Edge Effects Research Articles

Removing 65 Years of Approximation in Rotating Ring Disk Electrode Theory with Physics-Informed Neural Networks.

The rotating Ring Disk Electrode (RRDE), since its introduction in 1959 by Frumkin and Nekrasov, has become indispensable with diverse applications in electrochemistry, catalysis, and material science. The collection efficiency () is an important parameter extracted from the ring and disk currents of the RRDE, providing valuable information about reaction mechanism, kinetics, and pathways. The theoretical prediction of is a challenging task: requiring solution of the complete convective diffusion mass transport equation with complex velocity profiles. Previous efforts, including by Albery and Bruckenstein who developed the most widely used analytical equations, heavily relied on approximations by removing radial diffusion and using approximate velocity profiles. 65 years after the introduction of RRDE, we employ a physics-informed neural network to solve the complete convective diffusion mass transport equation, to reveal the formerly neglected edge effects and velocity corrections on , and to provide a guideline where conventional approximation is applicable.

What makes a habitat a home? Habitat associations of juvenile European sea bass, Dicentrarchus labrax, in estuarine nurseries.

Selection of nursery habitats by marine fish, such as European sea bass (Dicentrarchus labrax), is poorly understood. Identifying and protecting the full range of juvenile nursery habitats is vital to supporting resilient fish populations and economically important fisheries. We examined how the condition, stomach fullness, and diet of juvenile European sea bass, along with their abundance, differ at high or low tide between the following estuarine habitats: saltmarsh, oyster reefs, shingle, sand, and mud edge habitats. Using a combination of fyke and seine netting we found no difference in sea bass abundance or condition across high-tide habitats, suggesting that rather than differentially selecting between them, juvenile sea bass use all available shallow habitats at high tide. Stomach fullness was significantly higher on saltmarsh and sand compared to mud, and thus these habitats may support better foraging. Dietary DNA metabarcoding revealed that sand and saltmarsh diets mostly comprised Hediste polychaetes, whereas zooplanktonic taxa dominated diets over mud. At low tide, sea bass abundance was highest in shingle and oyster reefs, where stomach fullness and condition were lowest. This may indicate a potential trade-off between using habitats for foraging and refuge. Although sea bass abundance alone does not capture productivity, the high abundance across all estuarine habitats at high tide suggests that it is important to consider the protection of a mosaic of interconnected habitats to support nursery functions rather than focus on individual habitat types.

3D analytical magnetic model calculation for Halbach PM induction heater planar topology

In this work, a 3D analytical magnetic model based on hybridation of the sub-domain’s method and the image’s theory to compute magnetic field and translational motion eddy current in the conducting plate of the Halbach permanent magnet induction heater planar topology is developed. The main objective is to remedy the problem of the transverse edge effect, and hence improving the efficiency of analytical model and the accuracy of results. The developed model also allows fast and precise simulations of 3D magnetic phenomena, and presents an important reduction in computation time compared to 3D finite element simulations.

Time-dependent Kohn-Sham electron dynamics coupled with nonequilibrium plasmonic response via atomistic electromagnetic model.

Computational modeling of plasmon-mediated molecular photophysical and photochemical behaviors can help us better understand and tune the bound molecular properties and reactivity and make better decisions to design and control nanostructures. However, computational investigations of coupled plasmon-molecule systems are challenging due to the lack of accurate and efficient protocols to simulate these systems. Here, we present a hybrid scheme by combining the real-time time-dependent density functional theory (RT-TDDFT) approach with the time-domain frequency dependent fluctuating charge (TD-ωFQ) model. At first, we transform ωFQ in the frequency-domain, an atomistic electromagnetic model for the plasmonic response of plasmonic metal nanoparticles (PMNPs), into the time-domain and derive its equation-of-motion formulation. The TD-ωFQ introduces the nonequilibrium plasmonic response of PMNPs and atomistic interactions to the electronic excitation of the quantum mechanical (QM) region. Then, we combine TD-ωFQ with RT-TDDFT. The derived RT-TDDFT/TD-ωFQ scheme allows us to effectively simulate the plasmon-mediated "real-time" electronic dynamics and even the coupled electron-nuclear dynamics by combining them with the nuclear dynamics approaches. As a first application of the RT-TDDFT/TD-ωFQ method, we study the nonradiative decay rate and plasmon-enhanced absorption spectra of two small molecules in the proximity of sodium MNPs. Thanks to the atomistic nature of the ωFQ model, the edge effect of MNP on absorption enhancement has also been investigated and unveiled.

