Effect Of Loading Research Articles

Design and Biomechanical Analysis of Customized Angled Abutment Based on Tooth Inclination Angle for Immediate Implant Placement on Maxillary Anterior Region.

Finite element analysis and an in vitro experiment were employed to investigate the loading effects of angled abutments, comparing various customized angled abutments derived from the average angle of incisors in patients with a commercial 15°∆ angled abutment, on both the implant and surrounding bone. Four customized angled abutment models (21.9°∆, 24.15°∆, 20.22°∆, 33°∆) were developed using cone-beam computed tomography (CBCT) images of incisor inclination from various age groups of patients. 3D maxillary bone models were created from CBCT images of four individual patients. Finite element analysis and in-vitro strain gauge experiments were conducted, applying 100N or 50N of axial or oblique force, to assess the differences in stress/strain between the customized and the commercial 15°∆ angled abutments in both the implants and surrounding bone. Under axial loading, the stress values in the dental implant and surrounding bone were elevated due to the relatively higher angles of the customized angled abutments (21.9°∆, 24.15°∆, 20.22°∆, 33°∆) when compared to the commercial 15°∆ angled abutment; however, under oblique loading the commercial 15°∆angled abutment exhibited higher stress values in both the implant and surrounding bone. For in vitro experiment, there is no statically difference in bone strain between the customized (21.9°∆) and the commercial 15°∆ angled abutments in axial loading. Nevertheless, in oblique loading using a commercial 15°∆ angled abutment induced the higher bone strains. Customized angled abutments offer lower stress/strain under oblique loads but higher stress/strain under axial loads compared to commercial ones. Therefore, in the design and application of angled abutments, careful consideration of the occlusal load direction is paramount for achieving biomechanical success of dental implant.

The behavior of reinforced concrete frames exposed to high temperature under cyclic load effect

Continued use of the structure through minor renovations and repairs without a complete and accurate determination of the extent of damage to the structure and its elements exposed to high temperature effects due to fire, etc. will cause more loss of life and property in the event of an earthquake that may occur later. The aim of this study is to determine the losses on the lateral load and energy damping capacities and stiffness of reinforced concrete frames exposed to 200, 400, 600 and 800 ℃ high temperatures for 60, 120 and 180 min. For this purpose, 13 reinforced concrete frame test elements with the same concrete and steel material properties and dimensions were produced. All reinforced concrete frame test members were brought to the specified target temperature within one hour and exposed to high temperature effects for 60, 120 and 180 min at these target temperatures. The test members then allowed cooling down on their own and when they reached room temperature, they removed from the oven and subjected to cyclic lateral loading tests. The data obtained from the cyclic lateral loading tests processed to obtain lateral load - horizontal displacement, stiffness - horizontal displacement, cumulative energy consumption - horizontal displacement and strength envelope curves for each test element. According to the results of the cyclic lateral loading tests, it was determined that the lateral load carrying capacities of the test members exposed to high temperature for 60, 120 and 180 min decreased by 24 %, 33.33 % and 36 % in push, and by 25.76 %, 37.6 % and 38.72 % in pull, respectively. In addition, the energy consumption of the test elements exposed to high temperature for 60, 120 and 180 min decreased by 30.98 %, 42.41 % and 39.62 %, respectively, compared to the reference test element. The initial stiffness of all test elements exposed to the high temperature effect decreased compared to the initial stiffness of the reference test element not exposed to the high temperature effect. According to these results, the effect of high temperature causes losses in many parameters that are of vital importance in the building elements, but also highly affects the earthquake behavior of the building.

Cyclic loading behavior of concrete with thermally-induced damage

The paper reports a study on concrete specimens that were subjected to constant amplitude, low-strain cyclic (LSC) and high-strain cyclic (HSC) tests to evaluate their cyclic behavior after they had been subjected to either ambient or elevated temperatures. Parameters examined included maximum normal stress, dynamic modulus, and extent of damage observed in specimens. An equation is proposed to help quantify the extent of damage in specimens, which accounts for both thermal and cyclic loading effects. Ultrasonic Pulse Velocity (UPV) measurements were also used to quantify the damage in both the LSC and HSC tests. Results show that losses in compressive strength and dynamic modulus are greater in cases with higher temperature exposures due to thermally induced damages. Also, cyclic characteristics of the specimens were found to be significantly influenced by the strain amplitude used in cyclic loading tests.

