Metallic Edge Research Articles

Self-assembled 3D-flowers of CoS2-MoS2@NGA grown on graphene aerogel: As an emerging reliable electrocatalyst for hydrogen production in alkaline and acidic medium

The world is transitioning to more ecologically friendly and renewable energy sources, and hydrogen has enormous prospects for consumption in the future (2050). An electrochemical water-splitting (WS) is the most effective approach for separating pure hydrogen (H2) from water, however, the production rate depends on the catalyst activity. Recent strategies are focused on modifying the morphological structure, altering the metal edges, and increasing the active sites of catalysts to enhance their electrochemical performance. Herein, the solvothermal structural modification methods employed to achieve the 3D nanoflowers CoS2-MoS2@NGA, the cost-effective metal catalyst were grown on a graphene aerogel (GA) surface. The electrochemical accomplishments of the as-prepared catalyst were examined in the alkaline and acid medium to determine the optimal electrolyte. The CoS2-MoS2@NGA composite material achieved a noticeably low overpotential of 38 mV at a current density of 10 mA/cm2 and the fastest Tafel slope of 63 mV/dec towards the hydrogen evolution reaction (HER) compared to pure CoS2, MoS2, and N-doped GA (NGA). The composite exhibits an extraordinary specific surface area of 53.6 m2/g and an electrochemical active surface area (EASA) of 24.77 mF/cm2, contributing to its stability over 2000 CV cycles without significant activity loss. Overall, the composite materials achieved a comparatively high surface, low overpotentials, faster kinetics, a highly active electrochemical surface, and excellent long-term robustness. This work presents a promising approach for the elegant structural modification of non-noble metals, positioning CoS2-MoS2@NGA 3D flowers as an extremely efficient electrocatalyst for HER in an acidic medium.

Computational Study on the Octahedral Surfaces of Magnetite Nanoparticles and Their Solvent Interaction.

Magnetite nanoparticles (MNPs) play an important role in geological and environmental systems because of their redox reactivity and ability to sequester a wide range of metals and metalloids. X-ray absorption spectroscopy conducted at metal and metalloid edges has suggested that the magnetite {111} faces of octahedrally shaped nanoparticles play a dominant role in the redox and sorption processes of these elements. However, studies directly probing the magnetite surfaces, especially in their fully solvated state, are scarce. Therefore, we investigated the speciation and stability over a wide Eh/pH range of octahedrally shaped MNPs of 2 nm size by means of Kohn-Sham density functional theory with Hubbard correction (DFT+U). By altering the protonation state of the crystals, a redox-sensitive response of the octahedrally coordinated Fe could be achieved. Furthermore, the preferential H distribution could be identified, highlighting the difference between the edges, vertices, and facets of the nanocrystals. Subsequently, the interactions of the MNPs with a solvent of pure water or a 0.5 M NaCl solution were studied by classical molecular dynamics (MD) simulations. Finally, a comparison of the corresponding macroscopic magnetite (111) surface to the investigated MNPs was conducted.

Algorithmic assessment of drag on thermally cut sheet metal edges

Abstract Drag is a key criterion in assessing the quality of thermally cut sheet metal edges, which is critical to the reliability of the final product. The evaluation of drag has been described qualitatively and quantitatively, but the scientific literature lacks a methodical description of algorithmic tracking of the drag lines themselves. This absence of a standardized approach has hindered the objective determination of drag. With recent advances in the field towards automated quality assessment aimed at autonomous adaptation of process parameters, the need for consistent, fast and reliable assessment of drag lines has become apparent. To address this gap, this study introduces an innovative drag line tracking algorithm, inspired by the behavior of fluid flowing towards the lowest points, to compute a generalized drag line for an edge with a homogeneous cutting pattern. The algorithm utilizes the height data of the measured cut edges as a data base for the assessment of the drag lines. The results indicate that the drag lines identified by the algorithm are not only subjectively accurate, but also show a strong correlation with human-annotated drag lines across several metrics. This work lays the foundation for the objective evaluation of drag by not only describing an algorithm for the consistent determination of drag lines, but also by presenting a tool for human annotation and suitable customized metrics. As a result, it contributes significantly to the comprehensive evaluation of edge quality and represents a step forward in the automatic optimization of process parameters and the improvement of cutting edge quality.