Hanning FIR window filtering analysis for EEG signals

The window function is a mathematical function in signal processing that is multiplied by a signal to lessen or eliminate the impact of undesired characteristics such as spectral leakage and edge effects that might arise while analyzing finite-duration signals. The Hanning window is just one of several window functionalities available. It is designed to gradually taper the endpoints of a signal to zero, reducing spectral leakage in the frequency domain. Filtering is commonly employed in Electroencephalography (EEG) signal processing to remove noise, artifacts, or undesired frequency components while retaining the desired information. Filtering techniques include band pass, low pass, and high pass and band reject filtering. Hanning window technique using low pass, high pass, band pass, and band reject is used for filtering of EEG signal. The response time analysis for the Hanning window is calculated using low, high, band pass, and band-reject filters for different types of EEG waves alpha, beta gamma, theta, and delta using the signal processing simulation tool MATLAB 2023. The response time for delta wave using a low pass filter has a low response time of 14.125 sec which is comparatively less than another filter. For theta wave high pass filter has a low response time of 11.965 seconds. For alpha wave low pass filter has a low response time of 16.706 seconds whereas for beta wave low pass filter has a low response time of 15.202 seconds. For gamma waves high pass filter has a low response time of 11.349 seconds. Hanning band-reject filter has proven low response time for delta, theta, and gamma waveforms of 16.475 seconds, 16.182 seconds, and 17.743 seconds respectively. The novelty of the work is that the Hanning window improves frequency resolution by balancing the main lobe width with side lobe attenuation Hanning band-reject filter is suited best to figure out the widest main-lobe peak and highest peak for different EEG waveforms.

Effect of airfoil trailing edge up on the performance of gas-liquid multiphase pumps

Abstract In this study, the impact of blade trailing edge structure on the performance of multiphase pumps was investigated. The modification parameters of the impeller blade airfoil were characterized by defining and adjusting the chord length ratio l/l 0 and deflection k, based on the design methodology employed for wing flap lifting devices. The impeller blade airfoil was modified using the trailing edge up design approach. Comparative analysis was conducted to evaluate the effectiveness of elevating the trailing edge of the airfoil in improving flow channel blockage, reducing turbulent energy at the impeller outlet, minimizing energy dissipation, and ultimately enhancing the efficiency of multiphase pumps. Remarkably, a maximum efficiency improvement of up to 3.04% was observed when the inlet gas content reached 70%.

A full wave solver integrated with a Fokker–Planck code for optimizing ion heating with ICRF waves for the ITER deuterium–tritium plasma

Efficient ion heating is crucial for future fusion devices, and the only way to heat ions directly is ion cyclotron resonance heating. Reported here is a full wave solver integrated with a Fokker–Planck code for optimizing ion heating with ion cyclotron range of frequency waves for the International Thermonuclear Experimental Reactor deuterium–tritium plasma. Both the direct absorption of minority ions and the power transfer to bulk ions via collisions are considered, while also accounting for the edge effects on ion absorption near the core. The simulation results show that the appropriate scrape-off layer density profile and parallel wave number lead to enhanced edge coupling and broaden the absorption region with moderate absorption intensity of the minority ions, which is very important for ion heating. More power from the heated ions is transferred to bulk ions than to electrons through collisions in our simulation via optimization, and reducing the total RF power results in a significant increase of the absorbed fraction of bulk ions.

