cracks in the oxide scale, and subsequent cooling can lead to the propagation of interfacial cracks. Additional modifications were introduced in the model to account for the porosity of the oxide scale. Parametric investigations illustrate the effects of oxide scale thickness and porosity on the resulting crack patterns.

Thermal cycle behaviour of plasma sprayed thermal barrier coatings on cast iron substrate for the application of liner of internal combustion engine

In the present scenario, research on Thermal Barrier Coatings (TBCs) is attracting significant attention in high-temperature applications due to the rising demand in industrial applications, such as gas turbine blades and internal combustion engine components. To meet these demands, it is essential to enhance the mechanical and oxidation properties of thermal barrier coatings. The atmospheric plasma spray methodology for producing these coatings has become a central focus in recent times. In this work, TBCs were prepared by blending pure alumina and Yttria-Stabilized Zirconia (YSZ) in equal proportions. Extensive study of TBCs carried out under high-temperature conditions through thermal cycle tests at elevated temperatures, around 850 °C. A total of 350 thermal cycles were conducted, and microstructures of the coating surface were examined at 150, 250, and 350 cycles. High-temperature stress, generated due to the sintering of the coating, also influences the life of the coatings. Specimen with a topcoat thickness of 300 μm, exhibited good thermal shock resistance compared to the specimens with topcoats of thickness of 100 μm and 200 μm. The effects of process parameters, porosity, and thermal shock resistance are presented in detail. The topcoat with a thickness of 300 μm demonstrated excellent thermal shock resistance and reduced formation of thermally grown oxide (TGO). The porosity of the coating, found to be between 2% and 3%, contributed to its dense nature, effectively reducing oxidation rates and enhancing the coating's lifespan under cyclic high-temperature conditions.

Experimental study of vortex-induced vibration of stay cables installed with two types of perforated shroud light devices

To address both illumination issues and the common vortex-induced vibration (VIV) of bridge cables, a perforated shroud light device is proposed. The effect of the different porosities (20%, 35%, 42%, and 55%) on VIV of the rigid segmented shroud cable models is studied first by wind tunnel tests. It reveals that shrouds with porosities of 20% and 35% could reduce the VIV amplitude of the smooth cables by 26% and 46%, respectively. However, shrouds with porosities of 42% and 55% tend to increase the complexity and risk associated with VIV. Vibration measurements on flexible should cable with 20% porosity were conducted for both vertical and inclined models with an inclination of 35° and yaw angles of 0°, 30° and 60°. Shrouds with a porosity of 20% exhibit similar effects on vertical flexible cables as on horizontal rigid cables, in both cases mitigating VIV. The impact on the inclined flexible cables depends on the yaw angle. At the yaw angle of 0°, the shroud effectively mitigates VIV in flexible cables. However, at yaw angles of 30° and 60°, the same porosity level shroud exacerbates the risk of VIV in the inclined flexible cable. This may be due to the enhanced wind velocity along the cable axial direction and decreased penetrating flow rate through the shroud as the wind yaw angle increases. Overall, it was found that a shroud with a porosity of 20%–35% performed the best and was recommended for applications on cables with no inclination and inclined cable at yaw angle β = 0°.

Laser Powder Bed Fusion of Copper-Tungsten Powders Manufactured by Milling or Co-Injection Atomization Process.

The processing of pure copper (Cu) has been a challenge for laser-based additive manufacturing for many years since copper powders have a high reflectivity of up to 83% of electromagnetic radiation at a wavelength of 1070 nm. In this study, Cu particles were coated with sub-micrometer tungsten (W) particles to increase the laser beam absorptivity. The coated powders were processed by powder bed fusion-laser beam for metals (PBF-LB/M) with a conventional laser system of <300 watts laser power and a wavelength of 1070 nm. Two different powder manufacturing routes were developed. The first manufacturing route was gas atomization combined with a milling process by a planetary mill. The second manufacturing method was gas atomization with particle co-injection, where a separate W particle jet was sprayed into the atomized Cu jet. As part of the investigations, an extensive characterization of powder and additively manufactured test specimens was carried out. The specimens of Cu/W powders manufactured by the milling process have shown superior results. The laser absorptivity of the Cu/W powder was increased from 22.5% (pure Cu powder) to up to 71.6% for powders with 3 vol% W. In addition, a relative density of test specimens up to 98.2% (optically) and 95.6% (Archimedes) was reached. Furthermore, thermal conductivity was measured by laser flash analysis (LFA) and thermo-optical measurement (TOM). By using eddy current measurement, the electrical conductivity was analyzed. In comparison to the Cu reference, a thermal conductivity of 88.9% and an electrical conductivity of 85.8% were determined. Moreover, the Vickers hardness was measured. The effect of porosity on conductivity properties and hardness was investigated and showed a linear correlation. Finally, a demonstrator was built in which a wall thickness of down to 200 µm was achieved. This demonstrates that the Cu/W composite can be used for heat exchangers, heat sinks, and coils.