Effect of staggered sublattice potential on electronic and transport properties of Bi(111) pristine and hydrogen-passivated nanoribbons

We investigate the impact of staggered sublattice potential (SSP) on the electronic and transport properties of Bi(111) bilayer and nanoribbons through first-principle calculations and the nonequilibrium Green's function method. We find that the topological phase transition of Bi(111) bilayer from topologically nontrivial (Z 2 = 1) to topologically trivial (Z 2 = 0) occurs at Δ = 1.77 eV SSP. Our study also reveals that energy bandgap opens for both pristine zigzag and armchair nanoribbon as the strength of the SSP (Δ > 1.50 eV for armchair nanoribbons and Δ > 1.90 eV for zigzag nanoribbons) increases, transitioning from non-trivial metallic edge states to insulating edge states. Furthermore, we explore the influence of SSP on edge-passivated zigzag nanoribbon. Through edge passivation, the dangling bonds are eliminated. As a result, it requires 0.4 eV less SSP to open an energy gap in edge-passivated nanoribbons compared to pristine nanoribbons. These findings hold promise for the advancement of Bi(111) nanoribbon-based field-effect transistors and spintronic devices.

Effect of grain boundary ferrite morphologies on impact toughness of X80 girth weld

The X80 girth weld microstructure formed by high-strength acicular ferrite and low-strength grain boundary ferrite was studied to investigate the effect of grain boundary ferrite morphologies on impact toughness. The results show that due to the difference in direction of heat loss caused by the narrow groove, the grain boundary ferrite morphology of the weld metal center and the weld metal edge are continuous network structure and parallel layered structure, respectively. The continuous network structure grain boundary ferrite causes strain localization, resulting in the formation of a large number of secondary cracks in the crack propagation process, which seriously deteriorates the toughness.

Role of electrostatic doping on the resistance of metal and two-dimensional materials edge contacts

In this theoretical study, we compare electrostatically doped metal-transition metal dichalcogenide (TMD) edge-contacts versus substitutionally doped edge-contacts in terms of their contact resistance. Our approach involves the utilization of electrostatic doping achieved by applying back-gate bias to the metal-TMD edge contacts, where carrier injection is primarily governed by the Schottky barrier at the interface. To analyze these contacts, we employ the Wentzel-Kramers-Brillouin (WKB) approximation to calculate the transmission coefficient and use density functional theory (DFT)-derived band structures. We numerically solve the Poisson equation to capture the electrostatic potential. We also account for the impact of the image force using Green's function for the Poisson equation with boundary conditions appropriate to our specific geometry. Our findings reveal that electrostatically doped TMD edge contacts exhibit higher contact resistance compared to impurity-doped edge contacts at equivalent carrier concentrations. At the same time, we find that, among the electrostatically doped edge contacts, a low-κ back-gate oxide in conjunction with low-κ top oxide is preferable in terms of improvement in contact resistance. For instance, in a metal-TMD edge contact scenario involving a monolayer MoS2 as the channel, SiO2 as the infinitely thick top oxide, and a SiO2 back-gate oxide with an equivalent oxide thickness (EOT) of 1nm, we demonstrate that it is possible to achieve an impressively low contact resistance of 50Ωµm when the back-gate bias exceeds or equals 2 V. Published by the American Physical Society 2024

Influence of local structure and metal-oxygen hybridization on the electrical and magnetic properties of alkaline earth metal (Mg2+, Ca2+, Sr2+) substituted LaFeO3 ceramics

Pristine and alkaline-earth metal-substituted LaFeO3 (La1−xAxFeO3−δ; x = 0 and 0.2; A = Mg2+, Ca2+, and Sr2+) sintered ceramics are prepared from nanoparticles synthesized via a low-temperature citrate sol–gel technique. X-ray diffraction studies confirm the formation of a phase-pure LaFeO3 structure without any secondary phases for all the La1−xAxFeO3−δ compositions. LaFeO3 and La0.8Mg0.2FeO3−δ ceramics show Raman active modes related to La vibration, oxygen octahedral tilting, bending, and stretching. The optical bandgap is estimated to be 2.34 eV for pure LaFeO3 and reduces to 2.23 eV for La0.8Mg0.2FeO3−δ ceramics. On the contrary, La0.8Ca0.2FeO3−δ and La0.8Sr0.2FeO3−δ ceramics show no features in Raman spectra, consistent with the observation of metallic nature and diffuse band edge without any indication of sharp band edge noted. X-ray absorption spectroscopy (XAS) studies on La-L3 and Fe-K-edges confirm the oxidation states of La3+ and Fe3+ in all these ceramics. Local structural distortions and formation of oxygen vacancies in La0.8A0.2FeO3−δ (A = Mg2+, Ca2+, and Sr2+) ceramics are discerned from XAS structure analysis compared to the pristine LaFeO3 ceramics. Magnetic measurements of La1−xAxFeO3−δ reveal weak ferromagnetic nature except for La0.8Mg0.2FeO3−δ, which shows a large magnetization of 4.6 (6.7) emu/g at 300 (5) K. The ferromagnetic behavior of La0.8Mg0.2FeO3−δ ceramics seems to originate from the modification of hybridization between Fe(3d)–O(2p), La(5d)–O(2p), and Fe(4sp)–O(2p) orbitals. An anomalous magnetic transition observed only in zero-field-cooled curves at 88 K in La0.8Ca0.2FeO3−δ and La0.8Sr0.2FeO3−δ ceramics is correlated to the formation of new electronic states containing O 2p character as discerned from pre-peak O-K-edge.