Research on the Support Performance of Internal Feedback Hydrostatic Thrust and Journal Bearing Considering Load Effect

This study aims to analyze the impact of uniform and eccentric load conditions on the performance of internal feedback hydrostatic thrust and journal bearing. Two distinct models are established: a three-degrees-of-freedom uniform load model and a five-degrees-of-freedom eccentric load model. The support stiffness, overturning stiffness, and flow rate for both thrust and journal bearings are calculated. Additionally, numerical analysis is conducted to examine the influence of oil film thickness, inlet pressure, and restrictor size on the operational characteristics of the bearings, revealing the interplay between an eccentric load and journal bearing speed. The validity of the theoretical algorithm is verified through finite element simulation. The research outcomes hold significant guiding implications for the design and application of internal feedback hydrostatic bearings.

Foundation Types of Fixed Offshore Wind Turbine

Offshore wind turbines are supported by various foundations, each with its considerations in design and construction. Gravity, monopile, and suction bucket foundations encounter geotechnical issues, while jacket and tripod foundations face fatigue problems. Considering this, a gravity foundation based on a steel skirt was developed, and a monopile foundation was analyzed for Pile-Soil Interaction using the p–y curve and 3D finite element method (3D FEM). In addition, for suction bucket foundations, the effects of lateral and vertical loads were analyzed using 3D FEM and centrifuge tests. Fatigue analysis for jacket and tripod foundations was conducted using a hotspot stress approach. Some hybrid foundations and shape optimization techniques that change the shape to complement the problems of each foundation described above were assessed. Hybrid foundations could increase lateral resistance compared to existing foundations because of the combined appendages, and optimization techniques could reduce costs by maximizing the efficiency of the structure or by reducing costs and weight. This paper presents the characteristics and research directions of the foundation through various studies on the foundation. In addition, the optimal design method is presented by explaining the problems of the foundation and suggesting ways to supplement them.

Centrifuge modelling of end-bearing slender energy pile performance under temperature cycles

Slender energy pile shows a buckling deformation behavior under the coupling effect of temperature cycles and external loads, significantly affecting the long-term serviceability and even leading to the buckling failure. To investigate the thermo-mechanical performance of end-bearing slender energy piles under the long-term effect of temperature cycles, a centrifuge modelling experiment was conducted in this work, in which the temperature distribution, displacement, axial force and bending moment of the energy pile during the long-term temperature cycle were measured. The results unveiled that the axial force of the end-bearing slender pile increases as temperature rises, potentially leading to a displacement neutral point in the lower part of the pile. Meanwhile, there was an embedding effect in the lower part of the slender pile, with a preliminary calculated embedment depth of 36.2 meters. Temperature fluctuations can soften the soil at the pile end over time, diminishing the embedding effect on slender piles, and causing a reverse bending point to emerge at a depth of 45.5 meters. The appearance of bending moments in the pile signaled the horizontal displacement encountered in the pile service life, warning the bearing capacity loss problem from changes in pile deflection.

Revealing the Effect of Typhoons on the Stability of Residual Soil Slope by Wind Tunnel Test

Typhoon-induced slope failure is one of the most important geological hazards in coastal areas. However, the specific influence of typhoons on the stability of residual soil slopes still remains an open issue. In this study, the Feiyunjiang catchment in Zhejiang Province of SE China was chosen as the study area, and a downscaling physical model of residual soil slopes in the region was used to carry out the wind tunnel test. Our aim was to answer the question, How does the vegetation on the slope and slope stability respond during a typhoon event? For this purpose, multiple aspects were monitored and observed under four different wind speeds (8.3 m/s, 10.3 m/s, 13.3 m/s, and 17 m/s), including vegetation damage on the slope, macrocracks on the slope surface, wind pressure, wind load, permeability coefficient of the soil layer, and slope stability. The results showed that the plants on the slope could restore to their original states when the wind speeds ranged from 8.3 m/s to 13.3 m/s, but were damaged to the point of toppling when the wind speed increased to 17 m/s. Meanwhile, evident cracks were observed on the ground under this condition, which caused a sharp increase in the soil permeability coefficient, from 1.06 × 10−5 m/s to 6.06 × 10−4 m/s. The monitored wind pressures were larger at the canopy than that at the trunk for most of the trees, and generally larger at the crown of the slope compared with the toe of the slope. Regarding the wind load to the slope ground, the total value increased significantly, from 35.4 N under a wind speed of 8.3 m/s to 166.5 N under a wind speed of 17 m/s. However, the wind load presented different vector directions at different sections of the slope. The quantitative assessment of slope stability considering the wind load effect revealed that the safety factor decreased by 0.123 and 0.1 under the natural state and saturated state, respectively, from no wind to a 17 m/s strong wind. Overall, the present results explained the mechanism of slope failure during typhoon events, which provided theoretical reference for revealing the characteristics of residual soil slope stability under typhoon conditions.