Evaluation of a prototype variable frequency mode soil moisture and EC probe for its final development

AbstractA prototype dielectric probe developed by the Daiki Rika Kogyo Co., Ltd, Japan, was evaluated by controlled laboratory experiments. The probe simultaneously measures the real and imaginary parts of the dielectric permittivity, which are comparable to the measurements obtained with a vector network analyser (VNA) at frequencies ranging from 10 to 160 MHz. The probe accurately (±2% error) measures the real parts of the dielectric permittivity of oil–ethanol and ethanol–water mixtures over a wide range of real permittivities (3.26 ~ 79) at frequencies ranging from 70 to 90 MHz. The imaginary parts of the dielectric permittivity of aqueous solutions are related to the electrical conductivity (EC) through a unique rational model (±2.5% error) over 80–90 MHz. Dielectric measurements by probes at the desired frequencies can eliminate/reduce the limitations of fixed‐frequency measurements, such as the effects of EC, clay composition, porosity, and organic matter, of currently available probes.

Effect of Porosity and Pore Size of a Silicon Target on the Laser Ablation Threshold

Effect of Porosity and Pore Size of a Silicon Target on the Laser Ablation Threshold

A coupled phase-field model for sulfate-induced concrete cracking

The performance of concrete will decrease when subjected to external sulfate corrosion, and numerical models are effective means to analyze the mechanism. Most models cannot efficiently consider the effect between cracks and ionic transport because crack initiation and propagation are ignored. In this paper, a coupled chemical-transport-mechanical phase-field model is developed, in which the phase-field model is applied for the first time to predicate the cracking of sulfate-eroded concrete. The chemical-transport model is established based on the law of conservation of mass and chemical kinetics. The phase-field model equivalents the discrete sharp crack surface into a regularized crack, making it convenient to couple with the chemical-transport model. The crack driving energy in the phase-field model is computed by the expansion strain, which can be obtained from the chemical-transport model. The coupling of crack propagation and ionic transport is achieved by a theoretical equation, which considers both the effects of cracking and porosity. Complex erosion cracks can be automatically tracked by solving the phase-field model. The simulation results of the multi-field coupling model proposed in this paper are in good agreement with the experimental data. More importantly, the spalling phenomenon observed in physical experiments is reproduced, which has not been reported by any other numerical models yet, and new insight into the spalling mechanism is provided.

Constraining the Effect of Climate and Rock Porosity on Weathering Extent in the Volcanic Island of Santa Cruz (Galápagos, Ecuador)

Constraining the Effect of Climate and Rock Porosity on Weathering Extent in the Volcanic Island of Santa Cruz (Galápagos, Ecuador)

A new fractal model for flow-solid-chemical multi-field coupling in underground engineering

The permeation diffusion behavior of chloride ions with seawater is one of the key factors causing damage to reinforced concrete structures due to seawater erosion of steel bars. This study establishes a new mathematical model for chloride ion transport in reinforced concrete structures exposed to seawater. The model captures the effect of chloride ions on underwater tunnel structures effectively and provides a valuable theoretical basis for the maintenance and safety of these structures. The proposed model uniquely incorporates the microscopic pore structure characteristics of concrete and the effects of static water pressure and porosity on chloride ion diffusion. The results show that: (1) the diffusion coefficient of chloride ions first increases rapidly, then remains basically unchanged and gradually decreases; (2) there is a non-linear positive correlation between porosity, static water pressure, and maximum corrosion thickness; and (3) the fractal dimension of pore curvature is opposite to the fractal dimension of pore size and crack length.