Enhancement of NO[formula omitted] sensing in Sb[formula omitted]Te[formula omitted]Se by vacancies

Topological insulators (TI) are a class of materials characterized by metallic edge states protected by time reversal symmetry from local perturbations such as defects while having a bulk insulating gap. Since the topological surface states are exposed to the environment, gas sensing applications could benefit from the higher carrier mobility of the topological surface states. In this work, we study the resistance response of Sb2Te2Se towards NO2 and the effects of vacancies introduced by annealing. We found that the vacancies greatly enhance the response and inferred the significant role the vacancies play in the mechanism of NO2 adsorption in Sb2Te2Se.

(Invited) Synthesis and Visible-Plasmonic Properties of Intermetallic Nanoparticles

The past research on inorganic nanomaterials that exhibit intrinsic localized surface plasmon resonance (LSPR) in the visible region has focused on well-disperse nanoparticles (NPs) including group 11 elements (Au, Ag, and Cu) [1]. Recent theoretical studies on photo-excited electron dynamics in Au NPs have revealed that not only the interband transition but also the screening caused by the vibrations of bound electrons by visible light are important for visible LSPR [2]. However, the correlation between the electronic and crystal structure (as a means of controlling the screening effect) remains unclear because most alloys based on group 11 elements have a face-centered cubic (fcc)-based structure. Here, we show that well-disperse spherical intermetallic Pd-based alloy NPs and Pt-based alloy NPs with non-close packed structure intrinsically exhibit LSPR absorption in the visible region.It is well known that chemical conversion of inorganic NPs via element substitution reactions, such as ion exchange reactions [3] and galvanic replacement reactions, can overcome the difficulties associated with controlling the size, shape, chemical composition, and crystal structure in conventional syntheses [4-6]. Especially, alloying enables us to drastically modulate the electronic properties of metallic NPs. The retained shape of the parent-NPs in element replacement reactions provides an opportunity to obtain non-equilibrium unique structures and even new structures of inorganic NPs. We demonstrate that various Pd-based alloy NPs with a B2 structure were synthesized by the element replacement reactions with Pd–P NPs and showed LSPR in the visible region [7]. On the other hand, we successfully synthesized pseudospherical PtIn2 intermetallic NPs with a C1 structure as uncommon types of visible plasmonic NPs [8].Consequently, we can extract the design principles of intermetallic NPs that exhibit LSPR in the visible region in terms of the crystal and electronic structures as follows. (i) The electronic structure of intermetallic NPs should be similar to that of group 11 element NPs, that is, the sp-band crossing the Fermi level and d-band edge of noble metal like Pt around the visible region. The deeper d-band edge of another base metal like indium less affects the red-shift of LSPR wavelength. (ii) The intermetallic NPs should have non-close packed structure to cause strong screening effect by a small number of d-electrons of noble metal. The intermetallic NPs, which satisfy the above two requirements, are expected to show LSPR in the visible region and serve as novel plasmonic photocatalysts [9].[1] Kawawaki, T.; Teranishi, T. et al., J. Am. Chem. Soc. 2019, 141, 8402–8406.[2] Iida, K.; Noda, M.; Ishihara, K.; Nobusada, K. J. Phys. Chem. A 2014, 118, 11317–11322.[3] Saruyama, M.; Sato, R.; Teranishi, T. Acc. Chem. Res. 2021, 54, 765–775.[4] Wu, H.-L.; Sato, R.; Teranishi, T. et al., Science 2016, 351, 1306–1310.[5] Li, Z.; Saruyama, M.; Asaka, T.; Tatetsu, Y.; Teranishi, T. Science 2021, 373, 332–337.[6] Matsumoto, K.; Sato, R.; Tatetsu, Y.; Teranishi, T. et al., Nat. Commun. 2022, 13, 1047.[7] Sato, R.; Takekuma, H.; Teranishi T. et al., to be submitted.[8] Takekuma, H.; Sato, R.; Iida, K.; Teranishi, T. et al., Adv. Sci., in revision.[9] Lian, Z; Teranishi, T. et al., J. Am. Chem. Soc. 2019, 141, 2446–2450.

