Effect Of Freeze-thaw Process Research Articles

Water storage effect of soil freeze-thaw process and its impacts on soil hydro-thermal regime variations

In the soil freeze/thaw phenomenon, the soil water phase and energy budget change, which can affect the soil-vegetation-atmosphere system. Herein, the basic role of freeze–thaw–process (FTP) in soil water and heat transport and its impact on soil moisture and temperature variation were investigated using the observations and numerical experiments with and without FTP in Community Land Model version 4.5 (CLM4.5) on the Tibetan Plateau (TP). The results averaged over the whole TP revealed that no soil FTP (i.e., no water phase change occurred) resulted in lower surface soil temperature by about -1.02 ℃ in freeze-thaw (FT) period, while surface soil temperature is higher by about 0.91 ℃ and surface soil moisture is drier by about -0.02 mm3/mm3 in after-thaw (AT) period. Soil FTP has a water storage effect, the storage index (SI) can reach 0.95 at surface layer. Without soil FTP, the surface soil water content at the AT period can be reduced by ∼10% (SI is decreased by about -0.05) as a result of enhanced evaporation; the soil moisture memory was shortened by about -20 days in March. Accordingly, surface latent heat decreased by -1.07 W/m2, while the surface sensible heat increased by 4.72 W/m2. The effects of FTP on soil water and heat transport at deep layer are distinguished from that at the surface layer. These imply that the biases of soil temperature and moisture simulation in models during FT period could lead to large uncertainties in estimating climate effects of TP. Under climate warming background in recent decades, with the delaying of soil freeze-beginning date and advancing of soil thaw-end date, changes of soil FTP regime would lead to loss of spring soil moisture.

Effect of freeze-thaw process on partitioning of contaminants in ferric precipitate

The primary interest of this work was to determine the processing conditions which will provide the most water removal from the precipitate after freezing and thawing. The work examined the effect of variables such as freezing time, freezing temperature, and pre-treatment steps, e.g. agitation or concentration, on the freeze thaw process of ferric precipitates. The extent of dewatering of freeze thawed samples was not significantly affected by freezing rate or curing time, provided the floc was completely frozen. However, a pre-concentration step was found to produce a more concentrated residual. The relatively low degree of structure within the ferric flocs makes them particularly suitable for freeze-thaw conditioning. Only a slight increase in leach out of contaminant from the floc was observed. Thus, the experiments indicate that this is a very simple and effective method of dewatering precipitates, which does not require the use of additional additives.