Graphene/graphene oxide and melamine as synergistic additives for polyester nanocomposite coatings

Ensuring mechanical robustness is crucial for polyester coatings on pre-coated metal (PCM). The incorporation of nanofillers such as graphene nanoplatelets (GNP) and graphene oxide (GO) has demonstrated potential in enhancing mechanical properties of polymeric nanocomposites. However, the utilisation of these nanofillers in saturated polyester systems remains largely unexplored. Therefore, this study developed polyester-based nanocomposite coatings incorporating GNP or GO and systematically investigated the effects of the nanofiller loading and the hexa (methoxymethyl)melamine (HMMM)/polyester ratio on the properties of the coatings. Adding nanofillers led to the reduction of both glass transition temperature (Tg) and hardness (H) of the coating. Specifically, at a 1:5 HMMM/polyester ratio, Tg reduced from 29.9 °C for plain polyester (Blank) to 26.1 °C and 22.0 °C for polyesters with 5 wt% GNP (A-5.0GNP) and GO (A-5.0GO) respectively; H values also decreased from 274 MPa for Blank polyester to 222 MPa and 143 MPa for A-5.0GNP and A-5.0GO, respectively. The hydroxyl groups on the nanofillers affected crosslinking between HMMM and polyester by reacting with HMMM, thereby reducing the crosslink density of the cured coatings. Increasing nanofiller loading led to a more significant reduction in crosslink density, resulting in decreased Tg and H values. At the same loading level, the significantly higher hydroxyl content of GO had a more pronounced effect in reducing crosslink density compared to GNP. Furthermore, an increase in HMMM compensated for the HMMM loss to GO and facilitated the polyester crosslinking reactions, leading to significant increase in both Tg and H. Specifically, for the 2 wt% GO nanocomposites, Tg increased significantly from 24.7 °C to 32.1 °C with a rise in the HMMM/polyester ratio from 1:5 to 1:2, while the H value increased notably from 193 MPa to 452 MPa.

Analyzing the Seasonal Vertical Displacement Fluctuations Using the Global Navigation Satellite System and Hydrological Load: A Case Study of the Western Yunnan Region

The non-tectonic deformation caused by hydrological loads is an important influencing factor in GNSS vertical displacement. Limited by the temporal and spatial resolution of global models and model errors, the hydrological load results calculated by traditional methods are difficult to meet the high temporal and spatial resolution requirements of small to medium-scale regions. This paper introduces the idea of the remove–restore method, assimilates regional high-resolution hydrological data, and obtains higher temporal and spatial-resolution hydrological load results. Subsequently, utilizing data from 12 CORS observed in the western Yunnan region between January 2018 and December 2020, the quantitative relationship and variation characteristics between GNSS vertical displacement and hydrological load displacement were analyzed in detail. Furthermore, the annual signals of both were extracted using the SSA method for comparative analysis. After removing the effects of atmospheric load and non-tidal ocean load, the average correlation coefficient between GNSS vertical displacement and hydrological load displacement is 0.84, with an average reduction of WRMS (%) reaching 37.17%. The average correlation coefficient of the annual signals between GNSS vertical displacement and hydrological load deformation is 0.94, with an average reduction of WRMS (%) reaching 46.5%, indicating that the contribution of hydrological load to the GNSS non-tectonic vertical displacement annual signal is close to 50%. The research results provide scientific support and important references for studying surface tectonic deformation by removing non-tectonic deformations such as hydrological loads from GNSS vertical displacement. Additionally, it helps to explore the mechanisms of interaction between water storage migration and surface deformation.