Optimizing sheet metal edge quality with laser-polishing: surface characterization and performance evaluation

Dual-phase (DP) steels are widely used in the automotive industry due to their exceptional performance. It offers excellent strength, ductility, formability, and weldability. However, there is a high risk of edge cracking, particularly in materials like DP1000 steel, caused by residual damage from blanking, such as microcracks and burrs, which needs further investigation. In this study, the transformative potential of laser-polishing on DP1000 steel was investigated. The goal was to reduce edge crack sensitivity and enhance edge formability. In this work, laser-polished samples produced by various pre-manufacturing techniques such as sawing, punching, and waterjet cutting were examined. Various evaluations were performed on laser-polished samples. Those included white-light-confocal microscopy, scanning electron microscopy, and Electron Backscatter Diffraction (EBSD) analysis. Those evaluations aimed to analyze the microstructural transformation, surface roughness, and micro grain size distribution resulting from laser-polishing. Laser-polishing is a process in which the edge of the sample is remelted locally. Hence, residual damage vanishes, and surface defects disappear, which should be beneficial for edge formability. On the other hand, the cooling rate during re-solidification is high, leading to high strength and reduced ductility compared to the initial DP steel. Therefore, hole expansion tests were conducted to evaluate the edge formability of the steel. The results indicated a significant improvement in the hole expansion ratio of the laser-polished samples compared to samples with conventional manufactured edges. These findings will help to assess the advantages and limitations of laser-polishing in sheet material manufacturing.

Spin-filtering properties of topological structures based on stanene and bismuthene nanoribbons with one edge magnetism

The transport properties of spin filters based on two-dimensional magnetic topological insulators (TI) with magnetism at one edge are theoretically studied. The non-equilibrium-Green’s-function (NEGF) formalism based on density functional theory (DFT) derived Hamiltonian is used to study the one-way helical edge states in these structures. We investigated the electronic and magnetic properties of stanene and bismuthene nanoribbons with various metal edge modifications. Our DFT simulations predict the formation of one-way helical edge states in stanene nanoribbons with asymmetric edge passivation. Our results suggest that the spin filtering properties of such structures outperform a comparable spin filter based on spin-polarized quantum-anomalous-Hall effect, as it bypasses a need for a strict interplay of magnetism, topology, and a large electric field (around 2 V gate voltage difference).

Metal edge confined platinum atoms in metal/hydroxide hierarchy structure for multiple hydrogen conversion and evolution

Single-atom catalysts (SACs), as a thriving subfield of catalysis, have progressed tremendously. However, the contradiction between the isolated dispersion feature of metal sites and the high mass-specific activity of the catalyst inhibits the advances of the SACs. Herein, the Pt atoms are confined at the metallic Co phase edge in two-dimensional Co/Co(OH)2 hierarchy structure (PtSA-Co@Co-Co(OH)2) by the defect inducted order electrodeposition strategy. Both integrations of in-situ/ex-situ experimental characterizations and theoretical calculation reveal that such metal edge confined Pt atoms possess an enlarged atom exposure ratio, high stability, and the like-metal electronic state contributed by metal Co 3d, which enables the Pt atoms with more suitable affinity to simultaneously bind the multiple H atoms for durable H*-H2 conversion and H2 evolution. Moreover, the metallic PtSA-Co collaborated Co/Co(OH)2 interfaces demonstrate a strong H2O dissociation capacity by the preference adsorption of H* on metallic PtSA-Co and OH*on Co/Co(OH)2 interfaces. Combining a further enhancement of constructing the catalysts on an Ag nanowire network to form a seamlessly conductive nanostructure, the PtSA-Co@Co-Co(OH)2 achieves a high mass activity with 5.92 A mg−1 at the overpotential of 100 mV in alkaline condition, 37 times to that of the benchmark Pt/C catalyst and significantly outperforming the reported catalysts. While our work has focused on the hydrogen evolution reaction, this class of metal edge collaborated single-atom catalysts may be conducive to unlock the low mass-specific activity of atomically dispersed catalysts for various processes, such as oxygen evolution reactions (OER), CO2 reduction, and biomass conversion, etc.