Study on performance regulation of electro-mechanical properties 3D printed BaTiO3/HA porous structure composite ceramic

BaTiO3/Ca10(PO4)6(OH)2 composite ceramic is an outstanding representative of piezoelectric biomaterials, with excellent biocompatibility and piezoelectric effect, and has potential applications in the field of bone tissue repair. In this work, vat photopolymerization 3D printing technology was used to fabricate triply periodic minimal surface structure BaTiO3/Ca10(PO4)6(OH)2 composite ceramic bone tissue scaffolds with different pore sizes and porosity, and their mechanical and electrical properties were studied. First, the ceramic slurry configuration process was optimized to obtain a ceramic slurry with high solid content (45 vol%) and excellent rheological properties. Then the effect of sintering temperature on microstructure, relative density, mechanical properties, and electrical properties is discussed. The results show that when sintering at 1300 °C, the BaTiO3/Ca10(PO4)6(OH)2 composite ceramic has the highest relative density (99.18 %), the highest compressive strength (44 MPa), large relative dielectric constant (379–389), and low dielectric loss. The polarization electric field strength of the BaTiO3/Ca10(PO4)6(OH)2 composite ceramic was set to 15 kV/cm through the test of the hysteresis loop. Finally, based on multi-physics coupled finite element simulation, the effects of different porosity and different pore sizes on stress distribution and piezoelectric potential were analyzed, and the relationship between them was explored through experiments. The results show that as the porosity increases and the pore size decreases, the mechanical properties of the scaffold decrease significantly, and its compressive strength ranges between 1.67 and 4.26 MPa; as the porosity increases and the pore size increases, the piezoelectric coefficient (d33) of the scaffold showed a decreasing trend, and its d33 ranged between 2 and 9 pC/N. The mechanical and electrical properties of the scaffold meet the performance requirements of cancellous bone. In summary, this work provides a strategy for the application of customized BaTiO3/Ca10(PO4)6(OH)2 composite ceramic scaffolds in new-generation orthopedic implants.

Investigation of Effects of Porosity and Coarsening on Thermal and Mechanical Properties of Sintered Silver Die Attachment

Investigation of Effects of Porosity and Coarsening on Thermal and Mechanical Properties of Sintered Silver Die Attachment

An Experimental Study on the Thermal Performance of a Heat Sink Filled with Porous Aluminum Skeleton/Paraffin Composite Phase Change Material.

Organic phase change material is an ideal solution to solve the heat dissipation problem of electronic devices. However, its low thermal conductivity limits its application. To solve this problem, a new porous aluminum skeleton/paraffin composite phase change material (AS-PCM) was prepared. The effects of porosity and porous aluminum skeletons on temperature control performance were explored. The experimental results show that the addition of AS significantly improves the thermal conductivity of organic PCM, and the thermal conductivity of AS-PCM is 32.3-59.6 times higher than that of pure paraffin. In addition, the temperature difference in AS-PCM with 75% porosity is 1-2 °C lower than that of AS-PCM with 85%, and 5-8 °C lower than that of AS-PCM with 95% porosity. The skeleton structure has an impact on the temperature control performance. The Mcc porous aluminum skeleton/paraffin composite phase change material (MAS-PCM) yields the best thermal performance compared with the Fcc porous aluminum skeleton/paraffin composite phase change material (FAS-PCM). The temperature control time of the MAS-PCM heat sink is increased by 5.3-50.8% relative to the FAS-PCM heat sink. The research results provide a novel approach for improving the thermal conductivity of PCMs.

An improved method for evaluating fracture density using pulsed neutron capture logging

Fracture density is a critical fracture evaluation parameter for the optimization and production prediction of hydraulic fracturing models. Nonradioactive tracer (NRT) techniques have successfully used a quantitative fracture density method based on neutron-induced gamma rays from formation elements. Furthermore, fracture density can be calculated using the formation capture cross section before and after hydraulic fracturing based on pulsed neutron capture logging. However, the response sensitivity of the macroscopic scattering cross section to the fractures decreases when the fracture density is high due to the neutron self-shielding phenomenon. Therefore, an improved fracture density evaluation method is applied, which combines the macroscopic capture cross section and the neutron self-shielding correction factor. In the new method, the peak area of titanium from the captured gamma spectrum is used to obtain a neutron self-shielding correction factor to improve the sensitivity of fracture density determination. Furthermore, the response of capture cross-section variation to fracture density at various tagged proppant concentrations and formation backgrounds is investigated. The findings indicate that the tagged proppant concentration influences the detection limit of fracture density and the sensitivity of fracture density identification. The accurate calculation range of fracture density using the new method has been extended from 5% to 10% under the condition that the tagged proppant concentration is 0.2%. Meanwhile, whereas water salinity significantly impacts capture cross-section variation, the effects of porosity, lithology, and fluid type on capture cross-section variation are negligible. A simulated fracturing example demonstrates the method’s applicability in various measurement environments. The results show that fracture density and height are consistent with the model settings after correcting for water salinity, and the fracture density calculation error is less than 3%. Therefore, our evaluation method for fracture density corrected for the neutron self-shielding effect improves response sensitivity and fracture density calculation accuracy.