Biodegradable maleic–itaconic polymer‐coated phosphatic fertilizer improved phosphorous recovery in calcareous soil

AbstractBackgroundThe poor nutrient recovery of phosphatic (P) fertilizers in calcareous soils is a serious worldwide problem resulting in sub‐optimal P use efficiency. This is mainly attributed to P fixation with calcium (Ca) and magnesium (Mg) ions in the soil solution. As a result, most of the applied P (in the form of fertilizer) becomes insoluble or immobilized in soil due to complex edaphic processes, making it unavailable to plants. Polymer‐coated fertilizers are relatively new approaches to minimizing P‐fixation. However, concerns have been recently raised on the environmental effects of synthetic polymers and microplastic loads in agroecosystems.AimHere we developed and investigated the effectiveness of biodegradable polymer‐coating on commercial diammonium phosphate (DAP) fertilizer to improve P availability in the soil, hence making P more accessible for plant uptake.MethodsThe polymers were coated on DAP fertilizer granules, and two products based on increasing polymer concentration (namely, C‐1 and C‐2, respectively) were achieved. The coated and uncoated DAP granules were characterized for surface properties to confirm the appropriate coating of polymers using scanning electron microscopy (SEM) and crushing strength by a universal telson machine. The biodegradable polymer‐coated C‐1 and C‐2 fertilizers were tested for P availability compared to commercial DAP using spinach as a test plant.ResultsThe SEM micrographs indicated a uniform coating of biodegradable polymers on DAP granules. Application of C‐1 increased the plant's fresh and dry biomass (+10.71% and +18.09%) over commercial DAP, respectively. The C‐1 application increased the N, P, and K uptake by +24.9%, +66.7%, and +11% over commercial DAP. In contrast, C‐2 produced less biomass than C‐1 due to relatively less nutrient uptake and different concentrations of ingredients in C‐2.ConclusionTogether, our results showed that the novel biodegradable polymer approach has demonstrated the potential to improve P recovery and agronomic yield in alkaline soils.

The effect of filler loading, biological treatment, and bioplastic blend ratio on flexural and impact properties of blended bioplastic reinforced with spent coffee ground

AbstractIn this study, the mechanical and morphological characteristics of poly(hydroxyalkanoate) (PHA)/poly(lactic acid) (PLA) blend matrix reinforced with spent coffee ground (SCG) were investigated across various weight ratios (100/0, 75/25, 50/50, 25/75, and 0/100) and SCG contents (10–40 wt%). SEM micrographs revealed a phase‐separated structure with cracks on the fracture surface, consistent with the lower flexural properties of biocomposites. The incorporation of SCG reduced mechanical properties, mainly due to its incompatibility with the PHA/PLA matrix. Biocomposites with high SCG content demonstrated lower energy absorption capabilities, likely due to SCG aggregates acting as stress concentrators and disrupting load‐transferring mechanisms. Moreover, increasing PHA content in the blends led to higher PLA crystallinity, as PHA acted as a nucleating agent for PLA. For biological treatment, biocomposites with PHA/PLA ratio (50/50) and SCG loading (20 wt%) were employed. The microscopic analysis highlighted well‐dispersed treated SCG within the matrix and improved interfacial contact. Biocomposites with treated SCG demonstrated remarkable enhancements of 52% and 113% in flexural strength and modulus, respectively. These findings proved the effectiveness of sustainable fungal treatment in enhancing interfacial adhesion and improving the mechanical performance of biocomposites.Highlights Percentage of SCG in bioplastic blend as a significant effect on the flexural properties and impact strength. The ratio of the bioplastic blend has the strong influence on the flexural properties and impact properties. Biological treatment of SCG has improved the interfacial interaction between SCG and bioplastic blend. The treated SCG has rougher surface which facilitates the interfacial locking between bioplastic blend and treated SCG. The biological treatment of SCG has improved the mechanical properties of the composites.