Large-Gap Quantum Spin Hall Insulators in Two-Dimensional Hafnium Halides: Unraveling the Impact of Strain and Substrate.

Two-dimensional (2D) topological insulators (TIs) or quantum spin Hall (QSH) insulators, characterized by insulating 2D electronic band structures and metallic helical edge states protected by time-reversal symmetry, offer a platform for realizing the quantum spin Hall effect, making them promising candidates for future spintronic devices and quantum computing. However, observing a high-temperature quantum spin Hall effect requires large-gap 2D TIs, and only a few 2D systems have been experimentally confirmed to possess this property. In this study, we employ first-principles calculations, combined with a structural search based on an evolutionary algorithm, to predict a class of 2D QSH insulators in hafnium halides, namely, HfF, HfCl, and HfBr with sizable band gaps of 0.12, 0.19, and 0.38 eV. Their topological nontrivial nature is confirmed by a Z2 invariant which equals to 1 and the presence of gapless edge states. Furthermore, the QSH effect in these materials remains robust under biaxial tensile strain of up to 10%, and the use of h-BN as a substrate effectively preserves the QSH states in these materials. Our findings pave the way for future theoretical and experimental investigations of 2D hafnium halides and their potential for realizing the QSH effect.

Anomalous supercurrent and diode effect in locally perturbed topological Josephson junctions

The simultaneous breaking of time-reversal and inversion symmetry can lead to peculiar effects in Josephson junctions, such as the anomalous Josephson effect or supercurrent rectification, which is a dissipationless analog of the diode effect. Due to their impact in new quantum technologies, it is important to find robust platforms and external means to manipulate the above-mentioned effects in a controlled way. Here, we theoretically consider a Josephson junction based on a quantum spin Hall system as the normal channel, subjected to a magnetic field in the direction defined by spin-momentum locking, and in the presence of a local tip in close proximity to one of the metallic edges in the normal region. We consider different local perturbations, model normal and magnetic tips, and study how they affect the Josephson response of the device. In particular, we argue that magnetic tips are a useful tool that allows for tunability of both ϕ0 response and supercurrent rectification.

Anisotropic charge transport at the metallic edge contact of ReS2 field effect transistors

The in-plane anisotropy of electrical conductance in two-dimensional materials has garnered significant attention due to its potential in emerging device applications, offering an additional dimension to control carrier transport in 2D devices. However, previous research has primarily focused on the anisotropy within electrical channel, neglecting the significant impact of anisotropic electrical contacts of 2D materials. Here, we investigate anisotropic charge transport at the metal contacts of hBN-encapsulated ReS2 using edge-contacted Field Effect Transistors. We observed the marked difference in contact resistance between the cross-b and b directions, suggesting that charge transport from the metal to ReS2 is more efficient along the b direction. This difference in efficiency results in a substantial contact anisotropy, reaching ~70 at 77 K. Our findings indicate that the measured Schottky Barrier Height along the b direction is ~35 meV, which is smaller than along the cross-b direction. Moreover, the tunneling probability along the b direction is two times larger than along the cross-b direction. Our results indicate that both Schottky Barrier Height and tunneling amplitude are the primary contributors to the high contact anisotropy of ReS2. This work provides a valuable guideline for understanding how in-plane orientation influences charge transport at metallic contacts in 2D devices.

First-principles investigation on potential profile induced in graphene by surface and edge metal contacts

To utilize graphene as an electronic device graphene has to be brought into contact with a metal electrode and the metal contact has a significant impact on the characteristics of the device. We have investigated the potential profile induced in graphene layer by metal contacts, which describes how charges are redistributed between metal and graphene in order to eliminate the difference in work function between them, by using first-principles calculations. It is found that the potential profiles are much different between surface and edge contact metal/graphene junctions. For surface contacts the potential profile is significantly influenced by Pauli exclusion interactions and bond formation between metal and graphene. On the other hand, the edge contacts lack Pauli exclusion interactions and the non-graphene-like metallic states of C atoms near the metal edges, which are induced by bond formation, are suggested to have a major effect on eliminating the work function difference.

