Zr1−xNdxSiO4−x/2 (0≤x≤0.1) ceramics were prepared by solid-state reaction method. The effects of Nd content on the phase structure of the ceramics were investigated. The chemical durability of Nd-doped zircon ceramic waste forms was also examined. The results show that the ceramics with x<0.04 show homogeneous single zircon phase, while the samples with x≥0.04 exhibit coexistence of two crystal phases (zircon and Nd2Si2O7). The bulk density of the Nd-doped zircon ceramics increases with the increase in neodymium content. Moreover, the normalized element release rates of Nd element in Nd-doped zircon ceramics firstly decrease with leaching time and almost no change after 14 days (~10−4gm−2d−1), demonstrating its good chemical durability. These results indicate that the obtained zircon ceramics waste forms are promising candidate for immobilization of trivalent actinides.