Geometrically nonlinear vibration of toroidal sandwich shells with auxetic honeycomb core under periodic/impulsive pressure

The main objective of this paper is to evaluate the dynamic behaviour of sandwich toroidal shells composed of a core with negative Poisson ratio (auxetic honeycomb material) and nanocomposite enriched coating layers under impulsive/periodic pressures considering the geometrical nonlinearity. The set of nonlinear equilibrium equations based on the first-order shear deformation theory are and the resultant nonlinear differential motion equations are approximately solved by the Galerkin method and 4th-order Runge–Kutta solution, respectively. The achieved responses show that the amplitude of outward deformations is intensively increased when the proposed sandwich shells are subjected to rectangular periodic and impulsive loadings which shows the destructive effects of this type dynamic loading. The performed parametric studies shows that these destructive effects can be controlled by changing the geometrical properties of the honeycomb cells and the volume fractions of the nanocomposites in the coating layers. It is notable that in the previous studies the nonlinear dynamic response of toroidal shells subjected to various periodic and impulsive pressures was not investigated. However, in the present work, the mentioned dynamic responses were achieved and investigated without spending time-consuming computational. In fact, the novelty of this work is to develop such a robust and efficient tool.

In vitro development of a muscle-tendon junction construct using decellularised extracellular matrix: Effect of cyclic tensile loading

The muscle tendon junction (MTJ) plays a crucial role in transmitting the force generated by muscles to the tendon and then to the bone. Injuries such as tears and strains frequently happen at the MTJ, where the regenerative process is limited due to poor vascularization and the complex structure of the tissue. Current solutions for a complete tear at the MTJ have not been successful and therefore, the development of a tissue-engineered MTJ may provide a more effective treatment. In this study, decellularised extracellular matrix (DECM) derived from sheep MTJ was used to provide a scaffold for the MTJ with the relevant mechanical properties and differentiation cues such as the relase of growth factors. Human mesenchymal stem cells (MSCs) were seeded on DECM and 10 % cyclic strain was applied using a bioreactor. MSCs cultured on DECM showed significantly higher gene and protein expression of MTJ markers such as collagen 22, paxillin and talin, than MSCs in 2D culture. Although collagen 22 protein expression was higher in the cells with strain than without strain, reduced gene expression of other MTJ markers was observed when the strain was applied. DECM combined with 10 % strain enhanced myogenic differentiation, while tenogenic differentiation was reduced when compared to static cultures of MSCs on DECM. For the first time, these results showed that DECM derived from the MTJ can induce MTJ marker gene and protein expression by MSCs, however, the effect of strain on the MTJ development in DECM culture needs further investigation.

Spectrotemporal cortical dynamics and semantic control during sentence completion

ObjectiveTo investigate cortical oscillations during a sentence completion task (SC) using magnetoencephalography (MEG), focusing on the semantic control network (SCN), its leftward asymmetry, and the effects of semantic control load. MethodsTwenty right-handed adults underwent MEG while performing SC, consisting of low cloze (LC: multiple responses) and high cloze (HC: single response) stimuli. Spectrotemporal power modulations as event-related synchronizations (ERS) and desynchronizations (ERD) were analyzed: first, at the whole-brain level; second, in key SCN regions, posterior middle/inferior temporal gyri (pMTG/ITG) and inferior frontal gyri (IFG), under different semantic control loads. ResultsThree cortical response patterns emerged: early (0–200 ms) theta-band occipital ERS; intermediate (200–700 ms) semantic network alpha/beta-band ERD; late (700–3000 ms) dorsal language stream alpha/beta/gamma-band ERD. Under high semantic control load (LC), pMTG/ITG showed prolonged left-sided engagement (ERD) and right-sided inhibition (ERS). Left IFG exhibited heightened late (2500–2550 ms) beta-band ERD with increased semantic control load (LC vs. HC). ConclusionsSC involves distinct cortical responses and depends on the left IFG and asymmetric engagement of the pMTG/ITG for semantic control. SignificanceFuture use of SC in neuromagnetic preoperative language mapping and for understanding the pathophysiology of language disorders in neurological conditions.

Numerical Investigation on the Structural Behavior of a Short-Span Cable-Stayed Bridge with Steel and CFRP Hybrid Cables.