Simple, and highly efficient edge-effect surface acoustic wave atomizer

Conventional surface acoustic wave (SAW) atomizers require a direct water supply on the surface, which can be complex and cumbersome. This paper presents a novel SAW atomizer that uses lateral acoustic wetting to achieve atomization without a direct water supply. The device works by simply pressing a piece of wetted paper strip against the bottom of an excited piezoelectric transducer. The liquid then flows along the side to the unmodified surface edge, where it is atomized into a well-converging mist in a stable and sustainable manner. We identified this phenomenon as the edge effect, using numerical simulation results of surface displacement mode. The feasibility of the prototype design was demonstrated by observing and investigating the integrated process of liquid extraction, transport, and atomization. We further explored the hydrodynamic principles of the change and breakup in liquid film geometry under different input powers. Experiments demonstrate that our atomizer is capable of generating high-quality fine liquid particles stably and rapidly even at very high input power. Compared to conventional SAW atomizer, the dispersion of mist width can be scaled down by 70%, while the atomization rate can be increased by 37.5%. Combined with the advantages of easy installation and robustness, the edge effect-based atomizer offers an attractive alternative to current counterparts for applications requiring high efficiency and miniaturization, such as simultaneous synthesis and encapsulation of nanoparticles, pulmonary drug delivery and portable inhalation therapy.

Analysis Of The Edge Effect On Bird And Primate Distribution In The Ecological Corridor Habitat Of Mount Halimun Salak National Park (TNGHS)

This study aims to analyze the threat of edge effects on endemic animal populations due to the presence of causeways in the TNGHS corridor habitat. Indicators of the occurrence of edge effects are characterized by the further distance of wildlife populations from sources of disturbance such as noise, light, and frequency of human activity mechanisms. Belt transect research method for population study and distribution of Javan Gibbon and Surili. Intensive Point Account (IPA) to measure the diversity index of bird species and Javan eagles. Encounter Rate is used for animal distribution studies. Results On the observation transect made along 3 km, the population density of Javan Gibbons was obtained 0.114 ind/ha, Surili 0.024 indv/ha, and Monkey 0.028 indv/ha. Bird species diversity index in 3 habitat patches each Purasari H'= 2.78 with 38 species; Garehong with 27 species, and Corridor H'= 3,087 with 27 species. The similarity of species is that there are only 7 species of birds found in the 3 habitats of the patch. As a result of primate population density and burng species similarity, it can be concluded that the cross-corridor access road area has experienced an edge effect and tends to be a bottle-neck area for the distribution of animals, especially primates.

Strategy for Ensuring the Metrological Traceability of Nanoparticle Size Measurements by SEM.

The concept of measurement traceability is crucial for ensuring the data reliability and the comparability of measurement results provided by different instruments and operators. In the field of nanoparticle metrology, determining the size of nanoparticles using electron microscopy-based techniques remains a real challenge. In laboratory settings, the establishment of traceability regarding the instrument calibration procedures, the assessment of uncertainties associated with instruments/operators/samples/environments, as well as the complexities related to electron-sample interactions, are often neglected. In this article, we describe the calibration procedure set up at the LNE (Laboratoire National de métrologie et d'Essais) and propose an evaluation method for determining the uncertainties in measuring nanoparticle size by SEM (Scanning Electron Microscopy). This study investigates the impact of the energy of the primary electrons (PEs) generated by the electron beam and accelerating voltage on the reliability of size measurements. The convolution between the signals coming from a nanoparticle and the substrate on which the particle is deposited induces edge effects that can have a negative impact on the measurement results. Finally, a diagram describing the various stages involved in establishing traceability for SEM measurements of nanoparticle size is proposed to facilitate the work of future operators.

Z-directional testing of paperboard in combined tensile and compression loading

The out-of-plane properties of paperboard are important in several converting applications such as printing, sealing, creasing, and calendering. A juxtaposed tensile and compression curve in the z direction (ZD) will, however, appear to have a kink or discontinuity at 0 stress. The purpose of the present work is to capture the continuous transition between tension and compression and to increase the understanding of the complex ZD properties of paperboard by cyclic testing. In this attempt to unify the ZD tensile and compressive behavior of paperboard, samples were laminated to the testing platens using heat seal laminate film. The method for adhering the samples was compared to samples that were laminated and glued to the testing platens. The edge effects of the cutting method were evaluated in compression testing with samples not attached to the testing platens. The flat slope seen in the initial part of the pure compression curve disappeared when the samples were laminated to the testing platens. The flat slope was instead replaced by a continuous response in the transition across 0 N. The stiffness in the transition region resembled the response in tensile testing. When the testing is cycled, the material exhibits a history dependence. Starting the cycle in either compression or tensile will show an effect on the stiffness at the transition, as well as the compressive stiffness. However, the ultimate tensile strength is unaffected.