Recent development in feeding mechanism of sheet metal shearing machine for productivity improvement: A review

Sheet metal working processes find extensive applications in industries such as automobile and aerospace. However, the sharp edges of sheet metal pose a safety hazard to workers, potentially leading to injuries. In response to this concern, we have conceived and developed an automatic sheet metal cutting machine. Feeding mechanism is one of the important part of sheet metal shearing machine. In this paper, recent research papers are reviewed. This papers also reports recent development in feeding mechanism and its role for productivity improvement. Also, proposed innovative feeding mechanism represents a pivotal advancement in the field of mechanical workshops, aligning with industry demands for increased productivity and safety in sheet metal processing. Paper throws lights on benefits of automation into the sheet metal cutting process, which a significantly reduces in labour costs while ensuring precise and efficient cutting operations. Paper also focuses the various parameter such as cutting speed, material properties.

Analysis and Basics of Improving the Process of Cutting Electrical Sheet Bundles with a High-Pressure Abrasive Water Jet.

Electrical steels are widely used in the electrical industry in the construction of many devices, e.g., power transformer cores and distribution transformers. An important parameter of electrical components that determines the efficiency of devices is energy loss during remagnetization. These losses are influenced, among other factors, by steel cutting processes. The common techniques for cutting electrical materials on industrial lines are mechanical cutting and laser cutting. High-pressure abrasive water jet (AWJ) cutting, unlike the technologies mentioned above, can ensure higher quality of the cut edge and limit the negative impact of the cutting process on the magnetic properties of sheet metal. However, the correct control of the process and the conditions of its implementation comprise a complex issue and require extensive scientific research. This work presents a new approach to cutting electric sheets, involving bundle cutting, which significantly increases the processing efficiency and the dimensional and shape accuracy of the cut details. The tests were carried out for bundles composed of a maximum of 30 sheets, ready to be joined in a stator and rotor in a motor. The influence of processing conditions on the quality of the cut edges of sheet metal, the width of the deformation zone, and the burr height were analyzed. The detailed analysis of the quality of the cut edges of electrical bundled sheets creates new possibilities for controlling the AWJ cutting process in order to obtain a product with the desired functional and operational properties.

Spreading of an active region of semi-insulating GaAs detectors after radiation degradation

The radiation hardness of GaAs detectors against high-energy electrons goes up to a few MGy. Their degradation is mainly connected to the decrease of the charge collection efficiency and the increase of the reverse current. On the other hand, an improvement in detection efficiency was observed at low degradation doses. The explanation that this could be caused by an enlargement of the detector active area due to spreading of the collecting electric field caused by radiation-induced defects is studied in this paper. We have used the alpha particles of 241Am, which interact in the GaAs surface layer, to study the enlargement of the detector active region after its degradation by 5 MeV electrons with doses ranging from 24 to 2000 kGy. The results show that the electric field spreads behind the Schottky contact metallization edges not only with increasing applied reverse bias but also with rising cumulative dose of radiation degradation in the dose range from 24 up to 100 kGy, followed by a slight reduction in area size. The electric collecting field keeps larger dimensions than before detector degradation for doses up to 600 kGy. For higher doses than 1000 kGy, the active area of the detector was reduced below its initial size before degradation. Moreover, the improvement of detection efficiency with increasing bias applied becomes weaker with increasing degradation dose. Radiation degradation affects the electric field distribution in semi-insulating GaAs detectors and the results obtained may provide useful knowledge to preparation of multi-pixel GaAs structures for imaging and particle tracking.

Designer artificial chiral kagome lattice with tunable flat bands and topological boundary states

The kagome lattice is a well-known model system for the investigation of strong correlation and topological electronic phenomena due to the intrinsic flat band, magnetic frustration, etc. Introducing chirality into the kagome lattice would bring about new physics due to the unique symmetry, which is still yet to be fully explored. Here we report the investigation on a two-dimensional chiral kagome lattice utilizing tight binding band calculation and topological index analysis. It is found that the periodic chiral kagome lattice would bring about a robust zero-energy flat band. Furthermore, in the Su–Schrieffer–Heeger type dimer-/trimerized breathing chiral kagome lattice with particular edge terminations, topological corner states or metallic edge states would appear, implying new candidates for the second-order topological insulator. We also proposed the construction strategy for such lattices employing the scanning tunneling microscope atom manipulation technique.