In this paper, a thorough investigation is presented on the static and dynamic behaviors of a short-span cable-stayed bridge (CSB) incorporating steel and carbon fiber reinforced polymer (CFRP) hybrid cables. The study focuses on the world's largest span and China's first highway, CFRP CSB. The performance of the CSB was compared using numerical simulations under four different cable patterns: steel cables, CFRP cables, and steel, and two types of hybrid cables with different structural arrangements. The results indicate that the use of the use of CFRP cables in the long cable region in the short-span CSB project investigated in this study offers improved performance in terms of stability, seismic response, and reduced displacements. In comparison to CFRP cables, hybrid cables have demonstrated a reduction of 12% in the maximum vertical displacement of the main girder. On the other hand, the hybrid cables result in reduced maximum internal forces and longitudinal and lateral displacements of the main girders and towers compared to steel cables. The difference in the arrangement of CFRP cables in the long cable region or short cable region is not obvious under dead loads, but significant differences still exist between the CFRP cable bridges in the short cable region and the long cable region in terms of live load effects, temperature effects, and dynamic characteristics.

Effect of alumina fillers on physical and mechanical properties of luffa/groundnut shell natural fiber reinforced polymer composites

AbstractThis study aims to investigate the physical and mechanical properties of epoxy composites reinforced with hybrid luffa waste and groundnut shell waste natural fibers and to evaluate the effect of different filler loadings of alumina on the mechanical behavior of the hybrid composites. The luffa fibers were made to undergo mercerization in 10% NaOH solution. All the treated fibers and the alumina fillers were characterized using X‐ray diffraction analysis (XRD). The study used three different filler loadings of alumina (Al2O3) (5%, 10%, and 15% by volume) and three different fractions of treated luffa‐waste groundnut shell hybrid fibers (10%, 30%, and 50% by volume). The composites were fabricated using the hand layup technique, and the prepared test specimens were subjected to mechanical and physical properties testing as per ASTM standards. The experimental findings indicated that the inclusion of Al2O3 filler improved the physical and mechanical characteristics of the natural fiber‐reinforced hybrid composites. The results showed that the composites with 30 vol. % fibers (1:1 luffa fiber: groundnut shell fiber) and 10 vol. % Al2O3 content showed enhanced tensile, flexural, shear, and impact strength and hardness. Besides, a good synergy between the alumina fillers, natural fibers, and the polymer matrix was observed in the surface morphology of the composite specimen. The developed composites can be used in low and medium‐load‐bearing structural and non‐structural applications.Highlights Development of hybrid polymer composites with luffa and novel groundnut shell fibers Hybridization of alumina ceramic particles with natural fiber hybrid composites Assessment of physical and mechanical properties of the polymer composites

Aviation fuel hydrocarbons from camphorwood and low-density polyethylene: Cascade catalytic approach with CaO and Zn/HBeta

In this study, the co-pyrolysis of camphorwood and low-density polyethylene employing a cascade catalyst system consisting of CaO and Zn-modified HBeta in a fixed-bed reactor was investigated for the production of aviation fuel hydrocarbons (C8–C16). The effect of Zn loading on HBeta, CaO to Zn/HBeta mass ratio, and the feedstock to catalyst mass ratio on both oil yield and composition was investigated. Results revealed that loading Zn onto HBeta led to ZnO cluster and oxygen-bridged Zn dimers ([ZnOZn]2+) formation, which affects HBeta's acid properties and aromatization capacity. The 10 wt%Zn/HBeta catalyst with more ZnO content exhibited weak acid sites, and moderate aromatization capacity, increasing oil yield from 32.06 to 44.25 wt% compared to 3 wt%Zn/HBeta and favoring presence of straight-chain components in oil products. CaO also enhanced straight-chain alkane formation. The highest oil yield, reaching 48.44 wt%, was obtained when CaO and 10 wt%Zn/HBeta cascade by a 1:1 mass ratio was adopted, producing oil with aviation fuel with a maximum yield of 18.45 wt%, and selectivity of 38.09 area%, of which 26.54 area% being aromatics and 11.55 area% being alkanes. Furthermore, the feedstock-to-catalyst ratio influenced the products significantly, with lower feedstock-to-catalyst ratio enhanced aromatization and the ratio of 2:1 recommended. Therefore, this cascade catalytic approach, which combines cost-effective CaO and 10 wt%Zn/HBeta catalysts shows significant potential for enhancing bio-aviation fuel production from solid wastes. Moreover, it provides a viable and promising solution for addressing concerns related to low oil yield and excessive aromatization.