Hover fly (Diptera: Syrphidae) diversity and seasonality in North Georgia apple and peach orchards.

Crop pollination and natural biological control provided by beneficial insects have an economic worth of hundreds of billions of dollars annually. Apple and peach production in North Georgia are economically important industries that benefit from these ecological services. Hover flies are dual ecosystem service providers that have been relatively understudied in orchard ecosystems. We investigated the diversity and seasonal activity of hover flies in apple and peach orchards at 2 sites in North Georgia from March to October 2020 and 2021. Bowl traps were used to sample hover flies in orchard edge and interior habitats. The aphidophagous species Toxomerus geminatus (Say) (Diptera: Syrphidae) and Toxomerus marginatus (Say) (Diptera: Syrphidae) comprised 86.6% of the total hover flies collected. Apple orchards yielded the greatest hover fly presence, species richness, and Toxomerus spp. abundance. Hover fly richness and diversity were greatest during postbloom, but Toxomerus spp. abundance was greatest during the bloom period. No differences in presence, richness, diversity, or Toxomerus spp. abundance were found between edge and interior habitats. Toxomerus geminatus and T. marginatus were dominant from March through August, with T. geminatus being more abundant than T. marginatus in March, early April, and August. October sampling produced the greatest hover fly richness. Our results suggest that hover flies are abundant in North Georgia orchards and exhibit substantial spatial and temporal variation in richness and diversity. Expanded studies incorporating additional sampling efforts and methods are needed to further characterize the hover fly fauna and their impact on North Georgia apple and peach orchards.

Seasonal Dynamics and Damage of Halyomorpha halys in Italian Vineyards.

The brown marmorated stink bug, Halyomorpha halys (Stål) (Hemiptera: Pentatomidae), is an invasive polyphagous pest often observed in vineyards. In Europe, a gap needs to be filled in the knowledge on H. halys seasonal dynamics and damage on grapes. With this study, we described the seasonal dynamics of H. halys and its distribution in multi-cultivar vineyards, and we evaluated the damage on grape clusters induced by different pest densities. In vineyards, the seasonal occurrence of H. halys varied across time and grape cultivars, and the pest was more abundant on Cabernet Franc, Merlot and, to a lesser extent, Pinot gris. Moreover, higher densities of H. halys were found on red berry cultivars than on white ones, and on cultivars ripening late in the season. An edge effect was also detected in pest distribution within vineyards, with more stink bugs observed in the borders. In the study on pest infestation density, H. halys caused damage on berries, showing differences in susceptibility among different cultivars and with regard to the time of infestation (i.e., plant phenological stages). Halyomorpha halys infestation induced an increase in Botrytis cinerea and sour rot incidence, which probably represents the main issue related to the impact of brown marmorated stink bug on grapevine.

Synchronization Mechanism for Controlled Complex Networks under Auxiliary Effect of Dynamic Edges

The scope of complex dynamical networks (CDNs) with dynamic edges is very wide, as it is composed of a class of realistic networks including web-winding systems, communication networks, neural networks, etc. However, a classic research topic in CDNs, the synchronization control problem, has not been effectively solved for CDNs with dynamic edges. This paper will investigate the emergence mechanism of synchronization from the perspective of large-scale systems. Firstly, a CDN with dynamic edges is conceptualized as an interconnected coupled system composed of an edge subsystem (ES) and a node subsystem (NS). Then, based on the proposed improved directed matrix ES model and expanded matrix inequality, this paper overcomes the limitations of coupling term design in node models and the strong correlation of tracking targets between nodes and edges. Due to the effect of the synthesized node controller and the auxiliary effect of the ES, state synchronization can be realized in the CDN. Finally, through simulation examples, the validity and advantages of our work compared to existing methods are demonstrated.