Temperature and porosity effect on Rayleigh velocity in superconducting material

Our work's objective is to study the temperature effect and the porosity on ultrasonic wave velocity (Longitudinal wave velocity (VL), transverse wave velocity (VT), and Rayleigh wave velocity (VR)) of superconductor material type Y123 (or YBa2Cu3O7-x). A new model rational of temperature-porosity depending on ultrasonic wave velocities of surface and volume for an Y123 superconducting material was proposed, with each parameter having a distinct physical meaning. The study allows us to deduct the Rayleigh velocity VR following their evolution as temperature and porosity functions, bringing into focus the modelling of both the reflection coefficient R(θ), By analysing it, we were able to determine the variations of the longitudinal wave velocity and transverse wave velocity of the superconducting material considered as a function of the porosity and the temperature, and attenuating oscillations of the acoustic material signature, V(z) curves. The vibration working frequency of 570 MHz at a sensor, according to the porosity. This quantitative investigation is based on the experimental results obtained on porous and non-porous Y123 superconducting materials in the 5 to 300 K temperature range, This enables the estimated evolution of the Rayleigh velocity, VR, variation on the temperature-porosity depending. Since the model can well predict the ultrasonic wave velocities of porous superconducting materials from extreme low temperature to ultrahigh temperature under different porosity rates. In addition, the models obtained could aid well understand the behavior and performance of porous superconducting materials, and offer a new method to describe the temperature-porosity dependent ultrasonic wave’s velocities of superconducting materials.

Linear stability analysis of the viscoelastic Navier–Stokes–Voigt fluid model through Brinkman porous media: Modal and non-modal approaches

The linear stability analysis of a viscoelastic Navier-Stokes-Voigt fluid flow, or the Kelvin-Voigt fluid of zero order in a Brinkman porous medium, is investigated using both modal and non-modal analysis. The numerical solution is obtained using the Chebyshev collocation method. The combined effects of the medium's porosity, represented by the porous parameter, the fluid viscosity, represented by the ratio of effective viscosity to fluid viscosity, and the fluid elasticity, represented by the Kelvin-Voigt parameter are investigated using both modal and non-modal analysis. The modal analysis describes the long-term behavior of the system, obtained through plotting the eigenspectrum, eigenfunctions, growth rate curves, neutral stability curves, and streamline plots, along with accurate values of critical triplets. In non-modal analysis, the pseudospectrum of the Orr-Sommerfeld operator, transient energy growth curves, and regions of stability, instability, and potential instability are depicted. The results obtained from modal analysis indicate that the porous parameter, Kelvin-Voigt parameter, and the ratio of effective viscosity to fluid viscosity act as stabilizing agents. However, using non-modal analysis, it is observed that while the porous parameter and the ratio of effective viscosity to fluid viscosity act as stabilizing agents, the Kelvin-Voigt parameter acts as a destabilizing agent over shorter periods.

Effect of chemical reaction on MHD Casson natural convection flow over an oscillating plate in porous media using Caputo fractional derivative

Fractional calculus is a branch of mathematics that extends the traditional definitions of calculus to include non-integer exponents. It has been successfully used to model a variety of physical processes, including the coiling of polymers, viscoelasticity, traffic flow, diffusive transport, fluid dynamics, electromagnetic theory, and electrical networks. However, fractional calculus has not yet been widely used to study the physical properties of non-Newtonian fluids flowing over accelerating porous plates. The present research examines the unsteady Casson flow over an infinitely horizontal porous plate, MHD and porosity impacts on fluid velocity are also discussed. The major goal here is to develop analytical outcomes for the tran-sient incompressible MHD Casson flow over an accelerating porous plate. This plate is oscillating in the x-direction and infinitely large in the y-direction and fluids flowing over it at y > 0 due to oscillation. Choosing the right choice of dimensionless variables allows the model's governing equations to become dimensionless. These dimensionless differential equations of the Casson fluid are calculated by applying the Laplace transform method. On velocity, the impacts of different factors are investigated. They are time, porosity parameter, oscillation frequency of plate, magnetic parameter, and Casson fluid parameter. As we rise the Casson flow parameter values, magnetic parameter, and Prandtl number we observe that the velocity drops. In contrast to other factors, the effects of Grashof number, oscillation frequency, fractional parameter, and porosity on the velocity profile are reversed. Using Mathcad software, graphs are sketched for various values of these parameters and are thoroughly described. The fluid properties discovered signif-icant findings and disclosed several characteristics for a range of flow parameters and fractional parameter values. Increasing the values of fractional parameters is shown to improve the characteristics of fluids, and this is beneficial in fitting experimental data related to heating and cooling processes, particularly in electronic equipment.