Structural, Optical and Dielectric Properties of Some Nanocomposites Derived from Copper Oxide Nanoparticles Embedded in Poly(vinylpyrrolidone) Matrix.

Polymer nanocomposite films based on poly(vinyl pyrrolidone) incorporated with different amounts of copper oxide (CuO) nanoparticles were prepared by the solution casting technique. The PVP/CuO nanocomposites were analyzed by X-ray diffractometry (XRD), scanning electron microscopy, UV-Visible absorption spectroscopy and dielectric spectroscopy. The XRD analysis showed that the monoclinic structure of cupric oxide was maintained in the PVP host matrix. The key optical parameters, such as optical energy gap Eg, Urbach energy EU, absorption coefficient and refractive index, were estimated based on the UV-Vis data. The optical characteristics of the nanocomposite films revealed that their transmittance and absorption were influenced by the addition of CuO nanoparticles in the PVP matrix. Incorporation of CuO nanoparticles into the PVP matrix led to a significant decrease in band gap energy and an increase in the refractive index. The dielectric and electrical behaviors of the PVP/CuO nanocomposites were analyzed over a frequency range between 10 Hz and 1 MHz. The effect of CuO loading on the dielectric parameters (dielectric constant and dielectric loss) of the metal oxide nanocomposites was also discussed.

ISSLS prize in clinical/bioengineering science 2024: How standing and supine positions influence nutrient transport in human lumbar discs?-A serial post-contrast MRI study evaluating interplay between convection and diffusion.

The intervertebral disc being avascular depends on diffusion and load-based convection for essential nutrient supply and waste removal. There are no reliable methods to simultaneously investigate them in humans under natural loads. For the first time, present study aims to investigate this by strategically employing positional MRI and post-contrast studies in three physiological positions: supine, standing and post-standing recovery. A total of 100 healthy intervertebral discs from 20 volunteers were subjected to a serial post-contrast MR study after injecting 0.3mmol/kg gadodiamide and T1-weighted MR images were obtained at 0, 2, 6, 12 and 24h. At each time interval, images were obtained in three positions, i.e. supine, standing and post-standing recovery supine. The signal intensity values at endplate zone and nucleus pulposus were measured. Enhancement percentages were calculated and analysed comparing three positions. During unloaded supine position, there was slow gradual increase in enhancement reaching peak at 6h. When the subjects assumed standing position, there was immediate loss of enhancement at nucleus pulposus which resulted in reciprocal increase in enhancement at endplate zone (washout phenomenon). Interestingly, when subjects assumed the post-standing recovery position, the nucleus pulposus regained the enhancement and endplate zone showed reciprocal loss (pumping-in phenomenon). For the first time, present study documented acute effects of physiological loading and unloading on nutrition of human discs in vivo. While during rest, solutes diffused gradually into disc, the diurnal short loading and unloading redistribute small solutes by convection. Standing caused rapid solute depletion but promptly regained by assuming resting supine position.

Effects of compressive cyclic loading on the fatigue properties of oil-well cement slurries serving in deep downhole environments

With the increasing demand for energy from deep oil and gas reservoirs, oil-well cement slurries are subjected to complex compressive cyclic loading in high-temperature and high-pressure (HTHP) environments. Currently, no standard to guide the evaluation of the fatigue performance of cement slurries under cyclic loading or a systematic investigation to help understand it exists. To fill this gap, this study used a set of innovative HTHP curing and testing devices to mimic the actual operating conditions of deep wells. Cement slurries were cast, cured, and subjected to quasi-static and cyclic loading tests at four downhole temperatures (25, 90, 115, and 140 °C). In the cyclic-loading tests, three loading levels (30%, 50%, and 70%) under 20 MPa confining pressure were applied to study the fatigue performance, and nuclear magnetic resonance (NMR) was employed to identify internal microcrack damage. When the downhole temperature increased from 25 to 140 °C and the cyclic loading level increased from 30% to 70%, the accumulated plastic strain of samples increased by 13.8 times. A large increase in the plastic strain of oil-well cement slurries can significantly reduce the fatigue resistance and service life of oil and gas wells. Based on this research, the authors propose the addition of compressive cyclic loading tests (particularly under HTHP testing conditions) to the current oil-well cement slurry testing standards, which will be very significant for the fatigue performance evaluation of cement slurries used in HTHP environments in deep wells.