Influence of resource gradients and habitat edges on density variation in tiger populations in a multi-use landscape

Spatial heterogeneity in the local densities of terrestrial carnivores is driven by multiple interacting biotic and abiotic factors. Space-use patterns of large carnivores reflect the competing demands of resource selection (e.g., exploitation of habitats with abundant prey) and minimization of risks arising from human interactions. Estimating the relative strength of these drivers is essential to understand spatial variation in densities of large carnivores and there are still key knowledge gaps for many large carnivore populations. To better understand the relative roles of environmental and human drivers of spatial variation in tiger (Panthera tigris) densities, we surveyed a 3000 km2 landscape in North India using camera trap data. Over two years, we photo-captured 92 unique adult tigers. Associating spatial covariates with patterns of detection allowed us to test hypotheses about the relative influence of prey abundance, habitat structure and extent, and proximity to habitat edges on spatial variation in tiger densities across a gradient of anthropogenic disturbance. We documented extensive variation in tiger density within and across management units and protected areas. Spatial variation in prey abundance and proximity to grassland habitats, rather than human use (e.g. extent of human-dominated edge habitat and protection status), explained most of the spatial variation in tiger density in two of the five surveyed sites. The region’s largest tiger population occurred in a multi-use forest beyond protected area boundaries, where wild ungulates were abundant. Our results suggest that tigers can occur at high densities in areas with extensive human use, provided sufficiently high prey densities, and tracts of refuge habitats (eg. areas with dense vegetation with low human use). We argue that tiger conservation portfolio can be expanded across multi-use landscapes with a focus on areas that are adaptively managed as “zones of coexistence” and “refuge habitats”. Advancing this conservation strategy is contingent on greatly strengthening systems to effectively and equitably redress human–wildlife conflict and leveraging existing policies to strengthen local participation in conservation planning and forest stewardship. Our insights into the environmental drivers of spatial heterogeneity in tiger populations can inform both local management and guide to species recovery in working landscapes.

Emerging Industrial Internet of Things Open-Source Platforms and Applications in Diverse Sectors

Revolutionary advances in technology have been seen in many industries, with the IIoT being a prime example. The IIoT creates a network of interconnected devices, allowing smooth communication and interoperability in industrial settings. This not only boosts efficiency, productivity, and safety but also provides transformative solutions for various sectors. This research looks into open-source IIoT and edge platforms that are applicable to a range of applications with the aim of finding and developing high-potential solutions. It highlights the effect of open-source IIoT and edge computing platforms on traditional IIoT applications, showing how these platforms make development and deployment processes easier. Popular open-source IIoT platforms include DeviceHive and Thingsboard, while EdgeX Foundry is a key platform for edge computing, allowing IIoT applications to be deployed closer to data sources, thus reducing latency and conserving bandwidth. This study seeks to identify potential future domains for the implementation of IIoT solutions using these open-source platforms. Additionally, each sector is evaluated based on various criteria, such as development requirement analyses, market demand projections, the examination of leading companies and emerging startups in each domain, and the application of the International Patent Classification (IPC) scheme for in-depth sector analysis.

Defect‐Rich Graphdiyne Quantum Dots as Efficient Electron‐Donors for Hydrogen Generation

AbstractDownsizing the graphdiyne (GDY) network to shape quantum dots (QDs) will provide attractive optical and electronic properties associated with quantum confinement and edge effects. Here, it is demonstrated that quantum confinement and defect introduction allow using GDY in donor–acceptor photocatalytic systems for solar‐to‐hydrogen conversion. The defect‐rich GDY QDs (GDYO‐QDs) exhibit a blue‐to‐green excitation‐dependent photoluminescence behavior, demonstrating their ability to harvest light over a wide energy range. Quantum‐chemical calculations evidenced an increase in the electronic bandgap of GDY upon quantum confinement and defect introduction without the appearance of trap states that can hamper charge transport properties. Such a unique optical behavior of QDs is used in photocatalytic hydrogen generation through the hybridization with TiO2 as a model photocatalyst. Theoretical and experimental results demonstrate that the donor−acceptor system tremendously boosts the photocatalytic performance, reaching 5288 µmol g−1 after 4 h of illumination at a constant rate of 1322 µmol g−1 h−1, using a low volume of a sacrificial electron donor (6% v/v). The QDs act as efficient chromophores harvesting UV and visible light while injecting electrons into the TiO2. This work opens a new area of using GDYO‐QDs as an efficient chromophore in developing donor–acceptor systems for photocatalysis and future photovoltaic devices.