Design of metal foam baffle to enhance the thermal-hydraulic performance of shell and tube heat exchanger

Solid baffles are widely used in shell and tube heat exchanger (STHX), while the highly increased flow resistance and dead zones remain serious drawbacks in the applications. To address this issue, metal foam baffle is proposed in this study to replace solid baffle. The numerical model with considering the thermal non-equilibrium between fluid and foam baffles was established. Laminar flow is assumed in the foam baffles region and the realizable k-ε turbulence model is assumed in the open region. Effects of porosity, pore density, thickness and number of foam baffle (N) on the performance were examined. Results show the foam baffles always lead to lower pressure drop of STHX compared to the solid baffles. Compared to five 2 mm thick solid baffles, five 6 mm thick metal baffles with the porosity of 0.80, 0.85 and 0.90 results higher outlet temperature at the pore density greater than 80, 120 and 160 PPI, respectively. The metal foam baffle leads to higher outlet water temperature compared with solid baffles at the baffle number N ≤ 7. The foam baffles with optimum pore parameters reduced the pressure drop by 12.9 % and increase the outlet and inlet temperature difference by 31.0 % compared to the solid baffles.

Hydromagnetic Turbulent Flow in Porous Media Over a Stretching Surface in a Rotating System with Heat

This study investigates the combined effects of magnetic fields, buoyancy forces, porosity, rotation, and Joule’s heating on fluid flow and heat transfer dynamics. The analysis is performed using a numerical approach, with the system oriented along three axes: the z-axis aligned with the plate, the y-axis perpendicular to the plate, and the x-axis orthogonal to the y-z plane. An infinite plate extends along the x and z axes, with a uniform transverse magnetic field applied parallel to the y-axis. By employing the finite difference method in MATLAB, we explore how various dimensionless parameters influence temperature and velocity profiles. Our findings reveal that an increase in the local temperature Grashof number enhances primary velocity while reducing secondary velocity near the fixed end. Temperature profiles show a decrease near the plate, increasing further away. The study also highlights that a higher Joule heating parameter leads to elevated primary velocity and temperature profiles but diminishes secondary velocity. Additionally, increasing rotational parameters is observed to decrease both primary and secondary velocities while augmenting temperature profiles near the plate. These results underscore the significant role that magnetic fields, rotational effects, and Joule heating play in modulating fluid flow and thermal behavior. The insights gained from this study can inform the design and optimization of engineering systems where control of velocity and temperature profiles is critical.

Design and development of a stand-off Raman brassboard (SDU-RRS) for the spectroscopic study of planetary materials

Raman spectroscopy has emerged as a crucial mineral analysis technique in planetary surface exploration missions. Nonetheless, the inherently low Raman scattering efficiency of planetary silicate materials makes it challenging to extract enough Raman information. Theoretical and experimental studies of the remote Raman scattering properties of planetary materials are also urgent requirements for future lunar and planetary explorations. Here, Shandong University Remote Raman Spectrometer (SDU-RRS) was developed to demonstrate the feasibility of lunar remote Raman technology and conduct preliminary research on remote Raman scattering properties. SDU-RRS utilizes a pulsed 532 nm laser, a non-focal Cassegrain telescope, a volume phase holographic grating, an intensified charge-coupled device, and the time-gating technique to detect weak-signal silicate minerals. The spectral resolution obtained with atomic emission lamps was <4.91 cm−1, and the wavelength accuracy was <1 cm−1, across the spectral range of 241–2430 cm−1. SDU-RRS can detect natural augite within a feldspar-olivine-augite matrix at a concentration of 20 % at ∼1 m under ambient lighting conditions. A series of experiments were conducted to evaluate the influence of measurement conditions and physical matrix effects on acquired Raman signals, either qualitatively or quantitatively, on geological materials. The study indicates that the transmission of Raman-scattered light conforms to Lambert’s cosine law, and a linear correlation exists between Raman intensity and laser power. The study also evaluated the impact of grain size, surface roughness, porosity, and shadow-hiding effects. Reducing grain size decreases Raman intensity and broadens Raman spectra. These characteristics are essential for achieving definitive mineralogical information from granular materials by remote Raman spectroscopy in lunar and planetary explorations.