Local factors influence the wild bee functional community at the urban-forest interface

IntroductionUrban forests provide necessary habitat for many forest-associated bee species amidst development and fragmentation. These forest fragments provide a variety of important floral and non-floral resources for bees that encompass a diversity of functional guilds characterized by size, diet breadth, nesting, sociality, origin, and seasonality. The relative importance of forest edge vs. interior habitats to these organisms is not well understood.MethodsHere, we compare bee communities between forest edge and interior locations at eight locations in Athens, GA, USA. We also explore the effects of stand structure, tree composition, ground cover type, and the presence of snags and downed wood on these organisms.ResultsWe found bee abundance and richness to be higher at the forest edge than interior with distinct community compositions at both locations. Canopy cover, invasive shrub cover, ground cover, and tree diversity influenced the observed community composition. We also determined that the most impactful functional traits influencing bee community structure in urban forest fragments were nesting substrate, origin (native or exotic to North America), sociality, and diet breadth.DiscussionOur findings will help establish the effects of local forest characteristics on the community composition, diversity, and abundance of wild bees and further our knowledge of the conservation value of urban forests for preserving wild bee communities.

Leveraging co-production within ecosystem restoration to maximize benefits to coastal birds

Coastal Louisiana's ecosystems are threatened by anthropogenic factors exacerbated by climate change induced sea-level rise. The 2010 Deepwater Horizon oil spill resulted in injuries and deaths to coastal birds in Louisiana, and the ongoing loss of habitat has limited the potential for successful nesting of resident birds throughout the coast. Habitat loss is being addressed through increased large-scale ecosystem restoration as a result of settlement funds from the Deepwater Horizon oil spill. To further inform bird restoration in Louisiana, an avian restoration guidance document (Guidance for Coastal Ecosystem Restoration and Monitoring to Create or Improve Bird-NestingHabitat, 2023) was developed to maximize restoration benefits for coastal breeding birds while also achieving broader habitat restoration objectives. The developed restoration guidance was co-produced by subject-matter experts and professionals, including avian experts, engineers, and coastal restoration project managers. The result of this cross-disciplinary effort was specific and targeted guidance that presents designable habitat features that are in the control of project engineers and are also important high-value bird nesting habitats (e.g., shoreline access, elevation heterogeneity and edge habitat). For the first time in Louisiana, defined nest-site characteristics and monitoring approaches are readily available to inform ecosystem restoration project implementation. The restoration document specifically emphasizes bird species that breed and nest in coastal habitats in Louisiana, and restoration managers can use these guidelines to explicitly incorporate bird nesting habitat features into coastal restoration planning, design, and implementation. In developing this guidance, many knowledge gaps and data needs were identified specific to engineering and project design, enabling the research community to frame research questions around specific coastal restoration questions. The co-production of science model applied here for avian resources is applicable to a wide range of other living marine resources that may benefit from large-scale ecosystem restoration and is an example of the benefits of working relationships, communications, and common goal setting.

Design and validation of a new ring hoop plane strain test for characterizing the anisotropic plastic behavior of tubular materials

The accurate characterization of the plastic behavior of tubular materials is challenging due to the difficulties in acquiring proper specimens for mechanical testing. In this study, we propose a novel testing technique, namely the ring hoop plane strain Test (RHPST), as a supplementary test for characterizing materials experiencing distinct strain paths compared to standard uniaxial tensile tests. To design a suitable ring specimen’s geometry that satisfies the necessary plane strain conditions, we developed a meta-modelling approach merging response surface method (RSM) and the finite element method (FEM). Experimental tests are conducted on RHPST specimens, and 3D digital image correlation (DIC) technique is used to monitor the strain fields within the specimen's gauge section. However, observations indicate the presence of edge effects on the gauge specimen. These edge effects significantly influence and limit the homogeneity of the plane strain field. To tackle this limitation, a correction procedure is developed for separating the authentic plane strain area, constituting approximately 78% of the RHPST specimen's width. Furthermore, we successfully fabricated a novel grooved ring specimen (GRHPST), which exhibits a wider region of the plane strain state encompassing up to 90% of the gauge width, while minimizing the impact of edge effects. The true stress-true strain curve obtained from the GRHPST specimen exhibits exceptional agreement with the curve predicted using the Hill48 yield criterion. Notably, no additional corrections are required for the measured true stress-true strain curve, thereby affirming the efficacy of the GRHPST specimen as an adept test for characterizing the anisotropic plastic behavior of AA6063 tubes.